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Methacrylic Acid Glycidyl Ester


Properties
Product Name Methacrylic acid glycidyl ester
Cas Number 106-91-2
Formula C7H10O3
Molar Mass 142.15
Density 1.1
Boiling Point 189
Melting Point -50
Flash Point 62
Refractive Index 1.434
Solubility Soluble in organic solvents
Viscosity 1.5 mPa·s
Autoignition Temperature 371
Vapor Pressure 1.3 mmHg
Hazard Class 6.1
FAQ

What are the main applications of methacrylic acid glycidyl ester?

Methacrylic acid glycidyl ester, often abbreviated as GMA, has several important applications across various industries.GMA (methacrylic acid-glycidyl ester) has many important applications in various industries.
In the coatings industry, GMA is widely used.GMA is widely utilized in the coatings industry. It can be incorporated into coating formulations to enhance the performance of the coatings.It can be added to coating formulations to improve the performance. For instance, in automotive coatings, it helps improve the adhesion of the paint to the substrate.In automotive coatings, for example, it improves the adhesion between the paint and the substrate. This is crucial as it ensures that the paint adheres firmly to the metal body of the vehicle, preventing peeling and chipping.This is important as it ensures the paint adheres firmly on the metal body of the car, preventing peeling or chipping. GMA also contributes to the chemical resistance of the coatings.GMA contributes to the chemical resistant of the coatings. It enables the coatings to withstand exposure to various chemicals, such as acids, alkalis, and solvents.It allows the coatings to resist exposure to different chemicals such as acids, solvents, and alkalis. This is beneficial for applications where the coated surface may come into contact with different substances, like in industrial settings or for household appliances.This is useful for applications in which the coated surface will come into contact with various substances, such as in industrial settings and household appliances.

The adhesives field also benefits from GMA.GMA is also beneficial to the adhesives industry. It can be used to modify the properties of adhesives.It can be used for modifying the properties of adhesives. GMA - containing adhesives show improved bonding strength to a wide range of materials, including plastics, metals, and composites.Adhesives containing GMA have improved bonding strengths to a variety of materials including plastics and metals. In the assembly of electronic devices, these adhesives are used to bond different components together.These adhesives are used in the assembly of electronic devices to bond components together. The ability of GMA - based adhesives to adhere well to various substrates and provide a strong bond helps ensure the reliability and durability of the electronic products.GMA-based adhesives adhere well to a variety of substrates and form a strong bond, which helps to ensure the reliability and durability electronic products.

In the polymer modification area, GMA is an important monomer.GMA is a monomer that is important in the polymer modification field. It can be copolymerized with other monomers to introduce functional groups into the polymer chain.GMA can be copolymerized to introduce functional groups in the polymer chain. This allows for the tailoring of polymer properties.This allows for tailoring polymer properties. For example, when copolymerized with polyolefins, it can improve the compatibility of polyolefins with polar polymers or fillers.When polyolefins are copolymerized, they can improve compatibility with polar polymers and fillers. This is useful in the production of polymer blends, where different polymers need to be combined to achieve specific properties.This is useful when producing polymer blends where different polymers are combined to achieve certain properties. GMA - modified polymers also find applications in the production of fibers.GMA-modified polymers are also used in the production fibers. The introduction of GMA can enhance the dyeability of fibers, making it easier to color them and obtain vibrant and fast - color results.GMA enhances the dyeability of fibers and allows for vibrant, fast color results.

In the field of composites, GMA can be used as a coupling agent.GMA is a good coupling agent in composites. It helps improve the interface between the fiber reinforcement and the polymer matrix.It improves the interface between the polymer matrix and the fiber reinforcement. This results in better stress transfer within the composite material, enhancing its mechanical properties such as strength and stiffness.This improves the stress transfer in the composite material and enhances its mechanical properties, such as strength. Composites with GMA - treated components are used in aerospace applications, where high - performance materials are required to withstand extreme conditions.Composites with GMA-treated components are used for aerospace applications where high-performance materials must withstand extreme conditions.

Overall, methacrylic acid glycidyl ester plays a vital role in many industries by enabling the development of high - performance materials with improved properties.Overall, methacrylic glycidyl ester plays a crucial role in many industries. It allows the development of high-performance materials with improved properties.

What are the safety precautions when handling methacrylic acid glycidyl ester?

