.
Product Name | Acrylic acid-hydroxypropyl acrylate polymer |
Cas Number | 100985-85-3 |
Formula | (C6H10O3)n |
Molar Mass | varies with n |
Density | 1.1 g/cm3 |
Glass Transition Temperature | approx. 20-30°C |
Refractive Index | 1.48-1.50 |
Solubility | soluble in water |
Appearance | clear to hazy viscous liquid |
Viscosity | depends on molecular weight |
Thermal Stability | stable under normal conditions |
Surface Tension | 35 to 50 mN/m |
Odor | mild |
Flammability | non-flammable |
Biodegradability | biodegradable |
What are the main applications of acrylic acid-hydroxypropyl acrylate polymer?
Acrylic acid-hydroxypropyl acrylate polymer has several main applications:The main applications of acrylic acid-hydroxypropylacrylate polymer include:
In the field of coatings, this polymer is widely used.This polymer is widely used in the field of coatings. It can improve the performance of coatings.It can improve coating performance. For example, it enhances the adhesion of the coating to various substrates, ensuring that the coating adheres firmly and does not easily peel off.It can improve the adhesion between the coating and the substrate, ensuring the coating adheres strongly and doesn't easily peel off. In architectural coatings, it helps to create a more durable and weather - resistant finish.It helps create a more durable, weather-resistant finish in architectural coatings. The polymer can also adjust the film - forming properties of the coating.The polymer can be used to adjust the coating's film-forming properties. It enables the coating to form a smooth, continuous film, which is beneficial for protecting the underlying surface from corrosion, abrasion, and environmental damage.It allows the coating to form an even, continuous film that protects the underlying surface against corrosion, abrasion and environmental damage. In industrial coatings, its use can improve the hardness and chemical resistance of the coating, making it suitable for applications in harsh environments.In industrial coatings it can increase the hardness and chemical resistant of the coating making it suitable for harsh environments.
In the area of adhesives, acrylic acid - hydroxypropyl acrylate polymer plays an important role.Acrylic acid-hydroxypropyl Acrylate Polymer plays a major role in the adhesives field. It provides good bonding strength.It has a good bonding strength. It can bond different materials such as plastics, metals, and papers effectively.It can bond materials like plastics, metals and papers. The polymer can be formulated into pressure - sensitive adhesives, which are used in products like tapes.The polymer can also be made into pressure-sensitive adhesives that are used in tapes and other products. These adhesives can adhere immediately upon contact and can be easily removed without leaving residue in some cases.These adhesives adhere instantly upon contact and are easily removed without leaving residue. In structural adhesives, its properties contribute to strong and long - lasting bonds, ensuring the integrity of the bonded components in various applications, from automotive manufacturing to electronics assembly.In structural adhesives its properties ensure strong and long-lasting bonds. This is important for a variety of applications, including automotive manufacturing and electronics assembly.
In the realm of water - treatment, this polymer has functions.This polymer is useful in the field of water treatment. It can act as a dispersant.It can be used as a dispersant. It helps to disperse suspended particles in water, preventing them from aggregating and settling.It disperses suspended particles in the water and prevents them from aggregating or settling. In industrial water systems, such as cooling towers and boilers, this helps to maintain the efficiency of the system by preventing scale formation.This helps maintain the efficiency of industrial water systems such as cooling towers or boilers by preventing the formation of scale. The polymer can also be used in wastewater treatment processes.The polymer is also used in wastewater treatment. It can assist in flocculation by interacting with pollutants in the water, making them easier to separate and remove from the water, thus improving the quality of the treated water.It can help in flocculation, by interacting with pollutants and making them easier to remove from water.
In the textile industry, acrylic acid - hydroxypropyl acrylate polymer is used for textile finishing.The textile industry uses acrylic acid-hydroxypropylacrylate polymer for textile finishing. It can improve the handfeel of fabrics, making them softer and more comfortable to wear.It can improve fabrics' handfeel, making them more comfortable to wear. Additionally, it can enhance the color fastness of dyed fabrics.It can also improve the colorfastness of dyed fabric. By forming a thin film on the fabric surface, it helps to lock in the dyes, reducing color fading during washing and sunlight exposure.It helps lock in dyes by forming a thin layer on the fabric surface. This reduces color fading when exposed to sunlight and washing. It can also provide some degree of wrinkle - resistance to the fabrics, making the textile products more presentable and easier to care for.It can also provide a degree of wrinkle-resistance to the fabrics. This makes the textile products easier to maintain and more attractive.
