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Acrylic Acid Methyl Ester


Properties
Product Name Methyl Acrylate
Cas Number 96-33-3
Formula C4H6O2
Molar Mass 86.09 g/mol
Physical State Liquid
Color Colorless
Odor Pungent
Density 0.954 g/cm³
Boiling Point 80.5 °C
Melting Point -75 °C
Refractive Index 1.4117
Flash Point -3 °C
Vapor Pressure 57 mmHg at 20 °C
Solubility 6.5 g/100 mL in water
Viscosity 0.64 mPa·s at 25 °C
Autoignition Temperature 385 °C
FAQ

What are the main applications of acrylic acid methyl ester?

Acrylic acid methyl ester, also known as methyl acrylate, has several important applications.Acrylic acid methyl ester, also known by the name methyl acrylate has many important applications.
One of the major application areas is in the production of polymers and copolymers.It is used to create acrylic resins. It is used to create acrylic resins.Acrylic resins are made from it. These resins are widely used in coatings.These resins are widely utilized in coatings. For instance, in the automotive industry, acrylic resin - based coatings are applied to cars.In the automotive industry, for example, acrylic resin-based coatings are used on cars. They offer excellent weather resistance, high gloss, and good adhesion to the vehicle's surface, protecting it from environmental factors like sunlight, rain, and corrosion.They provide excellent weather resistance, a high gloss and good adhesion, protecting the vehicle from environmental factors such as sunlight, rain and corrosion. In the construction industry, these coatings are used on buildings for a similar purpose, providing long - lasting protection and an aesthetically pleasing finish.These coatings are also used in the construction industry to provide long-lasting protection and a beautiful finish.

Another significant use is in the production of adhesives.Adhesives are another important application. Acrylic acid methyl ester is a key monomer in formulating pressure - sensitive adhesives.The acrylic acid methyl ester monomer is used to formulate pressure-sensitive adhesives. These adhesives are used in a wide range of products such as tapes, labels, and stickers.These adhesives can be found in many products, including tapes, stickers, and labels. They have the ability to stick to various surfaces upon the application of light pressure and can be easily removed without leaving much residue.They can stick to a variety of surfaces with a light touch and can be removed easily without leaving any residue. For example, the adhesive on a postage stamp or a price tag on consumer goods is often based on acrylic - based pressure - sensitive adhesives.The adhesive used on a stamp or price tag is often acrylic-based pressure-sensitive adhesive.

In the textile industry, acrylic acid methyl ester is used to modify the properties of fabrics.Acrylic acid methyl ester is used in the textile industry to modify fabric properties. By copolymerizing with other monomers, it can be incorporated into textile fibers.It can be incorporated in textile fibers by copolymerizing it with other monomers. This can enhance the fabric's dyeability, making it easier to achieve vivid and long - lasting colors.It can improve the fabric's dyeability and make it easier to achieve vibrant, long-lasting colors. It can also improve the fabric's wrinkle - resistance, allowing clothes to maintain their shape better during wearing and laundering.It can also improve fabric wrinkle resistance, which allows clothes to keep their shape during wear and washing.

The production of plastics also benefits from acrylic acid methyl ester.Acrylic acid methyl ester is also useful in the production of plastics. It can be used to manufacture specialty plastics with unique properties.It can be used to produce specialty plastics that have unique properties. For example, some acrylic - based plastics have high transparency, similar to glass, but are much lighter and more impact - resistant.Some acrylic-based plastics, for example, have a high transparency similar to glass but are lighter and more impact-resistant. These plastics are used in applications such as optical lenses, display screens, and protective covers for electronic devices.These plastics can be used for optical lenses, display screen, and protective covers of electronic devices.

Furthermore, in the field of leather finishing, acrylic acid methyl ester - based polymers are used.In the field of leather finishing polymers based on acrylic acid methyl ester are also used. They can improve the appearance of leather, making it more shiny and smooth.They can enhance the appearance of leather by making it more lustrous and smooth. At the same time, they enhance the leather's durability, protecting it from abrasion and moisture.They also increase the leather's durability by protecting it from abrasions and moisture.

