.
Product Name | Acrylic acid propargyl ester |
Cas Number | 5784-30-9 |
Formula | C6H6O2 |
Molar Mass | 110.11 g/mol |
Density | 0.997 g/cm3 |
Boiling Point | 97°C |
Melting Point | Not available |
Flash Point | 43°C |
Refractive Index | 1.442 |
Vapor Pressure | 20 mmHg at 20°C |
Solubility In Water | Slightly soluble |
Appearance | Colorless liquid |
Odor | Acrid |
What are the main applications of acrylic acid propargyl ester?
Acrylic acid propargyl ester has several main applications.Acrylic acid propargyl ester has many main applications.
One significant area is in the field of polymer synthesis.A significant area is the field of polymer syntheses. It can be used as a monomer to prepare special - functional polymers.It can be used to prepare polymers with special -functional properties. For example, in the synthesis of polymers with unsaturated triple - bond side - chains.For example, the synthesis of side-chains with triple-bond unsaturated polymers. These polymers can further participate in various post - polymerization reactions.These polymers may also be used in post-polymerization reactions. The triple - bond in acrylic acid propargyl ester can undergo cycloaddition reactions, such as the click reaction.The triple-bond in acrylic acid propargyl ester can undergo cycloadditions, such as the Click reaction. This allows for the introduction of different functional groups onto the polymer backbone, enabling the preparation of polymers with tailored properties.This allows the introduction of functional groups to the polymer backbone. This allows the preparation of polymers that have tailored properties. These polymers may find applications in areas like drug delivery systems, where the ability to modify the polymer structure precisely is crucial for controlling the release of drugs.These polymers could be used in areas such as drug delivery systems where the ability of the polymer to be modified precisely is critical for controlling the release.
In the coatings industry, acrylic acid propargyl ester can enhance the performance of coatings.Acrylic acid propargyl ester can improve the performance of coatings in the coatings industry. When incorporated into coating formulations, it can improve the cross - linking density of the coating film.It can increase the cross-linking density of coating films when incorporated into formulations. The presence of the propargyl group provides additional reactive sites for cross - linking reactions.Propargyl groups provide additional sites for cross-linking reactions. This leads to coatings with better hardness, abrasion resistance, and chemical resistance.This results in coatings that are harder, more resistant to abrasion, and more chemically resistant. For instance, in industrial coatings for metal substrates, these improved properties can protect the metal from corrosion and mechanical damage for a longer time, extending the lifespan of the coated objects.These improved properties can, for example, protect metal substrates from corrosion and mechanical damage over a longer period of time. This extends the lifespan of coated objects.
It also plays a role in the synthesis of fine chemicals.It is also used in the synthesis fine chemicals. Acrylic acid propargyl ester can serve as an important intermediate in organic synthesis.Acrylic acid propargyl ester can be used as an intermediate in organic synthesis. Its double - bond and triple - bond can participate in a variety of chemical reactions, such as addition reactions, substitution reactions, and rearrangement reactions.Its double-bond and triple-bond can be used in a variety chemical reactions such as addition reactions and substitution reactions. Chemists can use it to build complex molecular structures.Chemists use it to create complex molecular structure. For example, in the synthesis of certain natural - product - like compounds or biologically active molecules.In the synthesis of biologically active molecules or natural-product-like compounds. By carefully controlling the reaction conditions, different functionalized products can be obtained, which are valuable in the pharmaceutical and agrochemical industries.By carefully controlling reaction conditions, different functionalized compounds can be obtained that are valuable to the pharmaceutical and agrochemical industry.
Furthermore, in the field of materials science, it can be used to modify the surface of materials.In the field of materials, it can also be used to modify surfaces of materials. By grafting acrylic acid propargyl ester onto the surface of polymers, ceramics, or metals, the surface properties can be adjusted.Surface properties can be altered by grafting acrylic ester propargyl onto polymers, metals, ceramics or ceramics. This can improve the wettability, adhesion, and biocompatibility of the materials.This can improve wettability, adherent, and biocompatibility. For example, in biomedical materials, improving biocompatibility is essential to ensure that the material does not cause adverse reactions in the body when implanted or in contact with biological tissues.Biocompatibility is important in biomedical materials to ensure that they do not cause adverse reactions when implanted in the body or come into contact with biological tissue.