What are the advantages of using acrylic acid-hydroxypropyl acrylate polymer?
The acrylic acid - hydroxypropyl acrylate polymer offers several notable advantages.The acrylic acid-hydroxypropylacrylate polymer has several notable benefits.
One of the key benefits is its excellent water - solubility.Its excellent water-solubility is one of its key benefits. This property makes it highly suitable for applications in aqueous systems.This property makes it ideal for use in aqueous system. For instance, in the formulation of water - based paints and coatings, the polymer can be easily dispersed in water.The polymer can easily dissolve in water, for example, when forming water-based paints and coats. This not only makes the manufacturing process more environmentally friendly as it reduces the use of volatile organic solvents but also enables better handling and application.This makes the manufacturing process environmentally friendly, as it reduces volatile organic solvents. It also allows for better handling and application. When applied, the water - soluble nature allows for easy clean - up of equipment, which is a significant advantage in industrial settings.The water-soluble nature of the product allows for easy cleaning up of equipment in industrial settings.
The polymer also exhibits good film - forming properties.The polymer has good film-forming properties. It can form continuous and uniform films upon drying.It can form uniform and continuous films after drying. In the case of coatings, these films provide protection to the substrate.These films protect the substrate in the case of coatings. They can act as a barrier against moisture, oxygen, and other potentially harmful substances.They can act as a protective barrier against moisture, oxygen and other potentially harmful substances. For example, when used to coat metal surfaces, the film formed by the acrylic acid - hydroxypropyl acrylate polymer helps prevent corrosion by preventing the contact of the metal with water and oxygen in the air.When used to coat metal surfaces the film formed by acrylic acid-hydroxypropylacrylate polymer helps to prevent corrosion by preventing metal contact with oxygen and water in the air.
Another advantage lies in its ability to be cross - linked.Cross-linking is another advantage. Cross - linking can enhance the mechanical properties of the polymer.Cross-linking can improve the mechanical properties of polymers. Once cross - linked, the polymer becomes more rigid and has improved resistance to abrasion and chemicals.Once cross-linked, the polymer becomes rigider and more resistant to chemicals and abrasion. This makes it useful in applications where durability is crucial, such as in the production of industrial floor coatings or automotive finishes.This makes it ideal for applications that require durability, such as industrial floor coatings and automotive finishes. The cross - linking can be achieved through various methods, such as thermal or chemical means, providing flexibility in the manufacturing process.Cross-linking can be achieved by various methods such as chemical or thermal means, allowing flexibility in the manufacturing process.
In addition, the polymer shows good adhesion to a wide range of substrates.The polymer also adheres well to a variety of substrates. Whether it is applied to wood, plastic, or metal, it can adhere strongly.It can adhere to metal, wood, or plastic. This adhesion property is beneficial in many industries.This adhesion is useful in many industries. In the packaging industry, for example, it can be used as an adhesive layer in laminates, ensuring that different materials stick together firmly.It can be used in the packaging industry as an adhesive layer to ensure that different materials adhere firmly together. In the textile industry, it can be used to treat fabrics to improve the adhesion of dyes or finishes, resulting in more color - fast and durable products.In the textile industry it can be used as a treatment to improve the adhesion to dyes or finishes. This results in more durable and color-fast products.
Furthermore, the acrylic acid - hydroxypropyl acrylate polymer has good thermal stability.The polymer acrylic acid-hydroxypropylacrylate is also thermally stable. It can withstand a certain range of temperatures without significant degradation.It can withstand temperatures up to a certain point without any significant degradation. This makes it suitable for applications where the material may be exposed to heat, such as in some industrial drying processes or in applications in hot environments.It is therefore suitable for applications that may expose the material to heat. For example, in industrial drying processes and in applications in hot environments. Overall, these combined advantages make the acrylic acid - hydroxypropyl acrylate polymer a versatile and valuable material in numerous industries.These combined advantages make acrylic acid-hydroxypropylacrylate polymer an extremely versatile and valuable material for many industries.
