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Product Name | Methacrylic acid n-propyl ester |
Cas Number | 2555-49-5 |
Formula | C7H12O2 |
Molar Mass | 128.17 |
Boiling Point | 148 |
Melting Point | -65 |
Density | 0.89 |
Refractive Index | 1.415 |
Flash Point | 40 |
Vapor Pressure | 7.54 |
Solubility In Water | slightly soluble |
Viscosity | 0.5 |
Autoignition Temperature | 340 |
Heat Of Combustion | -35.1 |
Surface Tension | 27.2 |
What are the main applications of methacrylic acid n-propyl ester?
Methacrylic acid n - propyl ester has several important applications:There are many applications for methacrylic acid, n-propyl ester:
1. In the field of coatingsIn the field
Coatings are widely used to protect and decorate various substrates.Coatings can be used to protect or decorate a wide variety of substrates. Methacrylic acid n - propyl ester can be copolymerized with other monomers to prepare high - performance coating resins.Copolymerizing Methacrylic Acid n-propyl Ester with other monomers can produce high-performance coating resins. The resulting coatings have excellent weather resistance.The coatings are highly resistant to weather. This is crucial for applications such as automotive coatings and architectural coatings.This is important for applications like automotive coatings and architecture coatings. In automotive coatings, the weather - resistant property helps the car paint to maintain its color and gloss over a long time, even when exposed to sunlight, rain, and other harsh environmental conditions.In automotive coatings the weather-resistant property helps the car's paint to maintain its gloss and color for a long period of time, even if exposed to sunlight, rainfall, and other harsh conditions. In architectural coatings, it protects the building exterior from the elements, prolonging the life of the building materials.Architectural coatings protect the building's exterior from the elements and prolong the life of building materials. Additionally, these coatings also show good adhesion to different surfaces, ensuring a firm bond between the coating and the substrate, whether it is metal, wood, or plastic.These coatings are also very adhesive to different surfaces. This ensures a strong bond between the coatings and the substrate whether it be metal, wood or plastic.
2. For adhesives
Adhesives formulated with methacrylic acid n - propyl ester offer good bonding strength.Adhesives formulated using methacrylic acids n-propyl ester provide good bonding strength. They can be used to bond different types of materials.They can be used for different types of materials. For example, in the assembly of electronic devices, these adhesives can bond plastic components to metal parts.These adhesives can be used to bond metal parts and plastic components in electronic devices. Their ability to cure quickly under certain conditions, such as exposure to heat or light in some cases, makes them suitable for high - speed production lines.These adhesives are suitable for high-speed production lines because they can cure quickly in certain conditions. Moreover, they can withstand mechanical stress and temperature changes, which is important for applications where the bonded parts may be subject to vibration or thermal cycling, like in some industrial machinery or consumer electronics.They can also withstand mechanical stress, temperature changes and vibrations, which is essential for applications that may involve industrial machinery or consumer electronic devices.
3. In the production of polymers and plasticsIn the production and use of polymers
It serves as a monomer for the synthesis of specialty polymers.It is used as a monomer in the synthesis of speciality polymers. These polymers can have unique properties depending on the copolymerization partners.These polymers may have unique properties, depending on their copolymerization partners. For instance, when copolymerized with other monomers, it can improve the impact resistance of plastics.When copolymerized, it can increase the impact resistance of plastics. In the manufacturing of plastic pipes used in plumbing systems, the addition of polymers made from methacrylic acid n - propyl ester can enhance the pipes' ability to withstand pressure and impacts without cracking.The addition of polymers derived from methacrylic acids n-propyl ester to the manufacture of plastic pipes for plumbing systems can improve the pipes' ability resist pressure and impact without cracking. In the production of optical plastics, the resulting polymers can have good optical clarity, making them suitable for applications such as lenses or optical fibers.The polymers produced in the production of optical plastics can be very clear, making them ideal for lenses or optical fibers.
4. In the textile industryIn the textile industry
Methacrylic acid n - propyl ester can be used in textile finishing.Textile finishing can use n-propyl ester of methacrylic acid. It can improve the wrinkle - resistance of fabrics.It can improve the wrinkle-resistance of fabrics. When applied to textiles, it forms a cross - linked structure that helps the fabric maintain its shape.It forms a cross-linked structure when applied to textiles. This helps the fabric retain its shape. This is beneficial for clothing items, as it reduces the need for frequent ironing.It is especially useful for clothing, as it reduces ironing. It can also enhance the water - repellency of textiles to some extent, making the fabrics more suitable for outdoor or sports - related applications where protection from moisture is desired.It can also enhance water-repellency of textiles, making them more suitable for outdoor and sports-related applications that require protection from moisture.
