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Methacrylicacid,esterwith1,2-propanediol


Properties
Product Name Methacrylic acid, ester with 1,2-propanediol
Cas Number 27813-02-1
Formula C7H12O3
Molar Mass 144.17 g/mol
Density 1.05 g/cm³
Boiling Point 188 °C
Refractive Index 1.448
Flash Point 98 °C
Solubility In Water slightly soluble
Viscosity 12-18 mPa·s
Appearance colorless liquid
Vapor Pressure 0.3 mmHg at 20 °C
Autoignition Temperature 490 °C
FAQ

What are the main applications of methacrylic acid ester with 1,2-propanediol?

Methacrylic acid ester with 1,2 - propanediol, also known as 1,2 - propanediol methacrylate, has several main applications.There are several applications for 1,2 – propanediol - methacrylate.
In the coatings industry, it plays a crucial role.It is a vital component in the coatings industry. It can be used to formulate high - performance coatings.It can be used in the formulation of high-performance coatings. These coatings have excellent adhesion properties, enabling them to firmly attach to various substrates such as metals, plastics, and wood.These coatings are characterized by excellent adhesion, allowing them to adhere firmly to various substrates like metals, wood, and plastics. For example, in automotive coatings, the addition of this ester can enhance the scratch - resistance and weather - resistance of the paint.In automotive paints, for example, adding this ester can improve the paint's scratch-resistance and weather-resistance. The double - bond structure in the molecule allows for cross - linking during the curing process, which improves the hardness and durability of the coating film.The double-bond structure of the molecule allows cross-linking during the curing process. This improves the hardness, durability and longevity of the coating film. This makes the coated surfaces more resistant to abrasion, chemicals, and environmental factors, extending the lifespan of the coated products.This increases the durability of the coating film by making it more resistant to abrasion and chemicals.

In the field of adhesives, 1,2 - propanediol methacrylate is an important component.1,2 - Propanol Methacrylate is a key component in the field of adhesives. It can be used to create reactive adhesives.It can be used to make reactive adhesives. The reactive nature of this ester means that it can participate in polymerization reactions upon exposure to heat, light, or certain catalysts.This ester is reactive, which means it can participate in polymerization reaction when exposed to heat, light or certain catalysts. This results in the formation of a strong bond between the adhered materials.This leads to a strong bond being formed between the materials. These adhesives are often used in the assembly of electronic devices, where high - strength and reliable bonding are required.These adhesives are used in the assembly and repair of electronic devices where a high-strength bond is required. They can bond different types of materials together, such as bonding circuit boards to enclosures or attaching display panels, providing a stable connection that can withstand mechanical stress and temperature changes.They can bond materials together. For example, they can bond circuit boards to enclosures, or attach display panels.

The dental materials area also benefits from this ester.This ester is also used in the dental materials industry. It is used in the production of dental composites.It is used to make dental composites. Dental composites need to have good mechanical properties, biocompatibility, and aesthetic qualities.Dental composites must have good mechanical properties, as well as biocompatibility and aesthetic qualities. The methacrylic acid ester with 1,2 - propanediol can be copolymerized with other monomers to form a matrix for dental fillers.Copolymerizing the methacrylic ester with 1,2 propanediol with other monomers can form a matrix to hold dental fillers. It helps in achieving the right balance of hardness, flexibility, and wear - resistance in dental restorations.It helps to achieve the right balance between hardness, flexibility and wear-resistance in dental restorations. Additionally, its ability to polymerize quickly under light irradiation makes it suitable for use in dental procedures, allowing dentists to efficiently fill cavities and restore teeth while ensuring the long - term stability of the restoration.Its ability to polymerize rapidly under light irradiation also makes it suitable for dental procedures. This allows dentists to efficiently fill cavity and restore teeth, while ensuring long-term stability of the restoration.

