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Product Name | Acrylic acid n-propyl ester |
Cas Number | 999-61-1 |
Formula | C6H10O2 |
Molar Mass | 114.14 |
Boiling Point | 141-143°C |
Density | 0.898 g/cm³ |
Refractive Index | 1.415 |
Flash Point | 41°C |
Solubility | Slightly soluble in water |
Vapor Pressure | 5 mmHg (at 20°C) |
Viscosity | 0.7 mPa·s (at 20°C) |
Autoignition Temperature | 315°C |
Melting Point | <-60°C |
Appearance | Colorless liquid |
Odor | Fruity |
What are the main applications of acrylic acid n-propyl ester?
Acrylic acid n - propyl ester has several main applications:Acrylic acid n-propyl ester is used in a variety of applications.
1. Coatings Industry
In the coatings field, acrylic acid n - propyl ester is used to create high - performance coatings.Acrylic acid n-propyl ester can be used to make high-performance coatings. It can be copolymerized with other monomers to form polymers with excellent film - forming properties.It can be copolymerized to create polymers that have excellent film-forming properties. These coatings have good weather resistance, which means they can withstand long - term exposure to sunlight, rain, and temperature changes without significant degradation.These coatings are resistant to weather, meaning they can withstand exposure to sunlight, rain and temperature changes for a long time without degradation. For example, in automotive coatings, the use of polymers containing acrylic acid n - propyl ester can provide a durable and aesthetically pleasing finish.In automotive coatings, polymers containing acrylic n-propyl ester provide a durable, aesthetically pleasing finish. The ester group in the molecule contributes to the solubility of the polymer in organic solvents, enabling easy application of the coating.The ester group of the molecule helps the polymer dissolve in organic solvents and makes it easier to apply the coating. Additionally, it can improve the adhesion of the coating to various substrates, such as metal, wood, and plastic, ensuring that the coating adheres firmly and does not peel off easily.It can also improve the adhesion to different substrates such as wood, metal, and plastic. This ensures that the coating adheres strongly and doesn't peel off easily.
2. AdhesivesAdhesives
Acrylic acid n - propyl ester is an important raw material for producing adhesives.Acrylic acid n-propyl ester is a raw material used to make adhesives. Copolymers made from it can offer strong adhesion to different surfaces.Copolymers derived from it offer strong adhesion on different surfaces. Pressure - sensitive adhesives (PSAs) often incorporate acrylic acid n - propyl ester.Acrylic acid n-propyl ester is often used in pressure-sensitive adhesives (PSAs). These PSAs are used in a wide range of products, including tapes, labels, and stickers.These PSAs can be found in a variety of products including tapes and labels. The presence of the n - propyl ester group affects the rheological properties of the adhesive, making it have the right balance of stickiness and shear resistance.The presence of n-propyl ester affects the rheological characteristics of the adhesive. It gives it the right balance between stickiness and shear resistant. It allows the adhesive to stick quickly upon contact and yet maintain its hold under normal use conditions.The adhesive will adhere quickly to the surface and still hold its grip under normal conditions. In the packaging industry, adhesives based on acrylic acid n - propyl ester are used to seal cartons and bond different packaging materials together.In the packaging industry adhesives based upon acrylic acid n-propyl ester can be used to seal cartons or bond different packaging materials.
3. Textile Industry
In the textile industry, it is used for fabric finishing.In the textile industry it is used to finish fabrics. By applying polymers containing acrylic acid n - propyl ester to fabrics, the fabric can gain enhanced properties.Fabrics can be given enhanced properties by applying polymers that contain acrylic acid n-propyl ester. For instance, it can improve the wrinkle - resistance of the fabric.It can, for example, improve the fabric's wrinkle resistance. The polymer forms a thin film on the surface of the fabric fibers, which helps to keep the fabric in its original shape.The polymer forms an ultra-thin film on the fabric fibers that helps keep the fabric in the original shape. Moreover, it can also increase the fabric's resistance to staining.It can also increase fabric resistance to stains. The ester group can interact with the fabric fibers and the substances that cause stains, preventing them from adhering firmly to the fabric.The ester group interacts with the fibers of the fabric and substances that cause stains to prevent them from adhering strongly to the fabric. In addition, it can be used to impart softness to the fabric, making the textile products more comfortable to wear.It can also be used to give the fabric a softer feel, making textile products more comfortable.