How is methacrylic acid n-propyl ester produced?
Methacrylic acid n - propyl ester is typically produced through an esterification reaction.Esterification is the most common way to produce methacrylic acid. Here is an overview of the production process:Here is a brief overview of the production:
1. Starting MaterialsStart Materials
The main starting materials for the production of methacrylic acid n - propyl ester are methacrylic acid and n - propanol.Methacrylic Acid and n-propanol are the main materials used to produce methacrylic ester. Methacrylic acid can be obtained through various methods, such as the oxidation of isobutylene or the hydrolysis of methacrylonitrile.Methacrylic Acid can be produced in a variety of ways, including the oxidation or hydrolysis of isobutylene. n - propanol is a commonly available alcohol, which can be produced by the hydration of propylene or through fermentation processes.n-propanol, a common alcohol, can be produced through the hydration or fermentation of propylene.
2. Esterification Reaction
The esterification reaction between methacrylic acid and n - propanol is carried out in the presence of a catalyst.A catalyst is used to carry out the esterification reaction of methacrylic and n-propanol. Commonly used catalysts are sulfuric acid, p - toluenesulfonic acid, or ion - exchange resins.Catalysts commonly used are sulfuric acid or p-toluenesulfonic acids, as well as ion-exchange resins. The reaction equation is as follows:The reaction equation is:
Methacrylic acid + n - propanol = Methacrylic acid n - propyl ester + WaterMethacrylic Acid + n-propanol = Methacrylic Acid n-propyl ester and Water
This is a reversible reaction.This is a reversible chemical reaction. To drive the reaction forward, an excess of one of the reactants (usually n - propanol) is often used, and water is removed from the reaction system.To accelerate the reaction, excess n-propanol (usually) is used and water is removed.
3. Reaction ConditionsReaction Conditions
The reaction is usually carried out at elevated temperatures, typically in the range of 80 - 120 degC.The reaction is typically carried out at high temperatures, usually between 80 and 120 degC. The choice of temperature depends on factors such as the catalyst used and the desired reaction rate.The catalyst used and desired reaction rate are factors that influence the choice of temperature. Higher temperatures generally increase the reaction rate but may also lead to side reactions.Higher temperatures increase the rate of reaction, but can also cause side reactions. The reaction is often conducted under atmospheric pressure or slightly elevated pressures.The reaction is usually conducted under atmospheric pressure, or slightly elevated pressures.
4. Water RemovalWater Removal
As water is a by - product of the esterification reaction, its removal is crucial to shift the equilibrium towards the formation of the ester.Water is a by-product of the esterification process. Its removal is essential to shift the balance in favor of the ester. This can be achieved through azeotropic distillation.This can be done through azeotropic distillation. Azeotropes are mixtures of two or more substances that boil at a constant temperature and composition.Azeotropes consist of mixtures that boil at the same temperature and composition. For example, a mixture of n - propanol and water forms an azeotrope.A mixture of n-propanol and aqueous solution, for example, can form an azeotrope. By distilling the reaction mixture, the azeotrope of n - propanol and water can be removed, effectively driving the reaction forward.By distilling the mixture, it is possible to remove the azeotrope formed by n-propanol and the water. This will allow the reaction to proceed.
5. Product Separation and PurificationSeparation of products and purification
After the reaction is complete, the reaction mixture contains the desired methacrylic acid n - propyl ester, unreacted methacrylic acid and n - propanol, the catalyst, and water.The reaction mixture consists of the unreacted methacrylic acids and n-propanol, as well as the catalyst and water. First, the catalyst can be removed by methods such as neutralization (if an acid catalyst was used) followed by filtration.The catalyst can first be removed using methods such as neutralization, if an acidic catalyst was used, followed by filtration. Then, distillation is used to separate the components based on their different boiling points.Distillation is then used to separate components based on boiling points. Unreacted n - propanol, which has a lower boiling point than the ester, is distilled off first.The unreacted n-propanol is first distilled, as it has a lower melting point than the ester. Methacrylic acid, which has a higher boiling point than the ester in some cases, can be removed in a subsequent distillation step.In some cases, methacrylic acid can be removed by a subsequent distillation. The purified methacrylic acid n - propyl ester is obtained as the final product.The final product is the purified methacrylic n-propyl ester.
