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Product Name | Methacrylic acid methyl ester |
Cas Number | 80-62-6 |
Formula | C5H8O2 |
Molar Mass | 100.12 |
Density | 0.942 g/mL |
Boiling Point | 100 °C |
Melting Point | -48 °C |
Refractive Index | 1.414 |
Vapour Pressure | 38.66 mmHg at 20 °C |
Flash Point | 10 °C |
Autoignition Temperature | 421 °C |
Solubility In Water | 1.5 g/100 mL at 20 °C |
Viscosity | 0.6 cP at 20 °C |
Heat Of Vaporization | 32.62 kJ/mol |
Permittivity | 5.54 |
What are the main applications of methacrylic acid methyl ester?
Methacrylic acid methyl ester, also known as methyl methacrylate (MMA), has a wide range of important applications.The methyl ester of methacrylic acid, also known by the name methyl methacrylate or MMA, has a variety of important applications.
One of the most well - known applications is in the production of polymethyl methacrylate (PMMA).One of the best-known applications is the production of polymethylmethacrylate (PMMA). PMMA is a transparent thermoplastic often referred to as acrylic glass.PMMA is a thermoplastic that is transparent and often called acrylic glass. It has excellent optical clarity, high light transmission, and good weather resistance.It is a thermoplastic with excellent optical clarity and high light transmission. It is also resistant to weather. In the construction industry, PMMA is used for making skylights, large - scale transparent partitions, and decorative elements.PMMA is commonly used in the construction industry to make skylights, large-scale transparent partitions and decorative elements. For example, in modern architecture, it can be used to create unique and aesthetically pleasing facades that allow abundant natural light to enter buildings.In modern architecture, for example, it can create unique and aesthetically pleasing façades that allow natural light into buildings.
In the automotive industry, MMA is used to manufacture various components.MMA is used in the automotive industry to manufacture various components. PMMA - based materials are used for headlight lenses.Headlight lenses are made from PMMA-based materials. These lenses need to be highly transparent to ensure proper illumination and also have to withstand harsh environmental conditions such as temperature variations and impacts.These lenses must be highly transparent in order to provide proper illumination, and they also need to withstand harsh conditions such as temperature changes and impacts. Additionally, MMA can be used in the production of interior components like instrument panel covers, which require a combination of durability and good appearance.MMA is also used to produce interior components such as instrument panel covers that require a combination between durability and good looks.
The electronics industry also benefits from MMA.MMA is also beneficial to the electronics industry. It is used in the production of liquid crystal display (LCD) components.It is used to produce liquid crystal display (LCD). The optical properties of PMMA make it suitable for use in backlight units, which are crucial for the proper functioning of LCDs.PMMA's optical properties make it ideal for backlight units that are essential for LCDs to function properly. These backlight units need materials that can evenly distribute light, and PMMA meets this requirement well.PMMA is a good material for these backlight units because it can distribute light evenly.
MMA is also used in the coatings and adhesives sector.MMA is used in coatings and adhesives. Acrylic coatings made from MMA offer good hardness, abrasion resistance, and chemical resistance.Acrylic coatings made of MMA are hard, abrasion resistant, and chemically resistant. They are applied on metal surfaces, furniture, and automobiles to provide a protective and decorative layer.They are used on metal surfaces, furniture and automobiles as a protective and decorative coating. In the case of adhesives, MMA - based adhesives have strong bonding properties and are used in bonding various materials, especially in applications where a clear and durable bond is required.In the case adhesives, MMA-based adhesives are strong and can be used to bond various materials.
Another area of application is in the dental field.Dental prosthetics is another area of application. MMA is used to make dental prosthetics, such as dentures.MMA is used in the manufacture of dental prosthetics such as dentures. The material can be easily molded to fit the patient's mouth and has good biocompatibility, which means it is less likely to cause adverse reactions in the oral cavity.The material is easily molded and biocompatible, so it's less likely to cause adverse reactions within the oral cavity. It also has sufficient strength to withstand the mechanical forces during chewing.It is also strong enough to withstand mechanical forces when chewing.
