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Product Name | Benzyl methacrylate |
Cas Number | 2495-37-6 |
Formula | C11H12O2 |
Molar Mass | 176.21 |
Density | 1.045 g/cm³ |
Boiling Point | 235 °C |
Melting Point | N/A |
Flash Point | 94 °C |
Refractive Index | 1.514 |
Solubility | Insoluble in water |
Vapor Pressure | 0.02 mmHg at 25°C |
Viscosity | N/A |
Appearance | Colorless liquid |
Odor | Ester-like |
What are the main applications of benzyl methacrylate?
Benzyl methacrylate is an important monomer with several main applications.Benzyl Methacrylate is a monomer that has many applications.
One of the significant uses is in the field of coatings.Coatings is one of its most important uses. It can be polymerized to form hard and durable films.It can be polymerized into hard and durable films. In automotive coatings, benzyl methacrylate - based polymers contribute to the high - gloss finish and good scratch - resistance of car paint.In automotive paints, benzyl - methacrylate-based polymers are responsible for the high gloss and scratch resistance. The addition of benzyl methacrylate monomers helps to improve the mechanical properties of the coating, such as hardness and abrasion resistance.The addition of monomers based on benzyl-methacrylate helps improve the mechanical properties of coatings, such as their hardness and resistance to abrasion. This ensures that the car's exterior remains attractive and protected from environmental factors like sunlight, rain, and minor impacts.This helps to protect the exterior of the car from harmful environmental factors such as sunlight, rain and minor impacts. In industrial coatings, it is used to coat machinery and equipment.In industrial coatings it is used for machinery and equipment. The resulting coatings not only provide protection against corrosion but also enhance the aesthetic appearance of the products.The coatings that are produced not only protect against corrosion, but also improve the aesthetic appeal of the products.
In the production of adhesives, benzyl methacrylate plays a crucial role.The production of adhesives is a key process. It can be incorporated into adhesive formulations to improve their adhesion strength, especially to substrates like metals, plastics, and ceramics.It can be added to adhesive formulations to increase their adhesion strength to substrates such as metals, ceramics, and plastics. For example, in the assembly of electronic devices, adhesives containing benzyl methacrylate are used to bond components.In the assembly of electronic devices for example, adhesives that contain benzylmethacrylate are used. The monomer helps the adhesive to form a strong bond, ensuring the reliability and long - term stability of the electronic products.Monomer helps the adhesive form a strong bond and ensures the reliability and stability of electronic products. In the construction industry, adhesives with benzyl methacrylate are used for bonding building materials, such as laminating different types of sheets or fixing decorative elements.In the construction industry adhesives containing benzylmethacrylate are used to bond building materials such as laminating sheets of different types or fixing decorative elements.
Benzyl methacrylate is also widely used in the synthesis of polymers for optical applications.Benzylmethacrylate is widely used to synthesize polymers for optical purposes. Polymers made from this monomer often have good transparency, which makes them suitable for manufacturing optical lenses, light - guiding plates, and optical fibers.This monomer is used to make polymers that are transparent, making them ideal for optical lenses, light-guiding plates, and fibers. In the production of optical lenses, the properties of benzyl methacrylate - based polymers can be adjusted to control factors like refractive index and dispersion, providing high - quality vision correction solutions.The properties of benzyl-methacrylate-based polymers are adjustable to control factors such as refractive index and diffusion, providing high-quality vision correction solutions. For light - guiding plates in liquid crystal displays (LCDs), the monomer helps to create materials that can efficiently guide light, improving the brightness and uniformity of the display.Monomer is used to create materials for light-guiding plates in LCDs. This improves the brightness and uniformity.
In addition, it is used in the production of dental materials.It is also used to produce dental materials. Dental composites, which are used for filling cavities, often contain benzyl methacrylate.Benzyl methacrylate is often used in dental composites that are used to fill cavities. It helps in the polymerization process of the composite, forming a hard and durable material that can withstand the mechanical forces during chewing.It is used to polymerize the composite material, making it durable and hard. The biocompatibility of benzyl methacrylate - based polymers also makes them suitable for use in the oral cavity.Biocompatibility makes benzyl-methacrylate-based polymers suitable for use in the mouth.
What are the physical and chemical properties of benzyl methacrylate?