Methacrylic acid glycidyl ester is a potentially hazardous chemical, and the following safety precautions should be taken when handling it.The following safety precautions must be taken when handling methacrylic acid.
Firstly, personal protective equipment is crucial.Personal protective equipment is essential. Wear appropriate chemical - resistant gloves, such as those made of butyl rubber or nitrile rubber, to prevent skin contact.Wear gloves that are resistant to chemicals, such as those made from butyl rubber, nitrile, or other rubbers, to avoid skin contact. Skin exposure can lead to irritation, burns, and possible allergic reactions.Skin contact can cause irritation, burns and allergic reactions. A full - body chemical - resistant suit should also be worn, especially in cases where there is a risk of splashing.Wearing a full-body chemical-resistant suit is also recommended, especially if there is a chance of splashing. This helps to protect the entire body from any potential contact with the chemical.This will protect the entire body against any possible contact with the chemical.

Secondly, eye protection is essential. Safety goggles or a face shield should be worn at all times during handling.Wear safety goggles or face shields at all times when handling. Methacrylic acid glycidyl ester can cause severe eye damage if it comes into contact with the eyes, potentially leading to permanent vision impairment.If it comes in contact with the eye, Methacrylic Acid Glycidyl Ester can cause severe damage. This could lead to permanent vision impairment.

In terms of the handling environment, ensure good ventilation.As far as the handling environment is concerned, make sure that there is adequate ventilation. This chemical has a pungent odor, and in a poorly ventilated area, the concentration of its vapors can build up.In an area with poor ventilation, the concentration of vapors from this chemical can increase. Adequate ventilation helps to prevent inhalation of these vapors, which can irritate the respiratory tract, cause coughing, shortness of breath, and in severe cases, more serious respiratory problems.Adequate ventilation is important to prevent inhalation. These vapors can cause irritation of the respiratory tract and lead to coughing, shortness in breath, or in more severe cases, serious respiratory problems. If possible, handle the chemical in a fume hood to effectively remove any released vapors.Handle the chemical under a fume-hood to remove any released vapors.

When storing methacrylic acid glycidyl ester, keep it in a cool, dry place away from sources of heat, ignition, and incompatible substances.Store methacrylic glycidyl ester in a cool and dry place, away from heat sources, ignition sources, and other incompatible substances. It is flammable, so storing it near open flames or heat sources can pose a significant fire risk.Store it away from heat or open flames as it is flammable. Also, it may react violently with strong acids, bases, and oxidizing agents, so separate storage from such substances is necessary.It can also react violently with strong bases, acids, and oxidizing substances, so it is best to store it separately.

During the transfer and handling process, use appropriate containers and equipment.Use the appropriate containers and equipment during the transfer and handling process. Ensure that containers are well - sealed to prevent leakage.Containers should be well-sealed to prevent leakage. When pouring or transferring the chemical, do it slowly and carefully to avoid splashing.Pour or transfer the chemical slowly and carefully to prevent splashing. In case of a spill, immediately evacuate the area if the spill is large.If the spill is large, evacuate the area immediately. For small spills, absorb the chemical with an appropriate absorbent material, such as vermiculite or sand, and then dispose of it according to local regulations.If the spill is small, use an absorbent material such as vermiculite, sand or other suitable absorbent materials to absorb the chemical. Dispose of it according local regulations.

Finally, be aware of the first - aid measures.Be aware of first-aid measures. In case of skin contact, immediately remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes.If skin contact occurs, remove all contaminated clothing immediately and wash the affected area for at least 15 min. If eye contact occurs, flush the eyes with copious amounts of water for at least 15 minutes and seek immediate medical attention.If eye contact occurs flush the eyes for at least 15 minute with plenty of water and seek immediate medical assistance. In case of inhalation, move the affected person to fresh air and seek medical help if breathing difficulties persist.If inhalation occurs, move the person to fresh air. Seek medical attention if breathing problems persist.

How is methacrylic acid glycidyl ester produced?

Methacrylic acid glycidyl ester (GMA) is produced through an esterification reaction.Esterification is used to produce methacrylic acid-glycidyl ester (GMA). The main raw materials are methacrylic acid and epichlorohydrin.The main raw materials used are epichlorohydrin and methacrylic acids.
The production process typically involves several steps.The production process usually involves several steps. First, in the presence of a catalyst, methacrylic acid and epichlorohydrin react.In the presence of a catalyser, methacrylic and epichlorohydrin first react. The catalyst used can be an acidic catalyst, which helps to promote the esterification reaction.The catalyst can be acidic, which promotes the esterification. This reaction is an equilibrium process.This reaction is an equilibrium process. To drive the reaction forward, usually, an excess of epichlorohydrin is used.To accelerate the reaction, a large amount of epichlorohydrin can be used. This not only helps shift the equilibrium towards the formation of GMA but also acts as a solvent for the reaction mixture.This not only shifts the equilibrium in favor of GMA formation, but also acts as solvent for the reaction mix.

