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Product Name | Methylacrylic Acid |
Cas Number | 79-41-4 |
Formula | C4H6O2 |
Molar Mass | 86.09 g/mol |
Boiling Point | 162-163°C |
Melting Point | 15°C |
Density | 1.015 g/cm³ |
Solubility In Water | Soluble |
Refractive Index | 1.431 |
Viscosity | 5.5 mPa·s |
Vapor Pressure | 0.59 mmHg at 25°C |
Flash Point | 68°C |
Pka | 4.66 |
Logp | 0.93 |
What are the main applications of methylacrylic acid?
Methylacrylic acid, also known as methacrylic acid, has several important applications across various industries.Methacrylic acid is also known as methylacrylic acid and has many important applications in various industries.
One of the major applications is in the production of polymers and copolymers.It is used in the production and copolymerization of polymers. It can be polymerized to form poly(methylacrylic acid), which is used in the manufacturing of coatings.It can be polymerized into poly(methylacrylic acids), which is used to manufacture coatings. These coatings offer good adhesion, hardness, and chemical resistance.These coatings are chemically resistant, have good adhesion and hardness. They are applied in automotive finishes, where they help protect the vehicle body from scratches, corrosion, and environmental factors.These coatings are used in automotive finishes to protect the vehicle from environmental factors, corrosion and scratches. In the construction industry, such coatings are used on building facades to enhance durability and aesthetics.In the construction industry these coatings are applied to building facades in order to improve durability and aesthetics.
Methylacrylic acid is also crucial in the synthesis of acrylic resins.The synthesis of acrylic resins also relies on methylacrylic acid. When copolymerized with other monomers like methyl methacrylate, it can modify the properties of the resulting resin.It can be copolymerized to modify the properties of a resin when combined with other monomers, such as methyl methacrylate. These acrylic resins are widely used in the production of adhesives.These acrylic resins can be used to make adhesives. They provide strong bonding strength, quick drying, and good flexibility, making them suitable for bonding different materials such as plastics, metals, and glass.They are flexible, have a quick drying time, and provide a strong bonding strength. This makes them ideal for bonding materials like plastics, metals and glass. For example, in the assembly of electronic devices, these adhesives are used to bond components together.These adhesives are used in electronic device assembly to bond components.
In the area of dental materials, methylacrylic acid - based polymers play a significant role.Polymers based on methylacrylic acids are important in the field of dental materials. Dental composites often contain monomers derived from methylacrylic acid.Dental composites contain monomers derived methylacrylic acids. These materials are used for filling cavities as they can be easily molded into the desired shape, have good mechanical properties similar to natural teeth, and bond well to tooth structure.These materials are often used to fill cavities because they are easy to mold, have mechanical properties that are similar to natural teeth and bond well with tooth structure. Dental prosthetics, such as dentures, are also made from polymers based on methylacrylic acid due to their biocompatibility, ease of processing, and long - term stability in the oral environment.Dentures and other dental prosthetics are made of polymers based upon methylacrylic acids due to their biocompatibility.
Another application is in the production of ion - exchange resins.A second application is the production of resins that exchange ions. Methylacrylic acid can be incorporated into the resin structure to introduce acidic functional groups.The resin structure can be modified to include acidic functional groups by incorporating methylacrylic acid. These ion - exchange resins are used in water treatment processes to remove impurities, such as heavy metal ions and unwanted anions.These ion-exchange resins are used to remove impurities such as heavy metals ions and unwanted ions from water treatment processes. They can also be used in the purification of chemicals and in some industrial separation processes.They can be used to purify chemicals and in certain industrial separation processes.
In the textile industry, methylacrylic acid can be used to modify the properties of fibers.In the textile industry methylacrylic acids can be used to modify fiber properties. By copolymerizing with other monomers and applying the resulting polymer to fabrics, it can improve properties like dyeability, water - resistance, and soil - release.By copolymerizing and applying the polymer to fabrics it can improve properties such as dyeability, soil - release, and water resistance. This helps in creating textiles that are more durable, easier to clean, and have enhanced colorfastness.This allows for the creation of textiles with improved colorfastness, durability, and ease of cleaning.
