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Methacrylic Acid Hydroxypropyl Ester


Properties
Product Name Methacrylic Acid Hydroxypropyl Ester
Cas Number 27813-02-1
Formula C7H12O3
Molar Mass 144.17 g/mol
Boiling Point 130-132 °C
Density 1.08 g/cm³
Refractive Index 1.447
Flash Point 110 °C
Solubility In Water Moderate
Appearance Clear liquid
Viscosity 15 mPa·s
Odor Faint ester-like
Stability Stable under recommended storage conditions
Vapor Pressure 0.8 mmHg at 20°C
Autoignition Temperature Not available
Logp 1.1
FAQ

What are the main applications of methacrylic acid hydroxypropyl ester?

Methacrylic acid hydroxypropyl ester has several main applications:The main applications of hydroxypropyl esters of methacrylic acid include:
In the field of coatings, it is widely used.It is widely used in the field of coatings. This ester can improve the adhesion of coatings to various substrates.This ester improves the adhesion between coatings and substrates. For example, when applied on metal surfaces, it helps the coating to firmly adhere, preventing peeling and flaking.When applied to metal surfaces, for example, it helps the coating adhere firmly, preventing flaking and peeling. It also enhances the hardness and abrasion - resistance of the coatings.It also increases the hardness and resistance to abrasion of the coatings. In automotive coatings, it contributes to the long - lasting and high - quality appearance of cars.It contributes to the high-quality and long-lasting appearance of cars when used in automotive coatings. The addition of methacrylic acid hydroxypropyl ester allows the coating to withstand the wear and tear from daily driving, environmental factors like sunlight and rain, and mechanical impacts such as small stones hitting the car body.The addition of methacrylic acids hydroxypropyl esters allows the coatings to withstand daily driving, environmental factors such as sunlight and rain and mechanical impacts like small stones hitting the body.

In the production of adhesives, it plays a crucial role.It is crucial in the production of adhesives. It can be used to modify the properties of adhesives.It can be used for modifying the properties of adhesives. By incorporating this ester, adhesives can achieve better bonding strength, especially for materials that are difficult to bond, such as some plastics and rubbers.This ester can be used to improve adhesive bonding, especially with materials that are hard to bond, like some plastics and certain rubbers. It also helps to improve the flexibility of adhesives, enabling them to adapt to the movement and deformation of the bonded materials without losing their adhesive properties.It also improves the flexibility of adhesives by allowing them to adapt to movement and deformation without losing their adhesion properties. This is important in applications like bonding components in electronic devices, where the components may expand or contract slightly due to temperature changes.This is especially important when bonding electronic components, which may expand or shrink slightly due to temperature fluctuations.

In the area of polymers and resins, methacrylic acid hydroxypropyl ester is used as a monomer.As a monomer, methacrylic ester hydroxypropyl is used in the field of polymers and resins. It can be copolymerized with other monomers to create polymers with unique properties.It can be copolymerized to create polymers that have unique properties. For instance, when copolymerized with acrylic monomers, it can adjust the hydrophilicity and hydrophobicity of the resulting polymer.When copolymerized to acrylic monomers, for example, it can adjust hydrophilicity and Hydrophobicity in the resulting polymer. This is useful in the production of water - based polymers.This is helpful in the production water-based polymers. These polymers can be used in applications like textile finishing, where they can improve the dye - uptake and water - resistance of fabrics.These polymers are useful in textile finishing applications, where they improve the dye-uptake and water-resistance of fabrics. Additionally, in the production of ion - exchange resins, this ester can be used to introduce functional groups, enhancing the ion - exchange capacity of the resins, which is essential for applications in water treatment and purification processes.This ester can also be used in the production ion-exchange resins to introduce functional groups. This enhances the ion-exchange capacity of the resins which is important for applications in water purification and treatment processes.

In the field of inks, it is also applied.It is also used in the field of inks. It can improve the drying speed of inks and enhance their color fastness.It can increase the speed of drying and improve color fastness. In printing applications, especially for high - quality printing on various substrates like paper, plastic films, and textiles, inks containing methacrylic acid hydroxypropyl ester can provide vivid and long - lasting prints.Inks containing the methacrylic hydroxypropyl ester can produce vivid and long-lasting prints in printing applications. It also helps in the smooth transfer of ink from the printing plate to the substrate, ensuring clear and sharp images.It also ensures a smooth transfer of the ink from the plate to the substrate.

What are the properties of methacrylic acid hydroxypropyl ester?

