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Acrylic Acid Tridecyl Ester


Properties
Product Name Acrylic acid tridecyl ester
Cas Number 21643-43-0
Formula C16H30O2
Molar Mass 254.41 g/mol
Boiling Point 330 °C
Density 0.87 g/cm³
Refractive Index 1.448
Flash Point 139 °C
Viscosity 7.0 mPa·s at 20°C
Solubility Insoluble in water
Vapor Pressure 0.02 mmHg at 25°C
Appearance Clear liquid
Odor Mild, ester-like
Storage Temperature Store at +2°C to +8°C
FAQ

What are the main applications of acrylic acid tridecyl ester?

Acrylic acid tridecyl ester has several main applications:Acrylic acid tridecyl ester has many main applications.
In the field of coatings, it plays a significant role.It plays a major role in the field of coatings. It can be used as a monomer in the synthesis of coating resins.It can be used in the synthesis for coating resins. When incorporated into coatings, it can improve the film - forming properties.It can be incorporated into coatings to improve their film-forming properties. The long - chain tridecyl group in acrylic acid tridecyl ester imparts certain characteristics to the coating film.The tridecyl group of the acrylic acid tridecyl ester imparts certain properties to the coating film. For example, it can enhance the flexibility of the coating.It can, for example, increase the flexibility of the coating. This is crucial in applications where the coated surface may be subject to bending or deformation, such as in some industrial equipment coatings or automotive interior coatings.This is important in applications where the surface of the coating may be subjected to deformation or bending, such as some industrial equipment coatings and automotive interior coatings. Additionally, it can also improve the water - resistance of the coating.It can also improve water resistance. The hydrophobic nature of the long - chain alkyl group helps to repel water, protecting the substrate from moisture - induced damage like corrosion and degradation.The hydrophobic properties of the long-chain alkyl group repel water and protect the substrate against moisture-induced damage such as corrosion and degradation.

In the area of adhesives, acrylic acid tridecyl ester is also utilized.Acrylic acid tridecyl ester is also used in adhesive formulations. In adhesive formulations, it can contribute to the adjustment of adhesive properties.In adhesive formulations it can be used to adjust adhesive properties. It can improve the adhesion strength to various substrates, especially those with low - surface - energy materials.It can increase the adhesion to different substrates, particularly those with low surface energy materials. The long - chain structure can help the adhesive to better wet and spread on the substrate surface, forming a more stable adhesive bond.The long-chain structure helps the adhesive wetter and spread better on the surface of the substrate, forming a stronger adhesive bond. Moreover, it can influence the tack and peel strength of the adhesive.It can also influence the tackiness and peel strength. By properly formulating with other monomers and additives, adhesives with optimized performance for different application scenarios, such as in packaging adhesives or label - sticking adhesives, can be developed.Adhesives with optimal performance for different applications, such as packaging adhesives or adhesives that stick to labels, can be developed by formulating them with other monomers.

It is also applied in the production of polymers for textile finishing.It is also used in the production polymers for textile finishing. When used in textile - related polymers, it can endow fabrics with unique properties.It can give fabrics unique properties when used in polymers for textiles. For instance, it can improve the softness of the fabric.It can, for example, improve the softness. The long - chain tridecyl group gives a smooth and soft hand - feel to the fabric.The tridecyl long-chain group provides a smooth, soft feel to the fabric. At the same time, it can enhance the abrasion - resistance of the textile.It can also increase the abrasion-resistance of the textile. This is beneficial for textiles that are frequently used or rubbed, like work - wear or upholstery fabrics.This is especially beneficial for textiles like upholstery or workwear fabrics that are often used or rubbed. In addition, it may also have some influence on the dye - ability of the fabric, helping dyes to adhere more evenly and firmly, resulting in better - colored and more color - fast textiles.It may also have an impact on the dye-ability of the fabric by helping dyes adhere more evenly and firmly. This results in better-colored and more color-fast textiles.