What are the physical and chemical properties of methacrylic acid n-propyl ester?
Methacrylic acid n - propyl ester is an organic compound with the following physical and chemical properties:Methacrylic acid is an organic compound that has the following physical and chemical characteristics:
Physical properties:Physical Properties
Appearance: It is usually a clear, colorless liquid.Appearance: It's usually a clear liquid. This appearance makes it visually similar to many other common organic solvents in the liquid state, presenting a homogeneous and transparent look.This makes it look similar to other common organic solvents when in liquid form, giving a homogeneous, transparent appearance.
Odor: It has a characteristic, pungent odor.Odor: It emits a pungent, characteristic odor. The pungent smell is often associated with many esters and carboxylic acid - related compounds, and it can be easily detected even in relatively low concentrations in the air.The pungent smell can be detected in low concentrations of air, even when it is associated with esters and carboxylic acids.
Boiling point: The boiling point of methacrylic acid n - propyl ester is around 145 - 146 degC.Boiling Point: The boiling point for methacrylic n-propyl ester is approximately 145-146 degC. This boiling point is influenced by the molecular structure, including the length of the propyl chain and the presence of the ester functional group.This boiling point can be influenced by the molecule structure, such as the length of the chain of propyl and the presence or absence of the ester functional groups. The relatively moderate boiling point allows it to be vaporized and separated from other substances with significantly different boiling points through distillation processes.The relatively low boiling point allows it be vaporized, and separated from substances with boiling points that are significantly different through distillation processes.
Melting point: Its melting point is relatively low, typically below room temperature.Melting point: Its melt point is low, usually below room temperature. This property ensures that it remains in a liquid state under normal ambient conditions, which is beneficial for its use in various applications where a fluid state is required.This property ensures it remains in a fluid state under normal ambient temperatures, which is useful for its use in different applications that require a fluid state.
Density: The density of methacrylic acid n - propyl ester is approximately 0.89 g/cm3.Density: The methacrylic n-propyl ester density is approximately 0.89g/cm3. This density value is less than that of water, meaning it will float on water if the two substances are combined.This density value is lower than water, so it will float if you combine the two substances.
Solubility: It is slightly soluble in water.It is slightly soluble. Due to the non - polar nature of the propyl chain and the relatively hydrophobic character of the ester group, it has limited interaction with water molecules.It has a limited interaction with water due to the non-polar nature of the chain and the hydrophobic nature of the ester group. However, it is highly soluble in many organic solvents such as ethanol, acetone, and toluene.It is highly soluble, however, in many organic solvents, such as ethanol and acetone. This solubility in organic solvents makes it suitable for use in formulations and reactions that occur in organic media.Its solubility in organic solvants makes it ideal for use in formulations or reactions that take place in organic media.
Chemical properties:Chemical properties
Reactivity of the double bond: Methacrylic acid n - propyl ester contains a carbon - carbon double bond in its structure.Reactivity of the double bonds: Methacrylic Acid n-propyl Ester contains a double carbon-carbon bond in its structure. This double bond is highly reactive and can participate in addition reactions.This double bond can be highly reactive and participate in additional reactions. For example, it can undergo polymerization reactions.It can, for example, undergo polymerization. In the presence of appropriate initiators, the double bonds of multiple methacrylic acid n - propyl ester molecules can break and link together to form long - chain polymers.In the presence appropriate initiators, multiple methacrylic acids n -propyl esters molecules can break their double bonds and link together to create long-chain polymers. These polymers are widely used in the production of coatings, adhesives, and plastics.These polymers are widely utilized in the productions of plastics, adhesives and coatings.
Hydrolysis: The ester group in methacrylic acid n - propyl ester can undergo hydrolysis reactions.Hydrolysis: The ester groups in methacrylic acids n-propyl ester may undergo hydrolysis reactions. In the presence of an acid or a base and water, the ester bond can be cleaved.The ester bond may be cleaved in the presence of water and an acid or base. In acidic hydrolysis, the reaction produces methacrylic acid and n - propanol.In acidic hydrolysis the reaction produces n-propanol and methacrylic acids. In basic hydrolysis, the carboxylate salt of methacrylic acid and n - propanol are formed.In basic hydrolysis the carboxylate of methacrylic and n-propanol is formed. This hydrolysis reaction is important in understanding the degradation and chemical transformation of the compound in different environments.This hydrolysis reaction helps to understand the degradation and chemical changes of the compound under different environmental conditions.