How is acrylic acid-hydroxypropyl acrylate polymer produced?
The production of acrylic acid - hydroxypropyl acrylate polymer typically involves a polymerization process.A polymerization is usually required to produce acrylic acid-hydroxypropylacrylate polymer. Here is a general overview of how it is produced.Here is an overview of the production process.
1. Monomer PreparationMonomer Preparation
First, the monomers acrylic acid and hydroxypropyl acrylate need to be prepared.First, monomers acrylic acid (acid) and hydroxypropyl-acrylate (acrylate) must be prepared. Acrylic acid can be produced through several methods, commonly by the oxidation of propylene or by the hydrolysis of acrylonitrile.Acrylic acid can be made in several ways, most commonly by oxidizing propylene or hydrolyzing acrylonitrile. Hydroxypropyl acrylate is usually synthesized by the reaction of acrylic acid with propylene oxide in the presence of a catalyst.Hydroxypropyl Acrylate is typically synthesized through the reaction of acrylic with propylene oxide, in the presence a catalyst.
2. Polymerization Reaction2.
The polymerization reaction is often carried out in a solution, emulsion, or suspension system.Polymerization reactions are often carried out using a suspension, emulsion or solution system. A common method is solution polymerization.Solution polymerization is a common method. In solution polymerization, the monomers are dissolved in an appropriate solvent such as an organic solvent like toluene or xylene, or sometimes water in the case of water - soluble polymers.In solution polymerization the monomers are dissolved into an appropriate solvent, such as toluene, xylene or water, in the case water-soluble polymers.
A polymerization initiator is added to start the reaction.To start the reaction, a polymerization initiator must be added. Initiators can be thermal initiators, like azo - compounds (such as azobisisobutyronitrile - AIBN) which decompose upon heating to generate free radicals. These free radicals react with the double - bonds of the acrylic acid and hydroxypropyl acrylate monomers, causing them to link together.These free radicals react to the double-bonds of the acrylic acid monomers and hydroxypropylacrylate monomers causing them link together.
For example, the free radical from the initiator attacks the double - bond of acrylic acid, forming a new radical on the monomer unit.The free radical of the initiator, for example, attacks the double-bond of acrylic acid and forms a new radical in the monomer unit. This radical then reacts with a hydroxypropyl acrylate monomer, and the chain - growth continues.This radical then reacts to a hydroxypropyl-acrylate monomer and the chain – growth continues. The reaction conditions, including temperature, pressure, and monomer concentration, are carefully controlled.Temperature, pressure and monomer concentration are all carefully controlled. The temperature is usually set to a range where the initiator decomposes at an appropriate rate to promote polymerization without causing side - reactions.The temperature is set at a level where the initiator decomposes in a way that promotes polymerization, but without causing side-reactions. For most free - radical polymerizations, the temperature might be in the range of 60 - 120degC.The temperature range for most polymerizations involving free radicals is 60-120degC.
3. Polymer Chain TerminationPolymer Chain Termination
As the polymerization proceeds, the polymer chains grow.As polymerization progresses, the polymer chain grows. Eventually, the reaction needs to be terminated.The reaction must be stopped eventually. This can occur through different mechanisms.Different mechanisms can be used to achieve this. One common way is combination termination, where two growing polymer chains with radical ends react with each other, combining to form a single non - radical polymer molecule.Combination termination is a common method, whereby two growing polymer chain with radical ends react together, combining into a single non-radical polymer molecule. Another is disproportionation termination, where a hydrogen atom is transferred from one growing chain to another, resulting in one saturated and one unsaturated polymer chain.Another way is disproportionation, where an atom of hydrogen is transferred from one chain to another. This results in one saturated polymer chain and one unsaturated.
4. Product Isolation and PurificationProduct Isolation & Purification
After the polymerization reaction is complete, the polymer product needs to be isolated.The polymer product must be isolated after the polymerization has been completed. In solution polymerization, if the solvent is volatile, the polymer can be isolated by evaporating the solvent under reduced pressure.If the solvent is volatile in solution polymerization then the polymer can easily be isolated by evaporating it under reduced pressure. If the polymer is in an emulsion or suspension, methods such as coagulation, filtration, or centrifugation can be used to separate the polymer from the dispersion medium.If the polymer in an emulsion, suspension, or a solution is volatile, you can isolate the polymer by evaporating the solvent under reduced pressure.
