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Product Name | Methacrylic acid, isodecyl ester |
Cas Number | 29964-84-9 |
Formula | C14H26O2 |
Molar Mass | 226.36 |
Density | 0.874 g/cm³ |
Boiling Point | 256 °C |
Melting Point | -50 to -30 °C |
Appearance | Clear liquid |
Flash Point | 108 °C |
Refractive Index | 1.440 - 1.447 |
Solubility | Insoluble in water |
Vapor Pressure | 0.067 mmHg at 25 °C |
Viscosity | 10 - 20 mPa·s at 20 °C |
Stability | Stable under recommended storage conditions |
What are the main applications of methacrylic acid isodecyl ester?
Methacrylic acid isodecyl ester has several main applications:There are several applications for methacrylic acid Isodecyl Ester.
1. Coatings Industry
In the coatings field, it plays a crucial role.It is a key component in the coatings industry. It can be used as a monomer in the production of acrylic resins for coatings.It can be used to produce acrylic resins that are used in coatings. The resulting coatings have enhanced properties.The coatings that result have improved properties. For example, they can improve the weather resistance of the coatings.They can, for example, improve the weather resistance. The isodecyl group in methacrylic acid isodecyl ester contributes to better durability against sunlight, humidity, and temperature changes.The isodecyl groups in the methacrylic ester isodecyl contribute to better durability when it comes to sunlight, humidity and temperature changes. This makes the coatings suitable for various applications, such as automotive coatings.The coatings are therefore suitable for a variety of applications, including automotive coatings. In automotive finishes, the addition of this ester helps the paint to maintain its color and gloss over a long period, protecting the car's body from environmental damage.This ester is added to automotive finishes to help the paint maintain its color and gloss for a long time, protecting the car body from environmental damage. Additionally, in industrial coatings, it can enhance the hardness and abrasion resistance of the coating film.In industrial coatings, the ester can also increase the hardness and resistance to abrasion of the coating film. This is important for machinery and equipment that are subject to wear and tear during operation.This is especially important for machinery and equipment which are subject to wear during operation.
2. Adhesives
Methacrylic acid isodecyl ester is also used in the production of adhesives.It is also used to produce adhesives. It can improve the adhesion properties of adhesives to different substrates.It can improve adhesive adhesion to different substrates. The ester's chemical structure allows it to form strong bonds with materials like plastics, metals, and glass.The ester's chemical composition allows it to form strong bond with materials such as plastics, metals and glass. For instance, in the assembly of electronic devices, adhesives containing this ester can firmly attach components together.Adhesives containing this ester, for example, can be used to firmly attach electronic components. The flexibility provided by the isodecyl chain helps the adhesive to conform to the shapes of the substrates and withstand stress during use.The isodecyl chains flexibility allows the adhesive to conform to substrate shapes and withstand stress. It also contributes to the long - term stability of the adhesive joint, preventing delamination.It also contributes towards the long-term stability of the adhesive, preventing delamination. In the packaging industry, adhesives with this monomer can ensure that labels and packaging materials stick securely, even under different storage and transportation conditions.Adhesives containing this monomer are used in the packaging industry to ensure that labels and packaging materials adhere securely, even when stored and transported under different conditions.
3. Plastics ModificationPlastics Modification
When it comes to plastics, methacrylic acid isodecyl ester is used for modification purposes.In the case of plastics, it is used to modify them. It can be copolymerized with other monomers in the production of plastics.It can be copolymerized in the production process of plastics. This modification can enhance the impact resistance of plastics.This modification can increase the impact resistance of plastics. For example, in polypropylene - based plastics, the addition of this ester can make the plastic more resistant to breakage when subjected to impacts.This ester can be added to polypropylene-based plastics to make them more resistant to breaking when they are subjected to impact. It can also improve the processability of plastics.It can also improve plastics' processability. The isodecyl group reduces the viscosity of the polymer melt during processing, making it easier to mold and extrude the plastic into various shapes.The isodecyl groups reduce the viscosity during processing of the polymer melt, making it easier for the plastic to be molded and extruded into various shapes. This is beneficial for manufacturing plastic products with complex geometries, such as those used in the consumer goods industry, like housings for electronic appliances and automotive interior parts.This is especially useful for the manufacture of plastic products with complex shapes, such as those found in consumer goods, such as housings for electronic appliances or automotive interior parts.