Benzyl methacrylate is an organic compound with the following physical and chemical properties:The organic compound benzyl methacrylate has the following physical and chemistry properties:
Physical properties:Physical Properties
Appearance: Benzyl methacrylate is typically a colorless to slightly yellow liquid.Appearance: Benzyl Methacrylate is a clear liquid that can be colorless or slightly yellow. This clear - liquid state makes it easy to handle and observe in various applications.This clear liquid state makes it easier to handle and observe.
Odor: It has a characteristic, pleasant - smelling odor.Odor: It emits a pleasant, characteristic odor. However, like many organic compounds, at high concentrations, the odor can be quite pungent and may cause discomfort to the respiratory system.Like many organic compounds, the odor is quite pungent at high concentrations and can cause respiratory discomfort.
Boiling point: The boiling point of benzyl methacrylate is relatively high.The boiling point of benzylmethacrylate is relatively low. This property is important in processes such as distillation for purification or in formulating products where heat - stability during processing is required.This property is important for processes such as distillation or formulating products that require heat stability during processing. The high boiling point indicates strong intermolecular forces within the compound.The high boiling point indicates that there are strong intermolecular interactions within the compound.
Melting point: It has a low melting point, remaining in a liquid state under normal ambient conditions.Melting point: It is a low melting temperature, and remains liquid under normal ambient conditions. This liquidity allows for easy mixing with other substances in solution - based applications.This liquidity allows for easy mixing in solution-based applications.
Density: Benzyl methacrylate has a certain density, which is close to that of water but slightly higher.Density: Benzylmethacrylate is a dense material, similar to water but slightly more so. Density is a crucial property when it comes to formulating mixtures, as it affects the volumetric and mass - based ratios of components in a formulation.When formulating mixtures density is an important property, as it impacts the volumetric and mass-based ratios between components.
Solubility: It is sparingly soluble in water due to its non - polar nature.Due to its non-polar nature, it is only sparingly soluble. However, it is highly soluble in many organic solvents such as alcohols, esters, and aromatic hydrocarbons.It is highly soluble, however, in many organic solvents, such as alcohols and esters. This solubility behavior enables it to be used in a wide range of organic - based formulations.This solubility allows it to be used with a wide variety of organic-based formulations.
Chemical properties:Chemical properties
Polymerization: One of the most significant chemical properties of benzyl methacrylate is its ability to undergo polymerization.Polymerization is one of the most important chemical properties of benzylmethacrylate. It contains a vinyl group (C = C double bond), which can be initiated by heat, light, or chemical initiators.It contains a double-bond vinyl group (C=C) that can be initiated either by heat, light or chemical initiators. Polymerization leads to the formation of polymers with various applications, such as in coatings, adhesives, and plastics.Polymerization results in the formation of polymers that have many applications, including coatings, adhesives and plastics. The resulting polymers often have good hardness, abrasion resistance, and optical clarity.The polymers that result are often hard, abrasion resistant, and have excellent optical clarity.
Reactivity with nucleophiles: The carbonyl group (C = O) in the methacrylate part of the molecule can react with nucleophiles.Reactivity with nucleophiles. The carbonyl group in the methacrylate portion of the molecule (C = O), can react with nucleophiles. For example, amines or alcohols can react with benzyl methacrylate under appropriate conditions, leading to the formation of new chemical compounds.Under the right conditions, benzyl-methacrylate can react with amines or alcohols to form new chemical compounds. These reactions can be used to modify the properties of the molecule or to incorporate it into more complex chemical structures.These reactions can be used either to modify the molecule's properties or to incorporate it in more complex chemical structures.
Hydrolysis: In the presence of water and an appropriate catalyst (such as an acid or a base), benzyl methacrylate can undergo hydrolysis.Hydrolysis: In presence of water, and a suitable catalyst (such an acid or base), benzylmethacrylate undergoes hydrolysis. The ester bond in the molecule is cleaved, producing benzyl alcohol and methacrylic acid.The ester bond is cleaved in the molecule, resulting in benzyl acid and benzyl ethanol. This hydrolysis reaction is important to consider in environmental and storage conditions where exposure to moisture may occur.This hydrolysis reaction should be considered in storage and environmental conditions where moisture exposure may occur.