The isolated polymer may then be purified to remove any unreacted monomers, initiator residues, or other impurities.Purification of the isolated polymer is then possible to remove any unreacted initiator residues or other impurities. Purification can involve processes like washing with solvents, precipitation in a non - solvent, or dialysis in the case of water - soluble polymers.Purification may involve washing with solvents or precipitation in non-solvents. For water-soluble polymers, dialysis is an option. This final purified product is the acrylic acid - hydroxypropyl acrylate polymer ready for various applications such as in coatings, adhesives, and water - treatment agents.This final purified polymer is the acrylic acid-hydroxypropyl-acrylate polymer, ready for various applications, such as coatings, adhesives and water-treatment agents.
What are the safety precautions when handling acrylic acid-hydroxypropyl acrylate polymer?
When handling acrylic acid - hydroxypropyl acrylate polymer, several safety precautions should be observed.Safety precautions must be observed when handling acrylic acid-hydroxypropylacrylate polymer.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain degree of protection against the potential contact of the polymer with the skin.Nitrile gloves can offer a degree of protection from the polymer coming into contact with the skin. Skin contact can cause irritation, and some individuals may be allergic to the components of the polymer.Skin contact can cause irritation and some people may be allergic to polymer components. Additionally, put on safety goggles.Wear safety goggles. The polymer might splash during handling, and getting it into the eyes can lead to serious eye damage, including irritation, redness, and in severe cases, loss of vision.If the polymer splashes, it can cause serious eye damage. It can cause irritation, redness and, in severe cases, even loss of vision. A lab coat or other protective clothing should also be worn to prevent the polymer from soiling regular clothes and coming into contact with a large area of the body.Wearing a lab coat or other protective clothing will prevent the polymer from contaminating regular clothes and contacting a large part of the body.
Second, ensure proper ventilation. Work in a well - ventilated area, preferably in a fume hood if possible.Work in an area that is well-ventilated, preferably under a fume hood. Acrylic acid - hydroxypropyl acrylate polymers may emit volatile organic compounds (VOCs) during handling.When handled, acrylic acid-hydroxypropylacrylate polymers can emit volatile organic substances (VOCs). These emissions can be harmful if inhaled over time.These emissions are harmful if inhaled for a long time. Inhalation of these substances can cause respiratory problems such as coughing, shortness of breath, and may also irritate the nasal passages and throat.Inhaling these substances can cause respiratory issues such as coughing and shortness of breathe. They may also irritate nasal passages and the throat. Good ventilation helps to dilute the concentration of these potentially harmful vapors in the air.A good ventilation system can help to reduce the concentration of these potentially dangerous vapors.
Third, be cautious during storage.Third, take care when storing the polymer. Store the polymer in a cool, dry place away from sources of heat and ignition.Store the polymer away from heat and ignition sources in a cool, drier place. Some polymers can be flammable under certain conditions, especially if they come into contact with an open flame or a high - temperature source.Certain polymers are flammable in certain conditions, particularly if they are exposed to an open flame or high temperature. Keep the storage area clean and free from other chemicals that could potentially react with the polymer.Store the polymer in a clean, dry area that is free of other chemicals which could react with it. Also, make sure the containers are tightly sealed to prevent leakage and evaporation.Make sure that the containers are tightly closed to prevent leaking and evaporation.
Fourth, in case of accidental exposure.Fourth, in the event of accidental exposure. If the polymer comes into contact with the skin, immediately wash the affected area with plenty of water for at least 15 minutes.If the polymer gets in contact with your skin, wash it immediately with plenty of water and for at least 15 min. If irritation persists, seek medical attention. In the event of eye contact, flush the eyes with copious amounts of water for an extended period, preferably while keeping the eyelids open, and then seek immediate medical help.If you have eye contact, flush your eyes with a large amount of water, preferably with the eyelids still open, for a long period of time. Then, seek immediate medical attention. If inhaled, move to fresh air immediately.If inhaled, get to fresh air as soon as possible. If breathing difficulties occur, medical assistance should be obtained promptly.Immediately seek medical attention if breathing difficulties occur. And in case of ingestion, do not induce vomiting unless specifically directed by a medical professional, and seek emergency medical care right away.In the event of ingestion, you should not induce vomiting without a doctor's specific direction. Seek emergency medical attention immediately.
