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2-methylacrylic Acid


Properties
Product Name 2-Methylacrylic acid
Cas Number 37971-36-1
Formula C4H6O2
Molar Mass 86.09 g/mol
Appearance Colorless liquid
Odor Pungent
Melting Point -22°C
Boiling Point 161°C
Density 1.033 g/cm3
Solubility Miscible in water
Flash Point 65°C
Flammability Flammable
Ph Not applicable
FAQ

What are the main uses of 2-Methylacrylic acid?

2 - Methylacrylic acid, also known as methacrylic acid, has several important applications.Methacrylic Acid, also known by the name methacrylic, has many important applications.
One of the major uses is in the production of polymers.It is a key monomer in the manufacture of polymers. It is a key monomer for manufacturing poly(methyl methacrylate) (PMMA).It is the main monomer used in the manufacture of poly(methyl methacrylate). PMMA is a widely - used transparent thermoplastic.PMMA is an extremely popular transparent thermoplastic. It has excellent optical clarity, similar to glass, but is much lighter and more impact - resistant.It is similar to glass in optical clarity but lighter and more impact-resistant. PMMA is used in a variety of products such as acrylic sheets, which are used in architectural glazing, sign - making, and display cases.PMMA is used to make acrylic sheets that are used for architectural glazing, sign-making, and display cases. In the automotive industry, PMMA is used for headlights and taillights due to its good light - transmitting properties and durability.PMMA is used in the automotive industry for headlights, taillights, and other lighting fixtures due to its light-transmitting properties and durability.

2 - Methylacrylic acid is also used in the production of coatings.Coatings can also be made from 2 - Methylacrylic acids. Copolymers made from methacrylic acid can be used to formulate high - performance coatings.Copolymers derived from methacrylic acids can be used to create high-performance coatings. These coatings have good adhesion to various substrates, including metals, plastics, and wood.These coatings adhere well to a variety of substrates including metals and plastics. They can provide protection against corrosion, abrasion, and weathering.They can protect against corrosion, abrasion and weathering. For example, in the aerospace industry, coatings based on methacrylic - acid - containing polymers are used to protect aircraft surfaces from the harsh environmental conditions during flight.In the aerospace industry, for example, coatings based upon methacrylic-acid-containing polymers protect aircraft surfaces against the harsh environmental conditions that occur during flight.

In the field of adhesives, 2 - Methylacrylic acid plays a role.In the field adhesives, Methylacrylic Acid plays a key role. Acrylic adhesives often contain methacrylic acid monomers or polymers.Acrylic adhesives contain methacrylic monomers or polymers. These adhesives have strong bonding capabilities and can adhere to a wide range of materials.These adhesives are strong and can adhere to many different materials. They are used in industries such as electronics, where they are used to bond components together due to their reliable performance and the ability to cure quickly, either through heat or exposure to light.These adhesives are used in industries like electronics to bond components due to their reliability and ability to cure quickly through heat or light.

The textile industry also benefits from 2 - Methylacrylic acid.The textile industry also benefits 2 - Methylacrylic Acid. It can be used to modify the properties of textile fibers.It can be used for modifying the properties of textile fibres. By copolymerizing with other monomers, it can introduce functional groups to the fiber surface, improving properties such as dyeability, moisture - absorption, and anti - static properties.By copolymerizing it with other monomers, you can introduce functional groups on the fiber surface. This improves properties such as dyeability and moisture - absorption. This leads to the production of more comfortable and functional textile products.This results in the production of textiles that are more functional and comfortable.

In addition, 2 - Methylacrylic acid is used in the synthesis of various specialty chemicals.The synthesis of specialty chemicals also uses 2 - Methylacrylic Acid. For example, it can be used to prepare esters, which are used as solvents, plasticizers, and in the fragrance industry.It can be used, for example, to prepare esters that are used in the fragrance and plasticizer industries, as well as solvents. Some of its derivatives are also used in the pharmaceutical and agrochemical industries as intermediates for the synthesis of more complex molecules.Some of its derivatives can also be used in the pharmaceutical industry and agrochemical industry as intermediates to synthesize more complex molecules. Overall, 2 - Methylacrylic acid is a versatile chemical with a wide - reaching impact across multiple industries.2 - Methylacrylic Acid is a versatile chemical that has a wide-reaching impact across multiple industries.

