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Product Name | Methacrylic acid benzyl ester |
Cas Number | 2495-37-6 |
Formula | C11H12O2 |
Molar Mass | 176.21 |
Density | 1.064 g/cm³ |
Boiling Point | 238-240 °C |
Melting Point | -20 °C |
Flash Point | 104 °C |
Refractive Index | 1.536 |
Vapor Pressure | 0.0199 mmHg at 25 °C |
Appearance | Clear liquid |
Solubility In Water | Insoluble |
Viscosity | Not available |
Heat Capacity | Not available |
Logp | 3.13 |
What are the main applications of methacrylic acid benzyl ester?
Methacrylic acid benzyl ester has several main applications.The main applications of benzyl esters of methacrylic acid include:
One significant application is in the field of coatings.Coatings are a significant application. It can be used as a monomer in the synthesis of high - performance coating resins.It can be used to synthesize high-performance coating resins. When incorporated into coatings, it imparts good hardness, abrasion resistance, and chemical resistance.It imparts hardness, abrasion and chemical resistance to coatings when incorporated. For example, in automotive coatings, the use of methacrylic acid benzyl ester - based resins can enhance the durability of the paint finish, protecting the vehicle's body from scratches, weathering, and chemical corrosion.In automotive coatings, for example, the use methacrylic ester-based resins can increase the durability of the finish and protect the vehicle's surface from scratches, weathering and chemical corrosion. The benzyl group in the molecule can contribute to the formation of a dense and cross - linked structure, improving the overall performance of the coating film.The benzyl group can contribute to a dense, cross-linked structure that improves the overall performance of the film.
In the area of adhesives, methacrylic acid benzyl ester plays an important role.The methacrylic benzyl ester plays a major role in the field of adhesives. It can be copolymerized with other monomers to create adhesive polymers with excellent adhesion properties.It can be copolymerized to create adhesive polymers that have excellent adhesion. These adhesives can bond well to a variety of substrates, including metals, plastics, and glass.These adhesives are able to bond well with a variety substrates including metals and plastics. In the assembly of electronic devices, such adhesives are often used to attach components.These adhesives are used to attach electronic components during the assembly process. The presence of the methacrylic acid benzyl ester helps to ensure a strong and long - lasting bond, which is crucial for the reliable operation of the device.The presence of methacrylic acids benzyl esters helps to ensure that the device will operate reliably.
It is also utilized in the production of polymers for optical applications.It is also used in the production polymers for optical applications. Polymers derived from methacrylic acid benzyl ester can have good optical clarity.The polymers made from methacrylic acids benzyl esters can be very clear. They can be used to make optical lenses, optical fibers, and other optical components.They can be used for optical lenses, fibers, and many other optical components. The high refractive index and low birefringence of these polymers make them suitable for applications where light transmission and image quality are important.These polymers are suitable for applications that require high light transmission and good image quality. They have a low birefringence and a high refractive indices. For instance, in ophthalmic lenses, the use of such polymers can provide clear vision while also being lightweight and durable.These polymers are ideal for ophthalmic lenses because they provide clear vision and are lightweight and durable.
In addition, methacrylic acid benzyl ester is used in the synthesis of specialty polymers for biomedical applications.The methacrylic ester is also used to synthesize specialty polymers that are used in biomedical applications. Some of these polymers can be designed to be biocompatible.Some of these polymers are biocompatible. They can be used in drug delivery systems, where the polymer can encapsulate drugs and release them in a controlled manner.They can be used as drug delivery systems where the polymer can encapsulate and release drugs in a controlled way. The unique chemical structure of methacrylic acid benzyl ester allows for modification and functionalization, enabling the development of polymers with specific properties required for biomedical use.The unique chemical structure allows for modification and functionality, enabling polymers to have specific properties for biomedical applications. Overall, its diverse applications make methacrylic acid benzyl ester an important chemical in various industries.Methacrylic acid is a versatile chemical that has many applications.