What are the storage requirements for acrylic acid-hydroxypropyl acrylate polymer?
Acrylic acid - hydroxypropyl acrylate polymer has specific storage requirements to maintain its quality and performance.To maintain its quality, the hydroxypropyl-acrylate polymer acrylic acid must be stored in a specific way.
First, storage temperature is crucial.The temperature of the storage area is important. It should generally be stored in a cool environment.It should be stored in a cool, dry environment. High temperatures can accelerate chemical reactions within the polymer, leading to issues like premature polymerization or degradation.High temperatures can cause chemical reactions to accelerate within the polymer. This can lead to premature polymerization and degradation. A recommended temperature range is often between 5degC and 30degC.Temperatures between 5degC to 30degC are usually recommended. Temperatures above this range, especially in hot storage areas or during summer months without proper climate control, can cause the polymer to thicken, gel, or lose its desired physical and chemical properties.Temperatures higher than this range, particularly in hot storage areas, or during summer without proper climate control can cause the polymer gel or thicken. On the other hand, extremely low temperatures, below 5degC, may cause the polymer to freeze.A polymer can freeze at temperatures below 5degC. Freezing can disrupt the molecular structure of the polymer, and upon thawing, it may not regain its original consistency and performance.Freezing can cause the polymer to lose its molecular structure.
Second, the storage location should be dry.Second, the storage area should be dry. Acrylic acid - hydroxypropyl acrylate polymers are sensitive to moisture.Moisture is a problem for acrylic acid-hydroxypropylacrylate polymers. Exposure to high humidity or water can initiate hydrolysis reactions.Hydrolysis can be triggered by high humidity or water. Hydrolysis can break down the polymer chains, reducing its molecular weight and affecting its functionality.Hydrolysis can reduce the molecular weight of polymers and affect their functionality. For example, in applications where the polymer is used as a thickener or a binder, hydrolysis can lead to a significant decrease in its thickening or binding ability.Hydrolysis can reduce the ability of a polymer to thicken or bind, for example, when it is used in thickening or binder applications. Storage areas should be well - ventilated to prevent the buildup of moisture, and the containers should be tightly sealed to avoid any ingress of water vapor.Storage areas must be well-ventilated to prevent moisture buildup, and containers should be tightly closed to prevent water vapor from entering.
Third, protection from light is also necessary.Third, protection against light is also required. Ultraviolet (UV) light can trigger photochemical reactions in the polymer.UV light can trigger photochemical reaction in the polymer. These reactions can lead to oxidation, cross - linking, or chain scission.These reactions can result in oxidation, chain scission, or cross-linking. Oxidation can change the color of the polymer, making it yellowish or darker, and also affect its chemical properties.Oxidation changes the color of polymers, making them yellowish or darker. It can also affect their chemical properties. Cross - linking under UV light can cause the polymer to become more rigid and less soluble, while chain scission can result in a decrease in molecular weight and a loss of performance characteristics.Cross-linking under UV light may cause the polymer become less soluble and more rigid, while chain scission could result in a reduction in molecular mass and a loss in performance characteristics. Therefore, the polymer should be stored in opaque containers or in areas where it is shielded from direct sunlight and strong artificial light sources.The polymer should therefore be stored in opaque containers, or in areas that are shielded from strong artificial light and direct sunlight.
Finally, proper container selection is important.It is also important to choose the right container. The container should be made of a material that is compatible with the acrylic acid - hydroxypropyl acrylate polymer.The container should be made from a material compatible with the polymer acrylic acid-hydroxypropylacrylate. Materials like high - density polyethylene (HDPE) or stainless steel are often suitable as they do not react with the polymer.High-density polyethylene (HDPE), stainless steel, or other materials that do not react with polymer are often suitable. Avoid using containers made of materials that may leach substances into the polymer or react with it, such as some types of plastics that may contain plasticizers which could potentially interact with the polymer and alter its properties.Avoid containers made from materials that could react or leach substances in the polymer, such as certain types of plastics.