In the production of inks, especially UV - curable inks, this ester is utilized.This ester is used in the production of inks and UV-curable inks. UV - curable inks offer advantages such as fast drying, high color intensity, and environmental friendliness.UV-curable inks have many advantages, including fast drying, high color intensity and environmental friendliness. The 1,2 - propanediol methacrylate can be part of the monomer mixture in these inks.These inks can contain 1,2 - propandiol methacrylate as part of their monomer mixture. When exposed to ultraviolet light, it polymerizes rapidly, transforming the liquid ink into a solid, durable film on the printing substrate.It polymerizes quickly when exposed to ultraviolet light. This transforms the liquid ink onto the printing substrate into a durable, solid film. This is useful for printing on various materials like paper, cardboard, and plastics, providing high - quality prints with good adhesion and resistance to fading and scratching.This is ideal for printing on a variety of materials, including paper, cardboard and plastics. It provides high-quality prints with good adhesion, and resists fading and scratches.

What are the safety precautions when handling methacrylic acid ester with 1,2-propanediol?

Methacrylic acid ester with 1,2 - propanediol involves substances that need careful handling due to potential safety risks.There are potential safety hazards when handling Methacrylic Acid Ester with 1,2 – Propanol.
Firstly, personal protective equipment is crucial.Personal protective equipment is essential. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can resist the penetration of many organic chemicals including methacrylic acid esters.Nitrile gloves can be a good option as they resist the penetration by many organic chemicals, including methacrylic acids esters. This helps prevent skin contact, which can lead to irritation, burns, or potential absorption into the body.This will help prevent skin contact that can cause irritation, burns or absorption into the system. Additionally, wear safety goggles or a face shield.Wear safety goggles, or a face shield. These protect the eyes from splashes.These shield the eyes from splashes. Methacrylic acid esters can cause severe eye damage, and even a small drop in the eye can result in long - term vision problems.Even a small amount of methacrylic acid ester can cause serious eye damage.

Secondly, work in a well - ventilated area.Second, make sure you are working in an area that is well-ventilated. Methacrylic acid esters may emit vapors that can be harmful if inhaled.Inhaling vapors from methacrylic acid ester can be harmful. Adequate ventilation helps to disperse these vapors, reducing the risk of respiratory problems.Adequate ventilation can help disperse the vapors and reduce the risk of respiratory issues. A local exhaust ventilation system can be installed near the work area to effectively remove the vapors at the source.Installing a local exhaust ventilation system near the work area will remove the vapors directly at their source. If working in a large - scale setting, ensure the entire workspace has good general ventilation, such as through fans or air - conditioning systems designed for chemical - handling environments.If you are working in a large-scale setting, make sure that the entire workspace is well ventilated, either through fans or air-conditioning systems designed for chemical-handling environments.

Thirdly, be cautious about fire and explosion risks.Thirdly, be aware of the risks associated with fire and explosion. Methacrylic acid esters are often flammable.Methacrylic esters can be flammable. Keep all sources of ignition away, including open flames, sparks from electrical equipment, and hot surfaces.Keep away from all sources of ignition, such as open flames, sparks coming from electrical equipment and hot surfaces. Use explosion - proof electrical equipment in the work area.Use explosion-proof electrical equipment around the work area. If there is a risk of spillage, have appropriate fire - extinguishing equipment nearby.If there is any risk of spillage, keep the appropriate fire-extinguishing equipment near. Dry chemical extinguishers are suitable for dealing with fires involving these substances.Dry chemical extinguishers can be used to put out fires caused by these substances.

Fourthly, in case of spills, take immediate action.In the event of spills, you should take immediate action. First, evacuate the area if the spill is large enough to pose a significant risk.If the spill is large and poses a risk, you should evacuate the area. Then, wear the proper protective gear as mentioned above.Wear the appropriate protective gear, as described above. Use absorbent materials like sand or vermiculite to soak up the spill.To absorb the spill, use absorbent materials such as sand or Vermiculite. Avoid using materials that can react with the methacrylic acid ester.Avoid materials that may react with the ester of methacrylic. Dispose of the contaminated absorbent materials in accordance with local environmental regulations.Dispose the contaminated absorbent material in accordance with local regulations.

Finally, be aware of the reactivity of these substances.Be aware of their reactivity. Methacrylic acid esters can react with strong oxidizing agents, acids, and bases.Methacrylic acids esters can react strongly with acids, bases, and strong oxidizing agents. Store them separately from such substances to prevent potentially dangerous reactions.Store them away from these substances to avoid potentially dangerous reactions. Keep an emergency response plan in place, and ensure all workers are trained on how to handle accidents and exposures properly.Make sure you have an emergency response plan and that all workers are properly trained to handle accidents and exposures.