Methacrylic acid hydroxypropyl ester has several notable properties.The hydroxypropyl ester of methacrylic acid has several notable properties.
Physical properties
In terms of appearance, it is usually a clear, colorless liquid.It is usually a clear liquid without color. It has a characteristic odor, which is typical of many organic esters.It has a characteristic smell, which is common to many organic esters. Regarding solubility, it shows good solubility in a variety of organic solvents such as ethanol, acetone, and toluene.It is soluble in ethanol, toluene, and acetone. This solubility property makes it very versatile in different industrial applications, especially in formulations where it needs to be evenly dispersed in an organic - based system.This property of solubility makes it very versatile for different industrial applications. For example, in the production of coatings, it can dissolve well in the solvent phase, allowing for proper mixing with other components like resins and pigments.It can dissolve in the solvent phase in the production process of coatings. This allows for the proper mixing of other components such as resins and pigments.

Chemical properties
Methacrylic acid hydroxypropyl ester contains both a double - bond and a hydroxyl group, endowing it with high reactivity.The hydroxypropyl esters of methacrylic acids contain both a double-bond and a hydroxyl, which gives them a high degree of reactivity. The double - bond can participate in polymerization reactions.The double-bond can be involved in polymerization reactions. It can be polymerized via radical polymerization, either alone or in combination with other monomers.It can be polymerized by radical polymerization alone or in combination other monomers. This property is extensively utilized in the synthesis of polymers, copolymers, and homopolymers.This property is widely used in the synthesis and characterization of polymers, homopolymers, and copolymers. For instance, when copolymerized with other acrylic monomers, it can introduce specific functionality to the resulting polymer.When copolymerized, the resulting polymer can have a specific functionality. The hydroxyl group, on the other hand, can engage in reactions such as esterification, etherification, and cross - linking reactions.The hydroxyl group can be involved in reactions like esterification, cross-linking, and etherification. Through esterification, it can react with carboxylic acids to form new esters, expanding the range of chemical structures that can be created.It can also react with carboxylic acid to create new esters. This allows for a wider range of chemical structures. In the context of cross - linking, the hydroxyl groups can react with cross - linking agents like polyisocyanates, enhancing the mechanical properties of the resulting polymers.Cross-linking can be used to enhance the mechanical properties of polymers by reacting the hydroxyl groups with cross-linking agents such as polyisocyanates. This cross - linking can lead to the formation of a three - dimensional network structure, improving properties such as hardness, abrasion resistance, and chemical resistance of the polymer materials.This cross-linking can lead to a three-dimensional network structure that improves properties such as hardness and chemical resistance.

Thermal properties
The glass transition temperature of polymers derived from methacrylic acid hydroxypropyl ester can be adjusted depending on the polymerization conditions and the presence of other comonomers.The glass transition temperature can be adjusted based on the polymerization conditions, and the presence of comonomers. Generally, the polymers formed have relatively good thermal stability.In general, the polymers are thermally stable. They can withstand a certain range of temperatures without significant degradation or change in physical properties.They can withstand certain temperatures without any significant degradation or changes in their physical properties. This makes them suitable for applications where they may be exposed to elevated temperatures, such as in some industrial coating applications or in the production of heat - resistant plastics.They are therefore suitable for applications that may be exposed at high temperatures, like in industrial coatings or the production of heat-resistant plastics. However, like most organic compounds, at very high temperatures, decomposition will occur, releasing volatile organic compounds and potentially forming char residues.At very high temperatures however, as with most organic compounds, decomposition occurs, releasing volatile organic substances and possibly forming char residues.

How is methacrylic acid hydroxypropyl ester synthesized?

Methacrylic acid hydroxypropyl ester is synthesized through an esterification reaction.Esterification is used to synthesize the hydroxypropyl esters of methacrylic acid. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
The starting materials are methacrylic acid and propylene oxide.The starting materials for this synthesis are methacrylic and propylene oxide. In a typical synthesis, a reactor equipped with proper agitation, temperature control, and a means to remove by - products is used.In a typical synthetic process, a reactor with temperature control and proper agitation is used.

First, an appropriate catalyst is selected.The first step is to select the right catalyst. Commonly, strong acid catalysts like sulfuric acid or p - toluenesulfonic acid can be used.Strong acid catalysts such as sulfuric acid or the p-toluenesulfonic acids are commonly used. The role of the catalyst is to speed up the esterification reaction by protonating the carbonyl group of methacrylic acid, making it more reactive towards the nucleophilic attack by propylene oxide.The catalyst's role is to accelerate the esterification by protonating carbonyl groups in methacrylic acids, making them more reactive against the nucleophilic attack of propylene oxide.