What are the properties of methacrylic acid benzyl ester?
Methacrylic acid benzyl ester is an important organic compound with several notable properties.The benzyl ester of methacrylic acid is a compound that has many notable properties.
Physical properties:Physical Properties
In terms of appearance, it is typically a colorless to slightly yellow liquid.It is usually a colorless or slightly yellow liquid. It has a characteristic odor.It has a distinctive odor. It is insoluble in water but soluble in many organic solvents such as ethanol, ether, and chloroform.It is not soluble in water, but it is soluble in a variety of organic solvents, such as ethanol and chloroform. This solubility in organic solvents makes it useful in various organic synthesis and formulation processes where homogeneous mixtures with other organic substances are required.Its solubility in organic compounds makes it useful for various organic synthesis processes and formulations where homogeneous mixes with other organic substances is required.
The boiling point of methacrylic acid benzyl ester is relatively high.The boiling point of benzyl esters of methacrylic acids is relatively high. This property is related to the strength of the intermolecular forces in the compound.This property is a function of the strength of intermolecular forces within the compound. The presence of the benzyl group and the ester functional group contribute to the overall molecular interactions, resulting in a boiling point that allows it to remain in the liquid state under normal ambient conditions but also makes it possible to separate it from other components in a mixture through distillation processes at appropriate temperatures.The benzyl and ester functional groups contribute to the overall molecular interaction, resulting in an elevated boiling point. This allows the compound to remain liquid under normal ambient conditions. It also makes it possible to separate the compound from other components of a mixture using distillation processes.
Chemical properties:Chemical properties
The double bond in the methacrylic acid part of the molecule endows it with high reactivity towards addition reactions.The double bond in methacrylic acids part of the molecule gives it a high reactivity to addition reactions. It can participate in polymerization reactions, either by itself to form homopolymers or with other monomers to form copolymers.It can be used in polymerization reactions either alone to form homopolymers, or with other monomers for copolymers. For example, it can react with other acrylic monomers in a free - radical polymerization process.It can, for example, react with other acrylic monomers during a free-radical polymerization. The resulting polymers often have good mechanical properties, chemical resistance, and optical clarity.The polymers that result often have excellent mechanical properties, chemical resistance and optical clarity. The benzyl group attached to the ester also has its own reactivity.The benzyl group that is attached to the ester has its own reactivity. The aromatic ring can undergo electrophilic substitution reactions under appropriate conditions, which can be used to further modify the structure of the molecule and introduce new functional groups.Under the right conditions, the aromatic ring can undergo electrophilic substitute reactions. This can be used to further modify a molecule's structure and introduce new functional group. This provides opportunities for the synthesis of more complex and specialized organic compounds.This opens up the possibility of synthesising more complex and specialized compounds.
The ester functional group in methacrylic acid benzyl ester is subject to hydrolysis reactions.Hydrolysis reactions can occur in the ester functional group of methacrylic acid-benzyl esters. In the presence of water and an appropriate catalyst, such as an acid or a base, the ester bond can be broken, leading to the formation of methacrylic acid and benzyl alcohol.In the presence water and an appropriate catalyser, such as an base or acid, the ester bonds can be broken. This leads to the formation methacrylic alcohol and benzyl acid. This hydrolysis property needs to be considered during storage and handling, especially in environments where moisture is present.This hydrolysis property should be considered when handling and storing the product, especially in environments with moisture. However, it can also be exploited in certain chemical processes for the controlled breakdown of the compound or the synthesis of its components.It can also be used in certain chemical reactions to control the breakdown of the compound, or synthesise its components.
Overall, these physical and chemical properties make methacrylic acid benzyl ester a valuable building block in the fields of polymer chemistry, coatings, adhesives, and organic synthesis.Overall, methacrylic ester is a valuable building material in the fields such as polymer chemistry and coatings.