4. Inks
In the ink industry, methacrylic acid isodecyl ester is used to improve the performance of inks.In the ink industry the methacrylic ester is used for improving the performance of inks. It can enhance the drying speed of inks, especially in high - speed printing processes.It can increase the drying speed of inks. This is especially true for high-speed printing processes. The ester helps in the formation of a hard and durable ink film on the printed substrate.The ester aids in the formation of an ink film that is hard and durable on the printed substrate. This is important for ensuring that the printed images or texts are resistant to smudging, scratching, and fading.This is essential to ensure that printed images or text are resistant against smudging and scratching. In packaging inks, it can provide excellent adhesion to different packaging materials, whether it is paper, cardboard, or plastic films.In packaging inks it can provide excellent adhesion on different packaging materials such as paper, cardboard or plastic films. This allows for high - quality printing on packaging, which is essential for product marketing and brand recognition.This allows for high-quality printing on packaging which is essential for brand recognition and product marketing.
How is methacrylic acid isodecyl ester produced?
Methacrylic acid isodecyl ester is produced through an esterification reaction.Esterification is used to produce methacrylic acid and isodecyl esters. The key starting materials are methacrylic acid and isodecyl alcohol.The two main starting materials are isodecyl ethanol and methacrylic alcohol.
In the first step, appropriate amounts of methacrylic acid and isodecyl alcohol are carefully measured and introduced into a reaction vessel.In the first stage, methacrylic and isodecyl ethanol are carefully measured out and added to a reaction vessel. This vessel is typically made of materials that can withstand the reaction conditions, such as glass - lined or stainless - steel reactors.This vessel is usually made from materials that can withstand reaction conditions, like stainless steel or glass-lined reactors.
A catalyst is then added to the reaction mixture.The reaction mixture is then treated with a catalyst. Commonly used catalysts for this esterification reaction include sulfuric acid, p - toluenesulfonic acid, or some solid - acid catalysts.Catalysts commonly used for this esterification include sulfuric acid or p-toluenesulfonic acids. The catalyst plays a crucial role in accelerating the reaction rate by lowering the activation energy required for the reaction to occur.The catalyst is crucial in accelerating reaction rates by lowering activation energy.
Once the reactants and catalyst are in place, the reaction vessel is heated.The reaction vessel is heated once the reactants and the catalyst are in place. The temperature is carefully controlled, usually in the range of 100 - 150 degrees Celsius.Temperature is carefully controlled and usually between 100-150 degrees Celsius. At this elevated temperature, the carboxylic acid group of methacrylic acid reacts with the hydroxyl group of isodecyl alcohol.At this temperature, the carboxylic group of methacrylic reacts with the isodecyl group. During the reaction, a molecule of water is eliminated as a by - product.During the reaction a water molecule is eliminated as a side-product. This is a reversible reaction, and to drive the reaction towards the formation of the ester, the water formed is often removed continuously.This is a reversible process, and the water produced is often continuously removed to accelerate the reaction. One common method to remove water is by using azeotropic distillation.Azeotropic distillation is a common way to remove water. An entrainer, such as toluene or xylene, is added to the reaction mixture.Add an entrainer such as xylene or toluene to the reaction mixture. These substances form an azeotrope with water, which can be distilled out of the reaction system.These substances can be distilled from the reaction system after forming an azeotrope. As the water is removed, according to Le Chatelier's principle, the equilibrium of the esterification reaction shifts towards the formation of more methacrylic acid isodecyl ester.According to Le Chatelier’s principle, as the water is removed from the reaction system, the equilibrium shifts in favor of more isodecyl esters of methacrylic acids.
After the reaction has proceeded for a sufficient period, as determined by techniques such as gas chromatography to monitor the conversion of reactants, the reaction mixture is cooled.The reaction mixture can be cooled after the reaction has been allowed to proceed for a certain period of time, as determined using techniques such as gas-chromatography, which monitors the conversion of the reactants. The catalyst may need to be neutralized, for example, if sulfuric acid was used as a catalyst, a base like sodium carbonate or sodium hydroxide can be added to neutralize the acid.The catalyst can need to be neutralized. For example, if you used sulfuric acid as a catalyst, a base such as sodium carbonate or a sodium hydroxide could be added to neutralize it.
