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Acrylic Acid Tetrahydrofurfuryl Ester


Properties
Product Name Acrylic acid tetrahydrofurfuryl ester
Cas Number 2399-48-6
Formula C9H14O3
Molar Mass 170.21
Density 0.961 g/cm³
Boiling Point 231 °C
Flash Point 99 °C
Refractive Index 1.462
Viscosity 3.67 cP
Melting Point -29 °C
Vapor Pressure 0.05 mmHg at 25 °C
Autoignition Temperature 270 °C
Solubility slightly soluble in water
FAQ

What are the main applications of acrylic acid tetrahydrofurfuryl ester?

Acrylic acid tetrahydrofurfuryl ester has several main applications:The acrylic acid tetrahydrofurfuryl ester has many main applications.
1. CoatingsCoatings
In the coatings industry, it plays a crucial role.It is a vital component in the coatings industry. It can be used as a reactive diluent.It can be used to dilute reactive paints. Traditional diluents in coatings often just reduce viscosity, but acrylic acid tetrahydrofurfuryl ester not only reduces the viscosity of the coating formulation, allowing for better application and leveling, but also participates in the curing process through its unsaturated double bond.The traditional diluents used in coatings are often only designed to reduce the viscosity. However, the acrylic acid tetrahydrofurfuryl ester not only reduces viscosity but also helps in the curing of the coating through its unsaturated, double bond. This results in coatings with enhanced hardness, abrasion - resistance, and chemical - resistance.This produces coatings that are more resistant to abrasion, chemical resistance, and hardness. For example, in industrial coatings applied to metal surfaces, it helps to form a tough and durable film that can withstand harsh environments, protecting the metal from corrosion and wear.In industrial coatings, it can be used to create a durable and tough film that is resistant to harsh environments and protects metal surfaces from corrosion and wear. In addition, in UV - curable coatings, it is an important monomer.It is also an important monomer in UV-curable coatings. When exposed to UV light, it rapidly polymerizes, enabling fast - drying coatings, which is highly beneficial for high - speed production lines in the furniture, printing, and electronics industries.It quickly polymerizes when exposed to UV light. This is beneficial for high-speed production lines in the furniture and printing industries, as well as electronics.

2. AdhesivesAdhesives
Acrylic acid tetrahydrofurfuryl ester is also used in the production of adhesives.The tetrahydrofurfuryl ester of acrylic acid is also used to make adhesives. Its reactive nature allows it to form strong chemical bonds during the curing process.Its chemical bonding properties allow it to form strong chemical ties during the curing process. It can be copolymerized with other monomers to tailor the adhesive's properties.It can be copolymerized to customize the adhesive's characteristics. For instance, when copolymerized with acrylate monomers, it can improve the adhesive's adhesion strength to various substrates such as plastics, metals, and ceramics.When copolymerized, it can increase the adhesive's adhesion to different substrates like plastics, metals and ceramics. In pressure - sensitive adhesives, it helps to balance the tack, peel strength, and shear strength.In pressure-sensitive adhesives, it balances the tackiness, peel strength, shear strength. The tetrahydrofurfuryl group in its structure can also provide some degree of flexibility to the adhesive, making it suitable for bonding materials with different degrees of flexibility and expansion coefficients.The tetrahydrofurfuryl groups in its structure can provide some flexibility to the glue, making it suitable for materials with different degrees or expansion coefficients.

3. InksInks
In the ink industry, it is used in UV - curable inks.In the ink industry it is used to create UV-curable inks. Similar to its role in coatings, it participates in the UV - induced polymerization reaction.It plays a similar role to its role in coatings. It participates in UV-induced polymerization reactions. This enables inks to dry quickly under UV light irradiation, reducing drying time and increasing production efficiency.Inks can dry faster under UV light, which reduces drying time and increases production efficiency. Moreover, the resulting cured ink films have good abrasion - resistance, light - fastness, and chemical - resistance.The cured ink film has excellent abrasion resistance, light-fastness, and chemical-resistance. In printing applications, especially for high - quality printing on packaging materials like plastics and paper, these properties ensure that the printed patterns and texts remain clear and intact during storage and transportation.These properties are essential for printing applications. They are especially important when printing high-quality patterns and text on packaging materials such as plastics and papers.