What are the safety precautions when handling methylacrylic acid?
Methylacrylic acid is a colorless liquid with a pungent odor, and it is both corrosive and flammable.It is a colorless liquid that has a pungent smell. It is also corrosive, and flammable. Here are the safety precautions when handling it.Here are some safety precautions to take when handling it.
First, personal protective equipment is essential.Personal protective equipment is a must. Wear appropriate chemical - resistant clothing, such as a full - body chemical - resistant suit made of materials like neoprene or butyl rubber.Wear chemical-resistant clothing such as a full-body chemical-resistant suit made from materials like butyl or neoprene. This can prevent the acid from coming into contact with the skin and causing burns or irritation.This will prevent the acid from contacting the skin, causing irritation or burns. For the hands, use thick chemical - resistant gloves, preferably made of nitrile or neoprene, to ensure a good grip while handling containers and to protect against acid splashes.To protect your hands from acid splashes, wear thick, chemical-resistant gloves made of nitrile, neoprene or nitrile. Safety goggles or a face shield should be worn at all times.Always wear safety goggles or face shields. Methylacrylic acid can cause severe eye damage, and even a small splash can lead to permanent vision problems.Even a small splash of methylacrylic acid may cause permanent vision problems.
Second, ensure proper ventilation in the handling area.Install local exhaust ventilation systems near the workbench or storage area to remove any vapors that may be released. Install local exhaust ventilation systems near the workbench or storage area to remove any vapors that may be released.Install local exhaust ventilation near the workbench and storage area to remove vapors. Good general ventilation in the room is also necessary to prevent the accumulation of methylacrylic acid vapors, which can be harmful if inhaled.It is also important to have good ventilation in the room in order to prevent the accumulation methylacrylic acids vapors that can be harmful when inhaled. In case of a large - scale operation, consider using a fume hood to contain and exhaust the vapors safely.Consider using a fume-hood for large-scale operations to safely contain and exhaust vapors.
Third, when storing methylacrylic acid, keep it in a cool, dry, and well - ventilated place, away from sources of heat, ignition, and oxidizing agents.Third, store methylacrylic acids in a cool and dry place that is well-ventilated, away from heat sources, ignition sources, and oxidizing agents. It should be stored in tightly sealed containers made of suitable materials, such as polyethylene or stainless steel, to prevent leakage.To prevent leakage, it should be stored in tightly-sealed containers made from suitable materials such as stainless steel or polyethylene. Label the containers clearly with the name of the chemical, its hazards, and any relevant safety information.Label the containers with the name of chemical, its hazards and any relevant safety information.
Fourth, during the handling process, be extremely careful to avoid spills.Avoid spills by being extremely careful during the handling process. Use proper pouring and transfer techniques.Pouring and transferring should be done with the correct technique. If possible, use automated transfer systems to reduce the risk of human error.Use automated transfer systems if possible to reduce the risk. In case of a spill, immediately evacuate the non - essential personnel from the area.In the event of a spillage, evacuate all non-essential personnel from the area. Then, wearing appropriate protective gear, use absorbent materials like sand or vermiculite to contain and clean up the spill.Wearing appropriate protective gear, use absorbent material like sand, or vermiculite, to contain and clean the spill. Dispose of the contaminated absorbents in accordance with local environmental regulations.Dispose the contaminated absorbents according to local environmental regulations.
Finally, in case of contact with the skin, immediately remove contaminated clothing and wash the affected area with large amounts of water for at least 15 minutes.In the event of skin contact, remove the contaminated clothing immediately and wash the affected areas with large quantities of water for a minimum of 15 minutes. Seek medical attention promptly. If it gets into the eyes, rinse the eyes continuously with clean water for at least 15 minutes while keeping the eyelids open, and then get immediate medical help.If it gets in the eyes, rinse them continuously with clean water while keeping your eyelids opened for at least 15 minute, then seek immediate medical attention. If inhaled, move to fresh air immediately.If you inhale it, get to fresh air as soon as possible. If the person has trouble breathing, provide artificial respiration and call for emergency medical services.If the person is having difficulty breathing, call emergency medical services and provide artificial respiration.