In the ink industry, acrylic acid tridecyl ester can be used as a component in ink formulations.In the ink industry acrylic acid tridecyl ester can be used in formulations. It can improve the flow and leveling properties of the ink.It can improve ink flow and leveling. This ensures that the ink spreads uniformly on the printing substrate, whether it is paper, plastic, or other materials.It ensures that ink is evenly distributed on the substrate, whether it's paper, plastic or another material. It also contributes to the drying speed and durability of the printed ink.It also contributes towards the drying speed and durability. The long - chain structure can affect the evaporation rate of solvents in the ink and enhance the resistance of the printed pattern to scratching and fading.The long-chain structure can influence the evaporation of solvents and increase the resistance of printed patterns to scratching and fading.

How is acrylic acid tridecyl ester produced?

Acrylic acid tridecyl ester is typically produced through an esterification reaction.Typically, acrylic acid tridecyl esters are produced by esterification. Here is a general description of the production process.Here is a general description about the production process.
The starting materials are acrylic acid and tridecyl alcohol.Acrylic acid and tridecyl ethanol are the starting materials. In the presence of a catalyst, the esterification reaction occurs.Esterification occurs in the presence of a catalyser. A common catalyst for this type of reaction is an acid catalyst, such as sulfuric acid or p - toluenesulfonic acid.Acid catalysts, such as sulfuric or p-toluenesulfonic acids, are common catalysts for this type reaction. The acid catalyst helps to speed up the reaction by protonating the carbonyl group of acrylic acid, making it more reactive towards the nucleophilic attack by the hydroxyl group of tridecyl alcohol.The acid catalyst speeds up the reaction by protonating carbonyl groups in acrylic acid. This makes them more reactive to the nucleophilic attack of the hydroxyl groups of tridecyl ethanol.

The reaction is carried out under specific reaction conditions.The reaction takes place under specific conditions. Usually, it is conducted at an elevated temperature, typically in the range of 100 - 150 degrees Celsius.It is usually conducted at a high temperature, usually between 100 and 150 degrees Celsius. This temperature range is chosen to provide enough energy for the reaction to proceed at a reasonable rate while minimizing side reactions.This temperature range was chosen to provide sufficient energy to allow the reaction to proceed at an acceptable rate while minimising side reactions. The reaction is also often carried out under reflux conditions.Often, the reaction is carried out in reflux conditions. Refluxing helps to maintain a constant reaction temperature and allows any volatile components to condense and return to the reaction mixture, ensuring that the reaction proceeds to completion.Refluxing allows for a constant temperature in the reaction and allows volatile components to condense back into the reaction mixture. This ensures that the reaction is completed.

During the reaction, water is produced as a by - product.Water is produced during the reaction. To drive the reaction towards the formation of acrylic acid tridecyl ester, it is necessary to remove the water.It is necessary to remove water from the reaction in order to drive it towards the formation acrylic acid tridecyl ester. This can be achieved by using azeotropic distillation.Azeotropic distillation can be used to achieve this. For example, adding a solvent like toluene can form an azeotrope with water.Toluene, for example, can be added to water in order to form an azeotrope. The azeotrope is then distilled out of the reaction mixture, effectively removing water and shifting the equilibrium of the esterification reaction towards the formation of the ester.The azeotrope, which is effectively water removed from the reaction mixture and shifts the equilibrium towards the esterification reaction, is then distilled.

After the reaction is complete, the reaction mixture contains the desired acrylic acid tridecyl ester, unreacted starting materials, the catalyst, and any by - products.The reaction mixture will contain the desired acrylic acid tridecyl ester, unreacted materials, the catalyst and any by-products. The first step in the purification process is to neutralize the acid catalyst.The first step of the purification procedure is to neutralize any acid catalyst. This can be done by adding a base, such as sodium carbonate or sodium hydroxide, to the reaction mixture.Add a base such as sodium hydroxide or sodium carbonate to the reaction mixture. The neutralization reaction forms a salt, which can be separated from the organic phase.The neutralization reaction produces a salt that can be separated from organic phase.