4. Dental Materials
In the dental field, acrylic acid tetrahydrofurfuryl ester is used in dental composites.In the dental field acrylic acid tetrahydrofurfuryl ester is used in dental resin composites. It can be incorporated into the formulation to improve the mechanical properties of the composite.It can be added to the formulation of composites to improve their mechanical properties. By copolymerizing with other dental - grade monomers, it helps to enhance the hardness, wear - resistance, and esthetic properties of dental restorations.Copolymerizing it with other dental-grade monomers helps to improve the hardness, wear-resistance, and esthetic qualities of dental restorations. The ester group can also contribute to the biocompatibility of the material, reducing the risk of adverse reactions in the oral cavity.The ester group may also contribute to biocompatibility, reducing the risk for adverse reactions in the mouth.

What are the properties of acrylic acid tetrahydrofurfuryl ester?

Acrylic acid tetrahydrofurfuryl ester has several notable properties.The tetrahydrofurfuryl ester of acrylic acid has a number of notable properties.
Physical properties
In terms of appearance, it is typically a clear, colorless liquid.It is usually a clear liquid without color. It has a relatively low viscosity, which allows it to flow easily.It is relatively low in viscosity and flows easily. This characteristic makes it convenient for use in various applications where good fluidity is required, such as in coatings and inks formulations.This characteristic makes it suitable for various applications that require good fluidity, such as coatings and ink formulations. It also has a certain volatility.It also has some volatility. The volatility rate is moderate, which means it can gradually evaporate under appropriate conditions.It has a moderate volatility, meaning it can slowly evaporate under the right conditions. This property is beneficial in applications where the solvent needs to evaporate to leave behind a solid film, like in the drying process of coatings.This property is useful in applications where the solvent must evaporate to leave a solid film behind, such as in the drying process of paints.

Chemical properties
One of the most important chemical properties of acrylic acid tetrahydrofurfuryl ester is its high reactivity due to the presence of the acrylate double - bond.The presence of a double-bond acrylate is one of the most important properties of acrylic acid. This double - bond enables it to participate in a wide range of polymerization reactions.This double-bond allows it to participate in many polymerization reactions. It can readily polymerize under the influence of heat, light, or in the presence of suitable initiators.It can easily polymerize when exposed to heat, light or suitable initiators. For example, free - radical polymerization is a common method where the double - bond breaks and forms long - chain polymers.Free - radical polymerization, for example, is a method that is commonly used to break the double-bond and form long-chain polymers. This ability to polymerize makes it a valuable monomer in the production of polymers with specific properties.Its ability to polymerize is what makes it such a valuable monomer for the production of polymers that have specific properties.

The tetrahydrofurfuryl group in the molecule also imparts some unique chemical characteristics.The tetrahydrofurfuryl groups in the molecule also imparts unique chemical properties. It can influence the solubility of the ester.It can affect the solubility. Acrylic acid tetrahydrofurfuryl ester has good solubility in many organic solvents, such as esters, ketones, and aromatic hydrocarbons.The acrylic acid tetrahydrofurfuryl ester is soluble in a wide range of organic solvents such as esters and aromatic hydrocarbons. This solubility property allows it to be easily incorporated into different solvent - based formulations.This solubility allows it to be easily integrated into different solvent-based formulations. Additionally, the tetrahydrofurfuryl group can enhance the compatibility of the ester with other polymers and additives in a formulation, contributing to the overall stability and performance of the final product.The tetrahydrofurfuryl groups can also enhance the compatibility with other polymers or additives, contributing to the overall performance and stability of the final product.