How is methacrylic acid benzyl ester synthesized?
Methacrylic acid benzyl ester can be synthesized through the following common methods:The following common methods can be used to synthesize methacrylic acid-benzyl ester:
Esterification reaction
One typical approach is the direct esterification of methacrylic acid with benzyl alcohol.Direct esterification of benzyl Alcohol with methacrylic Acid is a typical method. In this process, an acid - catalyst is usually required.In this process, a catalyst - acid is usually needed. Sulfuric acid is a common choice.Sulfuric is a popular choice. The reaction mechanism involves the protonation of the carbonyl oxygen in methacrylic acid by the acidic catalyst.The acidic catalyst is responsible for protonating the carbonyl oxygen within methacrylic acids. This enhances the electrophilicity of the carbonyl carbon.This increases the electrophilicity. Then, the hydroxyl group of benzyl alcohol attacks the carbonyl carbon, forming a tetrahedral intermediate.The hydroxyl group from benzyl is then attacked by the carbonyl to form a tetrahedral intermediary. Subsequently, a series of proton - transfer steps occur, and finally, water is eliminated to form methacrylic acid benzyl ester.Then, a series proton-transfer steps are performed, and finally water is removed to form the methacrylic ester benzyl acid.
For example, in a reaction flask, appropriate amounts of methacrylic acid and benzyl alcohol are added in a certain molar ratio, usually with a slight excess of benzyl alcohol to drive the reaction forward according to Le Chatelier's principle.In a reaction flask for example, a certain amount of methacrylic and benzyl is added in a molar proportion, usually with an excess of benzyl to accelerate the reaction according to Le Chatelier’s principle. After adding the sulfuric acid catalyst, the reaction mixture is heated under reflux.The reaction mixture is heated in reflux after adding the sulfuric catalyst. A condenser is attached to the flask to prevent the loss of volatile reactants and products.The flask is fitted with a condenser to prevent the loss or volatile products and reactants. The reaction temperature is typically around 80 - 120 degC, depending on the reaction scale and the specific reaction conditions.The reaction temperature ranges between 80 and 120 degC depending on the scale of the reaction and the specific conditions. During the reaction, water is produced as a by - product.Water is produced during the reaction. To shift the equilibrium towards the formation of the ester, water can be removed continuously, for instance, by using a Dean - Stark apparatus.Water can be continuously removed, for example, using a Dean-Stark apparatus, to shift the equilibrium in favor of the ester. After the reaction is considered complete as determined by methods such as thin - layer chromatography (TLC), the reaction mixture is cooled.The reaction mixture is cooled after the reaction has been determined to be complete by thin-layer chromatography. Then, it is neutralized with a base, such as sodium carbonate solution, to remove the acidic catalyst.It is then neutralized with a base such as sodium carbonate to remove the acidic catalyst. The organic layer containing the methacrylic acid benzyl ester is separated, washed with water to remove any remaining salts, and finally dried over anhydrous magnesium sulfate or sodium sulfate.The organic layer that contains the methacrylic ester is separated and washed in water to remove any salts. It is then dried over anhydrous sodium or magnesium sulfate. The product can be further purified by distillation under reduced pressure to obtain pure methacrylic acid benzyl ester.The product can then be purified further by distillation at reduced pressure in order to obtain pure methacrylic ester.
Transesterification reaction
Another way is through transesterification.Transesterification is another way. Methyl methacrylate can be reacted with benzyl alcohol in the presence of a catalyst, such as a metal alkoxide.In the presence of a metal alkoxide catalyst, methyl methacrylate and benzyl alcohol can be reacted. The alkoxide catalyst promotes the exchange of the alkoxy groups.The alkoxide catalyzes the exchange of alkoxy groups. The methyl group in methyl methacrylate is replaced by the benzyl group from benzyl alcohol.The benzyl group of benzyl is substituted for the methyl group found in methyl methacrylate. Similar to the esterification reaction, after the reaction, the product needs to be purified through processes like neutralization, washing, drying, and distillation to obtain pure methacrylic acid benzyl ester.After the esterification, the product must be purified by neutralization, washing and drying.
