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Product Name | Acrylic Acid Anhydrous |
Cas Number | 79-10-7 |
Formula | C3H4O2 |
Molar Mass | 72.06 |
Boiling Point | 141 |
Melting Point | 13 |
Density | 1.051 |
Vapor Pressure | 3.8 |
Flash Point | 54 |
Autoignition Temperature | 438 |
Solubility In Water | miscible |
Viscosity | 1.3 |
Refractive Index | 1.417 |
Heat Of Vaporization | 47.2 |
What are the main uses of acrylic acid anhydride?
Acrylic acid anhydride is a chemical compound with several important uses in various industries.Acrylic acid anhydride has many important applications in different industries.
One of its main applications is in the field of polymer synthesis.Its main application is in polymer synthesis. It can be used as a monomer or a cross - linking agent in the production of polymers.It can be used either as a monomer, or a cross-linking agent in the production polymers. When used as a monomer, it can participate in polymerization reactions to form polymers with specific properties.As a monomer it can be used to participate in polymerization reactions and form polymers that have specific properties. These polymers often have good solubility, film - forming ability, and chemical resistance.These polymers are often characterized by good solubility, film-forming ability, and chemical resistant. For example, in the production of certain types of acrylic resins, acrylic acid anhydride can contribute to the formation of a network structure, enhancing the hardness and durability of the resulting resin.In the production of certain types acrylic resins, the acrylic acid anhydride may contribute to the formation a network structure that increases the hardness and durability. This is beneficial for applications such as coatings, where the final product needs to withstand wear and tear, environmental factors like moisture and UV radiation.This is especially useful for coatings where the final product must be able to withstand wear, moisture, and UV radiation.
In the field of pharmaceuticals and fine chemicals, acrylic acid anhydride is used in organic synthesis.Acrylic acid anhydride can be used to synthesize organic compounds in the pharmaceutical and fine chemical industries. It can react with other organic compounds to introduce specific functional groups.It can react with organic compounds to introduce functional groups. For instance, it can react with alcohols to form esters, which are key intermediates in the synthesis of many drugs.It can, for example, react with alcohols to produce esters, which are important intermediates in the synthesizing of many drugs. The anhydride group's reactivity allows for the creation of complex molecular structures with high precision.Reactivity of the anhydride group allows for highly precise creation of complex molecular structures. This is crucial in the pharmaceutical industry, where the slightest change in a molecule's structure can significantly affect its biological activity.This is important in the pharmaceutical industry where even the slightest changes in a molecule’s structure can have a significant impact on its biological activity.
Another area where acrylic acid anhydride is useful is in the production of adhesives.Acrylic acid anhydride can also be used to make adhesives. By incorporating acrylic acid anhydride into adhesive formulations, it can improve the adhesion properties of the adhesive.Acrylic acid anhydride can be added to adhesive formulations to improve adhesion. It can react with the surfaces of substrates, forming strong chemical bonds.It can react with substrate surfaces, forming strong chemical bond. This is especially important for bonding materials that are difficult to adhere to, such as some plastics and metals.This is important when bonding materials like metals and plastics that are difficult or impossible to adhere to. The enhanced adhesion strength provided by acrylic acid anhydride helps to ensure the long - term reliability of the bonded joints, whether in industrial applications or in consumer products like tapes and labels.Acrylic acid anhydride's enhanced adhesion strength helps to ensure long-term reliability of bonded joints in industrial applications and consumer products such as tapes and labels.
In addition, acrylic acid anhydride can be used in the synthesis of dyes.Acrylic acid anhydride is also used to synthesize dyes. It can be involved in reactions that build the chromophore structure of dyes, which is responsible for their color - giving properties.It can be used in reactions to build the chromophore structures of dyes that are responsible for their color-giving properties. The anhydride's chemical reactivity enables the construction of a wide variety of dye molecules with different colors and properties, such as light - fastness and solubility, to meet the requirements of different dyeing processes, whether for textiles, paper, or other materials.Chemical reactivity of the anhydride allows for the construction of dye molecules of various colors and properties such as light-fastness and solubility to meet the demands of different dyeing processes.
How is acrylic acid anhydride produced?
