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Product Name | Acrylic acid, 2-chloro-, methyl ester |
Cas Number | 3282-30-2 |
Formula | C4H5ClO2 |
Molar Mass | 120.53 |
Density | 1.180 g/cm³ |
Boiling Point | 140-142°C |
Melting Point | -49°C |
Flash Point | 38°C |
Refractive Index | n20/D 1.420 |
Solubility In Water | Reacts |
Vapor Pressure | 9 mmHg at 25°C |
Logp | 1.65 |
Viscosity | Not available |
Appearance | Colorless to pale yellow liquid |
What are the main applications of acrylic acid, 2-chloro-, methyl ester?
2 - Chloroacrylic acid methyl ester is an important organic chemical intermediate with several main applications:The chloroacrylic acid methyl ester is a very important organic chemical intermediate that has several main applications.
1. In the synthesis of pesticidesIn the synthesis and use of pesticides
It serves as a key raw material in the production of certain pesticides.It is a key ingredient in the production of some pesticides. For example, it can participate in reactions to form structures that have insecticidal or herbicidal properties.It can, for example, participate in reactions that form structures with insecticidal and herbicidal qualities. The chlorine atom in 2 - chloroacrylic acid methyl ester can enhance the biological activity of the final pesticide product.The chlorine atom of 2 - chloroacrylic acids methyl ester may enhance the biological activity in the final pesticide. Pesticides synthesized from it can target specific pests or weeds, helping to protect crops from damage.It can be used to synthesize pesticides that target specific pests and weeds. This helps protect crops. This contributes to increased agricultural productivity by reducing the loss of crops to pests and weeds.This increases agricultural productivity by reducing crop losses due to pests and weeds.
2. In the field of pharmaceuticalsIn the field
This compound can be used in the synthesis of some pharmaceutical intermediates.This compound can be used to synthesize some pharmaceutical intermediates. The unique structure of 2 - chloroacrylic acid methyl ester allows it to be incorporated into larger molecular frameworks during the multi - step synthesis of drugs.The unique structure of 2-chloroacrylic acid-methyl ester allows for its incorporation into larger molecular structures during the multi-step synthesis of drugs. These intermediates can then be further modified to develop medications for treating various diseases.These intermediates can be further modified to create medications for treating different diseases. For instance, some anti - inflammatory or anti - infectious drugs may have a synthesis route that involves the use of this compound at an early stage of the chemical synthesis process.Some anti-inflammatory or anti-infectious drugs may be synthesized using this compound in an early stage of chemical synthesis.
3. In the production of specialty polymersIn the production and use of specialty polymers
2 - chloroacrylic acid methyl ester can be copolymerized with other monomers to create specialty polymers.Copolymerization of 2 - chloroacrylic acids methyl ester with other monomers can create specialty polymers. These polymers often have unique properties such as enhanced chemical resistance, better adhesion, or improved mechanical strength.These polymers have unique properties, such as improved chemical resistance, adhesion or mechanical strength. For example, they can be used in coatings, where the resulting polymer - based coating can provide excellent protection against corrosion, abrasion, and chemical attacks.They can be used as coatings that provide excellent protection from corrosion, abrasion and chemical attacks. In the automotive industry, such polymers can be used to coat car parts, increasing their durability and lifespan.In the automotive industry, these polymers can be applied to car parts in order to increase their durability and lifespan. In the electronics industry, they may be used in the encapsulation of electronic components, protecting them from environmental factors.In the electronics industry they can be used to encapsulate electronic components and protect them from environmental factors.
4. In the synthesis of dyes4.
It plays a role in the synthesis of certain types of dyes.It is used in the synthesis for certain types of dyes. The reactive groups in 2 - chloroacrylic acid methyl ester can be used to attach chromophoric groups, which are responsible for the color of the dye.The reactive groups of 2 - chloroacrylic acids methyl ester are used to attach chromophoric group, which is responsible for the dye's color. These dyes can be used in textile dyeing, leather dyeing, and paper coloring.These dyes are used for textile dyeing and leather dyeing. They can also be used to color paper. The chlorine - containing structure can also affect the fastness properties of the dyes, such as light - fastness and wash - fastness, making the dyed materials retain their color for a longer time.The chlorine-containing structure can also influence the fastness properties, such as wash-fastness and light-fastness, of the dyes. This makes the dyed materials maintain their color for longer.