Performance - related propertiesPerformance-related properties
When used in coatings, the resulting polymers from acrylic acid tetrahydrofurfuryl ester can provide good hardness and abrasion resistance.The polymers that result from the acrylic acid tetrahydrofurfuryl ester can be used to provide good hardness and resistance to abrasion when used in coatings. The hardness of the coating helps to protect the substrate from scratches and mechanical damage.The coating's hardness helps protect the substrate against mechanical damage and scratches. At the same time, it can also offer good adhesion to various substrates, including metals, plastics, and wood.It can also adhere well to a variety of substrates including metals and plastics. This strong adhesion ensures that the coating remains firmly attached to the surface, enhancing its durability and long - term performance.This adhesion is strong enough to ensure that the coating stays firmly attached, improving its durability and performance over time. In addition, the cured polymers can have good chemical resistance, being able to withstand exposure to common chemicals, acids, and alkalis to a certain extent, which further broadens its application scope in different environments.The cured polymers are also chemically resistant, able to withstand common chemicals, alkalis, and acids to a certain degree, which broadens their application scope.

How is acrylic acid tetrahydrofurfuryl ester synthesized?

The synthesis of acrylic acid tetrahydrofurfuryl ester typically involves the reaction of acrylic acid with tetrahydrofurfuryl alcohol.The reaction of acrylic with tetrahydrofurfuryl is usually used to synthesize acrylic acid tetrahydrofurfuryl esters. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
First, the reactants need to be prepared.The first step is to prepare the reactants. High - purity acrylic acid and tetrahydrofurfuryl alcohol are essential for obtaining a good - quality product.To obtain a high-quality product, you need acrylic acid of high purity and tetrahydrofurfuryl alchohol. Acrylic acid is a common industrial chemical, and tetrahydrofurfuryl alcohol can be sourced from reliable chemical suppliers or prepared through specific processes.Acrylic acid is an industrial chemical that's widely used. Tetrahydrofurfuryl Alcohol can be purchased from reliable chemical suppliers, or prepared using specific processes.

The reaction is usually catalyzed.Catalysts are usually used to accelerate the reaction. An acidic catalyst is often used, such as sulfuric acid or p - toluenesulfonic acid.A catalyst acidic, such as sulfuric or p-toluenesulfonic acids, is often used. The catalyst helps to speed up the esterification reaction between the carboxylic acid group of acrylic acid and the hydroxyl group of tetrahydrofurfuryl alcohol.The catalyst speeds up the esterification between the carboxylic acids of acrylic acid and tetrahydrofurfuryl alchol.

The reaction is carried out under specific reaction conditions.The reaction is carried under specific conditions. A suitable reaction temperature is typically in the range of 80 - 120 degC.A reaction temperature suitable for most reactions is usually between 80 and 120 degC. At this temperature range, the reaction rate is favorable, and side reactions can be minimized to a certain extent.This temperature range is conducive to a good reaction rate, and side-reactions can be minimized. The reaction is usually carried out under reflux conditions.The reaction is typically carried out in reflux conditions. A reflux condenser is attached to the reaction flask to ensure that the volatile reactants and products do not escape but are condensed and returned to the reaction system.A reflux condenser attached to the flask ensures that the volatile products and reactants do not escape, but are condensed back into the reaction system.

During the reaction, water is a by - product.Water is a by-product of the reaction. To drive the reaction forward according to Le Chatelier's principle, the water generated needs to be removed continuously.Water generated during the reaction must be continuously removed to drive the reaction according to Le Chatelier’s principle. This can be achieved by using a Dean - Stark apparatus.The Dean-Stark apparatus can be used to achieve this. The Dean - Stark apparatus allows the separation of water from the reaction mixture, which helps to shift the equilibrium of the esterification reaction towards the formation of acrylic acid tetrahydrofurfuryl ester.The Dean - Stark device allows water to be separated from the reaction mixture. This helps shift the equilibrium towards the formation of tetrahydrofurfuryl esters.

After the reaction is complete, the reaction mixture needs to be purified.Purification is required after the reaction has been completed. First, the catalyst is neutralized.The catalyst must first be neutralized. This can be done by adding a suitable base, such as sodium carbonate or sodium hydroxide solution, to adjust the pH of the reaction mixture to a neutral or slightly basic value.Add a base such as sodium hydroxide or sodium carbonate to the reaction mixture in order to adjust the pH to neutral or slightly basic. Then, the mixture is washed with water to remove the salts and other water - soluble impurities generated during the neutralization process.The mixture is then washed with a solution of sodium hydroxide or sodium carbonate to remove any salts or other water-soluble impurities that were generated during the neutralization procedure.