Acrylic acid anhydride can be produced through several methods.Several methods can be used to produce acrylic acid anhydride. One common approach is the reaction of acrylic acid with a dehydrating agent.One common method is to react acrylic acid with a hydrating agent.
One method involves using acetic anhydride as a reactant and a catalyst.Acetic anhydride is used as a catalyst and a reaction agent in one method. In this process, acrylic acid reacts with acetic anhydride.This process involves the reaction of acrylic acid with acetic ahydride. The reaction is typically carried out in the presence of a catalyst such as sulfuric acid or a Lewis acid like zinc chloride.The reaction is usually carried out with a catalyst, such as sulfuric or Lewis acids like zinc chloride. The acetic anhydride acts as a dehydrating agent, removing a water molecule from two acrylic acid molecules to form acrylic acid anhydride.The acetic acid acts as a dehydrating substance, removing the water molecule of two acrylic acid molecules in order to form acrylic anhydride. The chemical reaction can be represented as follows: 2CH2=CHCOOH + (CH3CO)2O - (CH2=CHCO)2O + 2CH3COOH.The chemical reaction is represented as: 2CH2=CHCOOH+ (CH3CO )2O – (CH2=CHCO )2O +2CH3COOH. The acetic acid by - product can be separated from the acrylic acid anhydride through techniques such as distillation.Distillation can be used to separate the acetic acid by-product from the acrylic anhydride.
Another way to produce acrylic acid anhydride is by the pyrolysis of acrylic acid esters.The pyrolysis process of acrylic acid esters is another way to produce anhydride. For example, methyl acrylate can be pyrolyzed at high temperatures.For example, methyl-acrylate can also be pyrolyzed. In this process, the methyl acrylate molecule undergoes a thermal decomposition reaction.This process involves the thermal decomposition of a methyl acrylate molecular. Through a series of bond - breaking and rearrangement steps, acrylic acid anhydride is formed along with methyl radicals or other by - products.Acrylic acid anhydride, along with methyl radicals and other by-products, is formed through a series bond-breaking and rearrangement stages. The reaction conditions need to be carefully controlled, including temperature, pressure, and the presence of any catalysts or inert gases to promote the formation of acrylic acid anhydride and minimize the formation of unwanted side - products.Temperature, pressure, and presence of any inert gases or catalysts are all factors that need to be carefully controlled to maximize the formation and minimize unwanted side-products.
In addition, it can also be synthesized from propylene - based routes.It can also be made from propylene-based routes. Propylene is first oxidized to form acrolein, and then further oxidized to acrylic acid.Propylene first becomes acrolein and is then further oxidized into acrylic acid. From there, through appropriate dehydration reactions similar to the above - mentioned methods using dehydrating agents, acrylic acid anhydride can be obtained.Acrylic acid anhydride is then obtained through dehydration reactions using dehydrating agents similar to those mentioned above. This multi - step process requires precise control at each stage to ensure high yields of the final product.This multi-step process requires precise control of each stage to ensure high yields. Overall, the production of acrylic acid anhydride requires careful selection of reactants, reaction conditions, and separation techniques to obtain a pure and high - quality product.To produce a high-quality product, it is important to carefully select the reactants, reaction conditions and separation techniques.
What are the safety precautions when handling acrylic acid anhydride?
Acrylic acid anhydride is a hazardous chemical, and when handling it, the following safety precautions must be taken.Acrylic acid anhydride can be a dangerous chemical. When handling it, you must take the following safety precautions.
First, personal protective equipment is essential.Personal protective equipment is a must. Wear appropriate chemical - resistant clothing, such as a full - body chemical - resistant suit.Wear chemical-resistant clothing, such a a full-body chemical-resistant suit. This helps prevent the liquid from coming into contact with the skin, as acrylic acid anhydride can cause severe skin burns and irritation.This will prevent the liquid from contacting the skin as acrylic acid anhydride is a chemical that can cause severe burns and irritation. Also, use chemical - resistant gloves made of materials like butyl rubber.Use gloves that are resistant to chemicals, such as butyl rubber. These gloves should be checked regularly for any signs of damage or leaks.Check these gloves regularly for signs of damage or leaks. Additionally, safety goggles or a face shield must be worn to protect the eyes from splashes.Safety goggles or face shields must also be worn to protect eyes from splashes. Inhalation is another risk, so a proper respiratory protection device, like a gas - mask with appropriate cartridges for acidic vapors, should be used in areas where there may be significant vapor exposure.Inhalation can also be a risk. A respiratory protection device such as a gas mask with cartridges for acidic vapours should be used where there is a high risk of vapor exposure.