How is methylacrylic acid produced?
Methylacrylic acid, also known as methacrylic acid, can be produced through several methods.Methacrylic Acid, also known by the name methacrylic, can be made in several ways. One common approach is the hydrolysis of methyl methacrylate.Hydrolysis of methylmethacrylate is a common method.
In the hydrolysis process, methyl methacrylate reacts with water.In the hydrolysis reaction, methylmethacrylate reacts to water. This reaction is typically catalyzed by an acid or a base.This reaction is usually catalyzed either by an acid, or a base. When using an acidic catalyst, such as sulfuric acid, the reaction proceeds as follows: Methyl methacrylate (CH2 = C(CH3)COOCH3) reacts with water (H2O) in the presence of sulfuric acid.In the presence of sulfuric, an acidic catalyst such as methyl methacrylate (CH2=C(CH3)COOCH3), the reaction proceeds in the following way: Methylmethacrylate (CH2=C(CH3)COOCH3) is reacted with water (H2O). The ester bond in methyl methacrylate is broken, and the products formed are methylacrylic acid (CH2 = C(CH3)COOH) and methanol (CH3OH).The ester bond is broken in methyl methacrylate, and the products are methylacrylic (CH2 = CH3)COOH) methanol (CH3OH). The reaction can be represented by the chemical equation: CH2 = C(CH3)COOCH3 + H2O - CH2 = C(CH3)COOH + CH3OH.The chemical equation for the reaction is: CH2 = CH3COOCH3 + H2O + CH2 = CH3OH + C(CH3)COOH. After the reaction, the mixture needs to be processed to separate and purify methylacrylic acid.After the reaction, the mixture must be processed to separate out and purify the methylacrylic. Methanol can be distilled off due to its relatively low boiling point compared to methylacrylic acid.Due to its lower boiling point than methylacrylic, methanol can be distilled. Further purification steps may include distillation under reduced pressure to obtain high - purity methylacrylic acid.Distillation under reduced pressure may be used to purify methylacrylic acids.
Another method involves the oxidation of isobutylene or tert - butanol.Another method involves oxidizing isobutylene, or tert-butanol. In the case of isobutylene oxidation, isobutylene (CH2 = C(CH3)2) is first oxidized to methacrolein (CH2 = C(CH3)CHO) using a suitable catalyst, often a metal - oxide - based catalyst such as a molybdenum - bismuth - based catalyst in the presence of oxygen.In the case where isobutylene is oxidized, isobutylene is first oxidized into methacrolein using a suitable catalyst, usually a metal-oxide-based catalyst, such as a Molybdenum-bismuth-based catalyst in presence of oxygen. Then, methacrolein is further oxidized to methylacrylic acid.Then, the methacrolein will be further oxidized into methylacrylic acids. The second - step oxidation of methacrolein to methylacrylic acid also requires a catalyst, and usually, a vanadium - based catalyst is used with oxygen as the oxidizing agent.The second-step oxidation of methylacrylic to methacrolein also requires a catalyst. Usually, a vanadium-based catalyst is used in conjunction with oxygen as an oxidizing agent. The overall process from isobutylene to methylacrylic acid involves two consecutive oxidation reactions.The overall process of converting isobutylene into methylacrylic acids involves two successive oxidation reactions. Similarly, when starting from tert - butanol, it is first dehydrogenated to isobutylene, and then the subsequent oxidation steps are the same as those starting from isobutylene.When starting with tert-butanol, the first step is to dehydrogenate it into isobutylene. Then, the oxidation steps proceed the same way as when starting with isobutylene.
These production methods need to be carefully controlled in terms of reaction conditions such as temperature, pressure, and catalyst concentration to ensure high yields and product purity.To ensure high yields and purity, these production methods must be carefully controlled with regard to reaction conditions, such as temperature and pressure, and catalyst concentration.
What are the physical and chemical properties of methylacrylic acid?