What are the safety precautions when handling acrylic acid, 2-chloro-, methyl ester?
When handling acrylic acid, 2 - chloro -, methyl ester, the following safety precautions should be observed:Safety precautions must be observed when handling acrylic acid, 2-chloro-, methyl ester:
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Workers must wear appropriate chemical - resistant clothing.Workers must wear clothing that is resistant to chemicals. This includes long - sleeved shirts, long pants, and full - body suits made of materials that can resist the penetration of this chemical.This includes long-sleeved shirts and pants, as well as full-body suits made from materials that resist chemical penetration. Chemical - resistant gloves are also essential.Chemical-resistant gloves are also necessary. Nitrile or neoprene gloves are often good choices as they can provide a barrier against contact with the skin.These gloves can protect the skin from contact. Additionally, safety goggles with side shields should be worn to protect the eyes from any splashes.Safety goggles with side shields are also recommended to protect your eyes from splashes. If there is a risk of inhalation, respiratory protection is required.Respiratory protection is needed if there is a chance of inhalation. For low - level exposure, a respirator with an appropriate filter for organic vapors can be used.A respirator with a filter that is suitable for organic vapors may be used in low-level exposure. In cases of higher - concentration or poorly - ventilated environments, a supplied - air respirator may be necessary.In environments with high concentrations or poor ventilation, a supplied-air respirator may be required.
Second, proper handling procedures are crucial.Second, it is important to follow the correct handling procedures. When transferring the methyl ester, use appropriate funnels and containers that are compatible with the chemical.Use containers and funnels compatible with the chemical when transferring methyl ester. Ensure that the containers are well - sealed to prevent leakage.To prevent leakage, ensure that the containers are tightly sealed. When opening containers, do it slowly and in a well - ventilated area to avoid sudden releases of vapors.Open containers slowly and in an area that is well-ventilated to avoid sudden vapor releases. Avoid any actions that could cause spills, such as over - filling containers.Avoid actions that can cause spills such as over-filling containers. If a spill does occur, immediately evacuate non - essential personnel from the area.If a spill occurs, evacuate all non-essential personnel from the area immediately. Contain the spill using absorbent materials like sand or vermiculite.Use absorbent materials such as sand or Vermiculite to contain the spill. Do not use materials that could react with the chemical.Avoid using materials that may react with the chemical. After containing the spill, carefully clean up the absorbed chemical and dispose of it in accordance with local regulations.After the spill has been contained, clean up the chemical absorbed and dispose of it according to local regulations.
Third, storage is an important aspect.Third, storage is important. Store acrylic acid, 2 - chloro -, methyl ester in a cool, dry, and well - ventilated area.Store acrylic acid, 2-chloro-, methyl ester in a well-ventilated, cool, dry area. Keep it away from sources of heat, ignition, and oxidizing agents.Keep it away form sources of heat, oxidizing agents, and ignition. It should be stored in a dedicated chemical storage cabinet or area that is clearly labeled.It should be kept in a cabinet or area designated for storing chemicals that is clearly marked. Separate it from incompatible substances, such as bases, as they can react violently.Separate it from other substances that can react violently, such as bases. Regularly check storage containers for signs of damage or leakage.Check storage containers regularly for signs of damage and leakage.
Finally, in case of contact with the skin, immediately remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes.If you have skin contact, remove the clothing immediately and wash the affected area thoroughly with water for at least 15 min. Seek medical attention if irritation persists. If it gets into the eyes, rinse the eyes continuously with water for at least 15 minutes, lifting the eyelids occasionally, and then seek immediate medical help.If it gets in the eyes, rinse them continuously with water for 15 minutes while lifting the eyelids periodically. Seek immediate medical attention if irritation persists. In case of inhalation, move the affected person to fresh air immediately.In the event of inhalation, immediately move the person to fresh air. If breathing is difficult, provide artificial respiration and call for medical assistance.If breathing is difficult, call for medical help and provide artificial respiration.
What is the physical and chemical properties of acrylic acid, 2-chloro-, methyl ester?
