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Product Name | Polyacrylic Acid Sodium |
Cas Number | 9003-04-7 |
Formula | (C3H3NaO2)n |
Molar Mass | variable |
Property 1 | Water solubility: soluble |
Property 2 | Appearance: white granules or powder |
Property 3 | Density: ~1.4 g/cm³ |
Property 4 | pH: 9-10 (1% aqueous solution) |
Property 5 | Boiling Point: not applicable |
Property 6 | Melting Point: not applicable |
Property 7 | Toxicity: low |
Property 8 | Polymer Type: anionic polymer |
Property 9 | Viscosity: varies with concentration |
Property 10 | Stability: stable under normal conditions |
What is the main application of Polyacrylic Acid Sodium?
Polyacrylic Acid Sodium, also known as Sodium Polyacrylate, has a wide range of applications.Polyacrylic acid sodium, also known by the name Sodium Polyacrylate has a variety of applications.
One of the most prominent applications is in the field of personal care products.Personal care products are one of the most common applications. It is commonly used in baby diapers, adult incontinence products, and feminine hygiene products.It is used in feminine hygiene products, adult incontinence and baby diapers. In these items, Sodium Polyacrylate acts as a superabsorbent polymer.In these products, Sodium Polyacrylate is used as a superabsorbent material. It can absorb and retain an extremely large amount of liquid, often many times its own weight.It can absorb and hold a large amount of liquid - often more than its own weight. This property helps keep the skin dry by quickly soaking up moisture, preventing skin irritation and ensuring comfort for the users.This property helps to keep the skin dry, by quickly absorbing moisture. It prevents skin irritation and ensures comfort for users.
In the agricultural sector, it plays an important role.It plays a major role in the agricultural sector. When added to soil, Sodium Polyacrylate can improve soil water - holding capacity.Sodium Polyacrylate, when added to soils, can improve the soil's water-holding capacity. It can absorb water during periods of high rainfall or irrigation and then slowly release it to plant roots during dry spells.It can absorb water in periods of heavy rainfall or irrigation, and then slowly release the water to plant roots in dry spells. This is beneficial for plants as it helps maintain an appropriate moisture level around the roots, enhancing plant growth and reducing the frequency of irrigation.This is good for plants because it maintains a moisture level around their roots. This enhances plant growth and reduces the frequency of irrigation. It is especially useful in arid and semi - arid regions where water resources are scarce.It is particularly useful in arid or semi-arid regions with limited water resources.
In the industrial field, Sodium Polyacrylate is used in water treatment processes.In the industrial sector, Sodium Polyacrylate can be used in water treatment. It can act as a flocculant, helping to aggregate suspended particles in water.It can act as flocculant and help to aggregate suspended particles within water. This makes it easier to separate the solids from the water, improving water quality.It makes it easier to separate solids from water, thereby improving the water quality. It is also used in some coatings and adhesives.It is also used to make some adhesives and coatings. In coatings, it can improve the adhesion and film - forming properties, enhancing the durability and performance of the coating.In coatings, the film-forming and adhesion properties can be improved, increasing the durability and performance. In adhesives, it can contribute to better adhesion strength and stability.In adhesives it can improve adhesion and stability.
In the food industry, although in a more limited capacity, Sodium Polyacrylate can be used as a thickening agent in some food products.Sodium Polyacrylate is used in the food industry as a thickening product, but in a limited capacity. It helps to adjust the texture and viscosity of food, providing a better mouthfeel in products like jams, sauces, and some dairy products.It can be used to improve the mouthfeel of products such as jams, sauces and dairy products. However, strict regulations govern its use in food to ensure safety.To ensure food safety, it is subject to strict regulations. Overall, the diverse applications of Polyacrylic Acid Sodium make it an important material in various industries.Polyacrylic acid Sodium is used in a wide range of industries due to its diverse applications.
Is Polyacrylic Acid Sodium harmful to the environment?
Polyacrylic acid sodium, also known as sodium polyacrylate, has both positive and potentially negative aspects regarding its environmental impact.The environmental impact of sodium polyacrylate (also known as polyacrylic acid sodium) is both positive and negative.
On the positive side, in some applications, it can contribute to environmental benefits.Positively, it can have an impact on the environment in certain applications. For example, in agricultural and horticultural settings, it is used as a soil conditioner.In agricultural and horticultural applications, it can be used as a soil conditioning agent. It can improve soil structure by enhancing water - holding capacity.It can improve soil structure through its ability to hold water. This reduces the need for frequent irrigation, thus conserving water resources.This reduces the frequency of irrigation, conserving water. In this sense, it indirectly benefits the environment by promoting more efficient use of a precious natural resource.In this way, it indirectly benefits the environmental by promoting more efficient usage of a precious resource.
