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Product Name | Acrylic acid, tridecyl ester |
Cas Number | 1561-89-7 |
Formula | C16H30O2 |
Molar Mass | 254.41 |
Density | 0.89 g/cm³ |
Boiling Point | 299 °C |
Melting Point | -45 °C |
Refractive Index | 1.448 |
Solubility | Insoluble in water |
Vapor Pressure | 0.000145 mmHg at 25°C |
Flash Point | 139 °C |
Viscosity | 8.1 mPa·s |
Autoignition Temperature | 245 °C |
What are the main applications of acrylic acid tridecyl ester?
Acrylic acid tridecyl ester has several main applications:Acrylic acid tridecyl ester has many main applications.
In the field of coatings, it plays a crucial role.It is a key component in the coatings industry. The ester can be incorporated into coating formulations to enhance various properties.The ester can enhance the properties of coating formulations by adding it. For instance, it improves the film - forming ability of coatings.It can improve the ability of coatings to form films. When applied to surfaces, it helps create a continuous and smooth film, which is essential for providing good protection.It helps to create a smooth and continuous film when applied to surfaces. This is important for good protection. Additionally, it can enhance the abrasion resistance of coatings.It can also improve the abrasion-resistance of coatings. Surfaces coated with formulations containing acrylic acid tridecyl ester are more resistant to wear and tear, whether from mechanical friction or environmental factors.Surfaces coated with formulations that contain acrylic acid tridecyl ester are more resistant to wear, whether it is from mechanical friction or external factors. This makes it suitable for use in industrial coatings, such as those applied to machinery, automotive parts, and metal structures, where long - lasting protection is required.This makes it ideal for industrial coatings such as those used on machinery, automotive parts and metal structures where long-lasting protection is needed.
In the production of adhesives, acrylic acid tridecyl ester is also of great significance.Acrylic acid tridecyl ester is also very important in the production of adhesives. It can modify the adhesive properties.It can change the adhesive properties. By adding this ester, adhesives can achieve better adhesion to different substrates.Adhesives can be made to adhere better to different substrates by adding this ester. It helps in improving the initial tack, which is the ability of the adhesive to stick immediately upon contact with a surface.It improves the initial tack of the adhesive, which is its ability to stick to a surface immediately upon contact. Moreover, it contributes to the long - term adhesion strength.It also contributes to long-term adhesion. This is especially important in applications like packaging adhesives, where the bond needs to hold the packaging materials together for an extended period.This is important for applications such as packaging adhesives where the bond must hold the packaging materials together over a long period of time. In pressure - sensitive adhesives, it can adjust the balance between stickiness and the ability to be peeled off without leaving residue, making them suitable for applications like labels and tapes.It can be used to adjust the balance of stickiness and peel-off ability in pressure-sensitive adhesives. This makes them suitable for labels and tapes.
In the area of polymers and plastics, acrylic acid tridecyl ester is used as a monomer or comonomer.Acrylic acid tridecyl ester is used in the field of polymers and plastics as a monomer. When copolymerized with other monomers, it can impart unique properties to the resulting polymers.It can give unique properties to polymers when copolymerized. For example, it can improve the flexibility of polymers.It can, for example, improve the flexibility of polymers. This is beneficial in the production of flexible plastics and elastomers.This is advantageous in the production flexible plastics and elastomers. These materials find applications in various industries, including the manufacturing of rubber - like products, flexible hoses, and some types of packaging films that require both strength and flexibility.These materials are used in a variety of industries, including the manufacture of rubber-like products, flexible hoses and some types packaging films that require both flexibility and strength. Also, it can influence the solubility and processability of polymers.It can also influence the solubility of polymers and their processability. This allows for easier shaping and processing of the polymers during manufacturing, reducing production costs and improving production efficiency.This allows for easier processing and shaping of polymers, reducing costs and improving efficiency. Overall, acrylic acid tridecyl ester is a versatile chemical with wide - ranging applications across multiple industries, contributing to the improvement of product performance and functionality.Acrylic acid tridecyl ester is a versatile and widely-used chemical that has many applications in multiple industries. It contributes to improving product performance and functionality.