Oxidation: It can potentially be oxidized under certain conditions.Oxidation is possible under certain conditions. Oxidation may lead to the formation of carbonyl - containing by - products, which can affect the quality and performance of products containing benzyl methacrylate.Oxidation can lead to carbonyl-containing by-products, which can have a negative impact on the quality and performance. Understanding its oxidation behavior is essential for ensuring product stability over time.Understanding its oxidation behaviour is essential to ensure product stability over time.
How is benzyl methacrylate synthesized?
Benzyl methacrylate can be synthesized through the following general approach:The following general approach can be used to synthesize Benzyl Methacrylate:
1. Starting Materials Preparation
The synthesis of benzyl methacrylate typically involves two main starting materials - benzyl alcohol and methacrylic acid.Benzyl alcohol and Methacrylic Acid are the two main materials used in the synthesis of benzylmethacrylate. Benzyl alcohol is an aromatic alcohol with a phenyl group attached to a hydroxymethyl group.Benzyl is an aromatic alcohol that has a phenyl attached to a group of hydroxymethyl. Methacrylic acid has a double - bond and a carboxyl group, which are crucial for the formation of the ester bond and the unsaturated nature of the final product.Methacrylic Acid has a double-bond and a carboxyl, which are essential for the formation and unsaturated nature the final product. These starting materials should be of high purity to ensure a good - quality synthesis.These starting materials must be high-purity to ensure a high-quality synthesis.
2. Esterification Reaction
The core reaction for synthesizing benzyl methacrylate is the esterification between benzyl alcohol and methacrylic acid.Esterification of benzyl alcohol and methacrylic acids is the core reaction in synthesizing benzylmethacrylate. This reaction is usually catalyzed by an acid catalyst.This reaction is normally catalyzed with an acid catalyst. Sulfuric acid or p - toluenesulfonic acid are common catalysts used in this process.This process is commonly catalyzed by sulfuric acid or p-toluenesulfonic acids. The reaction can be represented by the chemical equation:The chemical equation can be used to represent the reaction:
Benzyl alcohol + Methacrylic acid = Benzyl methacrylate + WaterBenzyl Alcohol + Methacrylic Acid = Benzyl Methacrylate + water
The reaction is an equilibrium reaction.The reaction is an equilibrium. To drive the reaction forward and increase the yield of benzyl methacrylate, several strategies can be employed.Several strategies can be used to accelerate the reaction and increase the yield. One common method is to remove the water formed during the reaction.One common method to remove water formed during the reactions is to use a Dean-Stark apparatus. This can be achieved by using a Dean - Stark apparatus, which allows the continuous separation of water from the reaction mixture.The Dean-Stark apparatus can be used to separate water continuously from the reaction mixture. Another approach is to use an excess of one of the starting materials, usually benzyl alcohol or methacrylic acid, to shift the equilibrium towards the product side according to Le Chatelier's principle.A second approach is to use excess of one of your starting materials, such as benzyl or methacrylic acids, to shift equilibrium to the product side, according to Le Chatelier’s principle.
3. Reaction ConditionsReaction Conditions
The reaction is usually carried out under reflux conditions.Reactions are usually carried out in reflux conditions. Refluxing ensures that the reaction mixture is maintained at a constant temperature, which is typically around the boiling point of the reaction mixture.Refluxing maintains the reaction mixture at a constant temperature. This is usually around the boiling point. The reaction temperature is important as it affects the reaction rate.The reaction rate is affected by the temperature of the reaction mixture. A higher temperature generally increases the reaction rate, but it also needs to be carefully controlled to avoid side - reactions such as polymerization of the methacrylic acid or decomposition of the reactants or products.A higher temperature will increase the reaction rate. However, it is important to control the temperature to avoid side reactions like polymerization of methacrylic acids or decompositions of the reactants and products. The reaction time can vary depending on factors like the catalyst concentration, temperature, and the ratio of reactants, but it usually ranges from several hours to overnight.The reaction time depends on factors such as the catalyst concentration, the temperature, and the ratio between reactants. It can range from several hours up to overnight.