How is methacrylic acid ester with 1,2-propanediol produced?

Methacrylic acid ester with 1,2 - propanediol, also known as 1,2 - propanediol methacrylate, can be produced through an esterification reaction.Esterification can produce 1,2 – propanediol - methacrylate.
The raw materials required are methacrylic acid and 1,2 - propanediol.Methacrylic acid is required, as well as 1,2 - propanol. Methacrylic acid has a carboxylic acid group (-COOH), and 1,2 - propanediol has two hydroxyl groups (-OH).Methacrylic Acid has a carboxylic group (-COOH), while 1,2 - Propanediol contains two hydroxyl groups. In the presence of a catalyst, an esterification reaction occurs between the carboxylic acid group of methacrylic acid and one of the hydroxyl groups of 1,2 - propanediol.In the presence a catalyst, the carboxylic group of methacrylic and the hydroxyl group of 1,2 – propanediol undergo an esterification.

Commonly used catalysts for this type of esterification reaction include sulfuric acid, p - toluenesulfonic acid, etc.Catalysts commonly used for this type esterification reaction are sulfuric acid, p-toluenesulfonic acids, etc. Sulfuric acid is a strong acid catalyst.Sulfuric is a powerful acid catalyst. It can protonate the carbonyl oxygen of methacrylic acid, making the carbonyl carbon more electrophilic.It can protonate carbonyl oxygen in methacrylic acids, making carbonyl carbons more electrophilic. Then, the hydroxyl group of 1,2 - propanediol can attack the carbonyl carbon, followed by a series of proton transfer and dehydration steps to form the ester product.The hydroxyl group from 1,2 - propanol can then attack the carbonyl, followed by a number of proton transfer steps and dehydration to form the ester. p - toluenesulfonic acid is a relatively mild and efficient catalyst.The p-toluenesulfonic is a mild and efficient catalyser. It also promotes the reaction by providing protons for the activation of the carboxylic acid group.It also promotes reaction by providing protons to activate the carboxylic group.

To drive the reaction forward, it is often necessary to remove the water generated during the reaction.It is often necessary, to drive the reaction along, to remove the water produced during the reaction. This can be achieved by using azeotropic distillation.Azeotropic distillation can be used to achieve this. For example, adding a solvent such as toluene, which can form an azeotrope with water.Addition of a solvent, such as toluene can create an azeotrope when combined with water. As the reaction proceeds, the water - toluene azeotrope is distilled out of the reaction system, shifting the equilibrium of the esterification reaction towards the product side according to Le Chatelier's principle.As the reaction progresses, the water-toluene azeotrope will be distilled out of reaction system, shifting equilibrium towards the product according to Le Chatelier’s principle.

In addition, during the reaction, temperature control is crucial.Temperature control is also crucial during the reaction. Usually, the reaction temperature is set in the range of 80 - 120 degC.The reaction temperature is usually set between 80 and 120 degC. If the temperature is too low, the reaction rate will be slow; if the temperature is too high, side reactions may occur, such as polymerization of methacrylic acid or decomposition of the product.If the temperature of the reaction is too low, it will slow down the rate of the reaction; if it is too high, there may be side reactions such as the polymerization of the methacrylic acids or the decomposition of product.

After the reaction is completed, the product needs to be purified.Purification is required after the reaction has been completed. This may involve processes such as neutralization to remove the catalyst (if an acidic catalyst was used), washing to remove unreacted raw materials and by - products, and distillation to obtain the pure 1,2 - propanediol methacrylate.This can involve processes such a neutralization to remove catalyst (if acidic catalysts were used), washing to remove unreacted materials and by-products, and distillation in order to obtain pure 1,2 – propanediol - methacrylate. First, the reaction mixture is neutralized with a base such as sodium carbonate solution.The reaction mixture is first neutralized using a base, such as sodium carbonate. Then, it is washed with water several times to remove water - soluble impurities.It is then washed several times with water to remove any water-soluble impurities. Finally, through distillation under reduced pressure, the pure 1,2 - propanediol methacrylate can be obtained, which can be used in various applications such as in the production of coatings, adhesives, and polymers.The 1,2 -propanediol methacrylate is then obtained by distillation under reduced pressurized. It can be used for various applications, such as the production of adhesives, polymers, and coatings.