Methylacrylic acid, also known as methacrylic acid, has distinct physical and chemical properties.Methacrylic Acid, also known by the name methacrylic, has distinct physical properties and chemical properties.
Physical Properties
Appearance
Methylacrylic acid is a colorless, clear liquid at room temperature.At room temperature, methylacrylic acid is an odorless, clear liquid. It has a pungent and sharp odor, which is characteristic of many carboxylic acids.It has a sharp and pungent odor that is typical of carboxylic acid. This odor can be quite strong and may cause discomfort if inhaled in high concentrations.This odor is quite strong and can cause discomfort if inhaled at high concentrations.
Boiling and Melting PointsBoiling Points and Melting Points
The boiling point of methylacrylic acid is approximately 161 - 163 degC.The boiling point for methylacrylic is between 161 and 163 degrees Celsius. This relatively high boiling point is due to the presence of strong intermolecular forces, specifically hydrogen bonding.This high boiling point is a result of strong intermolecular interactions, specifically hydrogen bonds. Hydrogen bonding occurs between the -COOH groups of different methylacrylic acid molecules.Hydrogen bonds are formed between the -COOH group of different methylacrylic acids. The melting point of methylacrylic acid is around 16 - 16.5 degC.Melting point of methylacrylic acids is between 16 and 16.5 degrees Celsius. These values determine its phase behavior under normal and industrial conditions.These values determine the phase behavior of methylacrylic acid under normal and industrial conditions.
Density and SolubilityDensity & Solubility
It has a density of about 1.015 g/cm3 at 20 degC.It has a density around 1.015g/cm3 when it is 20 degrees Celsius. Methylacrylic acid is soluble in water to a certain extent.In a certain degree, methylacrylic acid can be dissolved in water. The carboxylic acid group (-COOH) can form hydrogen bonds with water molecules, facilitating solubility.The carboxylic group (-COOH), which can form hydrogen bonds with the water molecules, facilitates solubility. It is also highly soluble in many organic solvents such as ethanol, diethyl ether, and acetone.It is highly soluble in organic solvents like ethanol, diethylether, and acetone. This solubility in organic solvents makes it useful in various chemical processes and formulations.Its solubility in organic solvants makes it useful for various chemical processes and formulations.
Chemical Properties
Acidity
Methylacrylic acid is a weak acid.Methylacrylic Acid is a weaker acid. The carboxylic acid functional group (-COOH) can donate a proton (H+) in an aqueous solution.In an aqueous solvent, the carboxylic acid functional groups (-COOH), can donate a proton. It undergoes dissociation to form a carboxylate ion and a proton.It undergoes a dissociation, forming a carboxylate and a proton. This acidic nature allows it to react with bases to form salts.Its acidic nature allows for it to react with bases and form salts. For example, when reacted with sodium hydroxide (NaOH), it forms sodium methylacrylate and water.When it reacts with sodium hydroxide, it forms sodium methylacrylate (NaOH) and water.
Polymerization
One of the most important chemical properties of methylacrylic acid is its ability to polymerize.The ability of methylacrylic acids to polymerize is one of its most important chemical properties. The double bond in the molecule makes it suitable for addition polymerization reactions.The double bond of the molecule makes addition polymerization possible. In the presence of initiators, such as peroxides or azo - compounds, methylacrylic acid monomers can react with each other, breaking the double bond and forming long - chain polymers.In the presence or initiators such as peroxides and azo-compounds, methylacrylic acids monomers can react, breaking the double-bond to form long-chain polymers. These polymers, known as polymethacrylic acids, have a wide range of applications, including in coatings, adhesives, and the production of acrylic resins.These polymers are known as polymethacrylic acid and have many applications, such as in adhesives, coatings, and the manufacture of acrylic resins.
Esterification
Methylacrylic acid can react with alcohols in the presence of an acid catalyst, typically sulfuric acid or p - toluenesulfonic acid, to form esters.In the presence of an acid catalyst, such as sulfuric acid or p-toluenesulfonic acids, methylacrylic acid can be used to react with alcohols to form esters. This is an esterification reaction.This is an esterification. For instance, when reacted with methanol, it forms methyl methacrylate, which is a key monomer in the production of polymethyl methacrylate (PMMA), a widely used transparent plastic.When reacted with the methanol it forms methylmethacrylate which is a key component in the production polymethylmethacrylate (PMMA), an widely used transparent plastic.