4. Product Isolation and PurificationProduct Isolation & Purification
After the reaction is complete, the reaction mixture contains the desired benzyl methacrylate, unreacted starting materials, catalyst, and water.The reaction mixture will contain the desired benzylmethacrylate, unreacted materials, catalyst and water. First, the catalyst needs to be neutralized.The catalyst must first be neutralized. This can be done by adding a base such as sodium carbonate or sodium hydroxide.This can be achieved by adding a base, such as sodium hydroxide or sodium carbonate. Then, the mixture is usually extracted with an organic solvent like diethyl ether or dichloromethane to separate the organic products from the aqueous layer.The mixture is then extracted with an organic solvent such as dichloromethane or diethylether to separate the organic product from the aqueous phase. The organic layer containing benzyl methacrylate is then dried over anhydrous sodium sulfate or magnesium sulfate to remove any remaining water.The organic layer containing the benzyl methylacrylate is dried over anhydrous magnesium sulfate, or sodium sulfate. This removes any remaining water. Finally, the solvent is removed by distillation under reduced pressure.The solvent is then removed using reduced pressure distillation. The benzyl methacrylate product can be further purified by techniques such as fractional distillation to obtain a high - purity product suitable for various applications like in the production of polymers and coatings.Fractional distillation can be used to further purify the benzyl-methacrylate product. This will produce a high-purity product that is suitable for various applications, such as in the production polymers and coatings.
What are the safety precautions when handling benzyl methacrylate?
Benzyl methacrylate is a chemical compound that requires certain safety precautions when being handled.When handling Benzyl Methacrylate, certain safety precautions are required.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Always wear appropriate respiratory protection.Always wear the appropriate respiratory protection. Since benzyl methacrylate may release vapors, a respirator with the right cartridge type can prevent inhalation of harmful fumes.A respirator with the correct cartridge type will prevent inhalation. For eye protection, chemical - splash goggles are essential.Chemical splash goggles provide eye protection. These goggles can shield the eyes from any splashes of benzyl methacrylate, which could cause serious eye irritation or damage.These goggles protect the eyes from any benzyl-methacrylate splashes that could cause serious eye irritation. In addition, protective gloves made of materials resistant to benzyl methacrylate, such as nitrile gloves, should be worn.Wearing protective gloves made from materials resistant to benzylmethacrylate such as nitrile is also recommended. This can prevent skin contact, as direct contact can lead to skin irritation and potential absorption into the body.This will prevent skin contact as direct skin contact can cause skin irritation and absorption into the system.
Second, when it comes to the handling environment.The second is the handling environment. Ensure good ventilation in the work area.Assure good ventilation in your work area. Adequate ventilation helps to disperse any vapors that may be released during handling, reducing the concentration of benzyl methacrylate in the air and thus minimizing the risk of inhalation.Adequate ventilation will help disperse any vapors released during handling. This will reduce the concentration of benzylmethacrylate in air and minimize the risk of inhalation. If possible, handle benzyl methacrylate in a fume hood.Handle benzyl methylacrylate under a fume-hood if possible. A fume hood can effectively capture and exhaust the vapors, providing an additional layer of protection.A fume hood will effectively capture and exhaust benzyl methacrylate vapors. This provides an additional layer of safety.
Third, in terms of storage.Third, storage. Store benzyl methacrylate in a cool, dry place away from sources of heat, sparks, and open flames.Store benzylmethacrylate in an area that is cool and dry, away from heat sources, sparks, or open flames. It is flammable, so any ignition source can pose a significant fire risk.It is flammable and any ignition source could pose a fire risk. Keep it in a tightly - sealed container to prevent leakage and evaporation.Store it in a tightly-sealed container to prevent leaking and evaporation. Also, store it separately from oxidizing agents and strong acids or bases, as it may react with these substances, potentially leading to dangerous chemical reactions.Store it away from strong acids and oxidizing agents. It may react with them, resulting in dangerous chemical reactions.
Fourth, in case of accidental exposure.Fourth, in the event of accidental exposure. If benzyl methacrylate comes into contact with the skin, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If benzylmethacrylate is in contact with your skin, wash it immediately with soap and water. Seek medical attention if irritation persists. In case of eye contact, rinse the eyes thoroughly with water for at least 15 minutes, lifting the eyelids occasionally.If you have had eye contact, rinse your eyes with water for 15 minutes at least, lifting your eyelids periodically. Get immediate medical help.Get immediate medical attention. If inhaled, move to an area with fresh air immediately.If inhaled, immediately move to a place with fresh air. If the person is not breathing, perform CPR if trained to do so and call for emergency medical services.If the person does not breathe, perform CPR on them if you are trained to do so. Call emergency medical services.