Subsequently, the reaction product is subjected to purification steps.Purification is then performed on the reaction product. This usually involves separation techniques such as distillation.This is usually done using separation techniques, such as distillation. Methacrylic acid isodecyl ester has a different boiling point compared to unreacted starting materials, by - products, and any remaining catalyst or neutralization salts.Methacrylic Acid Isodecyl Ester has a higher boiling point than unreacted starting materials or by-products, or any remaining neutralization salts. Through distillation, the pure methacrylic acid isodecyl ester can be isolated, typically as a colorless to pale - yellow liquid, ready for use in various applications such as in the production of coatings, adhesives, and polymers.By distillation, pure methacrylic isodecyl esters can be isolated. They are typically a colorless or pale-yellow liquid that can be used in a variety of applications, such as the production and use of polymers, adhesives, coatings, etc.
What are the physical and chemical properties of methacrylic acid isodecyl ester?
Methacrylic acid isodecyl ester is an important monomer in the field of polymers.The monomer isodecyl esters of methacrylic acid are important in the field polymers.
Physical properties:Physical Properties
1. Appearance: It is usually a colorless to light - yellow clear liquid.Appearance: The liquid is usually clear and colorless. This clear appearance makes it easy to observe and handle in industrial and laboratory settings.This clear appearance makes it easier to handle and observe in industrial and lab settings.
2. Odor: It has a characteristic, faint, and somewhat sweet - like odor.Odor: It is a characteristic, mild, and sweet-like odor. Although not extremely pungent, the odor can still be detected and may need to be considered in workplaces to ensure good ventilation.The odor is not very strong, but it can be detected.
3. Boiling point: The boiling point of methacrylic acid isodecyl ester is relatively high.The boiling point for methacrylic isodecyl ester is relatively high. A higher boiling point indicates that it has relatively strong intermolecular forces.A higher boiling point indicates a product with relatively strong intermolecular interactions. This property is beneficial in applications where it needs to withstand elevated temperatures without rapid evaporation.This property is useful in applications that require the material to be able to withstand high temperatures without evaporating rapidly. For example, during the polymerization process or in coatings applications where heat - curing might be involved.This property is beneficial in applications such as polymerization or coatings where heat-curing may be involved.
4. Viscosity: It has a moderate viscosity.Viscosity: The viscosity is moderate. This allows for good flowability during processing, such as when it is used in the production of paints, inks, or adhesives.This allows for good flowability when processing, as in the case of paints or inks. It can be easily dispensed, mixed with other components, and applied evenly on surfaces.It can be easily dispensed and mixed with other components to apply evenly on surfaces.
5. Solubility: It is soluble in many organic solvents like toluene, xylene, and esters.It is soluble with many organic solvents, such as toluene and xylene. This solubility in common organic solvents makes it versatile in formulating various polymer - based products.Its solubility in organic solvents is what makes it so versatile when formulating polymer-based products. It can be dissolved and combined with other solutes to create homogeneous mixtures for different applications.It can be dissolved with other solutes and mixed to create homogeneous mixes for different applications.
Chemical properties:Chemical properties
1. Polymerizability: Methacrylic acid isodecyl ester contains a reactive double bond in its molecular structure.Polymerizability - Methacrylic Acid Isodecyl Ester contains a reactive, double bond in its molecule structure. This double bond makes it highly polymerizable.This double bond makes the ester highly polymerizable. It can participate in free - radical polymerization reactions.It can participate in reactions of free-radical polymerization. In the presence of an initiator, such as a peroxide or an azo - compound, the double bond breaks, and monomers link together to form long - chain polymers.In the presence an initiator such as peroxide or azo-compound, the double bonds break and monomers join together to form long-chain polymers. This property is the basis for its use in the production of a wide range of polymers, including acrylic resins.This property is used to produce a variety of polymers including acrylic resins. These polymers can be used in coatings to provide good adhesion, hardness, and weather resistance.These polymers are used in coatings for their adhesion, hardness and weather resistance.
