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Product Name | Acrylic acid hydroxypropyl ester |
Cas Number | 25584-83-2 |
Formula | C6H10O3 |
Molar Mass | 130.14 |
Density | 1.049 g/cm³ |
Boiling Point | 120-122 °C |
Melting Point | -60.5 °C |
Refractive Index | 1.432 |
Flash Point | 110 °C |
Solubility In Water | soluble |
Viscosity | 4.8 mPa·s |
Vapor Pressure | 0.5 mmHg at 20°C |
Appearance | clear liquid |
Odor | mild odor |
What are the main applications of acrylic acid hydroxypropyl ester?
Acrylic acid hydroxypropyl ester has several important applications across various industries.The acrylic acid hydroxypropyl ester has many important applications in various industries.
In the coatings industry, it plays a crucial role.It is a vital component in the coatings industry. It can be used to modify the properties of coatings.It can be used for coatings to modify their properties. For instance, when incorporated into water - based coatings, it enhances the adhesion of the coating to different substrates.When incorporated into water-based coatings, for example, it increases the adhesion between the coating and different substrates. This is beneficial as it ensures that the coating adheres well to materials like metals, plastics, and woods, providing long - lasting protection.This is advantageous as it ensures the coating adheres to materials such as metals, woods and plastics. The presence of the hydroxypropyl group also contributes to the film - forming ability of the coating.The hydroxypropyl group is also important for the coating's ability to form a film. It helps in the formation of a smooth and continuous film, improving the overall appearance and performance of the coating.It improves the appearance and performance of coatings by forming a smooth, continuous film. Additionally, it can increase the hardness and abrasion resistance of the coating, making it more suitable for applications where the coated surface is likely to experience mechanical stress.It can also increase the hardness of the coating and its resistance to abrasion, making it better suited for applications that are likely to put the surface under mechanical stress.
The adhesives industry also makes good use of acrylic acid hydroxypropyl ester.The adhesives industry makes good use of the acrylic acid hydroxypropyl ester. It is used as a monomer in the synthesis of pressure - sensitive adhesives.It is used in the synthesis pressure-sensitive adhesives. These adhesives are widely used in applications such as label - making, tape production, and medical adhesives.These adhesives are used widely in applications like label-making, tape production, or medical adhesives. The properties imparted by acrylic acid hydroxypropyl ester, such as good tack and peel strength, are essential for these applications.These applications require properties such as good tack, peel strength and acrylic acid hydroxypropyl ester. In medical adhesives, for example, it needs to adhere well to the skin but also be easily removable without causing damage.In medical adhesives for example, the ester must adhere well to skin, but also be easily removed without causing any damage. The ester can also be used to improve the heat - resistance and aging - resistance of adhesives, ensuring their long - term performance.Ester can be used to improve heat resistance and age resistance of adhesives. This will ensure their long-term performance.
In the field of textiles, acrylic acid hydroxypropyl ester is used for textile finishing.Acrylic acid hydroxypropyl ester is used in textile finishing. It can be used to impart functional properties to fabrics.It can be used to give fabrics functional properties. For example, it can be used to create water - repellent or soil - resistant finishes.It can be used, for example, to create finishes that are water-repellent or soil-resistant. By reacting with the fabric fibers, it forms a thin layer that repels water and dirt, making the fabric more durable and easier to clean.It forms a thin film that repels dirt and water by reacting with fabric fibers. This makes the fabric more durable. Moreover, it can also be used to improve the dye - uptake of fabrics.It can also be used to enhance the dye-uptake of fabrics. The hydroxypropyl group can interact with dyes, allowing for better absorption and fixation of dyes on the fabric, resulting in more vibrant and color - fast textiles.The hydroxypropyl groups can interact with dyes to allow for better absorption and fixing of dyes onto the fabric. This results in vibrant and color-fast textiles.