Finally, in the art and craft industry, MMA - based products are popular.MMA-based products are also popular in the art and crafts industry. Acrylic paints, which often contain MMA derivatives, are widely used by artists due to their quick - drying nature, bright colors, and good adhesion to various surfaces like canvas, paper, and wood.Acrylic paints are popular among artists because of their bright colors, quick-drying nature, and good adhesion on various surfaces such as canvas, paper, or wood.
What are the properties of methacrylic acid methyl ester?
Methacrylic acid methyl ester, also known as methyl methacrylate, has several notable properties.The methyl ester of methacrylic acid, also known by the name methyl methacrylate has several notable properties.
Physical properties: It is a colorless, volatile liquid with a characteristic pleasant odor.Physical properties: It's a colorless liquid with a pleasant aroma. It has a relatively low boiling point of around 100 - 101 degrees Celsius, which allows it to vaporize relatively easily under normal heating conditions.It has a low boiling point, around 100-101 degrees Celsius. This allows it to vaporize easily under normal heating conditions. Its density is approximately 0.94 g/cm3.Its density is 0.94 g/cm3. It is sparingly soluble in water but is highly soluble in many organic solvents such as ethanol, acetone, and benzene.It is only sparingly soluble, but highly soluble, in organic solvents like acetone, benzene, and ethanol. This solubility in organic solvents makes it useful in various chemical processes and formulations that involve organic media.This solubility makes it useful for various chemical processes that use organic media.
Chemical properties: Methacrylic acid methyl ester contains a double bond in its structure, which imparts high reactivity.Chemical properties: The structure of methyl esters of methacrylic acids contains a double-bond, which confers high reactivity. It readily undergoes addition polymerization reactions.It is easily polymerized by addition reactions. This is the basis for the production of polymethyl methacrylate (PMMA), a widely used transparent plastic.This is the basis of the production polymethyl methacrylate, a widely used plastic. In the presence of appropriate initiators, such as peroxides or azo - compounds, the double bond breaks and monomers link together to form long - chain polymers.In the presence appropriate initiators such as peroxides and azo - compounds the double bond breaks, and monomers join together to form long-chain polymers. The polymerized form, PMMA, has excellent optical clarity, similar to glass, but is much lighter and more shatter - resistant.The polymerized PMMA has excellent optical clarity similar to glass but is lighter and more shatter-resistant.
Methacrylic acid methyl ester can also participate in other chemical reactions.The methyl ester of methacrylic acid can also be used in other chemical reactions. For example, it can react with nucleophiles in substitution reactions at the carbonyl group or the carbon - carbon double bond can react with electrophiles in addition reactions.It can, for example, react with nucleophiles during substitution reactions at carbonyl groups or the double bond between carbon and carbon can react electrophiles during addition reactions. It is relatively stable under normal storage conditions when protected from heat, light, and initiators that could trigger polymerization.It is relatively stable when stored under normal conditions, protected from heat, light and initiators which could trigger polymerization. However, exposure to high temperatures, strong oxidizing agents, or certain catalysts can lead to unwanted reactions, including polymerization or degradation.Exposure to high temperatures, strong agents of oxidation, or certain catalysts may cause unwanted reactions such as polymerization or degradation.
In terms of its mechanical properties when polymerized into PMMA, the resulting material has good hardness and abrasion resistance.The resulting material, PMMA, has excellent mechanical properties. It is hard and resistant to abrasion. It can withstand moderate mechanical stress without deforming easily.It can withstand moderate mechanical stresses without deforming. It also has good weather resistance, retaining its optical and mechanical properties over long periods when exposed to sunlight and normal outdoor conditions.It is also resistant to weather, and retains its optical and mechanical characteristics for long periods of time when exposed to sunlight or normal outdoor conditions. This makes PMMA suitable for applications such as automotive headlights, skylights, and outdoor signage.PMMA is therefore suitable for outdoor signage, automotive headlights and skylights. Overall, the unique combination of physical, chemical, and mechanical properties of methacrylic acid methyl ester and its polymer derivatives makes it a valuable compound in numerous industries, including plastics, coatings, and adhesives.The unique combination of physical and chemical properties of methacrylic acids methyl ester, and its polymer derivatives, makes it a valuable component in many industries, such as plastics, adhesives, and coatings.