2. Reactivity with other functional groups: The ester group in methacrylic acid isodecyl ester can react with compounds containing hydroxyl, amine, or carboxyl groups.Reactivity with other functional group: The ester in methacrylic acids isodecyl esters can react with compounds that contain hydroxyl, carboxyl, or amine groups. For example, it can undergo trans - esterification reactions with alcohols in the presence of a catalyst.It can undergo trans-esterification reactions, for example, with alcohols when a catalyst is present. These reactions can be used to modify the polymer structure or to create cross - linked polymers, which can enhance the mechanical and chemical properties of the final product.These reactions can be used for modifying the polymer structure, or to create cross-linked polymers that can enhance the mechanical properties and chemical properties of the end product.
3. Stability: Under normal storage conditions, it is relatively stable.Stability: It is stable under normal storage conditions. However, it should be stored away from heat, light, and oxidizing agents.Store it away from heat, sunlight, and oxidizing agents. Prolonged exposure to heat or light can initiate premature polymerization, while oxidizing agents can react with the double bond, leading to degradation of its chemical properties.Heat or light exposure can cause premature polymerization. Oxidizing agents can also react with the double bonds, resulting in degradation of chemical properties.
Is methacrylic acid isodecyl ester harmful to the environment?
Methacrylic acid isodecyl ester can have potential impacts on the environment.Environmental impacts of isodecyl esters of methacrylic acid can be significant.
In terms of aquatic ecosystems, if it is released into water bodies, it may pose risks to aquatic organisms.If released into water bodies it could pose a risk to aquatic organisms. High concentrations could potentially affect the survival, growth, and reproduction of fish, invertebrates, and other aquatic life.High concentrations of this chemical could affect the survival, growth and reproduction of aquatic organisms, including fish, invertebrates and other aquatic animals. It may have toxic effects on their physiological functions, disrupting metabolic processes or interfering with their nervous systems.It could have toxic effects on their physiological function, disrupting metabolism or interfering their nervous system. Some studies on similar esters have shown that they can accumulate in the tissues of aquatic organisms over time.Several studies have shown that similar esters can accumulate in the tissue of aquatic organisms. This bioaccumulation can then have implications for higher trophic levels in the food chain, as predators consume organisms containing the accumulated chemical.This bioaccumulation may have consequences for higher trophic level organisms in the food chain as predators consume organisms that contain the accumulated chemical.
In the atmosphere, if it is present in volatile forms, it can contribute to the formation of air pollutants.If it is present as a volatile form in the atmosphere, it can contribute towards the formation of air pollution. Methacrylic acid isodecyl ester may react with other chemicals in the atmosphere, such as ozone and free radicals.Methacrylic Acid Isodecyl Ester can react with other chemicals present in the air, such as free radicals and ozone. These reactions can lead to the production of secondary pollutants, which can have negative impacts on air quality.These reactions can produce secondary pollutants that can negatively impact air quality. They can also potentially contribute to the formation of smog, which can cause respiratory problems for humans and other animals, as well as damage to plants.They can also contribute to the formation smog which can cause respiratory issues for humans and animals as well as damage to plant life.
In soil, if it is introduced, it could potentially affect soil microorganisms.If introduced to soil, it may affect soil microorganisms. These microorganisms play crucial roles in processes like nutrient cycling and decomposition.These microorganisms are crucial in processes such as nutrient cycling and soil decomposition. Methacrylic acid isodecyl ester might inhibit the activity of these beneficial microorganisms, disrupting the natural balance in the soil ecosystem.The methacrylic acid ester could inhibit the activity of beneficial microorganisms and disrupt the natural balance within the soil ecosystem. This could then impact plant growth, as plants rely on the proper functioning of soil microorganisms for nutrient uptake.This could impact plant growth as plants rely on soil microorganisms to absorb nutrients.