What are the safety precautions when handling acrylic acid propargyl ester?
Acrylic acid propargyl ester is a chemical compound that requires careful handling due to its potential hazards.A chemical compound, acrylic acid propargyl ester, is one that should be handled with care due to the potential dangers. Here are some safety precautions.Here are some safety measures.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile or neoprene gloves are often good choices as they can provide a barrier against contact with the chemical.Gloves made of nitrile or neoprene are good options as they provide a barrier to the chemical. This helps prevent skin irritation, which can occur upon direct contact.This can help prevent skin irritation that can occur when direct contact occurs. Skin contact may lead to redness, itching, and in severe cases, chemical burns.Contact with the skin can cause redness, itchiness, and in some cases, chemical burns. Also, wear safety goggles or a face shield.Wear safety goggles and a face shield. This protects the eyes from any splashes of acrylic acid propargyl ester.This will protect your eyes from any splashes or splatters of acrylic acid propargyl ester. A splash in the eye can cause serious damage, including corneal abrasions and potential loss of vision.A splash in the eyes can cause serious injury, including corneal damage and loss of vision. Additionally, use a lab coat or other protective clothing to cover the body.Use a labcoat or other protective clothing on the body. This guards against spills onto clothing and subsequent contact with the skin.This will prevent spills from getting onto clothing, and then contacting the skin.
Second, proper ventilation is crucial.Second, it is important to have proper ventilation. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably under fume hoods. Acrylic acid propargyl ester may release vapors that are irritating to the respiratory system.The vapors released by acrylic acid propargyl ester can be irritating to the respiratory tract. Inhalation of these vapors can cause coughing, shortness of breath, and in more extreme cases, damage to the lungs.Inhalation can cause coughing and shortness of breathe, or in extreme cases, lung damage. A fume hood effectively captures and exhausts these vapors, reducing the risk of inhalation.A fume hood captures and exhausts the vapors effectively, reducing inhalation risk.
Third, when storing acrylic acid propargyl ester, keep it in a cool, dry place away from heat sources and open flames.Third, store acrylic acid propargyl ester in a cool and dry place, away from heat sources or open flames. This chemical is flammable, and heat or an open flame can ignite it, leading to a fire or explosion.This chemical is flammable and can be ignited by heat or open flames, resulting in a fire or explosion. Store it in a designated chemical storage area, separated from incompatible substances such as oxidizing agents.Store it in an area designated for chemical storage, away from incompatible substances like oxidizing agents. Contact with oxidizers can trigger a violent reaction.Contact with oxidizers may trigger a violent reaction.
Fourth, in case of spills.Fourth, in the event of spills. Immediately contain the spill to prevent its spread.Contain the spill immediately to prevent it from spreading. Use absorbent materials like sand or vermiculite to soak up the liquid.To absorb the liquid, use absorbent materials such as sand or Vermiculite. Then, carefully place the contaminated absorbent in a suitable waste container.Place the contaminated absorbent into a suitable container. Wash the affected area thoroughly with water.Wash the affected area with water. If the spill is large, evacuate the area and notify the appropriate safety personnel.If the spill is big, evacuate the area. Notify the appropriate safety personnel.
Finally, be aware of first - aid measures.Be aware of the first-aid measures. In case of skin contact, immediately wash the affected area with plenty of water for at least 15 minutes and seek medical attention if irritation persists.If skin contact occurs, wash the area immediately with plenty of water and wait at least 15 minutes before seeking medical attention. For eye contact, flush the eyes with copious amounts of water for at least 15 minutes and then get professional medical help.If you have eye contact, wash your eyes with plenty of water for 15 minutes. Then seek professional medical attention. In case of inhalation, move the affected person to fresh air immediately.In the event of inhalation, get the person to fresh air as soon as possible. If they are not breathing, start cardiopulmonary resuscitation (CPR) if trained to do so and call for emergency medical services.If they do not breathe, perform cardiopulmonary resuscitation if you are trained to do so. Call emergency medical services.