What are the safety precautions when handling 2-Methylacrylic acid?

2 - Methylacrylic acid, also known as methacrylic acid, is a colorless liquid with a pungent odor.2 - Methylacrylic Acid, also known by the name methacrylic, is a colorless, odorless liquid. When handling it, the following safety precautions should be taken.It is important to follow the safety precautions when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide effective protection against 2 - Methylacrylic acid.Nitrile gloves can be a good option as they provide protection against 2- Methylacrylic Acid. This helps prevent the acid from coming into direct contact with the skin, which can cause irritation, burns, and dermatitis.This will prevent the acid from contacting the skin directly, which could cause irritation, dermatitis, or burns. Also, use safety goggles or a face shield.Use safety goggles, or a face-shield. The pungent vapor of the acid can irritate the eyes, and in case of splashing, safety goggles can prevent serious eye damage.Safety goggles are recommended to protect your eyes from the vapors of the acid. A lab coat or chemical - resistant apron should be worn to protect the body from spills.Wear a lab coat or a chemical-resistant apron to protect your body from spills.

Second, ensure proper ventilation. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably under the fume hood. 2 - Methylacrylic acid gives off vapors that can be harmful if inhaled.Inhaling vapors of methylacrylic acid can be harmful. Prolonged exposure to its vapors may cause respiratory tract irritation, coughing, and shortness of breath.Prolonged exposure to the vapors can cause irritation of the respiratory tract, coughing and shortness in breath. A fume hood effectively removes these vapors from the breathing zone, reducing the risk of inhalation - related health problems.A fume hood removes these vapors effectively from the breathing zone and reduces the risk of inhalation-related health problems.

Third, when it comes to storage.Third, storage. Store 2 - Methylacrylic acid in a cool, dry, and well - ventilated place.Store 2 - Methylacrylic Acid in a place that is cool, dry and well-ventilated. Keep it away from heat sources, flames, and oxidizing agents.Keep it away form heat sources, flames and oxidizing agents. It is flammable, and contact with heat or oxidizers can initiate a fire or explosion.It is flammable and can ignite a fire or explode when in contact with heat, oxidizers or flames. Additionally, store it in a tightly closed container to prevent the release of vapors.Store it in a tightly-closed container to prevent vapors from escaping.

Fourth, in case of spills.Fourth, in the event of spills. If a spill occurs, immediately evacuate the area and alert others.If there is a spill, evacuate the area immediately and alert others. Do not attempt to clean it up without proper equipment.Do not attempt to clean up the spill without proper equipment. Use absorbent materials such as sand or vermiculite to contain the spill.Use absorbent materials like sand or Vermiculite to contain spills. Then, carefully transfer the absorbed acid to a suitable waste container.Then, transfer the acid that has been absorbed into a suitable container. Dispose of the waste in accordance with local environmental regulations.Dispose of waste according to local environmental regulations.

Finally, in case of contact.In case of contact, rinse the affected area immediately with plenty of water for at least 15 minutes. If the acid gets on the skin, immediately rinse the affected area with plenty of water for at least 15 minutes.If the acid touches the skin, rinse it immediately with plenty of water and for at least 15 min. Remove any contaminated clothing during the rinsing process.Remove any contaminated clothes during the rinsing procedure. If it gets into the eyes, rinse the eyes with copious amounts of water for at least 15 minutes while keeping the eyelids open, and seek immediate medical attention.If it gets in the eyes, rinse them with plenty of water for 15 minutes, keeping the eyelids wide open. Seek immediate medical attention if necessary. In case of inhalation, move to fresh air immediately and if breathing difficulties persist, seek medical help.In the case of inhalation move to fresh air and seek medical attention if breathing problems persist.

What is the solubility of 2-Methylacrylic acid in water?