2 - chloro - acrylic acid methyl ester is an organic compound with the following physical and chemical properties:The 2 - chloro-acryl acid methyl ester has the following physical and chemistry properties:
Physical Properties
Appearance: It is usually a colorless to light - yellow liquid.Appearance: The liquid is usually colorless or light yellow. This color range is characteristic of many relatively pure organic esters with certain substituents.This color range is typical of many relatively pure esters that have certain substituents. The liquid state at room temperature is due to the combination of its molecular structure and intermolecular forces.The liquid state is due to a combination of the molecular structure and the intermolecular force. The relatively low molecular weight and the nature of its functional groups do not lead to the formation of a solid lattice structure under normal conditions.Normal conditions do not allow for the formation of a solid structure due to its low molecular mass and nature of functional groups.
Boiling Point: The boiling point of 2 - chloro - acrylic acid methyl ester is typically in the range that reflects its medium - sized molecular structure and the strength of its intermolecular forces.Boiling point: The boiling points of 2 – chloro – acrylic acid methyl esters are typically within the range of their medium – sized molecular structures and the strength of their intermolecular forces. Esters generally have boiling points influenced by factors such as molecular weight, polarity, and the presence of functional groups.Esters have boiling points that are influenced by molecular weights, polarity and the presence functional groups. The chlorine atom and the ester group contribute to a certain degree of polarity, which affects the boiling point.The ester group and the chlorine atom contribute to the degree of polarity that affects the boiling temperature. Precise boiling point data may vary slightly depending on purity, but it is often in a range where it can be separated from other substances through distillation processes.The exact boiling point may vary depending on purity. However, it is usually in a range that allows it to be separated from other substances by distillation.
Density: It has a density greater than that of water, usually around 1.1 - 1.2 g/cm3.Density: It is heavier than water, typically around 1.1-1.2 g/cm3. The presence of the chlorine atom, which is relatively heavy, contributes to this higher density.This higher density is due to the presence of the relatively heavy chlorine atom. This property has implications in handling and separation processes, as it will sink in water if the two are immiscible.This property is important for handling and separation processes as it will sink if water and chlorine are incompatible.
Solubility: It is sparingly soluble in water.It is sparingly water soluble. The ester group and the chloro - substituent make the molecule relatively hydrophobic.The ester group, and the chloro-substituent make the molecule hydrophobic. However, it is soluble in many organic solvents such as ethanol, ether, and dichloromethane.It is soluble in organic solvents like ethanol, dichloromethane, and ether. This solubility in organic solvents is due to the similarity in polarity and intermolecular forces between the compound and these solvents, following the principle of "like dissolves like."This solubility is due to similarity in polarity, intermolecular forces and the solvents.
Chemical Properties
Reactivity of the Double Bond: The most reactive part of 2 - chloro - acrylic acid methyl ester is the carbon - carbon double bond.Double Bond Reactivity: The carbon-carbon double bond is the most reactive part of the 2 - chloro-acrylic acid methyl ester. It can undergo addition reactions, such as with hydrogen in the presence of a catalyst (hydrogenation) to form the saturated derivative.It can undergo addition reaction, such as hydrogenation in the presence a catalyst to form the saturated derivative. It can also react with halogens (e.g., bromine) in an addition reaction, where the double bond breaks and bromine atoms add to the carbon atoms of the double bond.It can also be added to halogens, such as bromine, in an addition reaction where the double bonds are broken and bromine atoms are added to the carbon atoms. This reactivity makes it useful in synthetic organic chemistry for building more complex molecules.This reactivity is useful in organic chemistry to build more complex molecules.
Reactivity of the Ester Group: The ester group can participate in hydrolysis reactions.Ester Group Reactivity: The ester groups can participate in hydrolysis. In the presence of an acid or a base, 2 - chloro - acrylic acid methyl ester will hydrolyze.In the presence of an base or acid, 2 – chloro – acrylic acid methyl ester will hydrolyze. In acidic hydrolysis, the ester will break down into 2 - chloro - acrylic acid and methanol.In acidic hydrolysis the ester will be broken down into 2 – chloro – acrylic acid and methanol. In basic hydrolysis (saponification), it will form the carboxylate salt of 2 - chloro - acrylic acid and methanol.In basic hydrolysis, it will form carboxylate salts of 2 – chloro – acrylic acid and methanol. The presence of the chlorine atom on the adjacent carbon may influence the rate of these hydrolysis reactions.The presence of a chlorine atom next to the carbon can influence the rate of hydrolysis reactions.