How is acrylic acid propargyl ester synthesized?
Acrylic acid propargyl ester can be synthesized through the following general methods.The following general methods can be used to synthesize acrylic acid propargyl ester.
One common approach is the esterification reaction between acrylic acid and propargyl alcohol.Esterification reactions between acrylic acid and propargyl alcohol are common. In this reaction, an appropriate catalyst is usually required.In this reaction, a suitable catalyst is often required. Sulfuric acid is a traditional and effective catalyst for esterification reactions.Sulfuric acids are a proven and effective catalyst in esterification reactions. However, its use may bring some drawbacks such as strong corrosiveness and potential side - reactions.Its use can have some disadvantages, such as corrosiveness or side reactions. Therefore, some solid - acid catalysts like p - toluenesulfonic acid supported on silica gel are also often employed.Some solid - acid catalysers, such as p -toluenesulfonic acids supported on silicagel, are also commonly used. These solid - acid catalysts are easier to separate from the reaction system and can reduce the corrosion problem.These solid - acids catalysts are easier for the user to separate from the reaction system, and can reduce corrosion.
The reaction is typically carried out in an organic solvent.The reaction is usually carried out in a solvent organic. Toluene is a frequently chosen solvent due to its good solubility for both reactants and the ability to azeotropically remove the water generated during the esterification process.Toluene, which is good at removing water from the esterification reaction, is often chosen as a solvent because of its solubility. The removal of water can shift the chemical equilibrium towards the formation of the ester product, improving the yield.The removal of water may shift the chemical balance towards the ester product and improve the yield.
The reaction process usually involves adding acrylic acid, propargyl alcohol, and the catalyst into a reaction flask equipped with a reflux condenser, a water - separating device, and a stirrer.The usual reaction process involves adding acrylic alcohol, propargyl alchohol, and the catalyst to a reaction flask with a reflux device, a water-separating device, as well as a stirring device. The reaction mixture is heated under reflux.The reaction mixture is heated by reflux. The reaction temperature is carefully controlled.The temperature of the reaction mixture is carefully monitored. If the temperature is too low, the reaction rate will be slow, and if it is too high, side - reactions such as polymerization of acrylic acid or propargyl alcohol may occur.If the temperature is low, the rate of reaction will be slow. If it is high, side-reactions such as polymerizations of acrylic acid or propargyl alchohol may occur. Generally, the reaction temperature is maintained in the range of 80 - 120 degC.The reaction temperature is generally maintained between 80 and 120 degC.
After the reaction is completed, the reaction mixture is cooled.After the reaction has been completed, the reaction mix is cooled. The catalyst can be removed by filtration if it is a solid - acid catalyst.If it is a solid-acid catalyst, the catalyst can be removed using filtration. Then, the organic layer is washed with water to remove unreacted acids or alcohols and other water - soluble impurities.The organic layer is then washed in water to remove any unreacted alcohols or acids. Subsequently, it is dried over anhydrous sodium sulfate to remove the remaining water.The remaining water is then dried over anhydrous sulfate. Finally, the acrylic acid propargyl ester product can be obtained by distillation under reduced pressure to purify the product and separate it from any remaining solvents or unreacted substances.The acrylic acid propargyl ester product can then be obtained through distillation at reduced pressure. This will purify the product, and separate it from unreacted substances or any remaining solvents. This purification step is crucial to obtain a high - purity acrylic acid propargyl ester for various applications.Purification is essential to get a high-purity acrylic acid propargyl ester for various applications.
What are the physical and chemical properties of acrylic acid propargyl ester?
Physical properties of acrylic acid propargyl ester:Physical properties of acrylic acid Propargyl Ester
Appearance: It is typically a colorless to slightly yellow liquid.Appearance: This liquid is usually colorless or slightly yellow. This visual characteristic makes it distinguishable in a laboratory or industrial setting.This characteristic makes it easy to identify in a laboratory setting or industrial environment. Its relatively clear nature allows for easy inspection of its purity and any potential contaminants.Its relatively transparent nature allows easy inspection of its purity and any potential contaminants.
