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Product Name | Acrylic acid, octyl ester |
Cas Number | 66017-44-1 |
Formula | C14H26O2 |
Molar Mass | 226.36 g/mol |
Physical State | Liquid |
Odor | Pungent |
Color | Colorless to pale yellow |
Boiling Point | 285-289°C |
Flash Point | 130°C |
Auto Ignition Temperature | 307°C |
Solubility | Insoluble in water, soluble in organic solvents |
Density | 0.879 g/cm3 |
Viscosity | 6.41 cP |
Refractive Index | 1.439 |
What are the main applications of acrylic acid octyl ester?
Acrylic acid octyl ester has several important applications.The acrylic acid octyl ester has many important applications.
In the field of coatings, it plays a significant role.It plays a major role in the field of coatings. It is used to modify the performance of coatings.It is used to modify coating performance. When incorporated into coating formulations, it can improve the flexibility of the coating film.It can be incorporated into the formulation of coatings to improve the flexibility. This is crucial for applications where the coated surface may experience bending or stretching, such as in the coating of flexible plastics or metal sheets used in some industrial products.This is important for applications in which the coated surface can be bent or stretched, such as the coating of flexible metal sheets or plastic sheets used in industrial products. Additionally, it enhances the adhesion of the coating to various substrates.It also improves the adhesion between the coating and various substrates. It helps the coating to better stick to materials like wood, metal, and plastic, ensuring long - lasting protection and a more aesthetically pleasing finish.It makes the coating adhere better to wood, metal and plastic. This ensures long-lasting protection and an aesthetically pleasing finish. For example, in automotive coatings, acrylic acid octyl ester can contribute to a more durable and scratch - resistant paint job.Acrylic acid octyl ester can be used in automotive paints to make them more durable and scratch-resistant.
In the production of adhesives, acrylic acid octyl ester is a key ingredient.Acrylic acid octyl ester is a key component in the production of adhesives. It helps to create adhesives with good peel strength.It is used to make adhesives that have good peel strength. These adhesives are suitable for applications where a strong bond is required, but also need to be easily removable in some cases, like in label adhesives.These adhesives can be used in applications that require a strong bond, but they also need to be removable in certain cases, such as label adhesives. The ester imparts flexibility to the adhesive matrix, enabling it to conform to different surfaces.The ester gives the adhesive matrix flexibility, allowing it to conform to various surfaces. This is beneficial for applications in the packaging industry, where adhesives need to bond well to different types of packaging materials, such as paper, cardboard, and plastic films.This is useful for packaging applications, where adhesives must adhere well to different types packaging materials such as cardboard, paper, and plastic film.
It is also used in the manufacture of polymers and copolymers.It is also used to manufacture polymers and copolymers. By copolymerizing acrylic acid octyl ester with other monomers, materials with tailored properties can be produced.Copolymerizing the acrylic acid octyl ester with other monomers can produce materials with tailored properties. For instance, when copolymerized with acrylic acid, it can result in polymers with a good balance of hydrophilic and hydrophobic properties.When copolymerized, for example, with acrylic acid, the polymers can have a good balance between hydrophilic and anti-hydrophilic properties. These copolymers can be used in applications such as water - based polymers for textile finishing.These copolymers are suitable for applications such as water-based polymers used in textile finishing. They can improve the softness, wrinkle - resistance, and water - repellency of fabrics.They can improve the softness of fabrics, their wrinkle resistance and water repellency.
In the area of emulsion polymerization, acrylic acid octyl ester is commonly used.Acrylic acid octyl ester is used in the area of polymerization of emulsions. The resulting emulsions can be used in a variety of applications, including the production of latex paints.The resulting emulsions are suitable for a wide range of applications, such as the production of latex. These paints offer advantages such as low - volatile organic compound (VOC) emissions, good color retention, and easy cleaning.These paints have many advantages, including low-volatile organic compound (VOC), good color retention and easy cleaning. The use of acrylic acid octyl ester in emulsion polymerization helps to control the particle size and morphology of the polymer particles, which in turn affects the performance of the final product.The use of acrylic acids octyl esters in emulsions polymerization helps control the particle size, morphology and performance of the final products.