What are the physical and chemical properties of methacrylic acid ester with 1,2-propanediol?

Methacrylic acid ester with 1,2 - propanediol likely refers to a compound formed by the reaction of methacrylic acid and 1,2 - propanediol, often a type of methacrylic ester with a propanediol - based structure.Methacrylic Acid Ester with 1,2 Propanol is a compound that is formed by the reaction between methacrylic and 1,2 propanediol. It's usually a type methacrylic esters with a propanediol-based structure.
Physical properties:Physical Properties

Appearance: It is usually a colorless to slightly yellowish liquid.Appearance: The liquid is usually colorless or slightly yellowish. This appearance is common for many organic esters.This is a common appearance for many organic esters. The color can be influenced by factors such as purity and the presence of minor impurities.The color of an ester can be affected by factors like purity and minor impurities.

Odor: It typically has a characteristic, somewhat sweet - fruity odor, which is a trait shared by many esters.Odor: It has a characteristic, sweet-fruity odor. This is a trait that many esters share. The odor can be relatively pungent in high concentrations but is often pleasant at lower levels.The odor is pungent at high concentrations, but pleasant at lower concentrations.

Boiling point: The boiling point depends on the specific structure of the ester.Boiling point: the boiling point depends on specific structure of ester. Generally, esters of this type have boiling points in the range where they can vaporize under normal laboratory or industrial heating conditions.Esters of this kind have boiling points that are within the range at which they can vaporize when heated under normal laboratory or industrial conditions. For esters derived from methacrylic acid and 1,2 - propanediol, the boiling point is likely to be in the range of several hundred degrees Celsius, depending on factors like molecular weight and the degree of branching in the molecule.Esters derived from 1,2 - propan-2-ol and methacrylic acids have boiling points that range between several hundred degrees Celsius depending on factors such as molecular weight or the degree of branching within the molecule.

Solubility: It is soluble in many organic solvents such as ethanol, acetone, and toluene.It is soluble with many organic solvents, such as ethanol and acetone. This solubility in organic solvents is due to the non - polar nature of the ester functional group and the hydrocarbon - like parts of the molecule.This is due to the non-polar nature of the ester group and the hydrocarbon-like parts of the molecule. However, it has limited solubility in water.It is only soluble in water. The polar - non - polar balance of the molecule restricts its miscibility with water, as water is a highly polar solvent.The polar-non-polar balance of the molecule limits its miscibility in water, which is a highly-polar solvent.

Density: The density is usually close to that of water but may be slightly less or more depending on the exact molecular structure.Density: The density of esters is typically close to water, but can be slightly higher or lower depending on their molecular structure. Esters with similar structures often have densities in the range of 0.9 - 1.1 g/cm3.Esters with similar structure often have densities between 0.9 and 1.1 g/cm3.

Chemical properties:Chemical properties

Reactivity towards polymerization: One of the most important chemical properties is its ability to polymerize.Reactivity towards polymerization is one of the most important properties. The methacrylic acid moiety contains a carbon - carbon double bond, which can undergo addition polymerization reactions.The methacrylic moiety contains a double carbon-carbon bond that can undergo addition polymerization. This makes it useful in the production of polymers such as poly(methacrylates).This makes it useful for the production of polymers, such as poly(methacrylates). Polymerization can be initiated by heat, light, or the use of initiators like peroxides.Heat, light or peroxides can initiate polymerization.

Hydrolysis: The ester bond in the methacrylic acid ester with 1,2 - propanediol is susceptible to hydrolysis.Hydrolysis: The ester bonds in the methacrylic ester with 1,2 propanediol are susceptible to hydrolysis. In the presence of water and an acid or base catalyst, the ester bond can break.The ester bond may break in the presence of an acid or a base catalyst and water. In acidic conditions, the reaction is reversible, and the methacrylic acid and 1,2 - propanediol are formed.In acidic conditions the reaction can be reversed and 1,2 – propanediol and methacrylic acids are formed. In basic conditions, the reaction goes to completion, forming the carboxylate salt of methacrylic acid and the alcohol.In basic conditions, this reaction is completed, forming methacrylic alcohol and its carboxylate salt.