In summary, acrylic acid methyl ester plays a crucial role in multiple industries, from coatings and adhesives to textiles, plastics, and leather finishing, contributing to the production of high - quality products with improved performance characteristics.Acrylic acid methyl ester is used in many industries. It can be found in coatings and adhesives, textiles, plastics and leather finishing. It contributes to the production of products with high-quality and improved performance.

How is acrylic acid methyl ester produced?

Acrylic acid methyl ester, also known as methyl acrylate, can be produced through several methods.The methyl ester of acrylic acid, also known by the name methyl acrylate can be made in several ways. One common approach is the esterification of acrylic acid with methanol.Esterification of acrylic acids with methanol is a common method.
In the esterification process, acrylic acid and methanol react in the presence of a catalyst.In the esterification reaction, acrylic acid and the methanol react with a catalyst. Sulfuric acid is a frequently used catalyst for this reaction.Sulfuric acids are often used as catalysts for this reaction. The reaction equation is as follows: acrylic acid + methanol = methyl acrylate + water.The reaction equation is: acrylic acid +methanol = methylacrylate +water. This is a reversible reaction.This is a reversible chemical reaction. To drive the reaction forward and increase the yield of methyl acrylate, an excess of methanol is often used.A large amount of methanol can be used to accelerate the reaction and increase the yield. Also, the water produced during the reaction can be removed continuously, which helps shift the equilibrium towards the product side according to Le Chatelier's principle.The water produced by the reaction can also be continuously removed, which helps shift equilibrium to the product side, according to Le Chatelier’s principle.

Another method is the transesterification of another ester of acrylic acid with methanol.Transesterification with methanol of another ester is a second method. For example, ethyl acrylate can react with methanol in the presence of a suitable catalyst, such as a metal alkoxide.In the presence of an appropriate catalyst, such a metal alkoxide, ethylacrylate can react to methanol. The reaction exchanges the alkyl group, resulting in the formation of methyl acrylate and ethanol.The alkyl group is exchanged, resulting in methyl acrylate (and ethanol). This method can be advantageous in cases where the starting ester is more readily available or when the reaction conditions can be better controlled.This method is useful when the starting ester can be readily obtained or the reaction conditions are more controlled.

The production of methyl acrylate also involves purification steps.Purification is also part of the production process. After the reaction, the mixture contains unreacted starting materials, by - products, and the desired methyl acrylate.After the reaction, the mixture consists of unreacted materials, by-products, and the desired product, methyl acrylate. Distillation is a key purification technique.Distillation is an important purification technique. Methyl acrylate has a specific boiling point, and by carefully controlling the temperature and pressure in the distillation column, it can be separated from other components.Methyl Acrylate has a very specific boiling point. By carefully controlling the temperature in the column and the pressure, it can be separated. Unreacted acrylic acid and methanol can be recycled back into the reaction system to improve the overall efficiency of the process.The unreacted acrylic acids and methanols can be recycled into the reaction system, improving the overall efficiency.

In industrial settings, safety precautions are of great importance.Safety precautions are very important in industrial settings. Methyl acrylate is a flammable and reactive compound.Methylacrylate is a reactive and flammable compound. Appropriate measures need to be taken to prevent fire and explosion hazards.To prevent fire and explosion hazards, it is necessary to take the appropriate measures. Also, proper handling of the chemicals involved, especially the catalyst like sulfuric acid, is crucial to ensure the safety of workers and the smooth operation of the production process.It is also important to ensure worker safety and smooth production by handling the chemicals properly, especially the sulfuric acid catalyst.

What are the safety precautions when handling acrylic acid methyl ester?