4. Polymer ModificationPolymer Modification
Acrylic acid n - propyl ester can be used to modify other polymers.Acrylic acid n-propyl ester is used to modify polymers. When copolymerized with engineering plastics, it can improve the impact resistance of the plastics.Copolymerizing with engineering plastics can improve impact resistance. For example, blending it with polypropylene can enhance the toughness of polypropylene, making it more suitable for applications where it may be subject to mechanical stress.Blending it with polypropylene for example can increase the toughness of this material, making it better suited to applications that may be subjected to mechanical stress. In the field of elastomers, adding acrylic acid n - propyl ester can adjust the cross - linking density and improve the elasticity and aging resistance of the elastomer.In the case of elastomers adding acrylic acid n-propyl ester to the cross-linking density can improve the elasticity of the elastomer and its resistance to aging. This modification can extend the service life of the elastomer products and expand their application range.This modification can increase the service life and application range of elastomer materials.
How is acrylic acid n-propyl ester produced?
Acrylic acid n - propyl ester is typically produced through the esterification reaction of acrylic acid with n - propanol.Acrylic acid n-propyl ester can be produced by esterifying acrylic acid with n-propanol.
The reaction usually occurs in the presence of a catalyst.The reaction occurs most often in the presence a catalyst. Sulfuric acid is a commonly used catalyst for this esterification process.This esterification is commonly carried out with sulfuric acid. It helps to increase the reaction rate by providing a proton source that activates the carbonyl group of acrylic acid.It increases the reaction rate by activating the carbonyl group in acrylic acid. This activation makes the carboxylic acid more reactive towards the nucleophilic attack by the hydroxyl group of n - propanol.This activation makes carboxylic acid more receptive to the nucleophilic attack of the hydroxyl groups of n-propanol.
The reaction equation can be written as follows: acrylic acid (CH2=CH - COOH) reacts with n - propanol (CH3CH2CH2OH) in the presence of a catalyst to form acrylic acid n - propyl ester (CH2=CH - COOCH2CH2CH3) and water (H2O).The reaction equation is as follows: acrylic (CH2=CH-COOH) reacts in the presence a catalyst with n-propanol (CH3CH2CH2OH), forming acrylic acid n-propyl ester and water (H2O).
In a typical industrial setup, the reactants are carefully mixed in a reactor.In a typical industrial setting, the reactants are carefully blended in a reactor. The ratio of acrylic acid to n - propanol is adjusted according to the stoichiometry of the reaction, often with a slight excess of one reactant to drive the reaction towards the formation of the ester.The ratio of acrylic to n-propanol can be adjusted according to the stoichiometry, and often a small excess of one of the reactants is used to drive the reaction in the direction of ester formation. For example, an excess of n - propanol may be used to shift the equilibrium of the reversible esterification reaction towards the product side, following Le Chatelier's principle.Le Chatelier's theory suggests that an excess of n-propanol can be used to shift equilibrium in the reversible esterification reaction in favor of the product.
During the reaction, the temperature is carefully controlled.The temperature is carefully monitored during the reaction. Generally, the reaction is carried out at an elevated temperature, usually in the range of 80 - 120 degC.The reaction is usually carried out at a high temperature, typically between 80 and 120 degC. This temperature range is chosen to ensure a reasonable reaction rate while also minimizing side reactions.This temperature range was chosen to maintain a reasonable rate of reaction while minimizing side reactions. Higher temperatures might increase the rate of side reactions such as polymerization of acrylic acid, which is an unwanted outcome as it can reduce the yield of the desired acrylic acid n - propyl ester.Higher temperatures may increase the rate of unwanted side reactions, such as polymerization. This can reduce the yields of desired acrylic acid n-propyl ester.
