.
Product Name | Acrylic acid, hexadecyl ester |
Cas Number | 21643-80-5 |
Formula | C19H36O2 |
Molar Mass | 296.49 |
Density | 0.86 g/cm³ |
Boiling Point | 419.6 °C at 760 mmHg |
Melting Point | 7-10 °C |
Flash Point | 238.2 °C |
Refractive Index | 1.447 |
Vapor Pressure | 2.44E-06 mmHg at 25 °C |
Logp | 8.39 |
Water Solubility | Insoluble |
Stability | Stable under normal temperatures and pressures |
Appearance | Transparent liquid |
What are the main uses of acrylic acid, hexadecyl ester?
Acrylic acid, hexadecyl ester, also known as hexadecyl acrylate, has several main uses.Hexadecyl ester, also known by the name hexadecyl acrylicate, is used for a variety of purposes.
In the field of coatings, it plays a significant role.It plays an important role in the field of coatings. It can be copolymerized with other monomers to produce high - performance coating materials.It can be copolymerized to produce high-performance coating materials. The resulting coatings have excellent properties such as good abrasion resistance.The coatings produced have excellent properties, such as high abrasion resistance. The long - chain hexadecyl group in the molecule can improve the film - forming property and hydrophobicity of the coating.The hexadecyl long-chain group in the molecule improves the film-forming property and hydrophobicity. For example, in industrial coatings, these characteristics help protect metal surfaces from corrosion and wear, prolonging the service life of the coated objects.These characteristics can be used in industrial coatings to protect metal surfaces against corrosion and wear. This prolongs the service life of coated objects. In architectural coatings, it can enhance the weather resistance and self - cleaning ability of the exterior wall coatings, making the buildings look clean and new for a longer time.Architectural coatings can be enhanced by this feature to increase the weather resistance of the exterior wall coatings and their self-cleaning ability. This will make the building look newer for longer.
In the area of adhesives, acrylic acid, hexadecyl ester is also an important raw material.Acrylic acid, hexadecyl ester is also a raw material important in the adhesives industry. When incorporated into adhesive formulations, it can adjust the adhesion strength and flexibility of the adhesives.It can be used to adjust the adhesion and flexibility of adhesives when incorporated into formulations. The long - chain structure provides certain softening and flexibility, enabling the adhesive to better adapt to the deformation of different substrates.The long-chain structure allows for a certain amount of flexibility and softening, which helps the adhesive adapt better to substrate deformation. It is widely used in pressure - sensitive adhesives, which are used in products like tapes and labels.It is widely used for pressure-sensitive adhesives that are used to make products such as tapes and labels. These adhesives need to have good adhesion to various surfaces while also being able to be easily peeled off without leaving residues, and the properties of hexadecyl acrylate contribute to achieving these requirements.Hexadecyl Acrylate is used to make adhesives that adhere well to different surfaces and can be peeled away without leaving residues.
In the polymer modification industry, it is used to modify polymers.In the polymer industry, it is used for polymer modification. By copolymerizing with polymers such as polyethylene or polypropylene, it can introduce new functional groups and change the physical and chemical properties of the polymers.By copolymerizing polymers like polyethylene or polypropylene it can introduce functional groups and change physical and chemical property of the polymers. For instance, it can improve the compatibility of polymers with other substances, which is beneficial for the preparation of polymer blends with enhanced performance.It can, for example, improve the compatibility between polymers and other substances. This is useful when preparing polymer blends that perform better. It can also enhance the surface properties of polymers, making them more suitable for applications that require specific surface characteristics, such as better printability or paintability.It can also improve the surface properties of polymers to make them more suitable for applications requiring specific surface characteristics such as better paintability or printability.
In addition, in some specialty applications, such as in the production of certain high - end cosmetics and personal care products, acrylic acid, hexadecyl ester can be used as an ingredient in formulations.Acrylic acid, hexadecyl ester can also be used in formulations for certain specialty applications, including the production of high-end cosmetics and personal care items. Its film - forming and emollient properties can be utilized to create products with smooth textures and good spreadability on the skin.Its emollient and film-forming properties can be used to create products that have a smooth texture and spread easily on the skin. However, in these applications, strict quality and safety standards need to be met.In these applications, however, strict safety and quality standards must be met. Overall, acrylic acid, hexadecyl ester is a versatile chemical with diverse applications across multiple industries.Acrylic acid, hexadecyl ester is a versatile chemical that has many applications in multiple industries.