In the area of polymer synthesis, acrylic acid hydroxypropyl ester is an important monomer.Acrylic acid hydroxypropyl ester is an important monomer in the field of polymer synthesis. It can be copolymerized with other monomers to produce polymers with tailored properties.It can be copolymerized to produce polymers that have tailored properties. For example, copolymerizing it with acrylamide can result in polymers with high water - absorbent properties, which are useful in products like disposable diapers and agricultural water - retaining agents.Copolymerizing with acrylamide, for example, can result in polymers that have high water-absorbing properties. These polymers are useful in products such as disposable diapers and agricultural agents. The resulting polymers can absorb and retain large amounts of water, providing practical solutions in different fields.The polymers produced can absorb and retain large quantities of water. They are useful in many different fields.
What are the properties of acrylic acid hydroxypropyl ester?
Acrylic acid hydroxypropyl ester has several notable properties.The hydroxypropyl esters of acrylic acid and acrylic acid have several notable properties.
Firstly, in terms of physical properties, it is typically a clear, colorless liquid.It is a clear liquid with no color. It has a relatively low viscosity, which allows for easy handling and processing in various industrial applications.It is relatively low in viscosity which makes it easy to handle and process for various industrial applications. This low - viscosity characteristic enables it to flow smoothly, facilitating its incorporation into different formulations.Its low-viscosity allows it to flow easily, making it easy to incorporate into different formulations. For example, in coatings and adhesives production, its good fluidity ensures even distribution within the mixture.Its good fluidity is ideal for coatings and adhesives, where it ensures an even distribution of the mixture.
Secondly, it has excellent reactivity.It is also highly reactive. The acrylate double - bond in acrylic acid hydroxypropyl ester is highly reactive, making it a valuable monomer for polymerization reactions.The acrylate double-bond in acrylic acid hydroxypropyl ester is highly reactive and makes it a valuable polymerization monomer. It can readily participate in radical polymerization processes.It is a good candidate for radical polymerization. This property is crucial in the synthesis of polymers with diverse structures and properties.This property is essential in the synthesis and characterization of polymers. For instance, it can be copolymerized with other monomers like styrene or methyl methacrylate to create polymers with tailored characteristics such as improved hardness, flexibility, or chemical resistance.It can be copolymerized, for example, with other monomers such as styrene and methyl methacrylate, to create polymers that have tailored characteristics, such as improved hardness or flexibility or chemical resistance.
The presence of the hydroxypropyl group also imparts unique properties.The presence of hydroxypropyl groups also confers unique properties. Hydroxypropyl groups provide the ester with the ability to form hydrogen bonds.The hydrogen bonding ability of the ester is due to the hydroxypropyl groups. This can enhance the compatibility of acrylic acid hydroxypropyl ester with other polar substances, including water - soluble polymers or certain solvents.This can improve the compatibility between acrylic acid hydroxypropyl ester and other polar substances such as water-soluble polymers or solvents. In addition, it can improve the adhesion of polymers made from this monomer to substrates that have polar surfaces, such as metals and glass.It can also improve the adhesion between polymers made with this monomer and substrates that have polar surface, such as metals or glass. This is beneficial in the production of adhesives where strong adhesion is required.This is useful in the production and use of adhesives that require strong adhesion.
Thermally, polymers derived from acrylic acid hydroxypropyl ester often exhibit good thermal stability.Polymers derived from the acrylic acid hydroxypropyl ester often have good thermal stability. They can withstand a certain range of temperatures without significant degradation, which is important for applications where the material may be exposed to elevated temperatures, like in automotive coatings or some industrial parts.They can withstand certain temperatures without degradation, which is useful for applications that may be exposed to high temperatures, such as automotive coatings and industrial parts.
Furthermore, acrylic acid hydroxypropyl ester - based polymers generally show good chemical resistance.Acrylic acid hydroxypropyl ester - based Polymers are generally resistant to chemicals. They can resist the attack of many common chemicals, such as acids, bases, and organic solvents to a certain extent.They can resist many common chemicals such as acids and bases, organic solvents, and organic solvents. This makes them suitable for use in environments where exposure to chemicals is likely, for example, in chemical storage containers or protective coatings in industrial settings.They are therefore suitable for environments where chemicals may be present, such as in chemical storage containers and protective coatings for industrial settings.
How is acrylic acid hydroxypropyl ester synthesized?