However, there are concerns as well.There are also concerns. One major issue is its persistence in the environment.Its persistence in the environment is a major concern. Sodium polyacrylate is relatively stable and may not degrade easily in natural ecosystems.Sodium polyacrylate may not degrade readily in natural ecosystems. If large amounts of it enter water bodies, it can potentially accumulate.It can accumulate in water bodies if large amounts are introduced. In aquatic environments, this could disrupt the natural balance.This could disturb the natural balance in aquatic environments. Although it is not highly toxic to most aquatic organisms at low concentrations, the long - term presence of non - biodegradable polymers can change the physical and chemical properties of water and sediment.Even though it is not toxic to most aquatic organisms in low concentrations, long-term presence of non-biodegradable polymers may alter the physical and chemical characteristics of water and sediment.
Another aspect is related to its production.A second aspect is its production. The manufacturing process of polyacrylic acid sodium may involve the use of chemicals and energy.The production of polyacrylic acids sodium may require the use of energy and chemicals. If not managed properly, the production can lead to emissions of greenhouse gases and other pollutants.The production of polyacrylic acid sodium can cause emissions of greenhouse gasses and other pollutants if it is not managed properly. For instance, the synthesis may require monomers that are derived from petrochemical sources.The synthesis, for example, may require monomers derived from petrochemicals. The extraction and processing of these petrochemical feedstocks contribute to environmental degradation, including habitat destruction and air pollution.The extraction and processing these petrochemicals feedstocks contributes to environmental degradation including habitat destruction and pollution of the air.
In summary, while polyacrylic acid sodium has some beneficial applications that can be environmentally friendly, its potential for environmental harm cannot be ignored.While polyacrylic acid sodium can be used in environmentally-friendly applications, it also has the potential to cause harm. The key lies in proper management, from production to disposal.Proper management is key, from production to disposal. More research is needed to better understand its long - term environmental fate and to develop strategies to mitigate any negative impacts, such as promoting biodegradable alternatives or improving waste treatment processes to remove it effectively from water and soil.It is important to conduct more research to better understand the long-term environmental fate of this substance and to develop strategies that will mitigate any negative effects, such as promoting alternative biodegradable products or improving waste treatment to remove it from water and soil.
How is Polyacrylic Acid Sodium produced?
Polyacrylic Acid Sodium, also known as sodium polyacrylate, is produced through the following common methods:The following methods are used to produce sodium polyacrylate or polyacrylic acid sodium:
1. Solution Polymerization MethodSolution Polymerization Method
The starting material is acrylic acid.Acrylic acid is the starting material. First, acrylic acid is neutralized with sodium hydroxide to form sodium acrylate.First, sodium hydroxide is used to neutralize acrylic acid. The reaction equation is: CH2=CH - COOH + NaOH - CH2=CH - COONa + H2O.The reaction equation is CH2=CH + COOH + H2O - CH2=CH + COONa + NaOH.
Then, in a suitable solvent such as water, with the addition of an initiator like potassium persulfate or ammonium persulfate, the sodium acrylate monomers undergo polymerization.The sodium acrylate is then polymerized in a suitable solvant, such as water, by adding an initiator, such as potassium persulfate (or ammonium persulfate). The initiator decomposes under certain conditions to generate free radicals.Under certain conditions, the initiator decomposes to produce free radicals. These free radicals react with the double - bonds of sodium acrylate monomers, causing them to link together to form long - chain polymers.These free radicals react to the double-bonds of sodium acrylate to cause them to link to form long-chain polymers. The polymerization reaction can be represented as: nCH2=CH - COONa - [-CH2 - CH(COONa)-]n.The polymerization can be expressed as: nCH2=CH-COONa [-CH2 -- CH(COONa-)-]n. After the polymerization reaction is completed, the solvent is removed through processes like evaporation, and the resulting product is further dried and processed to obtain polyacrylic acid sodium.The solvent is removed by evaporation after the polymerization is complete. The resulting product can then be dried and processed into polyacrylic acid sodium.