Overall, acrylic acid octyl ester is a versatile chemical with wide - ranging applications across multiple industries, contributing to the development of high - performance materials and products.Overall, acrylic acid is a versatile chemical that has wide-ranging applications in multiple industries. It contributes to the development and production of high-performance materials and products.
How is acrylic acid octyl ester synthesized?
The synthesis of acrylic acid octyl ester mainly involves the esterification reaction between acrylic acid and octanol.The esterification reaction of acrylic acid with octanol is the main step in the synthesis of acrylic octyl ester. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
Reactants and CatalystsReactants & Catalysts
The main reactants are acrylic acid and octanol.The main reactants in esterification are acrylic acid and Octanol. To promote the esterification reaction, a catalyst is usually required.A catalyst is required to promote the esterification. Commonly used catalysts include sulfuric acid, p - toluenesulfonic acid, etc.Catalysts commonly used include sulfuric acid and p-toluenesulfonic acids. Sulfuric acid is a strong acid with high catalytic activity, but it may cause side - reactions such as dehydration and charring.Sulfuric is a strong acid that has high catalytic activity. However, it can cause side reactions such as dehydration or charring. P - toluenesulfonic acid is a relatively mild solid - state catalyst, which is easier to separate from the reaction system after the reaction.P - toluenesulfonic is a relatively mild solid-state catalyst that is easier to separate after the reaction.
Reaction Conditions
The reaction is usually carried out under heating conditions.The reaction is normally carried out in a heated environment. The reaction temperature is generally in the range of 100 - 140 degC.The reaction temperature ranges between 100 and 140 degC. At an appropriate temperature, the reaction rate can be increased, but too high a temperature may lead to the decomposition of reactants or products and the occurrence of side - reactions.The reaction rate can be increased at an appropriate temperature. However, too high a heat may cause the decomposition or the products, and side reactions. Since the esterification reaction is a reversible reaction, to shift the equilibrium to the product side, an excess of one of the reactants is often used.To shift the equilibrium from the reactant side to the product, it is common to use an excess of one of them. Usually, octanol is used in excess because it is relatively easier to separate from the product.It is common to use octanol in excess, as it is easier to separate the product from octanol. In addition, azeotropic distillation is often used during the reaction.Azeotropic distillation can also be used to speed up the reaction. By adding a water - entraining agent such as toluene, the water generated during the reaction can be continuously removed from the reaction system, which promotes the forward progress of the reaction.The water generated by the reaction can be removed continuously from the system using a water-entraining agent, such as toluene. This promotes the progress of the reactions.
Reaction Process
In a reaction flask equipped with a stirrer, thermometer, reflux condenser, and water - separating device, the appropriate amounts of acrylic acid, octanol, and catalyst are added.In a reaction flask with a thermometer, stirrer and water-separating device, acrylic acid, octanol and catalyst in the correct amounts are added. Then, the reaction system is heated to the set temperature under stirring.The reaction system is then heated to the temperature set under stirring. As the reaction proceeds, the water generated by the esterification reaction is removed by azeotropic distillation with the water - entraining agent.As the esterification reaction proceeds, water generated from the esterification is removed using azeotropic distillation with water - entraining agents. After the reaction is completed, the reaction mixture is cooled.After the reaction has been completed, the reaction mixture must be cooled. First, the catalyst is neutralized.The catalyst must first be neutralized. If sulfuric acid is used as the catalyst, an appropriate amount of sodium carbonate or sodium hydroxide solution can be used for neutralization.For neutralization, if sulfuric acid was used as a catalyst, a suitable amount of sodium hydroxide or sodium carbonate solution can be used. Then, the organic layer is separated, washed with water to remove the remaining salts and unreacted substances, and finally, the product acrylic acid octyl ester is obtained by distillation under reduced pressure to purify the product and remove the unreacted octanol and other impurities.The organic layer is then separated and washed in water to remove any remaining salts or unreacted substances. Finally, the acrylic acid octyl ester is obtained through distillation at reduced pressure.
What are the physical and chemical properties of acrylic acid octyl ester?