Second, proper ventilation is crucial.Second, it is important to have proper ventilation. Work in a well - ventilated area, preferably a fume hood.Work in an area that is well-ventilated, preferably with a fume hood. A fume hood can effectively remove the vapors of acrylic acid anhydride from the work area, reducing the risk of inhalation.A fume hood will effectively remove the vapors from the area of work, reducing the risk for inhalation. Ensure that the ventilation system is operating correctly before starting any work with this chemical.Before beginning any work with acrylic acid anhydride, ensure that the ventilation system works properly.
Third, when storing acrylic acid anhydride, keep it in a cool, dry place away from heat sources, flames, and oxidizing agents.Third, store acrylic acid anhydride in a cool and dry place, away from heat sources, oxidizing agents, and flames. It should be stored in a tightly - sealed container to prevent leakage and evaporation.Store it in a tightly-sealed container to prevent leaking and evaporation. Label the storage container clearly with the chemical name, hazard warnings, and any relevant information.Label the container with the chemical name and any other relevant information.
Fourth, in case of accidental spills, act quickly.In the event of an accidental spill, act fast. First, evacuate the area to prevent exposure to others.First, evacuate the affected area to avoid exposing others. Then, use appropriate absorbent materials, like vermiculite or sand, to soak up the spill.Use absorbent materials like vermiculite, sand or a similar material to soak up the spill. Avoid using materials that may react with acrylic acid anhydride.Avoid materials that could react with acrylic anhydride. After absorption, carefully transfer the contaminated absorbent to a proper waste container.After absorption, transfer the contaminated absorbent into a suitable waste container. Clean the spill area thoroughly with a suitable neutralizing agent and water, following the proper procedures for disposing of the waste generated from the clean - up.After cleaning the spill, use a neutralizing agent to remove the contaminant and water. Dispose of the waste generated by the clean-up.
Finally, all personnel handling acrylic acid anhydride should be trained in its proper use, storage, and emergency response procedures.All personnel who handle acrylic acid anhydride must be trained on its proper handling, storage and emergency response procedures. They should know the symptoms of exposure and what to do in case of an accident, such as seeking immediate medical attention.They should be aware of the symptoms and know what to do if an accident occurs, such as seeking immediate medical care. Regular safety drills can also help ensure that everyone is prepared to handle potential emergencies effectively.Regular safety drills will also help to ensure that everyone is ready to handle any emergency.
What are the physical and chemical properties of acrylic acid anhydride?
Physical properties of acrylic acid anhydride:Physical properties of acrylic anhydride
Appearance: Acrylic acid anhydride is usually a colorless to slightly yellow - colored liquid.Appearance: Acrylic anhydride is a colorless or slightly yellow-colored liquid. This appearance is typical for many anhydrides of carboxylic acids.This is a common appearance for many carboxylic acid anhydrides. The color can sometimes be influenced by impurities or exposure to certain conditions.The color of anhydrides can be affected by impurities and exposure to certain conditions.
Odor: It has a pungent and irritating odor.It has an irritating and pungent odor. The strong smell is characteristic of anhydrides and is due to their reactivity and the presence of the acid - derivative functional groups.The strong smell of anhydrides is due to the reactivity of the anhydrides as well as the presence of acid-derivative functional groups. The pungent odor serves as a warning sign of its potentially harmful nature.The pungent smell is a warning of its potential harmful nature.
Boiling point: The boiling point of acrylic acid anhydride is around 169 - 170 degC.Boiling Point: The boiling point for acrylic acid anhydride ranges between 169 and 170 degrees Celsius. This boiling point is relatively high compared to some simple organic compounds.This boiling point is higher than some simple organic compounds. The relatively high boiling point is attributed to the presence of intermolecular forces such as dipole - dipole interactions and van der Waals forces.The relatively high boiling temperature is due to intermolecular interactions such as dipole-dipole interactions and van der Waals force. The polar nature of the carbonyl groups in the anhydride structure contributes to these intermolecular forces.These intermolecular interactions are a result of the polar nature the carbonyl groups have in the anhydride.