What are the properties of acrylic acid tridecyl ester?
Acrylic acid tridecyl ester is an organic compound with several notable properties.Acrylic acid tridecyl ester is a compound that has several notable properties.
Physical state and appearance: It is typically a colorless to slightly yellow - colored liquid.Physical state and appearance. It is usually a colorless or slightly yellow-colored liquid. Its liquid state at ambient conditions is due to the relatively long tridecyl carbon chain, which imparts certain fluidity characteristics.The liquid state of the compound at ambient temperatures is due to its relatively long tridecyl chain, which confers certain fluidity properties. The lack of intense color indicates a relatively pure and non - conjugated molecular structure in terms of chromophores.The lack of intense colour indicates a molecular structure that is relatively pure and non-conjugated.
Solubility: It has limited solubility in water.It is soluble in water, but only to a limited extent. This is because the long non - polar tridecyl chain dominates the molecule's hydrophobic nature.The hydrophobic nature of the molecule is dominated by the non-polar tridecyl chains. However, it is soluble in many organic solvents such as hydrocarbons (e.g., hexane, toluene), esters (e.g., ethyl acetate), and ketones (e.g., acetone).It is soluble in a wide range of organic solvents, including hydrocarbons, esters, and ketones, such as acetone, hexane or toluene. This solubility property makes it useful in various organic - based formulations, like in the preparation of coatings and adhesives where it can be easily incorporated into organic solvent systems.This property of solubility makes it useful for various organic-based formulations such as in the preparations of coatings and glues where it is easily incorporated in organic solvent systems.
Viscosity: The viscosity of acrylic acid tridecyl ester is relatively low compared to some polymers but higher than simple low - molecular - weight solvents.Viscosity. The viscosity is higher than that of simple low-molecular-weight solvents, but lower than some polymers. The long tridecyl chain contributes to a certain degree of intermolecular interaction, which leads to a viscosity higher than that of solvents with shorter carbon chains.The long tridecyl chains contribute to a certain level of intermolecular interactions, which results in a viscosity that is higher than solvents with shorter carbon chain. This property is important in applications where the flow and spreadability of the material need to be controlled, such as in paint - like formulations.This property is crucial in applications that require the control of flow and spreadability, such as paint-like formulations.
Chemical reactivity: The acrylate group in acrylic acid tridecyl ester is highly reactive.Chemical reactivity. The acrylate group is highly reactive. It can participate in polymerization reactions, typically through free - radical polymerization mechanisms.It can participate to polymerization reactions. This is usually done through free radical polymerization mechanisms. This allows it to be used as a monomer to form polymers.It can be used as a polymer monomer. When polymerized, the resulting polymers can have a wide range of properties depending on factors like the degree of polymerization and the presence of other comonomers.The properties of the polymers that result from polymerization can vary depending on factors such as the degree of polymerization or the presence of comonomers. For example, the long tridecyl side - chain in the polymer can impart hydrophobicity, low surface energy, and flexibility to the polymer matrix.The long tridecyl chain can, for example, impart hydrophobicity and low surface energy to the polymer matrix. It can also react with other reactive compounds containing functional groups like amines, alcohols, or thiols under appropriate reaction conditions, enabling the formation of cross - linked structures or the modification of the molecule's chemical and physical properties.It can also react under the right conditions with other reactive compounds that contain functional groups such as amines or alcohols. This allows the molecule to be modified in terms of its chemical and physical properties.
Thermal properties: It has a relatively low melting point due to the long, flexible tridecyl chain that disrupts the formation of highly ordered crystalline structures.Thermal properties: It is a relatively low melting material due to its long, flexible tridecyl chains that disrupt the formation of highly-ordered crystalline structures. In terms of thermal stability, it can withstand moderate temperatures before starting to decompose or undergo significant chemical changes.Thermal stability: It can withstand moderate temperature before decomposing or undergoing significant chemical changes. However, like many organic compounds with unsaturated bonds, it may be prone to thermal degradation or polymerization acceleration at elevated temperatures.It is susceptible to thermal degradation and polymerization acceleration, as are many organic compounds with unsaturated bonding.