How is methacrylic acid methyl ester produced?
Methacrylic acid methyl ester is produced through several main methods.There are several methods to produce methyl ester of methacrylic acid. One common approach is the esterification of methacrylic acid with methanol.Esterification of methacrylic acids with methanol is a common method.
In this process, methacrylic acid and methanol are reacted in the presence of a catalyst.In this process, methanol and methacrylic acids are reacting in the presence a catalyst. Sulfuric acid is a traditional catalyst used for this esterification reaction.This esterification reaction is traditionally catalyzed by sulfuric acid. However, its use has some drawbacks such as corrosion of equipment and generation of large amounts of waste acid.Its use is not without its drawbacks, such as corrosion to equipment and the generation of large quantities of waste acid. To address these issues, solid - acid catalysts like ion - exchange resins have become more popular.Solid - acid catalysers like ion-exchange resins are becoming more popular to address these issues. These solid - acid catalysts offer advantages like ease of separation from the reaction mixture, recyclability, and less corrosion to the equipment.These solid - acids catalysts have advantages such as easy separation from the reaction mix, recyclability, or less corrosion on the equipment.
The reaction conditions are carefully controlled.The reaction conditions are carefully monitored. The temperature is typically maintained within a certain range, usually around 60 - 100 degrees Celsius, depending on the catalyst used.Temperature is usually maintained within a range, typically between 60 and 100 degrees Celsius depending on the catalyst. A proper molar ratio of methacrylic acid to methanol is also crucial.It is also important to have the right molar ratio between methacrylic and methanol. An excess of methanol is often used to drive the reaction forward according to Le Chatelier's principle, shifting the equilibrium towards the formation of methacrylic acid methyl ester.Le Chatelier's theory dictates that an excess of methanol can be used to accelerate the reaction and shift the equilibrium in the direction of the formation of the methacrylic ester.
Another important method is the hydrolysis of methyl methacrylate - cyanohydrin.Hydrolysis of methylmethacrylate-cyanohydrin is another important method. This process starts with the reaction of acetone and hydrogen cyanide to form acetone cyanohydrin.This process begins with the reaction between acetone, hydrogen cyanide and acetone cyanohydrin. Then, acetone cyanohydrin reacts with methanol and sulfuric acid to form methyl methacrylate - cyanohydrin.The acetone-cyanohydrin then reacts with sulfuric acid and methanol to form methylmethacrylate-cyanohydrin. Finally, the hydrolysis of methyl methacrylate - cyanohydrin in the presence of an acid catalyst produces methacrylic acid methyl ester.The hydrolysis of the methyl methacrylate-cyanohydrin in presence of an acid catalyser produces methacrylic ester. This method is less common due to the use of highly toxic hydrogen cyanide.This method is less popular due to the toxic nature of hydrogen cyanide.
After the reaction is complete, the product mixture contains not only methacrylic acid methyl ester but also unreacted starting materials, by - products, and catalyst.After the reaction has been completed, the product mixture will contain not only the methacrylic ester, but also the unreacted materials, by-products, and catalyst. A series of separation and purification steps are required.Separation and purification are required. Distillation is a key purification method.Distillation is the key purification technique. By carefully controlling the distillation conditions, such as temperature and pressure, methacrylic acid methyl ester can be separated from other components based on their different boiling points.By carefully controlling the conditions of distillation, such as pressure and temperature, methacrylic methyl ester is separated from other components according to their different boiling points. Other purification techniques like extraction may also be used to remove impurities and obtain a high - purity methacrylic acid methyl ester product.Purification techniques such as extraction can also be used to remove any impurities in order to obtain a high-purity methacrylic ester.