2 - Methylacrylic acid, also known as methacrylic acid, has a relatively high solubility in water.2 - Methylacrylic Acid, also known by the name methacrylic, is relatively soluble in water.
The solubility of 2 - Methylacrylic acid in water is influenced by several factors.The solubility in water of 2-Methylacrylic Acid is affected by several factors. Firstly, its molecular structure plays a crucial role.Its molecular structure is the first factor that plays a major role. 2 - Methylacrylic acid contains a carboxyl group (-COOH).2 - Methylacrylic Acid contains a carboxyl (-COOH) group. This carboxyl group can form hydrogen bonds with water molecules.This carboxyl can form hydrogen bonds between water molecules. Hydrogen bonding is a strong intermolecular force that promotes the dissolution of the acid in water.Hydrogen bonding acts as a strong intermolecular attraction that encourages the dissolution and neutralization of acid in water. The carboxyl group's oxygen atoms can interact with the hydrogen atoms of water, and the hydrogen of the carboxyl group can interact with the oxygen atoms of water.The carboxyl's oxygen atoms interact with hydrogen atoms in water, and hydrogen from the carboxyl can interact with oxygen atoms in water.

Typically, 2 - Methylacrylic acid is miscible with water in all proportions at room temperature.At room temperature, 2 - Methylacrylic Acid is typically miscible in all proportions with water. This means it can dissolve in water to an almost unlimited extent.It can dissolve in water almost to an unlimited extent. This high solubility is in contrast to some larger organic acids or organic compounds with more hydrophobic (water - hating) groups.This high solubility contrasts with some larger organic acids and organic compounds that have more hydrophobic groups (water-hating). The relatively small size of the 2 - Methylacrylic acid molecule, aside from the carboxyl group, is also beneficial for its solubility.Aside from the carboxyl groups, the relatively small size of 2 - Methylacrylic Acid molecule is also beneficial to its solubility. The methyl group attached to the double - bonded carbon does not significantly disrupt the ability of the molecule to interact with water through hydrogen bonding.The methyl group on the double-bonded carbon does little to affect the ability of the molecule, through hydrogen bonding, to interact with water.

The solubility of 2 - Methylacrylic acid in water also has implications in various industrial and chemical processes.The solubility in water of 2 - Methylacrylic Acid has implications for various industrial and chemical processes. In the production of polymers, for example, its solubility in water can be exploited to create aqueous - based polymer systems.Its solubility in aqueous solutions can be used to create aqueous-based polymer systems. If the 2 - Methylacrylic acid is used as a monomer, its good solubility in water allows for easy incorporation into a reaction mixture.When 2 - Methylacrylic Acid is used as monomer, it can be easily incorporated into a reaction mix due to its solubility in the water. This can lead to more homogeneous polymerization reactions and better - controlled polymer properties.This can lead more homogeneous reactions of polymerization and better-controlled polymer properties.

In environmental contexts, the high solubility of 2 - Methylacrylic acid means that if it is released into water bodies, it will readily dissolve.In environmental contexts the high solubility means that 2 - Methylacrylic Acid will dissolve readily if released into water bodies. This can have consequences for aquatic life as it may affect the pH of the water due to its acidic nature.Acidity can affect the pH level of water, which could have serious consequences for aquatic life. However, due to its biodegradability in many cases, the long - term impact on the environment may be mitigated as it can be broken down by natural processes.In many cases, its biodegradability can reduce the impact of the acid on the environment over the long-term. Overall, the solubility of 2 - Methylacrylic acid in water is an important characteristic that influences its behavior in both chemical and environmental settings.Overall, the solubility in water of 2 - Methylacrylic Acid is an important characteristic which influences its behavior both in chemical and environmental settings.

How is 2-Methylacrylic acid synthesized?