What are the differences between methylacrylic acid and other related acids?
Methylacrylic acid, also known as methacrylic acid, has several differences compared to other related acids.Methylacrylic Acid, also known by the name methacrylic, differs from other acids in several ways.
One of the main related acids is acrylic acid.Acrylic acid is one of the most closely related acids. Structurally, the key difference lies in the presence of a methyl group in methylacrylic acid, while acrylic acid lacks this methyl substitution.The key structural difference is the presence of the methyl group in the methylacrylic acids, while acrylic acid does not have this methyl substitution. This seemingly small structural variation leads to significant differences in properties.This seemingly minor structural difference leads to significant properties. Methylacrylic acid has a higher molecular weight due to the extra methyl group, which affects its physical properties.The extra methyl group in methylacrylic acid gives it a higher molecular weight, which has an impact on its physical properties. For instance, it has a higher boiling point compared to acrylic acid.It has a higher melting point than acrylic acid. The methyl group in methylacrylic acid also increases the steric hindrance around the carboxyl group.The methyl group increases the steric barrier around the carboxyl groups in methylacrylic acids. This steric effect can influence its reactivity.This steric influence can affect its reactivity. In polymerization reactions, the steric hindrance caused by the methyl group in methylacrylic acid can slow down the polymerization rate compared to acrylic acid.The steric hindrance of the methyl group can slow down polymerization rates in methylacrylic acids compared to acrylic acids. As a result, polymers made from methylacrylic acid may have different chain lengths and architectures.Polymers made from methylacrylic acids may have different chain sizes and architectures.
Another related acid is crotonic acid.Crotonic acid is another related acid. Crotonic acid has a different double - bond configuration compared to methylacrylic acid.Crotonic has a different configuration of double-bonds than methylacrylic. Methylacrylic acid has a double bond in the alpha, beta - unsaturated carboxylic acid structure, but the geometry and the overall molecular shape are different in crotonic acid.Crotonic acid has a different double-bond configuration than methylacrylic acid. This difference in structure impacts their chemical reactivity.This difference in structure affects their chemical reactivity. Crotonic acid may participate in different types of chemical reactions due to its distinct double - bond arrangement.Crotonic acid can participate in different types chemical reactions because of its unique double-bond arrangement. For example, in addition reactions, the orientation of incoming reagents can be different for methylacrylic acid and crotonic acid.In addition to reactions, the orientations of incoming reagents for methylacrylic and crotonic acids can be different.
In terms of applications, these differences in properties translate into distinct uses.These differences in properties translate to different applications. Methylacrylic acid is commonly used in the production of poly(methyl methacrylate) (PMMA), a clear and hard - wearing plastic.Methylacrylic Acid is used to produce poly(methyl methacrylate), a hard-wearing plastic. Its relatively high reactivity and the ability to form strong polymers make it suitable for this purpose.Its high reactivity, and ability to form polymers that are strong, make it ideal for this application. Acrylic acid, on the other hand, is often used in the synthesis of superabsorbent polymers due to its high water - absorbing capacity, which is related to its more accessible carboxyl group without the methyl - induced steric hindrance.Acrylic acid is used to synthesize superabsorbent materials due to its high capacity to absorb water. This is due to the carboxyl group being more accessible without the steric hindrance caused by methyl. Crotonic acid finds applications in the synthesis of certain pharmaceuticals and flavors, taking advantage of its unique reactivity based on its double - bond geometry.Crotonic acid is used in the synthesis and flavoring of certain pharmaceuticals. Its unique reactivity is based on a double-bond geometry.
In summary, the differences in structure between methylacrylic acid and other related acids lead to variations in physical properties, reactivity, and ultimately, their applications in different industries.The differences in structure between methylacrylic and other related acids can lead to variations in their physical properties, reactivity and, ultimately, in their applications in various industries.