What are the safety precautions when handling methacrylic acid methyl ester?
Methacrylic acid methyl ester is a common chemical with certain risks, so specific safety precautions are needed during handling.Methacrylic Acid methyl Ester is a common chemistry with certain risks. Therefore, specific safety precautions must be taken when handling.
Firstly, in terms of personal protective equipment.First, personal protective equipment. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can resist the corrosive effect of methacrylic acid methyl ester to a certain extent.Nitrile gloves can be a good option as they are resistant to the corrosive effects of methacrylic acids methyl ester. Also, put on safety goggles to protect the eyes from potential splashes.Wear safety goggles as well to protect your eyes from possible splashes. In case of large - scale operations or in environments with higher risk of vapor exposure, a full - face respirator should be used to prevent inhalation of its vapors.If you are working in an environment with a higher risk of exposure to vapors, or if the operation is large-scale, a full-face respirator can be used.
Secondly, regarding the handling environment.Second, the handling environment. Ensure good ventilation in the work area.Assure good ventilation in your work area. This can be achieved through natural ventilation if possible, but in most cases, mechanical ventilation systems are necessary.If possible, this can be achieved by using natural ventilation, but in many cases, mechanical ventilation is necessary. Adequate ventilation helps to dilute the concentration of methacrylic acid methyl ester vapors in the air, reducing the risk of explosion and inhalation hazards.Adequate ventilation reduces the concentration of methacrylic acids methyl esters in the air. This reduces the risk of explosions and inhalation hazards. The work area should also be kept away from sources of ignition, such as open flames, sparks from electrical equipment, etc.Work areas should be kept away form sources of ignition such as open flames and sparks from electrical appliances. Since methacrylic acid methyl ester is flammable, any source of ignition can lead to a fire or explosion.Because methacrylic ester is flammable and can ignite, any source of ignition could cause a fire or explosion.
When it comes to storage, store methacrylic acid methyl ester in a cool, dry place.Store methacrylic ester in a dry, cool place. Avoid storing it in areas where the temperature can rise rapidly, such as near heating equipment or in direct sunlight.Avoid storing the product in places where temperatures can quickly rise, such as near heating appliances or in direct sunlight. It should be stored in a tightly - sealed container to prevent leakage and evaporation.Store it in a tightly-sealed container to prevent leaking and evaporation. Separate it from oxidizing agents, acids, and bases during storage as these substances may react with methacrylic acid methyl ester, leading to dangerous situations.Separate it from oxidizing substances, acids and bases when storing, as these substances can react with the methacrylic methyl ester to cause dangerous situations.
In the event of a spill, act quickly.Act quickly in the event of an oil spill. First, evacuate non - essential personnel from the area.First, remove all non-essential personnel from the area. Then, if it is a small spill, absorb it with an appropriate absorbent material like sand or vermiculite.If it is a small leak, you can absorb it using an absorbent material such as sand, vermiculite, or a similar product. For larger spills, dike the area to prevent the spread of the chemical.To prevent the spread, dikes should be used for larger spills. The collected spilled material should be disposed of properly according to local regulations.The collected material should be disposed according to local regulations. Do not wash it directly into the sewer system to avoid environmental pollution.Avoid environmental pollution by not washing it directly into the sewage system.
Finally, in case of contact with the skin, immediately remove contaminated clothing and rinse the skin thoroughly with plenty of water for at least 15 minutes.In the event of skin contact, remove the contaminated clothing immediately and thoroughly rinse the skin with plenty of water. This should be done for at least 15 minute. Seek medical attention if there are any signs of irritation or burns.If you notice any signs of irritation, or burns, seek medical attention. If it gets into the eyes, rinse the eyes continuously with running water for at least 15 minutes while keeping the eyelids open, and then see a doctor as soon as possible.If it gets in the eyes, rinse them continuously with running water while keeping your eyelids wide open for at least 15 minute. Then, see a doctor immediately. If inhaled, move the affected person to an area with fresh air immediately.If the person is inhaled, they should be moved to an area where there is fresh air. If the person has difficulty breathing, provide artificial respiration and call for emergency medical help.If the person is having difficulty breathing, call emergency medical help and provide artificial respiration.