2 - Methylacrylic acid, also known as methacrylic acid, can be synthesized through several methods.Methacrylic acid can be synthesized in several ways. One common approach is the hydrolysis of methyl methacrylate.Hydrolysis of methylmethacrylate is a common method.
Methyl methacrylate is first obtained from the reaction of acetone cyanohydrin with sulfuric acid and methanol.The first step is to react acetone cyanohydrin and sulfuric acid with methanol. In this initial step, acetone cyanohydrin reacts with sulfuric acid to form methacrylamide sulfate.In the first step, acetone-cyanohydrin reacts to form methacrylamidesulfate. Then, methanol is added, and an esterification reaction occurs, resulting in methyl methacrylate.Then, add methanol and undergo an esterification to produce methyl methacrylate. To synthesize 2 - Methylacrylic acid from methyl methacrylate, hydrolysis is carried out.Hydrolysis is used to synthesize 2- Methylacrylic Acid from methylmethacrylate. Hydrolysis can be achieved by reacting methyl methacrylate with water in the presence of an acid or a base catalyst.Hydrolysis is achieved by reacting water and methyl methacrylate in the presence of either an acid or base catalyst. When using an acid catalyst like sulfuric acid, the reaction proceeds as follows: Methyl methacrylate reacts with water, and the ester bond is broken.The ester bond is broken when using an acid catalyst such as sulfuric acid. The methyl group attached to the oxygen in the ester is replaced by a hydrogen atom from water, forming 2 - Methylacrylic acid and methanol as a by - product.The methyl group is replaced by the hydrogen atom in water by the oxygen group of the ester, forming 2 – Methylacrylic Acid and methanol by-product. The reaction is reversible, but by controlling reaction conditions such as temperature, concentration, and reaction time, the equilibrium can be shifted towards the formation of 2 - Methylacrylic acid.The reaction can be reversed, but the equilibrium can shift towards 2 - Methylacrylic Acid by controlling the reaction conditions, such as temperature and concentration. For example, using an excess of water can drive the reaction forward.For example, an excess of water will accelerate the reaction.

Another method for synthesizing 2 - Methylacrylic acid is from isobutyraldehyde.Isobutyraldehyde is another way to synthesize 2 - Methylacrylic Acid. Isobutyraldehyde can be oxidized to 2 - Methylacrylic acid.Isobutyraldehyde is oxidized into 2 - Methylacrylic Acid. The oxidation is usually carried out in the presence of a catalyst.The oxidation usually occurs in the presence a catalyst. One such catalyst system is based on metal - containing compounds, like cobalt or manganese salts.A catalyst system based on metal-containing compounds like cobalt and manganese salts is one such system. In the presence of air or oxygen as the oxidizing agent, isobutyraldehyde is gradually oxidized.Isobutyraldehyde slowly oxidizes in the presence of oxygen or air. The aldehyde group in isobutyraldehyde is transformed into a carboxylic acid group, resulting in the formation of 2 - Methylacrylic acid.The aldehyde in isobutyraldehyde transforms into a carboxylic group, leading to the formation of 2-Methylacrylic Acid. This method has the advantage of starting from a relatively simple aldehyde precursor.This method has the benefit of starting with a relatively simple precursor aldehyde. However, the choice of catalyst is crucial as it affects the reaction rate, selectivity, and yield.The choice of catalyst can affect the reaction rate, selectivity and yield. The reaction conditions need to be carefully optimized to ensure high - yield production of 2 - Methylacrylic acid while minimizing the formation of side products such as over - oxidized products or polymers.The reaction conditions must be optimized to maximize the yield of 2 - Methylacrylic Acid while minimizing side products, such as polymers or over-oxidized products.

What are the physical and chemical properties of 2-Methylacrylic acid?

2 - Methylacrylic acid, also known as methacrylic acid, has distinct physical and chemical properties.2 - Methacrylic Acid, also known by the name methacrylic, has distinct physical properties and chemical properties.
Physical Properties

Appearance: It is a colorless, viscous liquid at room temperature.At room temperature, it appears as a colorless viscous liquid. This clear and relatively thick liquid state allows it to flow, although not as freely as more volatile and less viscous substances.This clear, relatively thick liquid allows it to flow but not as freely as other substances that are less viscous and more volatile.

Odor: It has a pungent, sharp odor.It has a pungent and sharp smell. The strong smell can be easily detected even in small concentrations, which serves as an important sensory characteristic for identification purposes in a laboratory or industrial setting.The strong smell is easily detectable even in small concentrations. This sensory characteristic is important for identification in a laboratory or an industrial setting.

Melting and Boiling Points: The melting point of 2 - Methylacrylic acid is around 15 - 16 degC.Melting and boiling points: The melting point for 2 - Methylacrylic Acid is between 15 and 16 degrees Celsius. This relatively low melting point means that it can exist as a solid in cool environments but will quickly turn into a liquid at slightly higher temperatures, close to room temperature.This low melting point allows it to exist as a solid at cool temperatures but quickly transforms into a liquid when heated up. Its boiling point is approximately 161 - 163 degC.Its boiling temperature is between 161 and 163 degrees Celsius. The difference between the melting and boiling points defines the temperature range in which it remains in the liquid phase under normal atmospheric pressure.The difference between its melting and boiling point defines the temperature range at which it remains liquid under normal atmospheric pressure.