Methacrylic acid and propylene oxide are charged into the reactor in a certain molar ratio.In a reactor, propylene and methacrylic acids are mixed in a specific molar proportion. Usually, an excess of one reactant may be used to drive the reaction towards the formation of the desired product according to Le Chatelier's principle.Le Chatelier's Principle dictates that an excess of one of the reactants can be used to drive a reaction in the direction of the desired product. Propylene oxide is often used in a slight excess because it is relatively easy to remove unreacted propylene oxide later due to its relatively low boiling point.Propylene dioxide is often used at a slight surplus because its low boiling point makes it relatively easy to remove the unreacted propylene.

The reaction is carried out under specific temperature conditions.The reaction takes place under specific temperature conditions. Generally, the temperature is maintained in the range of 60 - 100 degC.The temperature is generally maintained between 60 and 100 degC. At this temperature range, the reaction rate is sufficient, and side reactions can be minimized to a certain extent.This temperature range allows for a sufficient reaction rate and can minimize side reactions to some extent. Side reactions may include polymerization of methacrylic acid or propylene oxide under more severe conditions.Under more severe conditions, side reactions can include polymerizations of propylene oxide or methacrylic acids.

During the reaction, water is generated as a by - product.Water is produced as a by-product during the reaction. To shift the equilibrium of the esterification reaction towards the formation of the ester, water needs to be removed continuously.Water must be continuously removed to shift the equilibrium in favor of esterification. This can be achieved by using techniques such as azeotropic distillation.This can be done by using techniques like azeotropic distillation. For example, adding a suitable azeotropic agent that forms a low - boiling mixture with water, and then distilling off the mixture to remove water from the reaction system.Addition of an azeotropic agent to water that forms a low-boiling mixture, followed by distillation, can be used.

After the reaction is complete, the reaction mixture contains the desired methacrylic acid hydroxypropyl ester, unreacted starting materials, catalyst, and possible by - products.The reaction mixture will contain the desired methacrylic ester, unreacted materials, catalyst and possible by-products. The catalyst can be neutralized, for example, by adding a base such as sodium carbonate.The catalyst can be neutralized by adding a base, such as sodium carbonate. Then, the mixture is subjected to separation and purification steps.The mixture is then subjected to purification and separation steps. These may include distillation to separate the product from unreacted substances based on their different boiling points.This may include distillation in order to separate the product based on boiling point from unreacted substances. Fractional distillation can be used to obtain a relatively pure methacrylic acid hydroxypropyl ester product.Fractional distillation is a method that can be used to produce a product with a high purity of methacrylic ester.

What are the safety precautions when handling methacrylic acid hydroxypropyl ester?

Methacrylic acid hydroxypropyl ester is a chemical compound that requires specific safety precautions during handling to prevent harm to human health and the environment.The hydroxypropyl ester of methacrylic acid is a chemical compound which requires special precautions to be taken when handling it to avoid harming the environment and human health. Here are some important safety measures.Here are some safety measures.
Firstly, in terms of personal protective equipment.First, personal protective equipment. When handling this substance, it is essential to wear appropriate chemical - resistant gloves.Wearing gloves that are resistant to chemicals is important when handling this substance. Nitrile or neoprene gloves are often good choices as they can provide a barrier against skin contact.These gloves can act as a barrier to skin contact. The gloves should be regularly inspected for any signs of damage.Regularly inspect the gloves for signs of damage. In addition, safety goggles with side - shields are necessary to protect the eyes from splashes.Safety goggles with side shields are also necessary to protect your eyes from splashes. If there is a risk of vapor inhalation, a respirator with an appropriate cartridge for organic vapors should be worn.A respirator with a cartridge that is suitable for organic vapors must be worn if there is a danger of vapor inhalation. This helps prevent the harmful vapors from entering the respiratory system.This prevents harmful vapors entering the respiratory system.

Secondly, proper ventilation is crucial.Second, ventilation is essential. Work with methacrylic acid hydroxypropyl ester in a well - ventilated area, preferably under a fume hood.Work with methacrylic acids hydroxypropyl esters in a well-ventilated area, preferably beneath a fume hood. Adequate ventilation helps to disperse any vapors that may be released during handling, reducing the concentration of the chemical in the air and minimizing the risk of inhalation.Adequate ventilation will help disperse vapors released during handling. This will reduce the concentration of chemical in the air, and minimize the risk of inhalation.

Thirdly, be careful about storage.Thirdly, you should be cautious about storage. Store the chemical in a cool, dry place away from sources of heat and ignition.Store the chemical in an area that is cool and dry, away from heat sources and ignition. It should be kept in a tightly - sealed container to prevent evaporation and leakage.Keep it in a tightly-sealed container to prevent evaporation or leakage. Also, keep it away from incompatible substances.Keep it away from other incompatible substances. Methacrylic acid hydroxypropyl ester may react with strong oxidizing agents, bases, and acids, so ensure that it is stored separately from these types of chemicals.Store it away from strong oxidizing agents and bases.