During the reaction, the carboxyl group of methacrylic acid reacts with the chlorine - containing group of epichlorohydrin.During the reaction the carboxyl group in methacrylic reacts with the chlorohydrin containing group. The reaction conditions, such as temperature and reaction time, are carefully controlled.Temperature and reaction time are carefully controlled. The temperature is usually maintained within a certain range, often around 80 - 120 degrees Celsius.Temperature is usually kept within a range, typically between 80 and 120 degrees Celsius. A proper reaction time is also crucial to ensure sufficient conversion of the reactants into GMA.It is important to have a proper reaction time in order to convert the reactants into GMA.

After the reaction is completed, the mixture contains not only the desired GMA but also unreacted raw materials, by - products, and the catalyst.After the reaction has been completed, the mixture will contain not only the GMA desired, but also unreacted materials, by-products, and the catalyst. A purification process is then necessary.Then, a purification process becomes necessary. One common purification method is distillation.Distillation is a common method of purification. Since GMA has different boiling points compared to other components in the mixture, distillation can be used to separate GMA from unreacted epichlorohydrin, methacrylic acid, and other impurities.Distillation can be used because GMA has a different boiling point than other components of the mixture. The distillation process may be carried out under reduced pressure to lower the boiling points of the substances and prevent thermal decomposition of GMA.Distillation can be performed under reduced pressure in order to lower the boiling point of the substances, and prevent the thermal decomposition.

Another aspect to consider is the removal of the catalyst.The removal of the catalyst is another aspect to be considered. Depending on the type of catalyst used, appropriate methods are employed.Depending on the type and quantity of catalyst, different methods are used. For some acidic catalysts, neutralization with a base might be the first step, followed by separation of the resulting salts from the reaction mixture.For some acidic catalysers, neutralization by a base may be the first step followed by the separation of the salts produced from the reaction mixture.

In summary, the production of methacrylic acid glycidyl ester involves an esterification reaction between methacrylic acid and epichlorohydrin, followed by a purification process to obtain pure GMA.Summary: The production of GMA is a result of an esterification between methacrylic and epichlorohydrin. This is followed by a purification step to obtain pure GMA. This process requires careful control of reaction conditions and effective purification methods to ensure high - quality GMA production.This process requires the careful control of reaction conditions as well as effective purification methods in order to produce high-quality GMA.

What are the properties of methacrylic acid glycidyl ester?

Methacrylic acid glycidyl ester (GMA) has several important properties.The glycidyl esters of methacrylic acid (GMA) have several important properties.
Physical properties: GMA is a colorless to slightly yellow liquid at room temperature.GMA is a colorless liquid that can be slightly yellow at room temperature. It has a characteristic odor.It has a distinctive odor. It has a relatively low viscosity, which makes it easy to handle and mix with other substances in various applications.It is easy to mix and handle because of its low viscosity. It is soluble in many organic solvents such as acetone, toluene, and ethyl acetate, which is beneficial for formulating coatings, adhesives, and inks where a homogeneous solution is required.It is soluble with many organic solvents like acetone, ethyl-acetate and toluene. This is useful for formulating inks, adhesives and coatings that require a homogeneous mixture.

Chemical properties: The most notable feature is the presence of two reactive functional groups.Chemical properties: The presence of two reactive functional group is the most notable feature. The methacrylate double bond is highly reactive towards free - radical polymerization.The double bond of the methacrylate is highly reactive to free radical polymerization. This allows GMA to participate in copolymerization reactions with a wide range of monomers.GMA can participate in copolymerizations with a wide variety of monomers. For example, it can copolymerize with styrene, methyl methacrylate, and acrylate monomers.It can, for example, copolymerize monomers such as styrene and methyl methacrylate. Through copolymerization, it can introduce epoxy - containing side - chains into the polymer backbone.By copolymerization it can introduce side-chains containing epoxy into the polymer's backbone. The epoxy group in GMA is also very reactive.The epoxy group is also very reactive. It can react with nucleophiles such as amines, carboxylic acids, and alcohols.It can react with nucleophiles like amines, carboxylic acid, and alcohols. This reactivity is exploited in curing reactions.This reactivity can be used to cure reactions. For instance, when reacting with amines, it forms a cross - linked network, which is crucial for the production of high - performance coatings and adhesives with excellent chemical resistance and mechanical properties.When reacting with amines it forms a cross-linked network which is crucial to the production of high-performance coatings and adhesions with excellent mechanical and chemical properties.