How is acrylic acid, hexadecyl ester produced?
Acrylic acid, hexadecyl ester is typically produced through an esterification reaction.The esterification process is used to produce acrylic acid, hexadecyl ester. Here is a general overview of the production process.Here is an overview of the production.
The starting materials for this synthesis are acrylic acid and hexadecyl alcohol.Acrylic acid and hexadecyl ethanol are the starting materials in this synthesis. Esterification is a reaction between an acid (in this case, acrylic acid) and an alcohol (hexadecyl alcohol) in the presence of a catalyst to form an ester (acrylic acid, hexadecyl ester) and water as a by - product.Esterification is the reaction between an alcohol (hexadecyl) and an acid (acrylic acid) in presence of a catalyser to form an ester (acrylic ester, hexadecyl ester) and water as by-product.
A common catalyst used in this reaction is a strong acid, such as sulfuric acid or p - toluenesulfonic acid.A strong acid such as sulfuric or p-toluenesulfonic acids is often used as a catalyst in this reaction. The role of the catalyst is to increase the rate of the reaction by lowering the activation energy.The catalyst's role is to increase the speed of the reaction by lowering activation energy.
The reaction is usually carried out under specific reaction conditions.The reaction is typically carried out under certain reaction conditions. The reaction mixture containing acrylic acid, hexadecyl alcohol, and the catalyst is heated to an appropriate temperature, typically in the range of 100 - 150 degC.The mixture of acrylic acid, hexadecyl alchohol, and catalyst is heated at a temperature that is appropriate, usually between 100-150 degC. The elevated temperature helps to drive the reaction forward, as esterification reactions are generally endothermic.The higher temperature accelerates the reaction, since esterification reactions tend to be endothermic.
To shift the equilibrium of the reaction towards the formation of the ester, water is often removed from the reaction system as it is formed.Water is often removed as it forms from the reaction system to shift the equilibrium towards the ester. This can be achieved through techniques such as azeotropic distillation.Using techniques like azeotropic distillation, this can be achieved. In azeotropic distillation, an azeotrope - forming agent (such as toluene) is added to the reaction mixture.In azeotropic distillation, an azeotrope-forming agent (such a toluene), is added to the reaction mix. The azeotrope (a mixture of water and the azeotrope - forming agent with a constant boiling point) is distilled out of the reaction vessel, effectively removing water and promoting the forward reaction.The azeotrope, a mixture of water with the azeotrope-forming agent that has a constant boiling temperature, is distilled from the reaction vessel. This removes water and promotes the forward reaction.
After the reaction has proceeded for a sufficient amount of time, as determined by analytical methods such as gas chromatography to monitor the conversion of reactants to products, the reaction mixture is worked up.The reaction mixture is then worked up after the reaction has been allowed to proceed for a sufficient time as determined by analytical techniques such as gas-chromatography, which monitors the conversion of reactants into products. This typically involves neutralizing the catalyst.Typically, this involves neutralizing catalyst. If sulfuric acid was used as the catalyst, it can be neutralized with a base such as sodium carbonate.If sulfuric acid is used as a catalyst, it can neutralized by using a base like sodium carbonate.
The resulting mixture is then separated to isolate the acrylic acid, hexadecyl ester product.The mixture is separated to obtain the acrylic acid and hexadecyl ester product. This can be done through techniques such as extraction and distillation.This can be achieved through techniques like extraction and distillation. Distillation is often an effective method as it can separate the ester from any unreacted starting materials, by - products, and neutralized salts based on differences in their boiling points.Distillation can be an effective method because it can separate the ester and any unreacted materials, by-products, and neutralized sodiums based on their differences in boiling points. The purified acrylic acid, hexadecyl ester can then be further characterized and used in various applications, such as in the production of coatings, adhesives, and polymers.Purified acrylic acid hexadecyl esters can be further characterized, and used for various applications such as the production of polymers, adhesives and coatings.
What are the physical and chemical properties of acrylic acid, hexadecyl ester?