The synthesis of acrylic acid hydroxypropyl ester mainly involves the reaction between acrylic acid and propylene oxide.The reaction between acrylic and propylene oxide is the main step in the synthesis of acrylic hydroxypropyl ester. Here is a general description of the synthesis process:Here is a description of the general synthesis process.
Reaction principle
The reaction between acrylic acid and propylene oxide is an addition reaction.The reaction between propylene oxide and acrylic acid is an addition reaction. In the presence of a catalyst, the double - bond of acrylic acid and the strained epoxide ring of propylene oxide react to form acrylic acid hydroxypropyl ester.The double-bond of acrylic acid and strained epoxide rings of propylene dioxide react in the presence of a catalyser to form acrylic acid's hydroxypropyl ester. The reaction equation can be simply written as: CH2=CH - COOH + C3H6O - CH2=CH - COOCH2CH(OH)CH3The equation for the reaction can be written as follows: CH2=CH-COOH + C3H6O- CH2=CH-COOCH2CH(OH).CH3
Reaction conditions and stepsReaction conditions & Steps
1. Raw material preparationRaw material preparation
High - purity acrylic acid and propylene oxide are required as raw materials.Raw materials are acrylic acid and propylene dioxide of high purity. Acrylic acid may need to be refined to remove impurities such as water and inhibitors.Acrylic acid may have to be refined in order to remove impurities like water and inhibitors. Propylene oxide should also meet certain purity standards to ensure the smooth progress of the reaction.Propylene oxide must also meet certain standards of purity to ensure a smooth reaction.
2. Catalyst selection2.
Commonly used catalysts for this reaction include alkaline catalysts such as potassium hydroxide or sodium hydroxide, and some organic metal salts.Catalysts commonly used for this reaction are alkaline catalysts, such as potassium or sodium hydroxide and organic metal salts. The catalyst can effectively promote the opening of the epoxide ring of propylene oxide and its addition to acrylic acid.The catalyst can promote the opening of the propylene oxide epoxide and its addition to the acrylic acid. The amount of catalyst used usually needs to be optimized according to the reaction scale and specific requirements, generally accounting for a certain percentage of the total mass of the reactants, such as 0.1% - 1%.The amount of catalyst to be used is usually optimized according to the scale of the reaction and the specific requirements. It generally accounts for a certain percent of the total mass reactants such as 0.1%-1%.
3. Reaction processReaction process
The reaction is usually carried out in a reaction vessel equipped with a stirrer, thermometer, and reflux device.The reaction is carried out in a reaction container equipped with a thermometer, stirrer and reflux device. First, put a certain amount of acrylic acid into the reaction vessel, and then add the catalyst under stirring.Add the catalyst to the reaction vessel after adding a certain amount acrylic acid. After that, propylene oxide is slowly added drop - by - drop to the reaction system while maintaining a certain reaction temperature.Propylene oxide will then be added to the reaction system drop-by-drop while maintaining a specific reaction temperature. The reaction temperature is usually controlled in the range of 60 - 100 degC.The reaction temperature is typically controlled between 60 and 100 degC. If the temperature is too low, the reaction rate will be slow; if it is too high, side reactions such as polymerization of acrylic acid may occur.If the temperature is low, the rate of reaction will be slow. If it is high, side reactions, such as the polymerization or acrylic acid, may occur. During the reaction, continuous stirring helps to ensure uniform mixing of the reactants and promote the reaction.During the reaction, constant stirring is important to ensure that the reactants are mixed uniformly and to promote the reaction.
4. Product separation and purificationSeparation and purification of products
After the reaction is completed, the reaction mixture contains the target product acrylic acid hydroxypropyl ester, unreacted raw materials, and catalyst.The reaction mixture will contain the acrylic acid hydroxypropyl ester, unreacted raw material, and catalyst. First, the catalyst can be neutralized with an appropriate amount of acid.The catalyst can first be neutralized by adding an appropriate amount acid. Then, through processes such as distillation, unreacted acrylic acid and propylene oxide can be recovered from the mixture.Through processes such as distillation it is possible to recover unreacted acrylic acids and propylene dioxide from the mixture. The remaining product is further purified by vacuum distillation or other purification methods to obtain high - purity acrylic acid hydroxypropyl ester.The remaining product can be purified further by vacuum distillation, or other purification techniques to obtain high-purity acrylic acid hydroxypropyl esters.