After the reaction is complete, the reaction mixture contains the product (acrylic acid n - propyl ester), unreacted reactants, the catalyst, and water.The reaction mixture, after the reaction is completed, contains the product (acrylic n-propyl ester), the unreacted reactants and the catalyst. The mixture then undergoes a series of separation steps.The mixture is then separated by a series steps. First, the catalyst may be neutralized, for example, by adding a base if sulfuric acid was used as the catalyst.The catalyst can be neutralized by adding a base, for example if sulfuric acids was used as a catalyst. Then, distillation is commonly employed to separate the components.To separate the components, distillation is often used. Since acrylic acid n - propyl ester has a different boiling point compared to acrylic acid, n - propanol, and water, it can be separated from the mixture.Acrylic acid n-propyl ester is separated from the mixture because it has a higher boiling point than acrylic acid, water, and n-propanol. The unreacted reactants can be recycled back into the reactor for further production, improving the overall efficiency of the process.The unreacted reactants are able to be recycled into the reactor, increasing the efficiency of the entire process.
What are the safety precautions when handling acrylic acid n-propyl ester?
Acrylic acid n - propyl ester is a flammable and potentially hazardous chemical.Acrylic acid n-propyl ester can be a potentially hazardous chemical. Here are some safety precautions when handling it.Here are some safety measures to take when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant clothing, such as a full - body chemical - resistant suit, to prevent skin contact.Wear chemical-resistant clothing, such a a full-body chemical-resistant suit, to avoid skin contact. The skin can be easily irritated or damaged by acrylic acid n - propyl ester.Acrylic acid n-propyl ester can cause irritation or damage to the skin. Additionally, use chemical - resistant gloves.Use chemical-resistant gloves. Nitrile gloves are often a good choice as they can provide a certain degree of protection against this substance.Nitrile gloves can offer a degree of protection from this substance. For eye protection, safety goggles or a face shield should be worn at all times when handling the chemical to prevent splashes from getting into the eyes, which could cause serious eye injuries.Wear safety goggles, or a face shield, at all times while handling the chemical. This will prevent splashes getting into your eyes and causing serious eye injuries.
Second, regarding the handling environment.Second, the handling environment. Ensure good ventilation in the work area.Assure good ventilation around the work area. Since acrylic acid n - propyl ester is flammable and may give off harmful vapors, a well - ventilated space helps to disperse these vapors, reducing the risk of explosion and inhalation of toxic fumes.A well-ventilated area is important because acrylic acid n-propyl ester can be flammable and emit harmful vapors. This reduces the risk of explosions and inhalation. If possible, conduct operations in a fume hood to further isolate the chemical and protect the handler.If possible, use a fume-hood to protect the worker and further isolate the chemical. Avoid any open flames, sparks, or heat sources in the vicinity of the handling area.Avoid open flames, heat sources, or sparks in the area of the handling. Keep all ignition sources away because acrylic acid n - propyl ester has a relatively low flash point, making it highly flammable.Keep all ignition sources far away from acrylic acid n-propyl ester because it has a low flash point and is highly flammable.
Third, in the aspect of storage.Third, the aspect of storage. Store acrylic acid n - propyl ester in a cool, dry, and well - ventilated storage area.Store acrylic acid n-propyl ester in an area that is cool, dry and well-ventilated. It should be separated from oxidizing agents, acids, and bases as these substances can react with it violently.It should be kept away from oxidizing agents and acids as they can react violently with it. Use storage containers that are specifically designed for flammable and reactive chemicals.Store flammable and reactive chemical in containers designed specifically for them. These containers should be tightly sealed to prevent leakage.These containers must be tightly sealed to avoid leakage. Regularly check the storage containers for any signs of damage or leakage.Check the storage containers regularly for signs of damage or leaking. If a leak is detected, take immediate action to contain and clean it up in accordance with proper procedures.If you detect a leak, act immediately to contain it and clean it according to proper procedures.
Fourth, during the handling process.Fourth, during the handling procedure. When transferring the chemical, use proper transfer equipment to avoid spills.Use the right equipment when transferring the chemicals to avoid spills. If a spill occurs, do not touch it directly.Do not touch the spill directly. Evacuate the area immediately, and if it is a small spill, use absorbent materials such as sand or vermiculite to soak up the liquid.If it is a small liquid spill, use absorbent material such as sand, or vermiculite, to soak up the liquid. For larger spills, follow the emergency response plan of the workplace, which may involve notifying relevant safety personnel and using specialized spill - control equipment.Follow the emergency response plan for larger spills. This may include notifying the relevant safety personnel or using specialized spill-control equipment.