Physical properties of acrylic acid octyl ester:Physical properties of acrylic Acid Octyl Ester1. Appearance: It is usually a colorless to slightly yellowish clear liquid.Appearance: The liquid is usually clear and colorless, or slightly yellowish. This appearance makes it relatively easy to identify and handle in industrial and laboratory settings.This makes it easy to identify in industrial and lab settings.
2. Odor: It has a characteristic, somewhat pungent odor.Odor: It emits a pungent, characteristic smell. The distinct smell can be used as an initial indication of its presence, but it should be noted that the odor can be irritating to the respiratory system.The distinctive smell can be used to indicate its presence. However, it is important to note that the odor may be irritating to respiratory systems.
3. Solubility: Acrylic acid octyl ester is insoluble in water.Solubility: Acrylic Acid Octyl Ester is not soluble in water. This property is due to the long - chain octyl group, which is hydrophobic.This is due to the hydrophobic long-chain octyl groups. However, it is soluble in many organic solvents such as alcohols, ethers, and aromatic hydrocarbons.It is soluble in a wide range of organic solvents including alcohols, aromatic hydrocarbons, ethers and acetones. For example, it can dissolve well in toluene or ethyl acetate.It can dissolve in toluene and ethyl-acetate, for example. This solubility in organic solvents is useful for formulating coatings, adhesives, and inks.This solubility is useful when formulating inks, adhesives and coatings.
4. Boiling point: The boiling point of acrylic acid octyl ester is relatively high.The boiling point for acrylic acid octyl ester is relatively high. It typically boils around 216 - 218 degC at normal atmospheric pressure.It boils at around 216-218 degC under normal atmospheric pressure. The high boiling point means that it is less volatile than some other low - molecular - weight esters, which is beneficial in applications where stability at elevated temperatures is required.It is less volatile due to its high boiling point than other low-molecular-weight esters. This is useful in applications that require stability at elevated temperature.
5. Density: It has a density of approximately 0.88 g/cm3 at 20 degC.It has a densities of 0.88 g/cm3 when at 20 degrees Celsius. This density value is lower than that of water, which is 1 g/cm3.This density value is less than water, which has a density of 1 g/cm3. This difference in density can be exploited in separation processes if needed.If needed, this difference in density could be used in separation processes.
Chemical properties of acrylic acid octyl ester:Chemical properties of acrylic acid Octyl Ester
1. Polymerizability: One of the most important chemical properties is its ability to polymerize.Polymerizability is one of the most important chemical properties. The double bond in the acrylic acid part of the molecule can undergo addition polymerization reactions.The double bond of the acrylic acid molecule can undergo polymerization addition reactions. In the presence of initiators such as peroxides or azo - compounds, acrylic acid octyl ester monomers can link together to form long - chain polymers.Acrylic acid octyl ester monomers can be linked together in the presence of initiators, such as peroxides and azo - compounds. These polymers are widely used in the production of polymers for coatings, where they can provide good film - forming properties, hardness, and weather resistance.These polymers can be used to make polymers for coatings. They have good film-forming properties, are hard and resistant to weather.
2. Reactivity with nucleophiles: The ester group in acrylic acid octyl ester can react with nucleophiles.Reactivity with Nucleophiles. The ester group of acrylic acid octyl ester can react with nucleophiles. For example, it can undergo hydrolysis in the presence of an acid or a base.It can be hydrolyzed in the presence of acid or base. In acidic hydrolysis, the ester is broken down into acrylic acid and octanol.In acidic hydrolysis the ester is broken into acrylic acid and Octanol. In basic hydrolysis (saponification), the carboxylate salt of acrylic acid and octanol are formed.In basic hydrolysis (saponification), octanol and acrylic acid are converted to the carboxylate salt. This reactivity is important in chemical synthesis and in the degradation or modification of materials containing acrylic acid octyl ester units.This reactivity plays a key role in chemical synthesis, as well as in the degradation and modification of materials that contain acrylic acid octyl ester units.