What are the safety precautions when handling methacrylic acid benzyl ester?
Methacrylic acid benzyl ester is a chemical compound that requires careful handling due to certain safety risks.Due to safety risks, it is important to handle this chemical compound with care. Here are the safety precautions:Here are some safety precautions.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain degree of protection against contact with methacrylic acid benzyl ester.Nitrile gloves can offer some protection against methacrylic acids benzyl esters. This helps prevent skin absorption, which could lead to skin irritation, allergic reactions, or more serious health issues.This prevents skin absorption that could cause skin irritation, allergies, or other serious health issues. Additionally, wear safety goggles or a face shield.Wear safety goggles, or a face shield. The eyes are extremely sensitive, and splashes of this chemical can cause severe eye damage, including corneal burns and vision impairment.Splashes of this chemical may cause corneal burns or vision impairment. The eyes are very sensitive. A full - body chemical - resistant suit may be necessary in situations where there is a high risk of large - scale spills or splashes.In situations where there is high risk of large-scale spills or splashes, a full-body chemical-resistant suit may be required.
Second, ventilation is crucial.Second, ventilation is essential. Handle methacrylic acid benzyl ester in a well - ventilated area, preferably under a fume hood.Handle methacrylic acids benzyl esters in a well-ventilated area, preferably beneath a fume hood. This chemical may release vapors, which if inhaled, can irritate the respiratory tract, causing coughing, shortness of breath, and in severe cases, more serious lung problems.Inhaling vapors from this chemical can cause irritation of the respiratory tract. This can lead to coughing, shortness breath, or in more severe cases, serious lung problems. A fume hood effectively captures and exhausts these vapors, reducing the concentration in the breathing zone.A fume hood captures and exhausts the vapors, which reduces the concentration of these vapors in the breathing area.
Third, when it comes to storage.Third, storage. Store methacrylic acid benzyl ester in a cool, dry place away from sources of heat and ignition.Store methacrylic acids benzyl esters in a cool and dry place, away from heat sources and ignition. It is flammable, so keep it away from open flames, hot surfaces, and any potential ignition sources such as electrical equipment with exposed contacts.It is flammable so keep it away any open flames, hot surfaces and potential ignition sources like electrical equipment with exposed contact points. Also, store it in a properly labeled container to avoid confusion and ensure that it is stored separately from incompatible substances, such as strong oxidizing agents, which could lead to dangerous chemical reactions.Store it in a container that is clearly labeled to avoid confusion. Also, keep it away from other substances such as strong oxidizing agents which could cause dangerous chemical reactions.
Fourth, in case of spills.Fourth, in the event of spills. Have a spill response plan in place.Prepare a spill response strategy. If a spill occurs, immediately evacuate the area if the spill is large or if there is a significant release of vapors.If there is a spill, evacuate the area immediately if it is large or there is a significant release in vapors. For small spills, absorb the chemical with an appropriate absorbent material, such as vermiculite or sand.For small spills absorb the chemical using an absorbent material such as vermiculite, sand, or other suitable absorbent materials. Dispose of the contaminated absorbent according to local environmental regulations.Dispose of contaminated absorbents according to local environmental regulations. Do not rinse the spill area with water directly as it may spread the chemical.Do not rinse directly with water the spilled area as this may spread the chemical.
Finally, in case of contact.In case of contact, wash the affected area immediately with plenty of soap and water for at least 15 minutes. If the chemical comes into contact with the skin, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If the chemical gets into the eyes, flush the eyes with water and soap for at least 15 min. If it gets into the eyes, flush the eyes with copious amounts of water for at least 15 minutes and seek immediate medical attention.If it gets in the eyes, flush them with plenty of water for 15 minutes. Seek immediate medical attention. In case of inhalation, move to fresh air immediately and if breathing difficulties persist, call for emergency medical help.In the event of inhalation, you should move to fresh air as soon as possible. If breathing problems persist, seek emergency medical attention.