Reactivity of the Chlorine Atom: The chlorine atom can be involved in substitution reactions.Reactivity of the Chlorine atom: The chlorine atom is involved in substitution reactions. Nucleophiles can attack the carbon atom to which the chlorine is attached, replacing the chlorine atom.Nucleophiles attack the carbon atom that is attached to the chlorine, replacing the atom. For example, reaction with an alkoxide ion can lead to the formation of an ether - like product, where the alkoxide group substitutes the chlorine atom.As an example, a reaction with an alkoxide can lead to a product that is similar to ether, where the alkoxide substitutes the chlorine atom. This reactivity of the chlorine atom adds another dimension to the synthetic utility of 2 - chloro - acrylic acid methyl ester.This reactivity adds a new dimension to the synthetic utility for 2 - chloro-acrylic acid methyl ester.
How is acrylic acid, 2-chloro-, methyl ester synthesized?
The synthesis of methyl 2 - chloroacrylate can be achieved through the following general approaches:The following general approaches can be used to synthesize methyl 2 – chloroacrylate:
One common method is the reaction of acrylic acid derivatives with a chlorinating agent followed by esterification.A common method is to react acrylic acid derivatives first with a chlorinating compound, followed by esterification.
1. Starting from acrylic acid:Starting with acrylic acid
First, acrylic acid can react with a suitable chlorinating agent.First, acrylic acid reacts with a chlorinating agent. Thionyl chloride (SOCl2) is a frequently used chlorinating reagent.Thionyl Chloride (SOCl2), a commonly used chlorinating agent, is one of the most common chlorinating agents. When acrylic acid reacts with thionyl chloride, the -OH group of acrylic acid is replaced by a -Cl atom, forming 2 - chloroacrylic acid.When acrylic acid reacts thionyl chlorine, the -OH of acrylic acid is substituted by a Cl atom to form 2 - chloroacrylic acids. The reaction equation is as follows: CH2=CHCOOH + SOCl2 - CH2=CClCOOH + SO2+ HCl.The reaction equation is: CH2=CHCOOH+ SOCl2 + CH2=CClCOOH+ SO2+ HCL.
During this reaction, thionyl chloride first reacts with the carboxylic acid group.During this reaction, the thionyl group of the carboxylic acid is first reacted with. The oxygen of the -OH in the carboxylic acid attacks the sulfur atom of thionyl chloride.The carboxylic acid's oxygen attacks the sulfur of thionyl chloride. Then, a series of bond - breaking and forming processes occur, resulting in the formation of 2 - chloroacrylic acid along with the release of sulfur dioxide and hydrogen chloride gases.Then, a number of bond-breaking and forming processes take place, resulting in 2 - chloroacrylic acids along with the release sulfur dioxide and hydrogen chlorine gases.
2. Esterification of 2 - chloroacrylic acid:Esterification of 2-chloroacrylic acid
After obtaining 2 - chloroacrylic acid, it can be esterified with methanol to form methyl 2 - chloroacrylate.After obtaining 2 chloroacrylic acids, it can be esterified using methanol to produce methyl 2 chloroacrylate. Usually, an acid - catalyzed esterification reaction is carried out.Most often, the esterification is acid-catalyzed. Concentrated sulfuric acid or p - toluenesulfonic acid can be used as catalysts.Catalysts can be concentrated sulfuric acid or p-toluenesulfonic acids. The reaction equation is: CH2=CClCOOH + CH3OH = CH2=CClCOOCH3 + H2O.The reaction equation is CH2=CClCOOH+CH3OH =CH2=CClCOOCH3+H2O.
In this esterification reaction, the carboxylic acid group of 2 - chloroacrylic acid reacts with the hydroxyl group of methanol.The carboxylic acid group in 2 - chloroacrylic acids reacts with the hydroxyl groups of methanol. The acid catalyst protonates the carbonyl oxygen of the carboxylic acid, enhancing the electrophilicity of the carbonyl carbon.The acid catalyst protonates carbonyl oxygen in the carboxylic acids, increasing the electrophilicity. Then, the oxygen of methanol attacks the carbonyl carbon, and after a series of dehydration and de - protonation steps, methyl 2 - chloroacrylate is formed.The oxygen in methanol then attacks the carbonyl atom, and after several dehydration and de-protonation steps, methyl 2-chloroacrylate is produced. The reaction is an equilibrium reaction, and usually, excess methanol is used and water is removed during the reaction to shift the equilibrium towards the formation of the ester product.The reaction is an equilibrium reaction. Usually, excess methanol and water are used to shift the equilibrium in the direction of the ester product.