However, the actual environmental harm depends on several factors.The actual environmental damage depends on a number of factors. The amount released into the environment is a key determinant.The amount of material released into the environment will be a major determinant. Small, controlled releases may have minimal impacts compared to large - scale spills.Small, controlled releases can have minimal impact compared to large-scale spills. Also, the rate of degradation of methacrylic acid isodecyl ester in different environmental media is important.It is also important to know the rate of degradation in different media of methacrylic acids isodecyl esters. If it can be broken down relatively quickly by natural processes such as biodegradation in water, soil, or by photodegradation in the atmosphere, the long - term environmental harm may be reduced.The long-term environmental harm can be reduced if it is broken down by natural processes, such as photodegradation or biodegradation, in water, soil and the atmosphere. But overall, due to its potential to cause harm in various environmental compartments, proper handling and management of methacrylic acid isodecyl ester are necessary to minimize its negative impacts on the environment.Overall, however, because of its potential to cause harm to various environmental compartments and its need for proper handling and management, it is necessary to minimize the negative impacts on the planet.
What safety precautions should be taken when handling methacrylic acid isodecyl ester?
Methacrylic acid isodecyl ester is a chemical compound that requires certain safety precautions when being handled.When handling this chemical compound, it is important to take certain safety precautions.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Always wear appropriate respiratory protection.Always wear respiratory protection. Since vapors of methacrylic acid isodecyl ester may be present during handling, a respirator with suitable cartridges for organic vapors should be used to prevent inhalation of harmful fumes.To prevent inhalation, use a respirator equipped with cartridges that are suitable for organic vapors. This helps to avoid potential respiratory tract irritation, which can range from mild coughing to more serious long - term damage.This can help to prevent respiratory tract irritations, which range from mild coughing up to more serious long-term damage.
Eye protection is also crucial.Eye protection is equally important. Chemical - resistant goggles should be worn at all times.Wear chemical-resistant goggles at all times. Even a small splash of this substance into the eyes can cause severe irritation, redness, and potentially damage to the cornea.Even a small splash can cause severe irritation and redness to the eyes, as well as damage to the cornea.
Skin protection is equally important.Skin protection is also important. Long - sleeved chemical - resistant clothing and gloves made of materials like nitrile or neoprene should be worn.Wear gloves and long-sleeved clothing made of nitrile, neoprene or other chemical-resistant materials. Methacrylic acid isodecyl ester can penetrate the skin, and direct contact may lead to skin irritation, allergic reactions, or absorption into the body, which could have systemic effects.Direct contact with Methacrylic Acid Isodecyl Ester can cause skin irritation, allergic reactions or absorption of the substance into the body.
In the workplace, ensure good ventilation.Ensure good ventilation in the workplace. Install local exhaust ventilation systems near the areas where the compound is handled.Install local exhaust ventilation near the areas that handle the compound. This helps to remove vapors and keep the air quality within safe limits, reducing the risk of inhalation exposure for workers.This will help to remove vapors from the air and keep it within safe limits. It will also reduce the risk of workers inhaling the compound.
When storing methacrylic acid isodecyl ester, keep it in a cool, well - ventilated area away from sources of ignition such as open flames, sparks, and hot surfaces.Store methacrylic ester away from ignition sources such as sparks, open flames and hot surfaces. It is flammable, and a fire involving this substance can release toxic fumes.It is flammable and a fire can release toxic fumes. Store it in tightly closed containers to prevent leakage and evaporation.Store it in tightly sealed containers to prevent leaking and evaporation.
In case of a spill, take immediate action.Take immediate action in the event of a spill. First, evacuate the area to prevent others from being exposed.To prevent exposure to others, first evacuate the area. Then, use appropriate absorbent materials like sand or vermiculite to contain and clean up the spill.Use absorbent materials such as sand or Vermiculite to contain the spill and clean it up. Dispose of the contaminated absorbents according to local regulations.Dispose the contaminated absorbents in accordance with local regulations.
If a person comes into contact with methacrylic acid isodecyl ester, for skin contact, immediately remove contaminated clothing and wash the affected area with plenty of soap and water for at least 15 minutes.If you come into contact with the methacrylic ester, remove all contaminated clothing immediately and wash affected skin with lots of soap and water. This should be done for at least 15 min. For eye contact, flush the eyes with copious amounts of water for at least 15 minutes and seek medical attention promptly.If you have come into contact with methacrylic acid isodecyl ester, remove all clothing and wash the affected area for at least 15 mins. In case of inhalation, move the person to fresh air and if breathing is difficult, provide oxygen and call for emergency medical help.If inhalation occurs, move the victim to fresh air, and if breathing becomes difficult, give oxygen and call emergency medical help.