Reaction with amines: It can react with amines to form amides.Reaction with Amines: It can form amides by reacting with amines. This reaction is useful in the synthesis of various organic compounds, especially those with amide functional groups, which are important in the fields of pharmaceuticals and materials science.This reaction is useful for the synthesis of organic compounds with amide functional groups. These compounds are important in pharmaceuticals and materials sciences.
What safety precautions should be taken when handling methacrylic acid n-propyl ester?
When handling methacrylic acid n - propyl ester, several important safety precautions should be taken.Safety precautions are important when handling methacrylic n-propyl ester.
First, ensure proper ventilation. Methacrylic acid n - propyl ester is volatile, and its vapors can be harmful if inhaled.Inhaling the vapors of Methacrylic Acid n - Propyl Ester can be dangerous. Working in a well - ventilated area, preferably with local exhaust ventilation systems, helps to remove the vapors from the work environment.The vapors can be removed from the workplace by working in an area that is well-ventilated, preferably with local exhaust ventilators. This reduces the risk of respiratory problems such as irritation of the nose, throat, and lungs.This reduces the likelihood of respiratory problems, such as irritation to the nose, throat and lungs. Inadequate ventilation can also lead to the accumulation of vapors, which may pose a fire or explosion hazard as the substance is flammable.Inadequate air circulation can lead to an accumulation of vapors that may pose a fire hazard or explosion risk as the substance in question is flammable.
Second, wear appropriate personal protective equipment (PPE).Wear appropriate personal protective equipment. This includes chemical - resistant gloves, usually made of materials like nitrile or neoprene, to prevent skin contact.Chemical-resistant gloves made from materials such as nitrile and neoprene are recommended to avoid skin contact. Skin exposure to methacrylic acid n - propyl ester can cause irritation, redness, and in severe cases, chemical burns.Skin contact with methacrylic acids n-propyl ester may cause irritation, redness and, in severe cases chemical burns. Safety goggles or a face shield should be worn to protect the eyes.To protect the eyes, safety goggles or face shields should be worn. Splashes of the substance into the eyes can result in significant eye damage, including corneal abrasions and potential vision impairment.Splashes into the eye can cause serious damage, including corneal erosions and vision impairment. A lab coat or other protective clothing should be worn to cover the body and prevent contamination of regular clothing.Wear a lab coat or other protective clothing to cover your body and prevent contamination.
Third, be cautious about its flammability.Third, be careful about its flammability. Methacrylic acid n - propyl ester has a relatively low flash point.The flash point of n-propyl ester is relatively low. Keep it away from sources of ignition such as open flames, sparks from electrical equipment, and hot surfaces.Keep it away form sources of ignition, such as open flames and sparks from electrical appliances. Use explosion - proof electrical equipment in areas where the substance is handled.Use explosion-proof electrical equipment in the areas where this substance is handled. Store it in a cool, dry place, away from direct sunlight and heat sources.Store it in a dry, cool place away from heat sources and direct sunlight. Also, ensure that storage areas are designed to prevent the spread of fire in case of an ignition.Also, make sure that the storage area is designed to prevent fire spread in case of ignition.
Fourth, have spill response procedures in place.Fourth, implement spill response procedures. In case of a spill, immediately evacuate non - essential personnel from the area.In the event of a spillage, evacuate all non-essential personnel from the affected area. Wear appropriate PPE and use absorbent materials, like sand or vermiculite, to contain and clean up the spill.Wear the appropriate PPE, and use absorbent material, such as sand or Vermiculite to contain and clean up a spill. Do not use water to clean up the spill directly as it may spread the substance.Water can spread the substance, so do not use it to clean the spill. Dispose of the contaminated absorbent materials properly according to local environmental regulations.Dispose the contaminated absorbent material according to local environmental regulations.
Finally, be aware of its potential health effects.Be aware of the potential health effects. Besides the immediate risks to the skin, eyes, and respiratory system, long - term exposure may have more serious health consequences.Long-term exposure can have more serious health effects than the immediate risks for the skin, eyes and respiratory system. Workers should be informed about the hazards of the substance and trained on proper handling procedures.Workers should be trained in the proper handling of the substance, and informed about its hazards. Regular health check - ups for those frequently exposed can help detect any early signs of health issues related to the handling of methacrylic acid n - propyl ester.Regular health check-ups for those who are frequently exposed to methacrylic acids n -propyl ester can help detect early signs of any health issues.
What are the storage requirements for methacrylic acid n-propyl ester?