Next, the mixture is typically subjected to distillation.The mixture is then typically subjected next to distillation. Distillation separates the components based on their different boiling points.Distillation separates components based on boiling points. Acrylic acid tridecyl ester has a specific boiling point, and by carefully controlling the distillation temperature and pressure, the pure acrylic acid tridecyl ester can be isolated from the remaining components in the reaction mixture, resulting in a high - purity product suitable for various applications such as in the production of polymers and coatings.Acrylic acid tridecyl ester has a specific melting point. By carefully controlling the temperature and pressure of the distillation, the pure acrylic acids tridecyl esters can be separated from the other components in the reaction mix.

What are the physical and chemical properties of acrylic acid tridecyl ester?

Acrylic acid tridecyl ester is an organic compound with the following physical and chemical properties:Acrylic acid tridecyl ester is an organic compound that has the following physical and chemistry properties:
Physical properties:Physical Properties

Appearance: It is usually a colorless to slightly yellowish liquid.Appearance: This liquid is usually colorless or slightly yellowish. This appearance is common for many esters with longer alkyl chains.This is a common appearance for many esters that have longer alkyl chains. The lack of intense color indicates a relatively simple and non - conjugated molecular structure in terms of chromophores.The lack of color intensity indicates a simple, non-conjugated molecular structure.

Odor: It likely has a characteristic, somewhat sweet - fruity odor typical of esters.Odor: It is likely to have a fruity, sweet aroma that is typical of esters. Esters are well - known for their pleasant scents, which are often used in the fragrance and flavor industries.Esters are known for their pleasant smells and are used in the fragrance industry.

Density: The density of acrylic acid tridecyl ester is relatively close to that of water but slightly less dense.Density: The acrylic acid tridecyl ester is similar to water in density, but a little less dense. This is because the long alkyl chain in the molecule has a lower mass - to - volume ratio compared to water molecules.This is due to the fact that the long alkyl chains in the molecule have a lower volume-to-mass ratio than water molecules. The specific gravity is typically in the range where it would float on water if mixed.The specific gravity of the mixture is usually in the range that it would float if it were mixed with water.

Viscosity: Due to the presence of the long tridecyl chain, it has a moderate viscosity.Viscosity is moderate due to the presence of a long tridecyl ring. The long hydrocarbon chain can interact with neighboring molecules through van der Waals forces, causing the liquid to flow less freely compared to less - viscous substances.The long hydrocarbon chains can interact with neighboring molecule through van der Waals force, causing the fluid to flow less freely than less viscous substances.

Boiling point: It has a relatively high boiling point.It has a relatively higher boiling point. The long alkyl chain increases the molecular weight and also the strength of the intermolecular forces, mainly van der Waals forces.The long alkyl chains increase the molecular mass and also the strength between the molecules, mainly van der Waals force. These forces need to be overcome for the compound to transition from the liquid to the gaseous state, thus resulting in a higher boiling point.These forces must be overcome in order for the compound to transition to the gaseous phase, resulting in an increased boiling point.

Solubility: It is insoluble in water.Insoluble in water. The long non - polar tridecyl chain dominates the molecule's polarity, making it hydrophobic.The tridecyl chain is dominant in the polarity of the molecule, making it hydrophobic. However, it is soluble in many organic solvents such as alcohols, ethers, and hydrocarbons.It is soluble in a wide range of organic solvents including alcohols, hydrocarbons, and ethers. The non - polar nature of these solvents allows for favorable interactions with the non - polar part of acrylic acid tridecyl ester.These solvents are non-polar, which allows them to interact well with the non-polar part of tridecyl esters.

Chemical properties:Chemical properties

Reactivity: It contains a reactive double bond in the acrylic acid part of the molecule.Reactivity: The acrylic acid part of this molecule contains a reactive, double bond. This double bond makes it susceptible to addition reactions.This double bond makes the molecule susceptible to addition reactions. For example, it can undergo polymerization reactions under appropriate conditions.Under the right conditions, it can undergo polymerization. Radical polymerization is a common method where initiators generate free radicals that react with the double bond, leading to the formation of long - chain polymers.Radical polymerization, a method that is common, involves initiators that generate free radicals which react with the double bonds to form long-chain polymers. These polymers are used in various applications such as coatings, adhesives, and plastics.These polymers can be used for a variety of applications, including coatings, plastics, and adhesives.