Finally, in case of contact.In the event of contact, you should seek medical attention. If the chemical comes into contact with the skin, immediately rinse the affected area with plenty of water for at least 15 minutes and then seek medical attention.If the chemical gets into contact with your skin, rinse the area thoroughly with water for at least fifteen minutes before seeking medical attention. If it gets into the eyes, rinse the eyes continuously with clean water for 15 - 20 minutes and then get immediate medical help.If it gets in the eyes, rinse them continuously with clean water between 15 and 20 minutes. Then seek immediate medical attention. In case of inhalation, move to fresh air immediately and, if breathing difficulties persist, seek medical assistance promptly.If you inhale the substance, get to fresh air as soon as possible. If breathing problems persist, contact a doctor immediately.
What are the physical and chemical properties of acrylic acid n-propyl ester?
Acrylic acid n - propyl ester is an important organic compound with the following physical and chemical properties:Acrylic acid n-propyl ester has the following physical and chemical characteristics:
Physical properties:
1. Appearance: It is usually a colorless liquid.Appearance: This liquid is usually colorless. This clear and colorless nature is common among many esters, allowing for easy visual inspection in industrial and laboratory settings.Many esters are clear and colorless, making them easy to inspect in industrial and lab settings.
2. Odor: It has a characteristic, pungent odor.It has a pungent, characteristic odor. The smell can be quite strong and is often described as sharp, which serves as an early warning sign of its presence in the environment.The smell is strong and sharp, which can serve as a warning of its presence.
3. Boiling point: The boiling point of acrylic acid n - propyl ester is around 122 - 123 degC.Boiling point of acrylic acid, n-propyl ester: The boiling point is approximately 122-123 degC. This relatively moderate boiling point makes it possible to separate it from other substances with significantly different boiling points through distillation processes.This relatively low boiling point allows it to be separated from substances with boiling points that are significantly different through distillation processes. For example, in a mixture with higher - boiling or lower - boiling compounds, distillation can be used to isolate acrylic acid n - propyl ester based on this property.This property can be used, for example, to separate acrylic acid n-propyl ester from a mixture of higher- or lower-boiling compounds.
4. Melting point: Its melting point is relatively low.Melting point: Its melt point is low. Precise values may vary slightly depending on purity, but generally, it is well below room temperature, ensuring that it remains in a liquid state under normal ambient conditions.The exact values may vary depending on purity but, in general, they are well below room temperatures, ensuring it remains liquid under normal ambient conditions.
5. Solubility: It is sparingly soluble in water.It is sparingly water soluble. This is because esters are relatively non - polar due to the presence of the ester functional group (-COO-), while water is a highly polar molecule.Esters are non-polar due to their ester functional group, (-COO), whereas water is a polar molecule. However, it is soluble in many organic solvents such as ethanol, ether, and chloroform.It is soluble in ethanol, chloroform, and ether. This solubility in organic solvents makes it useful in various chemical reactions and formulations where organic media are involved.Its solubility in organic solvants makes it useful for various chemical reactions and formulations that involve organic media.
Chemical properties:
1. Reactivity of the double bond: The most prominent chemical feature of acrylic acid n - propyl ester is the presence of a carbon - carbon double bond in the acrylic acid moiety.Reactivity of double bond: The presence of a double carbon-carbon bond in the acrylic moiety is the most prominent chemical characteristic of acrylic acid n-propyl ester. This double bond is highly reactive and can participate in addition reactions.This double bond can be highly reactive and participate in additional reactions. For instance, it can undergo polymerization reactions.It can, for example, undergo polymerization. In the presence of initiators, the double bonds of multiple acrylic acid n - propyl ester molecules can break and link together to form long - chain polymers.In the presence of initiators the double bonds between multiple acrylic acid n-propyl ester molecule can break and link to form long-chain polymers. These polymers find wide applications in the production of coatings, adhesives, and plastics.These polymers are widely used in the productions of plastics, adhesives and coatings.