Reactivity and polymerizability: As mentioned, its polymerizability is high due to the methacrylate double bond.Reactivity and polymerizability. As mentioned above, its polymerizability has a high level due to the double bond of methacrylate. This enables the formation of polymers with different molecular weights and architectures.This allows the formation of polymers that have different molecular masses and architectures. The resulting polymers can have unique properties depending on the copolymerization partners and the reaction conditions.The polymers formed can have unique properties, depending on the copolymerization partner and the reaction conditions. The reactivity of the epoxy group also provides opportunities for post - polymerization modification.The reactivity in the epoxy group allows for post-polymerization modifications. After the formation of the polymer backbone through radical polymerization of the methacrylate part, the epoxy groups can be further reacted to introduce additional functionality or to improve the material's performance.After the radical polymerization is completed, the epoxy groups are reacted further to add functionality or improve the material.

Thermal properties: Polymers derived from GMA often exhibit good thermal stability.Polymers derived GMA usually exhibit good thermal properties. The cross - linking reactions involving the epoxy group can enhance the heat resistance of the final product.The cross-linking reactions involving epoxy groups can increase the heat resistance of a final product. This makes materials containing GMA suitable for applications where they need to withstand elevated temperatures, such as in automotive coatings and some industrial applications.Materials containing GMA are therefore suitable for applications that require them to withstand high temperatures, such automotive coatings and certain industrial applications.

In summary, the combination of the reactive methacrylate and epoxy groups in methacrylic acid glycidyl ester endows it with unique properties that are highly valuable in various industries, from coatings and adhesives to polymer synthesis and modification.The combination of reactive methacrylate groups and epoxy groups in the methacrylic ester glycidyl ester gives it unique properties, which are highly valuable for various industries. These include coatings, adhesives, polymer synthesis, and modification.

What are the storage requirements for methacrylic acid glycidyl ester?

Methacrylic acid glycidyl ester is a chemical compound with specific storage requirements to ensure safety and maintain its quality.The storage of this chemical compound is important to maintain its quality and safety.
Firstly, it should be stored in a cool and well - ventilated area.It should be stored in an area that is well-ventilated and cool. High temperatures can accelerate chemical reactions, potentially leading to polymerization or decomposition of methacrylic acid glycidyl ester.High temperatures can speed up chemical reactions and lead to polymerization of methacrylic acids glycidyl esters or their decomposition. A temperature range of around 2 - 8 degrees Celsius is often ideal for long - term storage.For long-term storage, a temperature range between 2 and 8 degrees Celsius is ideal. This helps to slow down any thermal - induced changes in the chemical structure of the compound.This will help to slow down any changes in chemical structure caused by heat.

Secondly, it must be stored away from sources of ignition and heat.Second, it should be stored away form sources of heat and ignition. Methacrylic acid glycidyl ester is flammable, and even a small spark or high heat source can initiate a fire.Even a small spark can ignite the flammable glycidyl esters. Storage areas should be equipped with proper fire - prevention measures, such as fire - resistant walls and appropriate fire - extinguishing equipment.Storage areas should have fire-prevention measures such as fire-resistant walls and fire-extinguishing equipment.

Thirdly, keep it in a tightly closed container.Thirdly, store it in a tightly sealed container. Exposure to air can cause oxidation, which may affect the properties of the ester.Air exposure can cause oxidation and affect the ester's properties. A sealed container also prevents the release of vapors, which are not only harmful if inhaled but can also contribute to environmental pollution.A sealed container prevents the release vapors that are not only harmful to inhale but can also contribute towards environmental pollution. The container material should be compatible with methacrylic acid glycidyl ester.The container material must be compatible with the methacrylic ester glycidyl acid. Materials like stainless steel or certain types of plastics are commonly used as they do not react with the compound.Materials such as stainless steel and certain types of plastics can be used because they do not react.

Fourthly, avoid storing it near strong oxidizing agents, reducing agents, acids, and bases.Avoid storing it near acids, bases, reducing agents and strong oxidizers. Methacrylic acid glycidyl ester can react with these substances, leading to unwanted chemical reactions.These substances can cause unwanted chemical reactions when Methacrylic Acid Glycidyl Ester is present. For example, reactions with acids or bases can cause hydrolysis of the ester bond, changing the chemical nature of the compound.For example, reactions between acids and bases can hydrolyze the ester bond and change the chemical nature of a compound.

Finally, proper labeling of the storage container is crucial.The labeling of the container is also important. The label should clearly indicate the name of the chemical, its hazards, and any special handling instructions.Labels should clearly state the name of the chemical and its hazards as well as any special handling instructions. This ensures that anyone who comes into contact with the stored methacrylic acid glycidyl ester is aware of the associated risks and how to handle it safely.This will ensure that anyone who comes in contact with the methacrylic acids glycidyl esters stored is aware of any risks and how to safely handle them. By following these storage requirements, the integrity and safety of methacrylic acid glycidyl ester can be maintained during storage.By following these storage requirements the safety and integrity of methacrylic acids glycidyl esters can be maintained.