Methacrylic acid n - propyl ester should be stored under the following conditions:The following conditions should be followed when storing Methacrylic Acid n-Propyl Ester:
1. Cool and Well - Ventilated LocationCool and well - Ventilated Location
- It is crucial to store methacrylic acid n - propyl ester in a cool place.It is important to store the methacrylic n-propyl ester at a cool temperature. High temperatures can accelerate its decomposition or polymerization reactions.High temperatures can speed up the decomposition and polymerization reactions. A storage temperature range of around 2 - 8degC is often recommended.It is recommended to store the product at a temperature between 2 and 8degC. This relatively low temperature helps to maintain its chemical stability.This low temperature helps maintain its chemical stability. For example, if the temperature is too high, the ester may start to break down into its components or polymerize into long - chain molecules, which can change its physical and chemical properties.If the temperature is too hot, the ester can start to break into its components, or polymerize, which can change the physical and chemical properties.
- Good ventilation is also essential.A good ventilation system is also important. Adequate ventilation helps to prevent the build - up of vapors.Adequate ventilation prevents the build-up of vapors. If the vapors accumulate in a confined space, they can pose a significant fire and explosion hazard due to the flammable nature of methacrylic acid n - propyl ester.The flammable nature methacrylic n-propyl ester can cause a fire or explosion hazard if the vapors are accumulated in a confined area.
2. Separation from Incompatible SubstancesSeparation from Incompatible Substances
- This ester should be stored away from strong oxidizing agents.This ester must be stored away from strong oxygenating agents. Oxidizers can react violently with methacrylic acid n - propyl ester, potentially leading to fires or explosions.Oxidizers may react violently with the methacrylic n-propyl ester and cause fires or explosions. For instance, substances like potassium permanganate or hydrogen peroxide are strong oxidizers and must be kept far from the ester.For example, substances such as potassium permanganate and hydrogen peroxide can be strong oxidizers. They should be kept away from the ester.
- It should also be separated from bases.It should be kept away from bases. Bases can cause hydrolysis of the ester, breaking it down into methacrylic acid and n - propyl alcohol.Bases can cause the ester to hydrolyze, resulting in methacrylic alcohol and n-propyl alcohol. This not only ruins the integrity of the product but can also be a hazardous reaction in some cases, especially if heat is generated during the hydrolysis process.This can not only ruin the integrity of the product, but it can also be a dangerous reaction in some cases.
3. Use of Appropriate ContainersUse of Appropriate Canisters
- The storage containers for methacrylic acid n - propyl ester should be made of materials that are resistant to its corrosive effects.Containers for n-propyl ester of methacrylic acids should be made from materials that resist its corrosive properties. Commonly, stainless - steel or high - density polyethylene (HDPE) containers are used.Most commonly, stainless steel or high-density polyethylene (HDPE), containers are used. Stainless - steel provides good durability and resistance to chemical attack, while HDPE is lightweight, cost - effective, and also has good chemical resistance.HDPE is lightweight and cost-effective, while stainless - steel offers good durability and chemical resistance.
- The containers should be tightly sealed to prevent leakage and evaporation.Containers should be tightly sealed in order to prevent leakage or evaporation. Leakage can lead to environmental contamination and also increase the risk of fire and explosion in the surrounding area.Leakage may cause environmental contamination, and increase the risk of a fire or explosion in the area. Evaporation not only results in the loss of product but also contributes to the presence of flammable vapors in the air.Evaporation can lead to a loss of product, but it also contributes flammable vapors into the air.
4. Fire - Prevention MeasuresFire Prevention Measures
- Since methacrylic acid n - propyl ester is flammable, the storage area should be equipped with appropriate fire - fighting equipment.Fire extinguishers for flammable liquid fires, such as dry-chemical or foam extinguishers, are required. This includes fire extinguishers suitable for flammable liquid fires, such as dry - chemical or foam extinguishers.Fire extinguishers for flammable liquids such as dry-chemical or foam extinguishers are recommended. The storage facility should also have a clear evacuation plan in case of a fire.The storage facility must also have a clearly defined evacuation plan in the event of a fire.
- Avoid any potential sources of ignition in the storage area, such as open flames, sparks from electrical equipment, or hot surfaces.Avoid any sources of ignition, such as open fires, sparks or hot surfaces. All electrical equipment in the storage area should be explosion - proof to prevent the ignition of flammable vapors.To prevent the ignition of flammable gases, all electrical equipment in the storage space should be explosion-proof.