In summary, acrylic acid tridecyl ester's properties make it a valuable compound in industries such as coatings, adhesives, and polymer synthesis, where its solubility, reactivity, and physical characteristics can be harnessed to create materials with specific performance requirements.The properties of acrylic acid tridecyl ester make it a valuable chemical compound for industries such as coatings and adhesives. Its solubility, reactivity and physical characteristics are used to create materials that meet specific performance requirements.
How is acrylic acid tridecyl ester synthesized?
Acrylic acid tridecyl ester can be synthesized through the esterification reaction between acrylic acid and tridecyl alcohol.The esterification reaction of acrylic acid with tridecyl ethanol can be used to synthesize acrylic acid tridecyl ester. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
1. Reaction materials and catalystsReaction materials and catalysers
The main reactants are acrylic acid and tridecyl alcohol.The main reactants in esterification are tridecyl alcohol and acrylic acid. To promote the esterification reaction, an acid - catalyst is usually required.Acid - catalysts are usually needed to promote the esterification. Commonly used catalysts include sulfuric acid, p - toluenesulfonic acid, etc.Catalysts commonly used include sulfuric acid and p-toluenesulfonic acids. Sulfuric acid is a strong acid catalyst with high catalytic activity, but it may cause side - reactions such as dehydration and charring.Sulfuric is a strong acid catalyst with high catalytic activities, but can cause side-reactions such as dehydration or charring. P - toluenesulfonic acid is a relatively mild and efficient catalyst, which can reduce side - reactions to some extent.P - toluenesulfonic is a mild and efficient catalyzer that can reduce side-reactions to varying degrees.
2. Reaction processReaction process
- In a suitable reaction vessel, such as a round - bottom flask equipped with a reflux condenser, a stirrer, and a thermometer, add a certain amount of acrylic acid and tridecyl alcohol according to a specific molar ratio.Add tridecyl and acrylic acid in a reaction vessel equipped with a reflux-condenser and stirrer. Usually, an excess of one reactant is used to drive the reaction forward according to Le Chatelier's principle.Le Chatelier's Principle dictates that an excess of one reaction agent is used to accelerate the reaction. For example, an excess of tridecyl alcohol can be used to shift the equilibrium of the esterification reaction towards the formation of the ester.An excess of tridecyl ethanol, for example, can be used to shift equilibrium in the esterification process towards the ester.
- Then, add an appropriate amount of the selected catalyst.Add the appropriate amount of catalyst. The amount of the catalyst is usually a certain percentage of the mass or mole of the reactants, typically around 1 - 5% depending on the catalyst and reaction conditions.The amount of catalyst is usually a percentage of the mass of the reactants. This can range from 1 to 5%, depending on the catalyst used and the reaction conditions.
- Heat the reaction mixture slowly with stirring.Heat the reaction mixture slowly while stirring. The reaction temperature is an important factor.The reaction temperature is important. Generally, the esterification reaction of acrylic acid and tridecyl alcohol occurs at a temperature in the range of 100 - 150 degC.The esterification of acrylic acid and tridecyl alchohol occurs in general at temperatures between 100-150 degC. Heating is carried out under reflux conditions, which means that the volatile components in the reaction system (such as water generated during the reaction) are condensed and returned to the reaction flask to ensure the progress of the reaction.The heating is done under reflux conditions. This means that the volatile components of the reaction system, such as the water generated during the reactions, are condensed into a liquid and returned to flasks to ensure the reaction progress.
3. Removal of by - products and purificationPurification and removal of by-products
As the reaction proceeds, water is generated as a by - product.Water is produced as a by-product of the reaction. To drive the reaction forward, it is necessary to remove water from the reaction system.It is necessary to remove the water from the system in order to drive the reaction. One way is to use a Dean - Stark apparatus, which can separate the water formed during the reaction from the reaction mixture and continuously remove it.The Dean-Stark apparatus can be used to separate the water produced during the reaction and remove it continuously.