Physical properties of acrylic acid, hexadecyl ester:Physical properties of acrylic Acid, Hexadecyl Ester
Appearance: It is usually a colorless to pale - yellow liquid.Appearance: It's usually a colorless or pale-yellow liquid. This relatively light color is common for many organic esters and can be attributed to the nature of its molecular structure which does not have highly conjugated chromophores that would impart a strong color.This color is common to many organic esters. It can be attributed the molecular structure of the esters, which lacks highly conjugated chromophores.
Boiling point: The boiling point of acrylic acid, hexadecyl ester is relatively high.Boiling point of acrylic acid hexadecyl ester is relatively high. Given the long - chain hexadecyl group attached to the acrylic acid moiety, the intermolecular forces, mainly van der Waals forces due to the large non - polar hydrocarbon chain, are significant.The intermolecular forces are significant due to the long-chain hexadecyl attached to the acrylic moiety. These forces require a substantial amount of energy to break, resulting in a high boiling point.These forces require considerable energy to break and result in a high boiling temperature. It typically boils in the range where the energy input can overcome these intermolecular attractions and convert the liquid to vapor.It boils when the energy input is sufficient to overcome the intermolecular attraction and convert the liquid into vapor.
Melting point: The melting point is also influenced by the long - chain structure.Melting point is also affected by the structure of the long-chain. The relatively large and flexible hexadecyl chain can pack in a somewhat ordered manner to a certain extent.The large and flexible hexadecyl chains can pack in an ordered manner up to a certain degree. However, due to the presence of the acrylic acid ester functional group which can disrupt the perfect packing of the hydrocarbon chains, the melting point is not extremely high.The melting point of acrylic acid ester is not very high due to the presence the functional group that can disrupt the perfect packing the hydrocarbon chains. It is usually low enough so that at room temperature, it exists as a liquid.It is usually low-enough to exist as a liquid at room temperature.
Density: It has a density less than that of water.Density: It is less dense than water. The long - chain hydrocarbon part of the molecule is less dense than water, and overall, the density of acrylic acid, hexadecyl ester is lower.The long-chain hydrocarbon part is less dense than the water and the overall density of acrylic ester, hexadecyl ester is lower. This is common for many organic esters with long - chain alkyl groups.This is true for many organic esters containing long-chain alkyl groups.
Solubility: It is sparingly soluble in water.Solubility: It's sparingly soluble. The non - polar long hexadecyl chain dominates the solubility behavior.The long non-polar hexadecyl chains dominate the solubility. Water is a polar solvent, and the large non - polar part of the molecule does not interact favorably with water molecules through hydrogen bonding or dipole - dipole interactions.Water is a polar liquid, and the large non-polar part of the molecule interacts negatively with water molecules via hydrogen bonding or dipole-dipole interactions. However, it is soluble in many organic solvents such as hydrocarbons (e.g., hexane), chloroform, and ethers.It is soluble in organic solvents like hydrocarbons (e.g. hexane), ethers, and chloroform. These organic solvents have similar non - polar characteristics to the acrylic acid, hexadecyl ester molecule, allowing for good dissolution.These organic solvents share similar non-polar characteristics with the acrylic acid hexadecyl ester molecule. This allows for good dissolution.
Chemical properties of acrylic acid, hexadecyl ester:Chemical properties of acrylic Acid, Hexadecyl Ester
Reactivity of the double bond: The most reactive part of the molecule is the carbon - carbon double bond in the acrylic acid moiety.Double bond reactivity: The most reactive part is the carbon-carbon double bond in acrylic acid moiety. It can undergo addition reactions.It can undergo addition reaction. For example, it can react with hydrogen in the presence of a catalyst (such as palladium on carbon) to form the saturated hexadecyl propionate.It can, for example, react with hydrogen when a catalyst is present (such as palladium and carbon) to produce saturated hexadecylpropionate. This hydrogenation reaction is an important process in some chemical industries to modify the properties of the compound.In some chemical industries, this hydrogenation reaction is used to modify the properties. It can also react with halogens (e.g., bromine) in an addition reaction, where the double bond breaks and two bromine atoms add across the double bond.It can also react in addition with halogens, such as bromine, where two bromine atoms are added across the double-bond.