2. Hydrolysis: Acrylic acid n - propyl ester can undergo hydrolysis in the presence of water and an acid or base catalyst.Acrylic acid n-propyl ester is hydrolyzed in the presence of acid or base catalysts and water. In acidic hydrolysis, the ester bond (-COO-) is broken, resulting in the formation of acrylic acid and n - propanol.In acidic hydrolysis the ester bond is broken (-COO) resulting in acrylic acid and n-propanol. In basic hydrolysis, the products are the carboxylate salt of acrylic acid and n - propanol.In basic hydrolysis the products are carboxylate salts of acrylic acid and N - propanol. This hydrolysis reaction is important in environmental degradation processes as well as in some chemical synthesis routes where the breakdown of the ester is desired.This hydrolysis reaction plays a key role in environmental degradation processes, as well as some chemical synthesis routes that require the breakdown of ester.
3. Ester - exchange reaction: It can participate in ester - exchange reactions.Ester-exchange reaction: It is capable of participating in ester-exchange reactions. When reacted with other alcohols in the presence of a catalyst, the n - propyl group can be replaced by another alkyl group, leading to the formation of different esters.In the presence of a catalyser, the n-propyl group of the alcohol can be replaced with another alkyl group to form different esters. This reaction is useful in the modification of esters to obtain products with specific properties for various applications such as in the synthesis of specialty chemicals and flavors.This reaction can be used to modify esters in order to obtain products that have specific properties, such as specialty chemicals or flavors.
Is acrylic acid n-propyl ester harmful to the environment?
Acrylic acid n - propyl ester can be harmful to the environment.Acrylic acid n-propyl ester is harmful to the environment.
In the aquatic environment, it has the potential to cause damage.It has the potential to cause harm in the aquatic environment. It may be toxic to fish, aquatic invertebrates, and other organisms that live in water.It can be toxic to aquatic invertebrates and fish. When it enters water bodies, it can disrupt the normal physiological functions of these organisms.It can disrupt the normal physiological function of these organisms when it enters waterbodies. For example, it might interfere with the respiratory systems of fish, making it difficult for them to take in oxygen, and could also affect the growth and reproduction of aquatic invertebrates like daphnia.It could, for example, interfere with the respiratory system of fish and make it difficult for them take in oxygen. It could also affect the reproduction and growth of aquatic invertebrates such as daphnia. This can lead to a decline in the populations of these organisms, which in turn can have a cascading effect on the entire aquatic ecosystem, disrupting food chains and ecological balance.This can cause a decline in these organisms' populations, which can then have a cascading impact on the entire aquatic eco-system, disrupting food chain and ecological balance.
In the atmosphere, if acrylic acid n - propyl ester is released as a vapor, it can participate in chemical reactions.If acrylic acid n-propyl ester is released into the atmosphere as a vapor it can participate chemical reactions. It may react with other pollutants and sunlight to form secondary pollutants such as ground - level ozone.It can react with other pollutants, sunlight and produce secondary pollutants like ground -level ozone. Ground - level ozone is harmful to plants, reducing their photosynthetic efficiency, which can slow down plant growth and productivity.Ground-level ozone can be harmful to plants by reducing their photosynthetic ability, which can slow plant growth and productivity. It can also cause damage to the leaves of plants, making them more susceptible to diseases.It can also damage the leaves of plants and make them more susceptible to disease.
In soil, the presence of acrylic acid n - propyl ester can impact soil microorganisms.The presence of acrylic acid, n-propyl ester in soil can have an impact on soil microorganisms. These microorganisms play crucial roles in processes like decomposition of organic matter, nutrient cycling, and soil structure formation.These microorganisms are crucial in processes such as decomposition of organic material, nutrient cycle, and soil formation. If their activities are inhibited by the presence of this chemical, it can lead to a decrease in soil fertility over time.This chemical can inhibit their activity, resulting in a decrease of soil fertility over time. This can then affect plant growth as plants rely on the proper functioning of soil microorganisms for nutrient uptake.This can affect plant growth, as plants rely upon the proper functioning soil microorganisms to absorb nutrients.
Overall, acrylic acid n - propyl ester has the potential to cause harm to different components of the environment, highlighting the importance of proper handling, storage, and disposal to minimize its release into the environment.Overall, acrylic n-propyl ester can cause harm to various components of the environmental, which highlights the importance of handling, storage, disposal, and minimizing its release into the atmosphere.