Finally, when disposing of benzyl methacrylate or any waste containing it, follow all local, state, and federal regulations.Follow all local, state and federal regulations when disposing of benzylmethacrylate, or any waste that contains it. Do not pour it down the drain or discard it in regular trash, as it can be harmful to the environment.Do not dispose of it in the regular trash or down the drain. It can be harmful to the environmental.
What are the storage requirements for benzyl methacrylate?
Benzyl methacrylate is a monomer commonly used in the production of polymers, coatings, and adhesives.Benzyl Methacrylate is used as a monomer in the production polymers, adhesives, and coatings. It has specific storage requirements to ensure its stability, safety, and quality.It has specific requirements for storage to ensure its quality, safety, and stability. Here are the key storage considerations for benzyl methacrylate.Here are some key storage considerations when it comes to benzylmethacrylate.
First, it should be stored in a cool and well - ventilated area.It should be kept in a cool, well-ventilated area. The recommended storage temperature is typically between 2 - 8degC.Storage temperatures are typically between 2 and 8degC. Higher temperatures can accelerate polymerization reactions, leading to the formation of lumps or gels in the benzyl methacrylate.Higher temperatures can speed up polymerization reactions and cause benzyl-methacrylate to form lumps or gels. If the temperature rises too much, the monomer may self - polymerize, which not only ruins the product but can also pose a safety hazard due to the exothermic nature of the polymerization process.If the temperature increases too much, monomer can self-polymerize. This not only damages the product, but also poses a safety risk due to the exothermic nature.
Second, benzyl methacrylate should be protected from light.Second, benzylmethacrylate must be protected from the light. Ultraviolet (UV) light can initiate free - radical polymerization reactions.UV light can initiate polymerization reactions that are free-radical. Therefore, it is best stored in opaque containers or in areas where it is shielded from direct sunlight.It is therefore best to store it in opaque containers, or in an area that is shielded against direct sunlight. Translucent or clear containers should be avoided unless they are specifically designed to block UV light.Translucent and clear containers should not be used unless they have been specifically designed to block ultraviolet light.
Third, storage containers for benzyl methacrylate must be tightly sealed.Third, containers for benzylmethacrylate should be tightly sealed. Exposure to air can lead to the absorption of moisture, which may cause hydrolysis reactions.The absorption of moisture by air exposure can cause hydrolysis reactions. Moisture can also introduce oxygen into the monomer, and oxygen can act as an inhibitor in small amounts but may also react with benzyl methacrylate over time, leading to the formation of peroxides.Moisture may also introduce oxygen to the monomer. Oxygen can act as a small inhibitor, but over time it can react with benzylmethacrylate, forming peroxides. These peroxides can be highly reactive and increase the risk of polymerization.These peroxides are highly reactive and can increase the risk of polymerization. A tightly sealed container also prevents the evaporation of benzyl methacrylate, which has a relatively high vapor pressure.A tightly sealed container will also prevent the evaporation benzyl methylacrylate which has a high vapor pressure. Evaporation not only results in product loss but can also create a flammable vapor cloud in the storage area.Evaporation can result in product loss, but it can also create a flammable cloud of vapor in the storage area.
Fourth, the storage area should be away from sources of ignition and incompatible substances.Fourth, the storage area must be away from ignition sources and incompatible substances. Benzyl methacrylate is flammable, and its vapors can form explosive mixtures with air.Benzyl Methacrylate is flammable and its vapors may form explosive mixtures when mixed with air. Substances such as strong oxidizing agents, acids, and bases should be stored separately from benzyl methacrylate as they can react violently with it, potentially leading to fires, explosions, or the formation of unwanted by - products.Store benzyl methylacrylate separately from strong oxidizing agents and acids. They can react violently, causing fires, explosions or the formation unwanted by-products.
Finally, proper labeling and inventory management are crucial.Labeling and inventory management is also crucial. The storage containers should be clearly labeled with the name of the substance, its hazard warnings, and the date of receipt or manufacture.Storage containers should clearly display the name of the substance and any warnings about its hazards, as well as the date of manufacture or receipt. Regular inventory checks should be carried out to ensure that the stock is used in a timely manner and that any signs of degradation or improper storage are detected early.Regular inventory checks are necessary to ensure that stock is used quickly and that signs of degradation or improper storing are detected early. This helps in maintaining the quality of benzyl methacrylate and preventing potential safety incidents.This helps to maintain the quality of benzylmethacrylate, and prevents potential safety incidents.