Reaction with nucleophiles: The carbonyl carbon of the ester is electrophilic, making it reactive towards nucleophiles.Reaction with nucleophiles. The carbonyl carbon in the ester is an electrophile, which makes it reactive to nucleophiles. Amines, for example, can react with the ester to form amides through a nucleophilic acyl substitution reaction.Amines can, for instance, react with the ester through a nucleophilic substitution reaction to form amides. This reactivity allows for the modification of the molecule to introduce different functional groups for various applications in materials science and organic synthesis.This reactivity allows the modification of a molecule to introduce functional groups for different applications in materials science or organic synthesis.

What are the storage requirements for methacrylic acid ester with 1,2-propanediol?

Methacrylic acid ester with 1,2 - propanediol has specific storage requirements to ensure its stability, safety, and quality.Storage requirements for Methacrylic Acid Ester with 1,2 – Propanol are specific to ensure its safety, stability, and quality.
First, storage temperature is crucial.The temperature of the storage area is important. It should be stored in a cool place.It should be kept in a cool area. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. An ideal storage temperature range is typically around 2 - 8 degrees Celsius.Ideal storage temperatures are typically between 2 and 8 degrees Celsius. Storing it at lower temperatures helps slow down any potential degradation processes and reduces the risk of premature polymerization.Storing it below this temperature range helps to slow down any possible degradation processes and reduces premature polymerization. Temperatures above this range can cause the ester to react more rapidly, potentially leading to changes in its physical and chemical properties.Temperatures higher than this range can cause an ester to react faster, which could lead to changes in the physical and chemical properties.

Second, the storage environment should be dry.Second, the environment in which you store your product should be dry. Moisture can have a significant impact on methacrylic acid ester with 1,2 - propanediol.Moisture has a major impact on the methacrylic ester with 1,2 propanediol. Water can initiate hydrolysis reactions, which can break down the ester into its component parts.Water can cause hydrolysis reactions that can break the ester down into its constituent parts. This not only changes the chemical composition but also affects the performance of the material.This not only affects the chemical composition, but also the performance of the material. Therefore, it is important to store it in an area with low humidity, and containers should be tightly sealed to prevent moisture ingress.It is therefore important to store the material in an area that has low humidity. Containers should also be tightly sealed to avoid moisture ingress.

Third, the storage location should be well - ventilated.Third, the storage area should be well-ventilated. Methacrylic acid esters may release volatile organic compounds (VOCs).Methacrylic esters can release volatile organic compounds. Adequate ventilation helps to prevent the build - up of these vapors.Adequate ventilation can help prevent the build-up of these vapors. If the vapors accumulate in a confined space, there is a risk of explosion or fire, especially as these esters are often flammable.The vapors can cause an explosion or fire if they are confined in a small space, especially since these esters tend to be flammable. A well - ventilated area also helps to keep the air around the storage containers fresh, reducing the potential for any chemical reactions caused by the presence of other reactive gases in the air.A well-ventilated area will also help to keep the air fresh around the storage containers, reducing any potential chemical reactions caused by other reactive gases.

Fourth, containers for storage must be carefully selected.The fourth thing to do is to carefully select the containers that will be used for storage. They should be made of materials that are compatible with methacrylic acid ester with 1,2 - propanediol.Materials that are compatible with 1,2 – propanediol and methacrylic ester should be used. For example, some plastics may react with the ester over time, while metal containers might cause corrosion or catalytic effects on certain reactions.Metal containers may cause corrosion or catalytic reactions on certain reactions. Some plastics, for example, may react with ester over a period of time. Glass containers are often a good choice as they are generally inert and do not react with the ester.Glass containers are a good option as they are inert, and don't react with ester. However, if metal containers are used, they should be lined with a suitable material to prevent any unwanted interactions.If metal containers are being used, it is important to line them with a suitable material in order to avoid any unwanted interactions.

Finally, storage areas should be separated from sources of ignition.Finally, storage areas must be kept away from ignition sources. Given the flammable nature of methacrylic acid esters, any open flames, sparks from electrical equipment, or hot surfaces should be kept well away from the storage location.Due to the flammability of methacrylic acids esters, open flames, sparks or hot surfaces must be kept away from the storage area. This includes ensuring that there are no smoking areas nearby and that electrical equipment in the storage area is properly grounded and explosion - proof if necessary.This includes making sure that there aren't any smoking areas near the storage area and that all electrical equipment is properly grounded, and explosion-proof if needed.