Density: It has a density of about 1.015 g/cm3 at 20 degC.Density at 20 degrees Celsius: It is about 1.015 grams/cm3. This density value indicates that it is slightly denser than water, which has a density of 1 g/cm3.This density value indicates it is slightly heavier than water which has a weight of 1 g/cm3. As a result, when mixed with water, 2 - Methylacrylic acid will sink to the bottom if it is immiscible with water.If 2 - Methylacrylic Acid is immiscible, it will sink to bottom when mixed with water.

Solubility: 2 - Methylacrylic acid is soluble in many organic solvents such as ethanol, ether, and acetone.Solubility: Methylacrylic Acid is soluble in ethanol, ether and acetone. It also has some solubility in water.It is also soluble in water. The solubility in water is due to the presence of the carboxylic acid group (-COOH), which can form hydrogen bonds with water molecules.The presence of the carboxylic group (-COOH) can form hydrogen bonds between water molecules. However, as the carbon chain length increases due to the methyl group substitution, its solubility in water is not as high as that of simpler carboxylic acids like acetic acid.As the carbon chain length increases, the solubility of acetic acid in water decreases.

Chemical Properties

Acidity: It is a moderately acidic compound.Acidity: It's a moderately-acidic compound. The carboxylic acid functional group (-COOH) is responsible for its acidic nature.Its acidic nature is due to the carboxylic acid functional groups (-COOH). In an aqueous solution, it can donate a proton (H+) to form a carboxylate anion.In an aqueous solvent, it can donate one proton (H+), forming a carboxylate anion. The pKa value of 2 - Methylacrylic acid is around 4.84.The pKa of 2 - Methylacrylic Acid is approximately 4.84. This value indicates that it is a weak acid compared to strong acids like hydrochloric acid, but it can still participate in acid - base reactions.This value indicates it is a weaker acid than strong acids such as hydrochloric, but can still participate in acid-base reactions. For example, it can react with bases such as sodium hydroxide (NaOH) to form the corresponding sodium salt and water.It can, for example, react with bases like sodium hydroxide to form sodium salts and water.

Polymerization: One of the most important chemical properties of 2 - Methylacrylic acid is its ability to polymerize.Polymerization is one of the most important chemical characteristics of 2 - Methylacrylic Acid. The double bond in the molecule provides the reactivity for polymerization reactions.The double bond of the molecule is responsible for the polymerization reaction's reactivity. It can undergo addition polymerization, typically in the presence of initiators such as peroxides.It can undergo addition-polymerization, usually in the presence or initiators like peroxides. Polymerization results in the formation of poly(methacrylic acid), which has various applications in industries such as coatings, adhesives, and water - treatment polymers.Polymerization produces poly(methacrylic acids), which is used in many industries, including coatings, adhesives and water-treatment polymers. The polymers formed can have different molecular weights and properties depending on the reaction conditions.The polymers can have different molecular masses and properties depending on reaction conditions.

Esterification: The carboxylic acid group of 2 - Methylacrylic acid can react with alcohols in the presence of an acid catalyst to form esters.Esterification: In the presence of an acid catalyst, the carboxylic acid group in 2 - Methylacrylic Acid can react with alcohols to form esters. This is an important reaction in the synthesis of methacrylic esters, which are widely used in the production of polymers, plastics, and coatings.This reaction is important in the synthesis methacrylic ester, which is widely used in polymers, coatings, and plastics. For instance, reacting 2 - Methylacrylic acid with methanol in the presence of sulfuric acid will yield methyl methacrylate, a monomer commonly used in the production of polymethyl methacrylate (PMMA), also known as acrylic glass.In the presence of sulfuric acids, 2 - Methylacrylic Acid can be reacted with methanol to yield methyl methacrylate. This monomer is commonly used in the manufacture of polymethylmethacrylate (PMMA), or acrylic glass.