What are the storage requirements for methacrylic acid benzyl ester?
Methacrylic acid benzyl ester has specific storage requirements to ensure its stability and safety.To ensure its safety and stability, the benzyl ester of methacrylic acid must be stored in a specific manner.
First, it should be stored in a cool place.It should first be stored in a place that is cool. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. If the temperature is too high, the double - bond in methacrylic acid benzyl ester may initiate self - polymerization, which can change its chemical properties and make it unusable for its intended applications.The double -bond in methacrylic acids benzyl esters can initiate self-polymerization if the temperature is high enough. This can change the chemical properties of the ester and make it unusable. A storage temperature in the range of 2 - 8 degrees Celsius is often recommended for long - term storage, similar to how many temperature - sensitive chemicals are stored.For long-term storage, a temperature range of 2 to 8 degrees Celsius is recommended. This is similar to the way many temperature-sensitive chemicals are stored. This helps to slow down any potential chemical changes and maintain its quality.This will help to maintain the quality of the product and slow down any possible chemical changes.
Second, it needs to be stored in a well - ventilated area.Second, it should be stored in an area that is well-ventilated. Methacrylic acid benzyl ester is a volatile organic compound.Methacrylic Acid Benzyl Ester is a volatile compound. In a poorly ventilated space, the vapors can accumulate, creating a fire or explosion hazard.In an area that is not well ventilated, vapors can build up, creating a fire hazard or explosion risk. Adequate ventilation dilutes the vapors, reducing the risk of a dangerous concentration build - up.Adequate ventilation dilutes vapors and reduces the risk of dangerous concentrations. Additionally, good ventilation can help remove any heat that may be generated during storage, contributing to the overall cool storage environment.A good ventilation system can also help remove heat generated during storage. This contributes to a cool storage environment.
Third, it must be stored away from sources of ignition.Third, it should be stored away from ignition sources. As it is flammable, any open flames, sparks from electrical equipment, or hot surfaces can cause it to catch fire.It is flammable and can catch fire if exposed to open flames, sparks or hot surfaces. This means keeping it at a safe distance from areas where welding, burning, or other ignition - prone activities are taking place.It is important to keep it away from areas that are prone to ignition, such as welding, burning or other activities. Storage areas should be clearly marked as non - smoking zones to prevent any accidental ignition.To prevent accidental ignition, storage areas should be clearly marked non-smoking zones.
Fourth, the storage container should be tightly sealed.The container should be tightly closed. Exposure to air can lead to oxidation reactions.Air exposure can cause oxidation reactions. Oxygen in the air can react with the double - bond in methacrylic acid benzyl ester, which may affect its chemical structure and performance.The double-bond in methacrylic benzyl ester can be affected by oxygen in the air. A tightly sealed container also helps prevent evaporation, ensuring that the concentration of the compound remains stable over time.A tightly sealed container helps to prevent evaporation and ensures that the concentration of compound remains stable.
Finally, it should be stored separately from incompatible substances.It should also be stored away from other substances that are incompatible. Methacrylic acid benzyl ester can react with strong oxidizing agents, acids, and bases.Methacrylic Acid Benzyl Ester can react with strong acids, bases, and oxidizing agents. Storing it near such substances can lead to dangerous chemical reactions, including the potential for heat generation, gas evolution, or even explosions.Storing it close to such substances can cause dangerous chemical reactions. These include the potential for heat production, gas evolution, and even explosions. It is essential to keep a clear inventory and separation of chemicals in the storage area to avoid any accidental mixing.To avoid accidental mixing, it is important to keep a list of all chemicals and separate them in the storage area.