What are the storage requirements for methacrylic acid methyl ester?
Methacrylic acid methyl ester, also known as methyl methacrylate, has specific storage requirements to ensure safety and maintain its quality.To maintain quality and safety, methyl methacrylate (also known as methacrylic acid) must be stored in a specific way.
Firstly, it should be stored in a cool and well - ventilated area.It should be stored in an area that is cool and well-ventilated. High temperatures can accelerate its polymerization.High temperatures can speed up its polymerization. A storage temperature preferably below 30degC is ideal.Ideal is a temperature of below 30degC. Heat can trigger an exothermic polymerization reaction, which not only ruins the product but also poses a safety hazard as it may lead to an increase in pressure within the storage container.Heat can trigger a polymerization exothermic reaction. This not only destroys the product, but also poses a danger to safety as it could lead to an increase of pressure in the storage container.
Secondly, it must be stored away from sources of ignition, such as open flames, sparks from electrical equipment, and hot surfaces.Second, it should be stored away from ignition sources, such as open fires, sparks generated by electrical equipment and hot surfaces. Methacrylic acid methyl ester is flammable.The methyl ester of methacrylic acid is flammable. Its vapors can form explosive mixtures with air, and even a small ignition source can cause a violent explosion.Its vapors are explosive and can mix with air to form explosive mixtures. Even a small ignition source is enough to cause a violent blast.
Thirdly, the storage container should be tightly sealed.Thirdly, the container should be tightly closed. Exposure to air can cause the absorption of moisture, which may initiate hydrolysis reactions.The exposure to air may cause moisture absorption, which can initiate hydrolysis reactions. Hydrolysis can lead to the formation of methacrylic acid and methanol, altering the chemical composition and properties of the methyl methacrylate.Hydrolysis can result in the formation of methanol and methacrylic acids, which alters the chemical composition of the methylmethacrylate. A sealed container also helps prevent the evaporation of the ester, which is volatile.A sealed container can also help prevent the volatile ester from evaporating.
Fourthly, it should be stored separately from oxidizing agents.Fourthly, the methyl ester should be stored away from oxidizing agents. Oxidizers can react vigorously with methacrylic acid methyl ester, potentially leading to a dangerous chemical reaction.Oxidizers may react violently with methyl methacrylic ester and cause a potentially dangerous chemical reaction. For example, strong oxidants can cause oxidation of the double - bond in the ester structure, resulting in the formation of by - products and potentially an exothermic reaction.Strong oxidants, for example, can cause the oxidation of double-bonds in the ester structure. This results in the formation by-products and possibly an exothermic chemical reaction.
When storing about 500 units (assuming liters or kilograms) of methacrylic acid methyl ester, the storage facility should be designed to handle such quantities.The storage facility should be designed for such quantities. Adequate space should be provided around the storage containers to allow for inspection, maintenance, and in case of any leakage, to facilitate proper containment and cleanup.It is important to provide adequate space around the containers for inspection, maintenance and, in case of a leak, for proper containment and cleaning. Additionally, the storage area should be equipped with appropriate safety equipment, such as fire - fighting devices suitable for flammable liquids, and leak - detection systems to promptly identify any potential problems.The storage area should also be equipped with safety equipment such as fire-fighting devices that are suitable for flammable fluids and leak-detection systems to identify potential problems. Regular inspections of the storage containers for signs of damage, leakage, or corrosion are also crucial to ensure the safe storage of methacrylic acid methyl ester.To ensure safe storage of methyl esters, it is important to inspect the containers regularly for signs of corrosion, leakage or damage.