Acrylic acid methyl ester is a potentially hazardous chemical, and the following safety precautions should be taken when handling it.The acrylic acid methyl ester is a potentially dangerous chemical. Safety precautions must be taken when handling this product.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Workers must wear appropriate chemical - resistant goggles to protect their eyes from possible splashes.To protect their eyes, workers must wear chemical-resistant goggles. A full - face shield can be used in cases where there is a higher risk of splashing.In cases where the risk of splashing is higher, a full-face shield can be used. Additionally, chemical - resistant gloves made of materials like neoprene or nitrile should be worn to prevent skin contact.To prevent skin contact, it is recommended that chemical-resistant gloves made from materials such as neoprene and nitrile are worn. The gloves need to be regularly inspected for any signs of damage.Regularly inspect the gloves for signs of damage. A chemical - resistant apron should also be worn to protect the body from spills.Wearing a chemical-resistant apron will protect your body from spills.

Second, proper ventilation is crucial.Second, ventilation is essential. Acrylic acid methyl ester is volatile, and its vapors can be harmful if inhaled.The vapors of acrylic acid methyl ester are volatile and can be harmful to inhale. Handling should be carried out in a well - ventilated area, preferably in a fume hood.Handling should take place in an area that is well-ventilated, preferably under a fume hood. If working in an open area, ensure there is sufficient cross - ventilation to disperse the vapors.If you are working in an area that is not well ventilated, make sure there is enough cross-ventilation to disperse vapors. Monitoring of the air quality in the working environment for the presence of acrylic acid methyl ester vapors is also necessary.It is important to monitor the air quality of the workplace for the presence or absence of acrylic acid methyl esters vapors.

Third, storage precautions are important.Third, it is important to take precautions when storing the product. It should be stored in a cool, dry, and well - ventilated place, away from heat sources, open flames, and oxidizing agents.Store it in a cool and dry place that is well-ventilated, away from heat sources and open flames. The storage containers must be tightly sealed to prevent leakage and evaporation.Storage containers must be tightly closed to prevent evaporation and leakage. The containers should be made of materials compatible with acrylic acid methyl ester, such as stainless steel or certain types of plastics.The containers must be made from materials compatible with acrylic methyl ester such as stainless steel and certain types of plastics.

Fourth, in case of spills.Fourth, in the event of spills. In the event of a spill, immediately evacuate the non - essential personnel from the area.In the event of spills, evacuate all non-essential personnel from the affected area. Wear appropriate personal protective equipment before starting the clean - up.Wear the appropriate personal protective gear before cleaning up. Use absorbent materials like vermiculite, sand, or activated carbon to soak up the spilled liquid.To soak up spilled liquid, use absorbent materials such as vermiculite or activated charcoal. The absorbed material should then be placed in a proper waste container for disposal according to local environmental regulations.The absorbed material can then be placed into a suitable waste container to dispose of it according to local environmental regulations.

Finally, emergency response knowledge is essential.It is also important to have a good understanding of emergency response procedures. Workers should be trained in first - aid procedures in case of contact with acrylic acid methyl ester.Workers should be trained on first-aid procedures in the event of contact with acrylic methyl ester. For skin contact, immediately wash the affected area with plenty of water for at least 15 minutes and seek medical attention.If skin contact occurs, wash the affected area immediately with plenty of water and seek medical attention. In case of eye contact, flush the eyes with copious amounts of water for at least 15 minutes and consult a doctor.If you have eye contact, wash your eyes with plenty of water for 15 minutes. Consult a doctor. If inhaled, move the person to fresh air and get medical help promptly.If inhaled move the person outside and seek medical attention immediately.

What are the physical and chemical properties of acrylic acid methyl ester?