Another possible approach could be starting from a precursor that already contains the chlorine atom and then building up the acrylate structure.Another approach would be to start with a chlorine-containing precursor and build up the acrylate. However, the above - described two - step process starting from acrylic acid is a relatively straightforward and commonly used synthetic route for the preparation of methyl 2 - chloroacrylate.The two-step process described above, starting with acrylic acid, is a fairly straightforward and common synthetic route to prepare methyl 2-chloroacrylate.
What are the storage requirements for acrylic acid, 2-chloro-, methyl ester?
Acrylic acid, 2 - chloro-, methyl ester is a chemical compound that requires specific storage conditions to ensure safety and maintain its integrity.Acrylic acid, 2-chloro-, methyl ester is a chemical compound which requires specific storage conditions in order to maintain its integrity and safety.
First, storage should be in a cool, well - ventilated area.Storage should be done in a well-ventilated, cool area. High temperatures can accelerate decomposition or polymerization reactions of this compound.High temperatures can speed up the decomposition and polymerization of this compound. A storage temperature preferably below 30degC helps to prevent such unwanted reactions.Preferably, a storage temperature below 30degC will help to prevent unwanted reactions. In warm climates, proper cooling systems like air - conditioning in the storage facility may be necessary.In hot climates, cooling systems such as air-conditioning in the storage facility might be necessary.
It must be stored away from sources of ignition, such as open flames, sparks from electrical equipment, and hot surfaces.Store it away from ignition sources, such as open fires, sparks generated by electrical equipment, or hot surfaces. This chemical is flammable, and even a small ignition source can lead to a dangerous fire or explosion.This chemical is flammable and a small ignition source could cause a dangerous explosion or fire. So, storage areas should have strict no - smoking policies and ensure that all electrical equipment is explosion - proof.Storage areas should be smoke-free and all electrical equipment should be explosion-proof.
Contact with oxidizing agents should be avoided.Avoid contact with oxidizing agents. Oxidizers can react violently with acrylic acid, 2 - chloro-, methyl ester, potentially causing fires or explosions.Oxidizers may react violently with the acrylic acid, 2-chloro-, methyl esters, causing explosions or fires. Separate storage areas for oxidizers and this particular ester are essential.It is essential to have separate storage areas for both oxidizers, and this particular ester. For example, if there are any perchlorates or permanganates in the facility, they should be stored in a completely different room or at least in a well - segregated area.If there are perchlorates and permanganates present in the facility, these should be stored in an entirely different room, or at least a well-segregated area.
The storage containers should be made of appropriate materials.The containers should be made from appropriate materials. Metal containers that are resistant to corrosion, such as stainless steel, can be a good choice.Metal containers made of stainless steel or other metals that resist corrosion are a good option. However, it's important to ensure that the container material does not react with the chemical.It is important to make sure that the container does not react with chemical. Plastic containers may also be suitable, but they need to be of a high - quality and compatible with the ester to prevent leakage.Plastic containers are also suitable, but must be compatible with the ester and of high quality to prevent leakage. All containers should be tightly sealed to prevent evaporation of the chemical, which not only causes loss of product but can also create a flammable vapor in the air.All containers must be tightly sealed in order to prevent the chemical from evaporating, which can cause product loss and create a flammable gas in the air.
If storing 500 words' worth of this chemical (presumably meaning a significant quantity, around 500 kg or liters based on the context), proper inventory management is crucial.Inventory management is essential if you are storing 500 words worth of a chemical (which could mean a large quantity, say 500 kg or liters depending on the context). Regular checks should be carried out to ensure there are no signs of leakage, corrosion of containers, or any changes in the physical appearance or smell of the chemical.Regular checks are needed to ensure that there are no signs such as corrosion, leakage or changes in the chemical's physical appearance or smell. Any damaged containers should be immediately replaced in a safe manner following proper waste - disposal procedures for potentially hazardous chemicals.All damaged containers must be replaced immediately in a safe way, following the proper waste disposal procedures for potentially dangerous chemicals. Additionally, the storage area should be clearly marked with appropriate hazard signs to alert anyone entering the area about the nature of the stored chemical.The storage area should also be clearly marked with appropriate warning signs to alert anyone entering about the chemical stored.