Boiling point: The boiling point of acrylic acid propargyl ester is around a specific value, which is important for processes involving distillation or separation.Boiling point. The boiling point of acrylic ester propargyl is around a certain value. This is important for processes that involve distillation or separation. Knowing the boiling point helps in designing appropriate heating and condensation systems to isolate the compound from mixtures.Knowing the boiling point is important for designing heating and condensation systems that will isolate the compound.
Melting point: Its melting point is another key physical property.Melting point is another important physical property. Understanding the melting point is crucial, especially when handling the substance in different temperature environments.Understanding the melting point of a substance is important, especially if you are handling it in different temperature environments. It determines the state (solid, liquid) of the compound at a given temperature, which can impact storage and processing conditions.It determines whether the compound is in a solid or liquid state at a certain temperature. This can have an impact on storage and processing conditions.
Density: The density of acrylic acid propargyl ester is significant as it affects its behavior in liquid - liquid or liquid - solid systems.Density: The acrylic acid propargyl ester's density is important as it can affect its behavior in liquid-liquid or liquid-solid systems. It can help in calculating volumes and masses accurately during formulation processes.It can be used to calculate volumes and masses accurately when formulating. A specific density value also contributes to its buoyancy and settling characteristics in mixtures.A specific density value can also affect the mixture's buoyancy and settling properties.
Solubility: It has certain solubility properties.Solubility: It possesses certain solubility characteristics. It may be soluble in some organic solvents, which is useful for applications such as formulating coatings or adhesives.It is soluble in certain organic solvents. This is useful when formulating adhesives or coatings. The solubility in organic solvents allows it to be incorporated into different formulations, enabling the creation of homogeneous mixtures.It can be dissolved in organic solvents to create homogeneous mixtures.
Chemical properties of acrylic acid propargyl ester:Chemical properties of acrylic acid Propargyl Ester
Reactivity of the double bond: The acrylic part of the molecule contains a carbon - carbon double bond.Double bond reactivity: The acrylic portion of the molecule has a double bond of carbon-carbon. This double bond is highly reactive.This double bond is highly reactive. It can participate in addition reactions, such as polymerization reactions.It can also participate in other reactions, like polymerization reactions. In polymerization, multiple molecules of acrylic acid propargyl ester can join together through the double bond to form long - chain polymers.Polymerization is a process where multiple molecules of acrylic propargyl ester can be joined together by the double bond. This creates long-chain polymers. These polymers are used in various applications, like the production of specialty plastics and coatings.These polymers can be used in a variety of applications, such as the production specialty plastics and coatings.
Reactivity of the triple bond: The propargyl group contains a carbon - carbon triple bond.Reactivity of triple bond: the propargyl group has a triple bond carbon-carbon. This triple bond is also reactive.This triple bond is reactive. It can undergo reactions such as cycloaddition reactions.It can undergo reactions, such as cycloadditions. For example, it can react with certain reagents in a 1,3 - dipolar cycloaddition reaction to form heterocyclic compounds.It can, for example, react with certain reagents to form heterocyclic molecules in a 1,3-dipolar cycloaddition. These reactions are important in organic synthesis for creating complex molecular structures.These reactions are crucial in the organic synthesis of complex molecular structure.
Ester hydrolysis: As an ester, acrylic acid propargyl ester is susceptible to hydrolysis in the presence of water and an appropriate catalyst (either acidic or basic).Ester hydrolysis. As an ester acrylic acid propargyl ester is susceptible to hydrolysis when in the presence of a suitable catalyst (either basic or acidic). In acidic hydrolysis, the ester bond is broken, resulting in the formation of acrylic acid and propargyl alcohol.In acidic hydrolysis the ester bond breaks, resulting acrylic acid and propargyl ethanol. Basic hydrolysis also leads to the cleavage of the ester bond but may result in the formation of the carboxylate salt of acrylic acid and propargyl alcohol.Basic hydrolysis can also lead to the cleavage the ester bond, but it may result in the carboxylate salts of acrylic acid andpropargyl alcohol. This property is important in understanding its stability in aqueous environments and in some chemical degradation processes.This property is crucial to understanding its stability in aqueous environment and in certain chemical degradation processes.