Hydrolysis: In the presence of water and an appropriate catalyst (either an acid or a base), acrylic acid tridecyl ester can undergo hydrolysis.Hydrolysis: Acrylic acid tridecyl esters can be hydrolyzed in the presence of water, and a suitable catalyst (either acid or base). Acid - catalyzed hydrolysis will break the ester bond, resulting in the formation of acrylic acid and tridecyl alcohol.Acid-catalyzed hydrogenation will break the ester bonds, resulting in acrylic acid and tridecyl ethanol. Base - catalyzed hydrolysis, also known as saponification, will produce the carboxylate salt of acrylic acid and tridecyl alcohol.Base-catalyzed Hydrolysis, or saponification, produces the carboxylate salts of tridecyl and acrylic acid. This hydrolysis reaction is important in understanding the environmental fate and degradation of the compound.This hydrolysis reaction plays a key role in understanding the degradation and fate of the compound.

Ester - exchange reaction: It can participate in ester - exchange reactions.Ester-exchange reaction: It is capable of participating in ester-exchange reactions. If it is reacted with another alcohol in the presence of a catalyst, the tridecyl group can be replaced by the other alcohol's alkyl group, forming a new ester.It can be reacted with an alcohol in the presence a catalyst to replace the tridecyl groups by the alkyl groups of the other alcohol, forming a brand new ester. This reaction is useful in the synthesis of different esters with specific properties for various industrial applications.This reaction can be used to synthesize different esters that have specific properties for different industrial applications.

Is acrylic acid tridecyl ester harmful to the environment?

Acrylic acid tridecyl ester may have certain impacts on the environment.Certain environmental impacts may be caused by acrylic acid tridecyl ester.
In the aquatic environment, if it is released into water bodies, it can potentially pose risks to aquatic organisms.If released into water bodies in the aquatic environment, it could pose a risk to aquatic organisms. Although specific toxicity data may vary, esters can sometimes partition into the water column and interact with organisms.Esters can interact with organisms and partition into the water column, even though specific toxicity data may differ. Some esters might be acutely toxic to fish, invertebrates like daphnia, or algae.Some esters may be toxic to fish, algae, or invertebrates such as daphnia. For example, they could disrupt the normal physiological functions of these organisms, affecting their growth, reproduction, and survival.They could, for example, disrupt the normal physiological function of these organisms and affect their growth, reproduction, or survival. If there is a significant release of acrylic acid tridecyl ester into a small water body, it could lead to a decline in the population of sensitive species, which in turn can disrupt the entire aquatic food chain.If there is an important release of acrylic acid tridecyl ester into a small body of water, it could lead a decline in sensitive species which can disrupt the entire aquatic ecosystem.

Regarding the soil environment, when it reaches the soil, it may interact with soil components.When it reaches soil, it can interact with soil components. It could potentially affect soil microorganisms that play crucial roles in nutrient cycling, decomposition of organic matter, and soil structure maintenance.It could potentially affect soil bacteria that play a crucial role in nutrient cycles, decomposition organic matter and soil structure maintenance. If the compound inhibits the activity of these microorganisms, it can have long - term consequences for soil fertility and the overall health of the terrestrial ecosystem.If the compound inhibits these microorganisms' activity, it can have long-term consequences for soil fertility as well as the health of the terrestrial eco system.

In the atmosphere, if acrylic acid tridecyl ester is volatile, it can contribute to air pollution.If acrylic acid tridecyl ester is volatile in the atmosphere, it can contribute air pollution. Once in the air, it may participate in chemical reactions, potentially forming secondary pollutants.Once in the atmosphere, it can participate in chemical reactions that could lead to secondary pollutants. For instance, in the presence of sunlight and other pollutants like nitrogen oxides, it could be involved in the formation of photochemical smog components, which can have negative impacts on air quality and human health.In the presence of sunlight, other pollutants such as nitrogen oxides and other pollutants, it may be involved in forming photochemical smog component, which can negatively impact air quality and human well-being.