3. Cross - linking ability: When copolymerized with other monomers that have reactive groups, acrylic acid octyl ester can participate in cross - linking reactions.Cross-linking ability: When copolymerized, acrylic acid octyl ester can participate in cross-linking reactions. This can enhance the mechanical properties, chemical resistance, and thermal stability of the resulting polymer materials.This can improve the mechanical properties, chemical stability, and thermal resistance of the polymer materials. For instance, when copolymerized with monomers containing hydroxyl or amino groups, cross - linking can occur through condensation reactions, leading to the formation of three - dimensional network structures.Cross-linking can be achieved through condensation reactions when monomers with hydroxyl or ammonium groups are copolymerized. This leads to the formation of a three-dimensional network structure.
Is acrylic acid octyl ester harmful to the environment?
Acrylic acid octyl ester can have potential harmful effects on the environment.The environment can be negatively affected by acrylic acid octyl ester.
In the aquatic environment, acrylic acid octyl ester may pose risks to aquatic organisms.Acrylic acid octyl ester can be toxic to aquatic organisms. When it enters water bodies, it can be toxic to fish, invertebrates, and other aquatic life.It can be toxic for fish, invertebrates and other aquatic animals when it enters waterbodies. It may interfere with their physiological functions, such as respiration, reproduction, and growth.It can interfere with their physiological functions such as respiration and reproduction. For example, it could disrupt the normal development of fish embryos, leading to deformities or reduced survival rates.It could, for example, disrupt the normal development in fish embryos resulting in deformities or a reduced survival rate. Aquatic invertebrates like daphnia may also be affected, with changes in their behavior, feeding patterns, and overall population dynamics.Aquatic invertebrates such as daphnia could also be affected by the changes in their behavior, eating patterns, and population dynamics.
In soil, acrylic acid octyl ester may have an impact on soil microorganisms.Acrylic acid octyl ester may have an effect on soil microorganisms. These microorganisms play a crucial role in processes such as decomposition of organic matter, nutrient cycling, and maintaining soil fertility.These microorganisms are crucial in processes like decomposition of organic material, nutrient cycles, and soil fertility. The presence of acrylic acid octyl ester might inhibit the activity of these beneficial soil microbes.The presence of acrylic octyl ester could inhibit the activity these beneficial soil microbes. This could slow down the decomposition of plant residues, affecting the release of nutrients back into the soil.This could affect the release of nutrients into the soil by slowing down the decomposition process of plant residues. As a result, plant growth could be indirectly affected, as they rely on these nutrients for healthy development.This could indirectly affect plant growth, as plants rely on nutrients for healthy development.
In the atmosphere, if acrylic acid octyl ester is released during industrial processes or from products containing it, it can contribute to air pollution.Acrylic acid octyl ester can contribute to air pollutants in the atmosphere if it is released from industrial processes or products that contain it. Once in the air, it may participate in chemical reactions, potentially forming secondary pollutants such as ozone.Once in the atmosphere, it can participate in chemical reactions and potentially form secondary pollutants like ozone. Ozone is a harmful air pollutant that can damage plants, reduce visibility, and have negative impacts on human health, including respiratory problems.Ozone is an air pollutant harmful to human health. It can damage plants and reduce visibility.
Moreover, acrylic acid octyl ester is persistent to some extent.The acrylic acid octyl ester is also persistent in a certain degree. It may not break down easily in the environment, remaining in soil, water, or air for an extended period.It may not degrade easily in the environment and remain in soil, water or air for a long time. This persistence means that the cumulative effects of its release can build up over time, causing more significant and long - term damage to the environment.This means that over time, the cumulative effects can cause more damage to the environment. Overall, while the exact level of harm depends on factors like the concentration, duration of exposure, and the specific ecosystem, acrylic acid octyl ester should be carefully managed to minimize its potential negative impacts on the environment.While the exact level depends on factors such as concentration, duration of the exposure, and specific ecosystems, acrylic acid octyl ester should be managed carefully to minimize its negative impacts on the environmental.
What safety precautions should be taken when handling acrylic acid octyl ester?