Acrylic acid methyl ester, also known as methyl acrylate, has the following physical and chemical properties:Acrylic acid methyl ester, also known by the name methyl acrylate has the following physical-chemical properties:
Physical properties:Physical Properties
1. Appearance: It is a colorless, transparent liquid.Appearance: It's a transparent, colorless liquid. This clear appearance allows for easy visual inspection in various applications.This clear appearance makes it easy to inspect in different applications.
2. Odor: It has a pungent, fruity odor.It has a pungent and fruity smell. The fruity aspect of the odor might seem somewhat pleasant at first, but the pungency indicates its potentially irritating nature.The fruity aspect might initially seem pleasant, but its pungency indicates that it could be irritating.
3. Boiling point: The boiling point of methyl acrylate is around 80 - 81 degC.Boiling Point: The boiling point for methyl acrylate is between 80 and 81 degrees Celsius. This relatively low boiling point means it can be vaporized at moderately high temperatures, which is useful in processes that involve distillation or vapor - phase reactions.This low boiling point allows it to be vaporized even at moderately high temperature, which is helpful in processes involving distillation or vapor-phase reactions.
4. Melting point: Its melting point is approximately -75 degC.Melting point: The melting point of this material is approximately -75 degrees Celsius. This low melting point keeps it in a liquid state under normal ambient conditions, facilitating its handling in most industrial settings.This low melting temperature keeps it liquid under normal ambient conditions. This makes it easier to handle in most industrial settings.
5. Density: It has a density of about 0.956 g/cm3 at 20 degC.Density: The density is approximately 0.956g/cm3 when the temperature is 20 degC. The density is relevant for determining the amount of methyl acrylate in a given volume, which is crucial in formulating mixtures and calculating reaction stoichiometries.The density is important for determining how much methyl acrylate is in a volume. This is crucial when formulating mixtures or calculating reaction stoichiometries.
6. Solubility: Methyl acrylate is slightly soluble in water but highly soluble in common organic solvents such as ethanol, ether, and chloroform.Methyl Acrylate is soluble only in water, but highly soluble with common organic solvents like ethanol, chloroform, and ether. This solubility behavior makes it suitable for use in organic - based reaction systems and formulations.This solubility makes it ideal for use in organic-based reaction systems and formulations.

Chemical properties:Chemical properties
1. Reactivity: It is highly reactive due to the presence of the carbon - carbon double bond and the ester functional group.Reactivity: Due to the presence the double carbon-carbon bond and the ester group, it is highly reactive. The double bond can undergo addition reactions, such as polymerization.The double bond is susceptible to addition reactions such as polymerization. Methyl acrylate is commonly used in the production of acrylic polymers.In the production of acrylics, methyl acrylate is a common ingredient. For example, through free - radical polymerization, it can form poly(methyl acrylate), which has applications in coatings, adhesives, and textiles.Through free-radical polymerization it can be converted into poly(methyl acrylate), a material that is used in textiles, coatings, and adhesives.
2. Hydrolysis: In the presence of water and an appropriate catalyst (such as an acid or a base), methyl acrylate can undergo hydrolysis.Hydrolysis: In presence of water, and a suitable catalyst (such an acid or base), methylacrylate can undergo a hydrolysis. The ester bond is cleaved, resulting in the formation of acrylic acid and methanol.The ester bond is broken, resulting in acrylic acid and methanol. This reaction is important in understanding the environmental fate of methyl acrylate as well as in some chemical processes where the breakdown of the ester is desired.This reaction is crucial in understanding the environmental fate methyl acrylate, as well as some chemical processes that require the breakdown of the esters.
3. Oxidation: It can be oxidized under certain conditions.Oxidation is possible under certain conditions. Oxidation can occur with strong oxidizing agents, which may lead to the formation of more oxidized products, potentially altering its chemical structure and properties.Oxidation may occur when strong oxidizing agents are used. This can lead to more oxidized products and alter the chemical structure of the product.
4. Polymerization reactivity: As mentioned, the double bond in methyl acrylate is highly reactive towards polymerization.As previously mentioned, the double-bond in methylacrylate is highly reactive towards polymerization. It can copolymerize with other monomers, such as styrene or acrylamide, to produce copolymers with a wide range of properties, expanding its utility in different industries.It can copolymerize, for example, with other monomers such as styrene and acrylamide to produce copolymers that have a variety of properties. This increases its utility in various industries.