However, it's important to note that the actual environmental harm depends on factors such as the amount released, the rate of degradation, and the environmental conditions.It's important to remember that the actual harm to the environment depends on factors like the amount released, degradation rate, and environmental conditions. If the compound is rapidly degraded in the environment through processes like biodegradation, photodegradation, or hydrolysis, its long - term harmful effects may be mitigated.The long-term harmful effects of the compound may be reduced if it is degraded rapidly in the environment by processes such as photodegradation or hydrolysis. But without proper management and control of its release, acrylic acid tridecyl ester has the potential to cause harm to the environment across different compartments.Acrylic acid tridecyl ester can harm the environment in different compartments if it is not managed and controlled properly.

What safety precautions should be taken when handling acrylic acid tridecyl ester?

Acrylic acid tridecyl ester is a chemical compound that requires certain safety precautions during handling to protect the health of individuals and prevent environmental damage.Acrylic acid tridecyl ester is a chemical compound which requires special precautions to be taken when handling it. This is done to protect the environment and people's health.
First, personal protective equipment is essential.Wearing appropriate chemical-resistant gloves is a must. Wear appropriate chemical - resistant gloves, preferably made of materials like nitrile or neoprene.Wear gloves that are resistant to chemicals, preferably made from nitrile or Neoprene. These gloves can prevent skin contact, which may lead to skin irritation or absorption of the chemical into the body.These gloves prevent skin contact that could lead to irritation or absorption into the body. Additionally, goggles or a full - face shield should be worn to safeguard the eyes.Goggles or a face shield with a full-face shield can also be worn to protect the eyes. Inhalation of acrylic acid tridecyl ester vapors can be harmful, so use respiratory protection.Respiratory protection is recommended to avoid inhaling acrylic acid tridecyl ester vapors. A respirator with an appropriate filter for organic vapors should be used, especially in areas with poor ventilation or when there is a risk of high - concentration exposure.Use a respirator with a filter that is suitable for organic vapors, especially when the area has poor ventilation or there is a high-concentration exposure risk.

Second, ensure proper ventilation. Work in a well - ventilated area, such as a fume hood if available.If possible, work in an area that is well-ventilated. Good ventilation helps to disperse any vapors that may be released during handling, reducing the risk of inhalation.Good ventilation will help disperse vapors released during handling and reduce the risk of inhalation. If working in an open - air environment, make sure there is sufficient air movement to carry away the vapors.If you are working in an open-air environment, ensure that there is enough air movement to remove the vapors.

Third, be careful during storage.Third, take care when storing. Store acrylic acid tridecyl ester in a cool, dry place away from heat sources, open flames, and oxidizing agents.Store acrylic acid tridecyl ester in a cool and dry place, away from heat sources, flames, or oxidizing agents. It is a flammable substance, and heat or contact with oxidizers can initiate a fire or explosion.Heat or contact with oxidizers may cause an explosion or fire. Keep it in a tightly sealed container to prevent leakage and evaporation.Keep it in an airtight container to prevent leaking and evaporation.

Fourth, in case of spills, act quickly and appropriately.In the event of spills, you should act quickly and appropriately. First, evacuate the area to prevent exposure of others.First, evacuate the affected area to avoid exposing others. Then, use absorbent materials like vermiculite or sand to soak up the spilled liquid.Use absorbent materials such as vermiculite, sand or a combination of both to soak up spilled liquid. Avoid using water directly on the spill as it may spread the chemical.Avoid using water on the spill, as it can spread the chemical. Dispose of the contaminated absorbent materials in accordance with local regulations.Dispose of contaminated absorbent material in accordance with local regulations.

Finally, have emergency procedures in place.Last but not least, you should have emergency procedures in place. Know the location of safety showers and eyewash stations in case of skin or eye contact.In the event of skin or eye contact, know where to find safety showers and stations for eyewashing. In case of ingestion or inhalation, seek immediate medical attention.Seek immediate medical attention in the event of ingestion or breathing. Provide the medical staff with information about the chemical to ensure proper treatment.To ensure proper treatment, provide the medical staff with information on the chemical.