Melting point: The melting point of acrylic acid anhydride is approximately - 62 degC.Melting point: The acrylic acid anhydride melting point is approximately -62 degC. It exists as a liquid at room temperature (around 25 degC) due to its low melting point.Due to its low melting temperature, it is a liquid at normal room temperatures (around 25 degC). This liquid state at room temperature makes it relatively easy to handle in some laboratory and industrial processes, although proper safety precautions must be taken due to its reactivity.Its liquid state at room temperatures makes it relatively easy for laboratory and industrial processes to handle, but safety precautions are necessary due to its reactivity.
Solubility: It is soluble in common organic solvents such as dichloromethane, chloroform, and ethyl acetate.Solubility: It's soluble in common organic solvants such as dichloromethane (dichloroform), chloroform and ethyl-acetate. This solubility in organic solvents is beneficial for its use in organic synthesis reactions.This solubility is advantageous for its use in organic reactions. However, it is not very soluble in water.It is not very water soluble. Instead, it reacts with water rather than dissolving, as will be discussed in its chemical properties.It reacts with the water, rather than dissolving it, as we will discuss in its chemical properties.
Chemical properties of acrylic acid anhydride:Chemical properties of acrylic anhydride
Hydrolysis: One of the most significant chemical properties is its reactivity with water.Hydrolysis: Reactivity with water is one of the most important chemical properties. Acrylic acid anhydride undergoes hydrolysis in the presence of water.In the presence of water, acrylic acid anhydride is hydrolyzed. The reaction results in the formation of acrylic acid.The reaction leads to the formation of acrylic acids. The chemical equation for this reaction is (CH2=CHCO)2O + H2O - 2CH2=CHCOOH.This reaction has the chemical equation (CH2=CHCO).2O + H2O = 2CH2=CHCOOH. This hydrolysis reaction is an example of a nucleophilic acyl substitution reaction, where water acts as a nucleophile attacking the carbonyl carbon of the anhydride.This hydrolysis reaction is a good example of a acyl substitution nucleophilic reaction. Water acts as the nucleophile, attacking the carbonyl of the anhydride.
Reaction with alcohols: It reacts with alcohols to form esters.Reaction with alcohols. It reacts with alcohols and forms esters. For example, when reacting with methanol (CH3OH), it forms methyl acrylate (CH2=CHCOOCH3) and acrylic acid.When reacting with methanol, it forms methyl-acrylate (CH2=CHCOOCH3) as well as acrylic acid. The reaction is also a nucleophilic acyl substitution, where the alcohol's - OH group attacks the carbonyl carbon of the anhydride.The reaction is a nucleophilic substitution of acyls, where the alcohol -OH group attacks carbonyl carbon in the anhydride. The general reaction equation is (CH2=CHCO)2O + ROH - CH2=CHCOOR + CH2=CHCOOH, where R represents the alkyl group of the alcohol.The general equation for the reaction is (CH2=CHCO2O) + ROH – CH2=CHCOOR – CH2=CHCOOH. R represents the alkyl groups of the alcohol.
Reaction with amines: Acrylic acid anhydride reacts with amines to form amides.Reaction with amines. Acrylic acid anhydride reacts amines into amides. In this reaction, the amine attacks the carbonyl carbon of the anhydride.In this reaction, amines attack the carbonyl carbon in the anhydride. For instance, with ammonia (NH3), it forms acrylamide (CH2=CHCONH2) and acrylic acid.With ammonia (NH3) it produces acrylamide (CH2=CHCONH2), and acrylic acid. The reaction is yet another example of nucleophilic acyl substitution and is an important method for the synthesis of acrylamide - based compounds.This reaction is another example of nucleophilic substitution of acyls and is a method that is important for the synthesis acrylamide-based compounds.
Polymerization: Acrylic acid anhydride can participate in polymerization reactions.Polymerization: The acrylic acid anhydride is a polymerization catalyst. The double bond in the acrylic acid moiety can be polymerized, either alone or in combination with other monomers.The double bond of the acrylic acid moiety is polymerisable, either by itself or in combination with monomers. This property makes it useful in the production of various polymers with different properties, such as coatings, adhesives, and some types of plastics.This property is useful in the production polymers with various properties, such coatings, adhesives and some types plastics. The polymerization can be initiated by heat, light, or the presence of initiator compounds.Heat, light or initiator compounds can initiate polymerization.