After the reaction is completed, the reaction mixture contains the target product acrylic acid tridecyl ester, unreacted reactants, and the catalyst.The reaction mixture contains the acrylic acid tridecyl ester, unreacted reaction products, and the catalyst after the reaction has been completed. First, the catalyst can be neutralized with a base, such as sodium carbonate solution.The catalyst can first be neutralized using a base such as sodium carbonate. Then, the mixture is subjected to liquid - liquid extraction.The mixture is then subjected liquid-liquid extraction. The organic layer containing the ester is separated, and then washed several times with water to remove the remaining salts and unreacted polar substances.The ester-containing organic layer is separated and washed with water several times to remove any remaining salts or unreacted polar substances. Finally, the product can be further purified by distillation.The product can then be further purified through distillation. Since acrylic acid tridecyl ester has a specific boiling point, by distilling the crude product, pure acrylic acid tridecyl ester can be obtained.Acrylic acid tridecyl ester has a specific boiling temperature, so by distilling the crude acrylic acid tridecyl ester, it can be obtained in its purest form.
What is the safety profile of acrylic acid tridecyl ester?
Acrylic acid tridecyl ester is a chemical compound.Acrylic acid tridecyl ester is a chemical compound. Regarding its safety profile, here are some aspects to consider.Here are some things to consider when it comes to its safety profile.
Firstly, in terms of skin contact, it may cause skin irritation.In the first place, skin contact can cause irritation. Prolonged or repeated contact can lead to redness, itching, and potential damage to the skin's protective barrier.Contact with the skin can cause irritation, redness and itching. The protective barrier of the skin may also be damaged by repeated or prolonged contact. This is because the compound might interact with the skin cells and disrupt normal cellular functions.This is because the compound may interact with skin cells and disrupt normal cell functions. Workers handling this substance should take precautions such as wearing gloves made of appropriate materials to prevent direct skin exposure.Workers handling this substance must take precautions, such as wearing gloves of the appropriate material to prevent direct exposure to skin.
Secondly, eye contact with acrylic acid tridecyl ester can be extremely harmful.Second, eye contact with tridecyl esters of acrylic acid can be extremely harmful. It can cause severe eye irritation, including pain, watering, and potential damage to the cornea.It can cause severe irritation of the eyes, including pain, tearing, and corneal damage. In case of eye contact, immediate and thorough flushing with large amounts of water is crucial to minimize the damage and seek medical attention promptly.If you have eye contact, it is important to flush the eyes immediately and thoroughly with large amounts water. This will minimize any damage and allow you to seek medical attention as soon as possible.
When it comes to inhalation, the vapor or mist of acrylic acid tridecyl ester can irritate the respiratory tract.Inhaling the vapor of acrylic acid tridecyl ester can cause irritation to the respiratory tract. Inhalation may lead to symptoms like coughing, shortness of breath, and irritation of the nasal passages and lungs.Inhalation can cause symptoms such as coughing, shortness-of-breath, and irritation to the nasal passages and lung. High - level or long - term inhalation exposure might even cause more serious respiratory problems.Inhalation at high levels or for a long time can cause respiratory problems. Adequate ventilation in areas where this chemical is used is essential to reduce the concentration of vapors in the air.To reduce the concentration of vapors, it is important to have adequate ventilation in areas that use this chemical.
From an environmental perspective, acrylic acid tridecyl ester may have some impacts.Acrylic acid tridecyl ester may have some environmental impacts. If it is released into the environment, it may pose a risk to aquatic life.If released into the environment it could pose a threat to aquatic life. It could potentially bioaccumulate in the food chain, although more research is needed to fully understand its environmental fate and long - term ecological impacts.It could bioaccumulate within the food chain. However, more research is required to fully understand its environmental fate.