Ester hydrolysis: The ester group in acrylic acid, hexadecyl ester can undergo hydrolysis reactions.Ester hydrolysis is possible in the case of hexadecyl esters, acrylic acids. In the presence of an acid or a base, the ester bond can be cleaved.The ester bond may be cleaved in the presence of an base or acid. In acidic hydrolysis, the reaction is reversible, and the products are acrylic acid and hexadecyl alcohol.In acidic hydrolysis the reaction is reversible and the products are hexadecyl and acrylic alcohol. In basic hydrolysis (saponification), the reaction goes to completion, and the products are the carboxylate salt of acrylic acid and hexadecyl alcohol.In basic hydrolysis, the reaction is completed and the products are hexadecyl and acrylic acid carboxylates. This hydrolysis reaction is important in understanding the degradation and reactivity of the compound in different environments.This hydrolysis reaction helps to understand the degradation and reactivity in different environments.
Polymerization: Due to the presence of the double bond, acrylic acid, hexadecyl ester can participate in polymerization reactions.Due to the double bond present, acrylic acid and hexadecyl ester can participate in polymerization. It can polymerize with itself (homopolymerization) or with other monomers (copolymerization).It can polymerize either with itself (homopolymerization), or with other monomers. Polymerization can be initiated by heat, light, or the use of initiators.Heat, light or initiators can initiate polymerization. The resulting polymers have applications in areas such as coatings, adhesives, and emulsions, taking advantage of the properties imparted by the long - chain alkyl group and the reactive acrylic acid - derived backbone.The polymers are used in coatings, adhesives and emulsions. They take advantage of the properties that the long-chain alkyl group, and the reactive backbone derived from acrylic acid, impart.
Is acrylic acid, hexadecyl ester harmful to the environment?
Acrylic acid, hexadecyl ester may have certain impacts on the environment.The environmental impact of acrylic acid, hexadecyl ester is unknown.
In the aquatic environment, when acrylic acid, hexadecyl ester enters water bodies, it can potentially affect aquatic organisms.Acrylic acid, hexadecyl ester can affect aquatic organisms when it enters water bodies. While its exact toxicity levels can vary, it may pose risks to fish, invertebrates, and other aquatic life.Its exact toxicity can vary. However, it may pose a risk to fish, invertebrates and other aquatic life. Some esters can be relatively persistent in water, meaning they do not break down quickly.Some esters are relatively persistent in water. This persistence could lead to bioaccumulation in the bodies of aquatic organisms over time.This persistence can lead to bioaccumulation over time in aquatic organisms. As organisms lower in the food chain consume or are exposed to the ester, it can then work its way up the food chain, potentially causing more significant impacts at higher trophic levels.As organisms at the bottom of the food chain consume the ester or are exposed to it, the ester can work its way upwards in the food web, potentially causing greater impacts at higher trophic level.
In soil, the presence of acrylic acid, hexadecyl ester can influence soil microorganisms.The presence of hexadecyl ester and acrylic acid in soil can influence soil microorganisms. These microorganisms play a crucial role in soil fertility, decomposition of organic matter, and nutrient cycling.These microorganisms are crucial to soil fertility, organic matter decomposition, and nutrient cycles. If the ester is toxic to these microorganisms, it could disrupt these important ecological processes.If the ester is toxic for these microorganisms it could disrupt important ecological processes. For example, it might inhibit the activity of bacteria and fungi that are responsible for breaking down plant residues, which in turn could affect the release of nutrients back into the soil.It could, for example, inhibit the activity or bacteria and fungi responsible for the breakdown of plant residues. This, in turn, could affect the release nutrients back into soil.
In the atmosphere, if acrylic acid, hexadecyl ester is volatilized, it could potentially contribute to air pollution.If acrylic acid, hexadecyl ester is volatilized in the atmosphere, it could contribute to air pollution. Although it may not be as well - known as some common air pollutants like particulate matter or sulfur dioxide, it could still have implications for air quality.It may not be as well-known as some other common air pollutants, such as particulate matter and sulfur dioxide, but it can still have an impact on air quality. Once in the atmosphere, it may react with other chemicals, such as those involved in the formation of smog.Once in the air, it can react with other chemicals that are involved in smog formation. Additionally, inhalation of the vapor by humans and animals in the vicinity of its release could also be a concern, not only from a direct health perspective but also in terms of the overall ecological balance in the area.Inhalation of the vapor in the vicinity by humans and animals could also pose a threat, not only in terms of health, but also the ecological balance of the area.