Overall, these physical and chemical properties of acrylic acid propargyl ester play vital roles in its applications in the fields of materials science, organic synthesis, and polymer chemistry.These physical and chemical properties play a vital role in its applications to the fields of polymer chemistry, organic synthesis and materials science.
What are the storage requirements for acrylic acid propargyl ester?
Acrylic acid propargyl ester is a chemical compound with certain storage requirements to ensure its stability and safety.The storage of acrylic acid propargyl ester is important to ensure its safety and stability.
Firstly, it should be stored in a cool and well - ventilated area.It should be stored in an area that is cool and well-ventilated. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. A temperature range around 2 - 8degC is often ideal for long - term storage.Temperatures between 2 and 8degC are often the best for long-term storage. If the storage environment is too hot, the acrylic acid propargyl ester may start to polymerize spontaneously, which not only changes its chemical properties but can also pose risks like blockage of storage containers and potential explosion hazards due to the heat generated during polymerization.If the storage environment becomes too hot, the acrylic ester can start to polymerize, which will change its chemical properties and also create risks such as blockage of containers or explosion hazards.
Secondly, it must be stored away from sources of ignition and oxidizing agents.Second, it should be stored away from sources that can cause ignition or oxidizing agents. Acrylic acid propargyl ester is flammable.Acrylic acid propargyl ester is flammable. Ignition sources, including open flames, sparks from electrical equipment, or hot surfaces, can easily ignite it.It can be ignited by a variety of sources, such as open flames, sparks generated by electrical equipment or hot surfaces. Oxidizing agents can react violently with it, leading to dangerous chemical reactions.Oxidizing agents may react violently, causing dangerous chemical reactions. For example, contact with strong oxidizers like potassium permanganate can cause a rapid and exothermic reaction.Contact with strong oxidizers such as potassium permanganate, for example, can cause an exothermic and rapid reaction.
Thirdly, the storage containers should be tightly sealed.Thirdly, the storage containers must be tightly sealed. Acrylic acid propargyl ester is volatile to some extent.Acrylic acid propargyl ester is volatile in some degree. A loose - fitting container can allow the evaporation of the compound, reducing its purity and concentration.A container that is not tightly sealed can allow the compound to evaporate, reducing purity and concentration. Additionally, exposure to air can also lead to oxidation reactions, which can degrade the quality of the chemical.Exposure to air can also cause oxidation reactions that can reduce the quality of the chemical. It is advisable to use containers made of materials that are resistant to corrosion by acrylic acid propargyl ester, such as certain types of plastics or stainless - steel containers specifically designed for chemical storage.It is best to use containers that are resistant to acrylic acid propargyl ester corrosion, such as stainless steel or certain types of plastic.
Fourthly, keep it away from direct sunlight.Keep it out of direct sunlight. Ultraviolet light in sunlight can initiate photochemical reactions in acrylic acid propargyl ester.The ultraviolet light from sunlight can cause photochemical reactions to occur in acrylic acid propargyl ester. These reactions can lead to changes in its structure and properties, for example, promoting polymerization or decomposition reactions.These reactions can cause changes in the structure and properties of acrylic acid propargyl ester, such as promoting polymerization reactions or decomposition reactions.
Finally, proper labeling of the storage containers is crucial.The labeling of storage containers is also crucial. The label should clearly indicate the name of the chemical, its hazardous nature, storage conditions, and emergency contact information.Labels should clearly state the name of the substance, its hazardous nature and storage conditions. This ensures that any personnel handling the storage area are well - informed about the potential risks associated with acrylic acid propargyl ester.This will ensure that all personnel who are involved in the storage area is well-informed about the risks associated with acrylic acids propargyl esters.