In terms of toxicity in general, studies on its acute toxicity have shown that it has a certain level of hazard.Studies on its acute toxicity show that it poses a certain amount of risk. However, the exact toxicity level can vary depending on factors such as the route of exposure (oral, dermal, or inhalation) and the dose.The exact level of toxicity can vary depending on factors like the route of exposure, (oral, dermal or inhalation), and the dose. Overall, proper handling, storage, and disposal of acrylic acid tridecyl ester are necessary to ensure the safety of human health and the environment.To ensure the safety of humans and the environment, it is important to handle, store, and dispose of acrylic acid tridecyl ester properly.
What are the typical uses of acrylic acid tridecyl ester in different industries?
Acrylic acid tridecyl ester has several applications across different industries.Acrylic acid tridecyl ester has many applications in different industries.
In the coatings industry, it is used to enhance the performance of coatings.In the coatings sector, it is used to improve the performance of coatings. When incorporated into paint formulations, it can improve the film - forming properties.It can be incorporated into paint formulas to improve film-forming properties. The long tridecyl chain in acrylic acid tridecyl ester contributes to better flexibility of the coating film.The long tridecyl chains in acrylic acid tridecyl ester contribute to the flexibility of the coating films. This is particularly useful for coatings applied on substrates that may undergo some degree of movement or bending, such as in the case of automotive parts or flexible packaging materials.This is especially useful for coatings applied to substrates that are subjected to some degree of movement, bending or movement. Examples include automotive parts and flexible packaging materials. It also helps in improving the adhesion of the coating to various surfaces, ensuring that the paint adheres firmly and resists peeling or flaking.It also improves the adhesion to different surfaces. This ensures that the paint adheres strongly and resists flaking or peeling. Additionally, it can enhance the weather resistance of coatings.It can also improve the weather resistance of paints. The hydrophobic nature of the tridecyl group helps protect the underlying substrate from the damaging effects of moisture, UV radiation, and other environmental factors, prolonging the lifespan of the coated object.The hydrophobic properties of the tridecyl groups protect the underlying substrate against moisture, UV radiation and other environmental factors. This helps to prolong the life of the coated item.
In the adhesives industry, acrylic acid tridecyl ester plays a significant role.Acrylic acid tridecyl ester plays a major role in the adhesives industry. It can be used to modify the properties of adhesive formulations.It can be used for modifying the properties of adhesive formulas. The long - chain ester can improve the tack and peel strength of adhesives.The long-chain ester can increase the adhesive's tackiness and peel strength. For example, in pressure - sensitive adhesives (PSAs), which are used in applications like labels, tapes, and stickers, the addition of acrylic acid tridecyl ester can enhance the ability of the adhesive to stick to different surfaces and remain adhered under various conditions.In pressure-sensitive adhesives (PSAs), such as labels, tapes and stickers, adding acrylic acid tridecyl ester can improve the adhesive's ability to adhere to different surfaces. It also contributes to the flexibility of the adhesive layer, allowing it to conform to irregular surfaces without losing its bonding capabilities.It also increases the flexibility of the layer, which allows it to conform to irregular surface without losing its bonding abilities. This is crucial in applications where the adhesive needs to bond to curved or uneven substrates.This is important in applications where adhesives need to adhere to curved or uneven surfaces.
In the polymer industry, acrylic acid tridecyl ester is used as a monomer for copolymerization.In the polymer industry acrylic acid tridecyl ester is used as a copolymer. By copolymerizing it with other monomers such as acrylic acid, methyl methacrylate, or styrene, polymers with tailored properties can be synthesized.Polymers with tailored properties are synthesized by copolymerizing acrylic acid tridecyl ester with other monomers, such as methyl methacrylate or styrene. For instance, the resulting copolymers can have improved solubility, which is beneficial for applications where the polymer needs to be dissolved in a particular solvent, such as in some printing inks or coating formulations.Copolymers with improved solubility can be used in applications that require the polymer to dissolve in a specific solvent, like in printing inks and coating formulations. The copolymerization can also lead to polymers with enhanced mechanical properties, like increased toughness and impact resistance.Copolymerization may also result in polymers with improved mechanical properties such as increased toughness and resistance to impact. These copolymers find applications in a wide range of products, from consumer goods to industrial components.These copolymers are used in a variety of products from consumer goods to industrial components.