Is acrylic acid methyl ester harmful to the environment?

Acrylic acid methyl ester can be harmful to the environment.Acrylic acid methyl ester can be harmful to environment.
In the aquatic environment, it poses risks.It poses risks in the aquatic environment. When it enters water bodies, it can be toxic to aquatic organisms.It can be toxic for aquatic organisms when it enters waterbodies. Fish, for example, may experience various adverse effects.Fish, for instance, may experience adverse effects. Exposure to acrylic acid methyl ester can disrupt their normal physiological functions, such as affecting their respiratory systems, which could lead to difficulties in obtaining oxygen.Acrylic acid methyl ester exposure can disrupt normal physiological functions. For example, it could affect their respiratory systems and cause them to have difficulty obtaining oxygen. It might also interfere with the nervous systems of aquatic invertebrates like daphnia, altering their behavior, including their ability to swim, feed, and reproduce.It could also affect the nervous systems of aquatic animals like daphnia. This can alter their behavior and their ability to feed, reproduce, and swim. This can have a cascading effect on the entire aquatic ecosystem.This can have a cascading impact on the entire aquatic eco-system. If the population of certain invertebrates declines due to the toxicity of acrylic acid methyl ester, it can disrupt the food chain, affecting species that rely on these invertebrates as a food source.If the population of invertebrates decreases due to the toxic effects of acrylic acid methyl ester, it can disrupt food chains, affecting species who rely on invertebrates for food.

In the atmosphere, acrylic acid methyl ester can contribute to air pollution.Acrylic acid methyl ester can contribute to air pollutants in the atmosphere. It is volatile, meaning it can easily evaporate into the air.It is volatile and can easily evaporate into the air. Once in the atmosphere, it can participate in chemical reactions.Once in the air, it can take part in chemical reactions. It may react with other pollutants, such as nitrogen oxides and sunlight, to form ground - level ozone.It can react with other pollutants such as sunlight and nitrogen oxides to form ground-level ozone. Ground - level ozone is a harmful air pollutant that can cause respiratory problems in humans and animals, as well as damage plants.Ground-level ozone can cause respiratory problems for humans and animals. It can also damage plants. It can reduce the photosynthetic capacity of plants, affecting their growth and productivity.It can reduce the photosynthetic ability of plants, affecting growth and productivity. Additionally, the release of acrylic acid methyl ester into the air can contribute to the formation of smog, which not only reduces visibility but also has negative impacts on the overall air quality in urban and industrial areas.The release of acrylic acid, methyl ester, into the air may also contribute to the formation smog. This can have negative effects on the air quality of urban and industrial areas.

When it comes to soil, if acrylic acid methyl ester contaminates the soil, it can potentially affect soil microorganisms.If acrylic acid methyl ester is contaminating soil, this can affect soil microorganisms. These microorganisms play crucial roles in processes like decomposition of organic matter, nutrient cycling, and soil structure formation.These microorganisms are crucial in processes such as decomposition of organic material, nutrient cycle, and soil formation. The presence of acrylic acid methyl ester may inhibit the growth and activity of these microorganisms.Acrylic acid methyl ester may inhibit the growth of these microorganisms. For instance, it could slow down the decomposition of plant residues, which would then affect the release of nutrients back into the soil.It could, for example, slow down the decomposition process of plant residues. This would then affect the release nutrients back into soil. This, in turn, can impact plant growth as plants rely on these nutrients for their development.This can then impact on plant growth, as plants rely heavily on these nutrients to grow.

Overall, acrylic acid methyl ester has the potential to cause significant harm to different components of the environment, highlighting the importance of proper handling, storage, and disposal to minimize its environmental impact.Overall, acrylic acid-methyl ester can cause significant harm to the environment. Proper handling, storage and disposal are essential to minimize the impact.