Overall, while more research may be needed to fully understand the extent of its environmental harm, acrylic acid, hexadecyl ester has the potential to cause negative impacts on various environmental compartments, highlighting the importance of proper handling, storage, and disposal to minimize its release into the environment.While more research is needed to fully understand its environmental impact, acrylic acid, Hexadecyl Ester, has the potential to have negative impacts on different environmental compartments. This highlights the importance of proper storage, handling, and disposal in order to minimize its release into environment.
What safety precautions should be taken when handling acrylic acid, hexadecyl ester?
Acrylic acid, hexadecyl ester is a chemical compound that requires certain safety precautions during handling.Acrylic acid, hexadecyl ester is a chemical compound which requires certain safety precautions when handling.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate protective clothing, such as long - sleeved chemical - resistant suits.Wear protective clothing such as chemical-resistant suits with long sleeves. This helps prevent skin contact with the chemical, as direct contact can cause skin irritation, redness, and potential allergic reactions.This will help prevent skin contact, which can cause irritation, redness and allergic reactions. Additionally, use chemical - resistant gloves made of materials like nitrile.Use chemical-resistant gloves made from materials such as nitrile. These gloves provide a barrier between the hands and the acrylic acid, hexadecyl ester, reducing the risk of absorption through the skin.These gloves act as a barrier to reduce the risk of skin absorption. For eye protection, safety goggles or a face shield should be worn at all times.Safety goggles or face shields should be worn at any time for eye protection. Splashes of the chemical into the eyes can lead to serious eye damage, including corneal abrasions and vision impairment.Splashes of the chemical can cause serious eye damage including corneal abrasions, vision impairment and even death.
Ventilation is crucial.Ventilation is essential. Ensure that the handling area is well - ventilated.Make sure that the area where you are handling is well-ventilated. This can be achieved through natural ventilation, like opening windows and doors, or by using mechanical ventilation systems such as exhaust fans.You can achieve this by opening windows and doors or using mechanical ventilation systems, such as exhaust fans. Good ventilation helps to remove any vapors of acrylic acid, hexadecyl ester that may be released into the air.Good ventilation will help remove any vapors that may have been released into the air. Inhalation of these vapors can irritate the respiratory tract, causing coughing, shortness of breath, and in severe cases, may affect lung function.Inhaling these vapors may cause irritation of the respiratory tract. This can lead to coughing, shortness in breath, and, in severe cases, lung damage.
When storing acrylic acid, hexadecyl ester, keep it in a cool, dry place away from sources of heat and ignition.Store acrylic acid, hexadecyl ester in a cool and dry place, away from heat sources and ignition. It is flammable, so any potential ignition sources like open flames, sparks from electrical equipment, or hot surfaces should be avoided.It is flammable so avoid any ignition sources such as open flames, sparks or hot surfaces. Store it in a properly labeled container that is tightly sealed to prevent leakage.Store it in a container that is clearly labeled and tightly sealed to avoid leakage. In case of a spill, have a spill - control plan in place.Prepare a spill-control plan. Use absorbent materials like sand or vermiculite to soak up the spilled chemical.To soak up spilled chemicals, use absorbent materials such as sand or Vermiculite. Then, carefully collect the contaminated absorbent and dispose of it according to local environmental regulations.Then, carefully remove the contaminated absorbent from the spilled chemical and dispose of it in accordance with local environmental regulations.
During handling operations, avoid creating dust or aerosols.Avoid creating aerosols or dust during handling operations. When transferring the chemical from one container to another, do it slowly and carefully to prevent splashing.Transferring the chemical from one container into another should be done slowly and carefully in order to avoid splashing. Also, ensure that all equipment used for handling, such as funnels and pumps, is in good working condition and compatible with acrylic acid, hexadecyl ester.As well, make sure that all handling equipment, such as pumps and funnels, are in good condition and compatible with hexadecyl ester and acrylic acid. Finally, those handling the chemical should be trained on its properties, potential hazards, and the appropriate safety procedures to follow.Finaly, those handling the chemical must be trained in its properties, possible hazards, and safety procedures. This knowledge enables them to respond correctly in case of any unexpected situations, ensuring their own safety as well as the safety of those in the surrounding area.This knowledge allows them to react correctly in case of an unexpected situation, ensuring both their safety and the safety of others in the area.