Fourthly, in case of accidental contact, immediate action is required.In the event of accidental contact, you must take immediate action. If it comes into contact with the skin, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If it comes in contact with skin, wash the affected area immediately with soap and water. If it gets into the eyes, flush the eyes with copious amounts of water for at least 15 minutes and seek medical attention promptly.If it gets in the eyes, flush them with plenty of water for 15 minutes at least and seek medical attention immediately. In case of inhalation, move to fresh air immediately.In the event of inhalation, you should move to fresh air as soon as possible. If breathing is difficult, provide artificial respiration and seek medical help.If breathing is difficult, seek medical attention and provide artificial respiration.

Finally, when disposing of methacrylic acid hydroxypropyl ester or any waste containing it, follow local environmental regulations.Follow local environmental regulations when disposing of wastes containing methacrylic acids hydroxypropyl esters or any other wastes containing them. Do not pour it down the drain or dispose of it in regular trash.Do not dispose of it in the regular trash or down the drain. Specialized waste management procedures are usually in place to ensure proper and environmentally - friendly disposal.Specialized waste management procedures ensure that the waste is disposed of in an environmentally-friendly manner.

What are the storage requirements for methacrylic acid hydroxypropyl ester?

Methacrylic acid hydroxypropyl ester has specific storage requirements to ensure its stability and safety.To ensure its safety and stability, the hydroxypropyl esters of methacrylic acid must be stored in a specific manner.
Firstly, it should be stored in a cool and well - ventilated place.It should be stored in an area that is cool and well-ventilated. High temperatures can accelerate its polymerization or other chemical reactions.High temperatures can speed up polymerization and other chemical reactions. A storage temperature preferably below 30degC helps prevent decomposition or unwanted reactivity.Storage temperatures below 30degC are best to prevent decomposition and unwanted reactivity. In a hot environment, the risk of self - polymerization increases, which can lead to the formation of polymers that may clog storage containers and pipelines, and also render the product unusable.In a warm environment, the risk for self-polymerization increases. This can lead to the formation polymers which can clog storage vessels and pipelines and also render the products unusable.

Secondly, it must be stored away from sources of ignition.Second, it should be stored far from ignition sources. Methacrylic acid hydroxypropyl ester is flammable.The hydroxypropyl esters of methacrylic acids are flammable. Keep it far from open flames, sparks from electrical equipment, and any potential heat sources that could initiate combustion.Keep it away from open flames and sparks from electrical appliances, as well as any other heat sources that may cause combustion. Storage areas should be equipped with proper fire - prevention and fire - fighting facilities to handle any potential fire hazards promptly.Fire - prevention and fire-fighting facilities should be installed in storage areas to deal with any potential fire hazards.

Thirdly, the storage container should be tightly sealed.Thirdly, it is important that the container be tightly sealed. Exposure to air can cause oxidation of the ester.The ester can be oxidized by air exposure. Oxygen in the air can react with the double bonds in the molecule, leading to changes in its chemical properties.The double bonds of the molecule can be affected by the oxygen in the air. A well - sealed container also prevents the evaporation of the volatile ester, reducing the risk of creating a flammable vapor - rich environment in the storage area.A well-sealed container prevents the volatile ester from evaporating, reducing the possibility of creating an environment rich in flammable vapors.

Fourthly, it should be stored separately from oxidizing agents, strong acids, and strong bases.Fourthly, the product should be stored away from strong acids, oxidizing agents and bases. Oxidizing agents can react violently with methacrylic acid hydroxypropyl ester, potentially causing explosions or fires.Oxidizing agents may react violently with the methacrylic acids hydroxypropyl esters, causing fires or explosions. Strong acids and bases can catalyze hydrolysis reactions of the ester, breaking it down into its component parts and thus ruining the product.Strong acids and bases may catalyze hydrolysis reactions, destroying the ester and causing it to break down into its constituent parts.

Finally, regular inspection of the storage conditions and the containers is necessary.It is important to inspect the storage conditions and containers regularly. Check for any signs of leakage, corrosion of the container, or changes in the physical state of the substance.Check for signs of leakage or corrosion in the container. Also, check the physical state of any substance. If any issues are detected, appropriate measures should be taken immediately, such as transferring the product to a new container or adjusting the storage environment.If any problems are detected, immediate action should be taken, such as moving the product to a different container or changing the storage environment.