When handling acrylic acid octyl ester, several safety precautions must be observed.There are several safety precautions to be taken when handling acrylic acid octyl ester.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Workers should wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can effectively resist the penetration of acrylic acid octyl ester.Nitrile gloves can be a good option as they are resistant to acrylic acid octyl ester. This helps prevent direct contact with the skin, which could lead to skin irritation, redness, and potential chemical burns.This will help prevent direct skin contact, which can lead to irritation, redness and possible chemical burns. A lab coat or protective clothing made of suitable materials should be worn to cover the body.Wear a lab coat or protective clothing made from suitable materials to cover your body. This protects the skin on the torso, arms, and legs from splashes.This will protect the skin on your torso, arms and legs from splashes. Safety goggles or a face shield must be used to safeguard the eyes.To protect the eyes, safety goggles or face shields must be worn. Even a small splash of acrylic acid octyl ester in the eyes can cause severe damage, including corneal abrasions and possible vision impairment.Even a small amount of acrylic acid octyl ester in the eye can cause severe damage. This includes corneal abrasions, and even vision impairment.
Second, proper ventilation is crucial.Second, ventilation is essential. Acrylic acid octyl ester has a certain vapor pressure, and its vapors can be irritating to the respiratory system.The vapors of acrylic acid octyl ester can irritate the respiratory system due to its high vapor pressure. Work should be carried out in a well - ventilated area, preferably under a fume hood.The work should be done in an area that is well-ventilated, preferably under the fume hood. The fume hood can effectively capture and exhaust the vapors, reducing the concentration of harmful substances in the breathing zone.The fume hood will effectively capture and exhaust vapors to reduce the concentration of harmful substances within the breathing zone. If working in an area without a fume hood, local exhaust ventilation systems should be installed to ensure that the air is continuously exchanged.If you are working in a place without a fume-hood, install local exhaust ventilation systems to ensure the air is constantly exchanged.
Third, storage precautions are necessary.Third, it is important to take precautions when storing the product. Acrylic acid octyl ester should be stored in a cool, dry, and well - ventilated storage area.The acrylic acid octyl ester should be kept in a well-ventilated, cool, and dry storage area. It should be kept away from sources of ignition such as open flames, sparks, and heat.It should be stored away from ignition sources such as heat, open flames and sparks. Since it is flammable, any potential ignition source could lead to a fire or explosion.It is flammable and any ignition source could cause a fire or an explosion. The storage containers should be tightly sealed to prevent leakage.To prevent leakage, the storage containers must be tightly sealed. Label the containers clearly with the name of the substance, its hazards, and handling instructions.Label the containers with the name of substance, its hazards and handling instructions.
Fourth, in case of accidental spills.Fourth, in the event of an accidental spill. If a spill occurs, immediately evacuate the non - essential personnel from the area.If a spill happens, evacuate all non-essential personnel from the area immediately. Wear appropriate personal protective equipment before attempting to clean up the spill.Wear the appropriate personal protective gear before cleaning up a spill. Use absorbent materials like vermiculite, sand, or special spill - control pads to soak up the liquid.To absorb the liquid, use absorbent materials such as vermiculite or sand. Dispose of the contaminated absorbent materials in accordance with local environmental regulations.Dispose the contaminated absorbent material in accordance with local regulations. Wash the spill area thoroughly with water to remove any remaining traces of acrylic acid octyl ester.The spill area should be thoroughly washed with water to remove all traces of acrylic octyl ester.
Finally, emergency response training.Finally, emergency response education. Workers who handle acrylic acid octyl ester should receive proper emergency response training.Workers who handle acrylic octyl ester should receive the proper emergency response training. They should know what to do in case of skin contact, eye contact, inhalation, or ingestion.They should be aware of what to do if they come into contact with skin, eyes, or ingestion. For skin contact, immediately wash the affected area with plenty of water for at least 15 minutes.Skin contact should be washed immediately with plenty of water and for at least 15 min. In case of eye contact, flush the eyes with copious amounts of water and seek immediate medical attention.If you have eye contact, immediately flush your eyes with water and seek medical attention. If inhaled, move the victim to fresh air and get medical help if symptoms such as coughing or difficulty breathing occur.If the victim inhales, move them to fresh air. Seek medical attention if symptoms like coughing or difficulty respiration occur. In case of ingestion, do not induce vomiting without medical advice and seek immediate medical assistance.In the case of ingestion do not induce vomiting unless medical advice is given. Seek immediate medical attention.