What are the safety precautions when using acrylic acid hydroxypropyl ester?
Acrylic acid hydroxypropyl ester is a chemical compound with certain reactivity and potential hazards.Acrylic acid hydroxypropyl ester is a chemical compound that has a certain level of reactivity. It also poses some potential hazards. Here are some safety precautions when using it.Here are some safety measures to take when using it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain degree of protection against the contact of acrylic acid hydroxypropyl ester with the skin.Nitrile gloves can offer some protection against the skin's contact with acrylic acid hydroxypropyl esters. Prolonged skin contact may cause irritation, redness, and even chemical burns.Prolonged skin contact can cause irritation, redness and even chemical burns. Also, wear safety goggles to protect the eyes.Wear safety goggles as well to protect your eyes. In case of accidental splashing, the eyes are extremely vulnerable, and any contact with this substance can lead to serious eye damage, such as corneal abrasions or chemical conjunctivitis.If the eye is accidentally splashed, it can be extremely vulnerable. Contact with this substance may cause serious eye damage such as corneal injuries or chemical conjunctivitis. A lab coat or other protective clothing should be worn to prevent the chemical from getting on regular clothes, which can not only protect the body but also prevent potential spread of the chemical.Wearing a lab coat or other protective clothing can help prevent the chemical from contaminating regular clothes. This will not only protect your body, but also prevent the spread of the chemical.
Second, pay attention to the working environment.Pay attention to the workplace environment. Ensure good ventilation in the workplace.Assure that the workplace is well ventilated. Acrylic acid hydroxypropyl ester may emit vapors, and in a poorly ventilated space, these vapors can accumulate, increasing the risk of inhalation.Acrylic acid hydroxypropyl ester can emit vapors. In a poorly ventilated area, these vapors may accumulate, increasing the risks of inhalation. Inhalation of its vapors can irritate the respiratory tract, causing symptoms like coughing, shortness of breath, and in severe cases, it may affect the lungs and other respiratory organs.Inhaling its vapors may cause irritation of the respiratory tract and symptoms such as coughing and shortness of breathe. In severe cases, the lungs and respiratory organs may be affected. If possible, use local exhaust ventilation systems near the work area where the chemical is being used to effectively remove the vapors.To remove the vapors, if possible, install local exhaust ventilation near the area where the chemical will be used.
Third, when handling the chemical.Third, be careful when handling the chemical. Avoid any sources of ignition.Avoid all sources of ignition. Acrylic acid hydroxypropyl ester is flammable.The acrylic acid hydroxypropyl ester is flammable. Keep it away from open flames, hot surfaces, and any potential ignition sources such as electrical sparks.Keep it away form open flames, hot surface, and any ignition sources, such as electrical sparks. During storage, store it in a cool, dry place, away from direct sunlight and heat.Store it in a cool and dry place away from heat and direct sunlight. Also, ensure that the storage containers are tightly sealed to prevent leakage and evaporation.Ensure that the storage containers have a tight seal to prevent leaking and evaporation. When transferring the chemical, use proper transfer equipment and follow standard operating procedures to avoid spills.To avoid spills, use the proper equipment to transfer the chemical and follow standard operating procedures. In case of a spill, immediately take appropriate clean - up measures.If a spill occurs, take immediate action to clean it up. Small spills can be absorbed with inert absorbent materials like vermiculite or sand, and then properly disposed of according to local regulations.Small spills can easily be absorbed by inert absorbents like vermiculite, sand or other absorbent materials. Then dispose of them according to local regulations. For large spills, evacuate the area, call for professional emergency response teams, and follow their instructions.For large spills you should evacuate the area and call professional emergency response teams. Follow their instructions.