What are the applications of acrylic acid anhydride in the chemical industry?
Acrylic acid anhydride is a reactive compound with various applications in the chemical industry.Acrylic acid anhydride, a reactive compound, has many applications in the chemical industries.
One significant application is in the field of polymer synthesis.Polymer synthesis is a significant application. It can be used as a monomer or a cross - linking agent.It can be used either as a monomer, or a cross-linking agent. When used as a monomer, it can participate in polymerization reactions to form polymers with unique properties.As a monomer it can be used to participate in polymerization reactions, resulting in polymers with unique characteristics. The resulting polymers often have good solubility, film - forming ability, and chemical resistance.The polymers formed are often chemically resistant, have good solubility and film-forming abilities. For example, in the production of specialty acrylic polymers, acrylic acid anhydride can introduce specific functional groups into the polymer chain, which can enhance the polymer's adhesion to different substrates.In the production of specialty polymers, such as acrylic acid anhydride, functional groups can be introduced into the polymer chains to enhance the polymer's adhesiveness to different substrates. This is useful in coatings, where the modified polymers can better adhere to metals, plastics, or woods, providing long - lasting protection and decorative effects.This is especially useful for coatings where the modified polymers adhere better to metals or plastics. They also provide long-lasting protection and decorative effects.
In the production of adhesives, acrylic acid anhydride plays an important role.Acrylic acid anhydride is a key ingredient in the production of adhesives. It can react with other components to form high - performance adhesive systems.It can react with other ingredients to form high-performance adhesive systems. The anhydride group can participate in chemical reactions with substances containing active hydrogen, such as amines or alcohols, to form strong chemical bonds.The anhydride group is capable of participating in chemical reactions that involve substances containing active hydrogen such as amines and alcohols to form strong chemical bonding. This leads to the formation of adhesives with high bonding strength, good heat resistance, and excellent durability.This results in adhesives that have excellent heat resistance and durability, as well as high bonding strength. These adhesives are widely used in the automotive, electronics, and packaging industries.These adhesives are widely utilized in the automotive, packaging, and electronics industries. For instance, in the electronics industry, they can be used to bond different electronic components due to their reliable performance under various environmental conditions.Due to their reliability, they can be used in the electronics industry to bond different electronic parts.
Acrylic acid anhydride is also used in the synthesis of fine chemicals.The synthesis of fine chemical compounds also uses acrylic acid anhydride. It can be used as a building block for the preparation of various organic compounds.It can be used to prepare various organic compounds. For example, it can react with nucleophiles in organic synthesis reactions to introduce acrylic - based functional groups into target molecules.It can, for example, react with nucleophiles to introduce functional groups based on acrylic into target molecules. This is valuable in the pharmaceutical and agrochemical industries.This is useful in the pharmaceutical and agricultural industries. In the pharmaceutical field, it may be used in the synthesis of drug intermediates, where the introduction of acrylic - related structures can potentially modify the biological activity, solubility, or stability of the final drug product.In the pharmaceutical industry, it can be used to synthesize drug intermediates. The introduction of acrylic-related structures may alter the biological activity, the solubility or the stability of the final product. In agrochemicals, it can contribute to the synthesis of active ingredients with improved properties, such as better pest - control efficacy or longer - lasting effects.In agrochemicals it can be used to synthesize active ingredients that have improved properties such as pest - control effectiveness or longer-lasting effects.
In addition, it can be used in the modification of natural polymers.It can also be used to modify natural polymers. For example, when reacting with cellulose or starch, it can introduce acrylic - based functional groups onto the natural polymer backbone.When reacting with starch or cellulose, it can introduce functional groups based on acrylic onto the backbone of natural polymers. This modification can improve the mechanical properties, water - resistance, and biodegradability of the natural polymers, expanding their applications in areas such as biodegradable packaging materials and textile finishing agents.This modification can improve mechanical properties, water-resistance, and biodegradability, expanding their application in areas such biodegradable packing materials and textile finishing agents.