Finally, the organic layer containing the acrylic acid tetrahydrofurfuryl ester is dried over an appropriate drying agent, such as anhydrous sodium sulfate or magnesium sulfate.The organic layer containing acrylic acid tetrahydrofurfuryl ester is then dried over a suitable drying agent such as anhydrous magnesium sulfate, or anhydrous sodium chloride. After drying, the solvent is removed by distillation under reduced pressure to obtain the pure acrylic acid tetrahydrofurfuryl ester product.After drying, the solvent must be removed by distillation at reduced pressure in order to obtain the pure product of acrylic acid tetrahydrofurfuryl ester.

What are the safety precautions when handling acrylic acid tetrahydrofurfuryl ester?

Acrylic acid tetrahydrofurfuryl ester is a chemical substance that requires certain safety precautions during handling.The acrylic acid tetrahydrofurfuryl ester is a corrosive substance that must be handled with care.
Firstly, in terms of personal protective equipment.First, personal protective equipment. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain degree of protection against contact with this ester.Nitrile gloves can offer a degree of protection from contact with this ester. This helps prevent skin irritation, burns, or potential absorption through the skin.This can help prevent skin irritations, burns or absorption through the body. Additionally, wear safety goggles to protect the eyes.Wear safety goggles as well to protect your eyes. Splashes of acrylic acid tetrahydrofurfuryl ester can cause serious eye damage, including corneal abrasions and long - term vision problems.Splashes of acrylic acids tetrahydrofurfuryl esters can cause serious eye injuries, including corneal damage and long-term vision problems. A lab coat or chemical - resistant clothing should also be worn to safeguard the body from spills.Wear a lab coat or chemical-resistant clothing to protect the body from spills.

Secondly, consider the work environment.Second, you should consider the working environment. Ensure good ventilation in the handling area.Assure good ventilation in the handling areas. Adequate ventilation can effectively reduce the concentration of vapors in the air.A good ventilation system can reduce the concentration of vapors. Since acrylic acid tetrahydrofurfuryl ester may release vapors, poor ventilation can lead to inhalation of these vapors, which may cause respiratory tract irritation, coughing, shortness of breath, and other discomforts.Poor ventilation can cause inhalation of these fumes. This may cause respiratory tract irritations, coughing, shortness or breath, and other discomforts. If possible, conduct operations in a fume hood to further control the release of vapors.To further control the release vapors, if possible, perform operations in a fume-hood.

Thirdly, pay attention to storage.Thirdly, be careful with storage. Store acrylic acid tetrahydrofurfuryl ester in a cool, dry place away from sources of heat and ignition.Store acrylic acid tetrahydrofurfuryl ester in a cool and dry place, away from heat sources and ignition. It is flammable, so any open flames, hot surfaces, or sparks should be kept at a safe distance.It is flammable so keep any open flames or sparks away from it. Also, store it in a well - sealed container to prevent leakage.Store it in a tightly sealed container to avoid leakage. Label the storage container clearly with the name of the chemical, its properties, and any relevant hazard warnings.Label the container with the name of chemical, its properties and any relevant hazards warnings.

Fourthly, in case of an accident.Fourthly, if there is an accident. If there is skin contact, immediately remove contaminated clothing and wash the affected area with plenty of soap and water for at least 15 minutes.If there is skin-to-skin contact, remove the contaminated clothing immediately and wash the affected area for at least 15 min. Seek medical attention if irritation persists. In the event of eye contact, rinse the eyes thoroughly with clean water for at least 15 minutes, lifting the eyelids gently to ensure all areas are washed, and then seek immediate medical help.If you have eye contact, wash your eyes thoroughly for at least 15 mins with clean water, lifting your eyelids gently so that all areas are cleaned. Seek immediate medical attention. If inhalation occurs, move to an area with fresh air immediately.Inhalation should be treated immediately by moving to a fresh air area. If the person is not breathing, perform artificial respiration if trained to do so, and call for emergency medical services.If the person cannot breathe, if you are trained, perform artificial breathing and call emergency medical services. In case of ingestion, do not induce vomiting unless directed by a medical professional, and seek medical help promptly.If you have ingested something, do not induce vomiting without the permission of a medical professional. Seek medical attention immediately.