Finally, be familiar with the first - aid measures.Be familiar with the first-aid measures. In case of skin contact, immediately rinse the affected area with plenty of water for at least 15 minutes and then seek medical attention.If you have skin contact, rinse the area thoroughly with water for at least fifteen minutes. Then seek medical attention. For eye contact, flush the eyes with copious amounts of water for at least 15 minutes, lifting the eyelids occasionally to ensure thorough rinsing, and then see a doctor as soon as possible.If you have eye contact, rinse your eyes for at least 15 mins with plenty of water, lifting the eyelids periodically to ensure thorough rinsing. Then, see a doctor immediately. If inhaled, move the victim to fresh air immediately.If the victim has inhaled, they should be moved to fresh air as soon as possible. If the victim is not breathing, perform CPR if trained, and call for emergency medical services promptly.If the victim does not breathe, perform CPR, if you are trained, and contact emergency medical services immediately.
What are the storage requirements for acrylic acid hydroxypropyl ester?
Acrylic acid hydroxypropyl ester has specific storage requirements to ensure its quality and safety.To ensure the safety and quality of acrylic acid hydroxypropyl ester, it is important to store it in a specific way.
Firstly, it should be stored in a cool place.It should be kept in a cool, dry place. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. If the temperature is too high, the acrylic acid hydroxypropyl ester may start to polymerize prematurely, changing its physical and chemical properties and rendering it unusable for its intended applications.If the temperature is high enough, the acrylic acid-hydroxypropyl ester may begin to polymerize too early, changing its chemical and physical properties, and making it unusable for the intended applications. A storage temperature in the range of around 5 - 25 degrees Celsius is often recommended.It is usually recommended to store the acrylic acid hydroxypropyl ester between 5 and 25 degrees Celsius.
Secondly, it must be stored in a well - ventilated area.Second, it should be stored in an area that is well-ventilated. This is because acrylic acid hydroxypropyl ester may release vapors.This is because the acrylic acid hydroxypropyl ester may release vapors. Good ventilation helps to prevent the accumulation of these vapors.This is because the vapors can be accumulated if there is not enough ventilation. In a poorly ventilated space, the concentration of vapors could reach dangerous levels, posing risks such as explosion or inhalation hazards to workers in the storage area.In a poorly ventilated area, the concentration of these vapors can reach dangerous levels. This could pose risks to workers, such as explosions or inhalation hazards.
Thirdly, storage containers should be tightly sealed.Thirdly, containers should be tightly closed. Exposure to air can lead to oxidation reactions.Air exposure can cause oxidation reactions. Oxygen in the air can react with the acrylic acid hydroxypropyl ester, potentially degrading its quality.The acrylic acid hydroxypropyl ester can be degraded by the oxygen in the air. Additionally, moisture in the air can also cause hydrolysis reactions.Hydrolysis can also be caused by moisture in the atmosphere. Hydrolysis can break down the ester bonds in acrylic acid hydroxypropyl ester, altering its chemical structure and functionality.Hydrolysis can alter the chemical structure and functionality of acrylic acid hydroxypropyl ester by breaking down ester bonds.
Fourthly, the storage area should be away from sources of ignition.Fourthly, the storage area must be far from ignition sources. Acrylic acid hydroxypropyl ester is flammable.The acrylic acid hydroxypropyl ester is flammable. Even a small spark from an electrical device, a lit cigarette, or other ignition sources can cause a fire or explosion due to the flammable nature of this chemical.This chemical is flammable. Even a small spark, such as from an electric device, a lit cigar, or another ignition source, can cause a fire.
Finally, it is crucial to store acrylic acid hydroxypropyl ester away from incompatible substances.It is important to store acrylic acid and hydroxypropyl ester away from incompatible substances. It should not be stored near strong oxidizing agents, bases, or acids.It should not be kept near acids, bases or strong oxidizing agents. Oxidizing agents can react violently with it, while bases and acids can catalyze hydrolysis or other unwanted chemical reactions, which can damage the product and pose safety risks.Oxidizing agents may react violently, while bases and acid can catalyze unwanted chemical reactions that can damage the product or pose safety risks.
In conclusion, proper storage of acrylic acid hydroxypropyl ester is essential for maintaining its integrity, preventing safety hazards, and ensuring its usability in various industrial processes.In conclusion, it is important to store acrylic acid hydroxypropyl ester properly in order to maintain its integrity, prevent safety hazards, as well as ensure its usability in different industrial processes.