What are the environmental impacts of acrylic acid tetrahydrofurfuryl ester?

Acrylic acid tetrahydrofurfuryl ester is a chemical compound used in various industries, mainly in the production of coatings, adhesives, and inks.The acrylic acid tetrahydrofurfuryl ester is a chemical compound that is used in many industries, including the production of inks, adhesives and coatings. While it offers certain benefits in these applications, it also has potential environmental impacts.It has certain advantages in these applications but also potential environmental effects.
One of the main concerns is its potential for aquatic toxicity.Its potential for aquatic toxicity is one of the biggest concerns. When acrylic acid tetrahydrofurfuryl ester enters water bodies, it can be harmful to aquatic organisms.Acrylic acid tetrahydrofurfuryl ester can be harmful for aquatic organisms when it enters waterbodies. Laboratory studies have shown that it can affect the survival, growth, and reproduction of fish, invertebrates, and other aquatic life.Laboratory studies have shown it can affect the growth, survival, and reproduction of aquatic life, including fish, invertebrates and other aquatic organisms. The compound may bioaccumulate in the tissues of these organisms over time.The compound can bioaccumulate over time in the tissues of aquatic organisms. This can disrupt the balance of aquatic ecosystems, as changes in the population of certain species can have a cascading effect on the entire food web.This can disrupt the balance in aquatic ecosystems as changes in population can have a cascading impact on the entire food chain.

Another aspect is its potential for air pollution.Its potential for air pollution is another aspect. During the manufacturing process or when products containing acrylic acid tetrahydrofurfuryl ester are used, volatile organic compounds (VOCs) may be released into the air.Volatile organic compounds (VOCs), which are released into the atmosphere during the manufacturing process and when products containing the acrylic acid tetrahydrofurfuryl ester are used, may occur. VOCs can react with other pollutants in the presence of sunlight to form ground - level ozone, a major component of smog.VOCs react with other pollutants when exposed to sunlight, forming ground-level ozone. This is a major component in smog. Ground - level ozone is harmful to human health, causing respiratory problems, and it can also damage plants, reducing their ability to photosynthesize and grow.Ground-level ozone can cause respiratory problems in humans and plants. It can also reduce their ability to photosynthesize or grow.

In terms of soil, if acrylic acid tetrahydrofurfuryl ester is spilled or disposed of improperly on land, it may contaminate the soil.If acrylic acid tetrahydrofurfuryl ester is spilled on land or improperly disposed of, it can contaminate soil. This can potentially affect soil microorganisms that play a crucial role in nutrient cycling and soil fertility.This could potentially affect soil microorganisms, which play a vital role in soil fertility and nutrient cycling. The compound may also leach into groundwater, further spreading the contamination and posing a risk to drinking water sources.The compound can also leach into the groundwater, spreading contamination and posing an increased risk to drinking sources.

However, it should be noted that with proper handling, storage, and waste management practices, the environmental impacts of acrylic acid tetrahydrofurfuryl ester can be minimized.It is important to note that the environmental impact of acrylic acid tetrahydrofurfuryl ester can be minimized with proper handling, waste management, and storage practices. Industries can implement measures to reduce VOC emissions, such as using more efficient production processes and installing pollution control devices.In order to reduce VOC emissions in industries, they can use more efficient production processes or install pollution control devices. Additionally, careful disposal of waste materials containing the compound can prevent soil and water contamination.Similarly, proper disposal of waste materials that contain the compound can help prevent soil and water contamination. Overall, understanding these potential environmental impacts is crucial for sustainable use and management of acrylic acid tetrahydrofurfuryl ester.Understanding these potential environmental effects is essential for the sustainable use and management acrylic acid tetrahydrofurfuryl ester.