2. Reverse - Phase Suspension Polymerization MethodReverse-phase Suspension Method
In this method, an organic solvent like cyclohexane is used as the continuous phase.This method uses cyclohexane as the continuous phase. An emulsifier is added to this organic phase to create a stable emulsion system.This organic phase is then stabilized by adding an emulsifier. Similar to the solution polymerization method, acrylic acid is first neutralized with sodium hydroxide to form sodium acrylate.In a similar way to the solution polymerization, acrylic acid is neutralized first with sodium hydroxide in order to form sodium acrylate. The sodium acrylate aqueous solution is then dispersed in the organic phase as tiny droplets.The sodium acrylate solution is dispersed as tiny droplets in the organic phase. An initiator is added to the system.The system is then treated with an initiator. In the dispersed droplets, the sodium acrylate monomers polymerize to form polyacrylic acid sodium particles.In the droplets, sodium acrylate monomers are polymerized to form polyacrylic acids sodium particles. After the reaction, the organic solvent is separated, and the polyacrylic acid sodium particles are washed and dried to obtain the final product.After the reaction is complete, the organic solvent will be separated and the polyacrylic acids sodium particles will be washed and dry to obtain the final product. This method can produce polyacrylic acid sodium with a relatively uniform particle size and good water - absorbent properties.This method produces polyacrylic acid with a uniform particle size, and good water-absorbing properties.
3. Bulk Polymerization MethodBulk Polymerization Method
Acrylic acid is directly neutralized with sodium hydroxide to obtain a high - concentration sodium acrylate solution.The sodium hydroxide is used to neutralize the acrylic acid, resulting in a solution of high concentration sodium acrylate. Without the addition of a solvent, an initiator is added to initiate the polymerization reaction.In order to initiate polymerization without the use of a solvent an initiator must be added. Since there is no solvent to dilute the reaction system, the heat generated during the polymerization process is relatively difficult to dissipate.The heat generated by the polymerization is difficult to dissipate because there is no solvent present to dilute the system. Therefore, strict temperature control is required during the reaction.During the reaction, temperature control must be strictly controlled. After the reaction, the resulting polymer is processed through crushing, drying, and other procedures to obtain polyacrylic acid sodium.The polymer produced is then processed by crushing, drying and other methods to obtain polyacrylic acids sodium. This method has the advantage of high production efficiency, but it is more challenging to control the reaction process.This method is highly efficient, but the reaction process can be difficult to control.
What are the physical and chemical properties of Polyacrylic Acid Sodium?
Polyacrylic Acid Sodium, also known as Sodium Polyacrylate, has the following physical and chemical properties:Polyacrylic acid sodium, also known by the name Sodium Polyacrylate has the following physical-chemical properties:
Physical PropertiesPhysical Properties
1. AppearanceAppearance
In its solid form, it usually appears as a white, granular or powder - like substance.It is usually a white granular or powder-like substance in its solid form. It is odorless, which makes it suitable for a wide range of applications where an absence of smell is crucial, such as in personal care products like baby diapers and sanitary napkins.It is odorless and can be used in a variety of applications that require a lack of smell, such as baby diapers or sanitary napkins.
2. SolubilitySolubility
It is highly water - soluble.It is highly - water soluble. When added to water, it can absorb a large amount of water, forming a clear, viscous solution.It can absorb a lot of water when added to water. This results in a viscous, clear solution. This property is due to the presence of numerous hydrophilic carboxylate groups in its molecular structure.This property is due the presence of many hydrophilic carboxylates in its molecular structures. The high water - absorbing capacity can be as much as several hundred times its own weight, depending on the degree of polymerization and other factors.The high water-absorbing capacity of the polymer can be several hundred times greater than its own weight depending on factors such as degree of polymerization.
3. ViscosityViscosity
The solutions of Polyacrylic Acid Sodium exhibit relatively high viscosity.The solutions of Polyacrylic acid Sodium have a relatively high viscosity. The viscosity can be adjusted by changing factors such as the concentration of the polymer in the solution, the degree of polymerization, and the pH value of the solution.You can adjust the viscosity by changing factors like the concentration of polymer in the solutions, the degree or polymerization and the pH of the solution. Higher concentrations and longer polymer chains generally result in higher viscosities.Viscosity is generally higher with higher concentrations and longer chains of polymer. This property makes it useful as a thickening agent in various industries, including the food and cosmetics industries.This property makes it useful in various industries including the food and cosmetics industry.
Chemical PropertiesChemical Properties
1. Acid - Base PropertiesAcid Base Properties
Polyacrylic Acid Sodium is a weak polyelectrolyte.Polyacrylic Acid Sodium (PAAS) is a weak polyelectrolyte. The carboxylate groups in its structure can react with acids or bases.The carboxylate groups can react with bases or acids. In acidic solutions, the carboxylate anions can be protonated, which may lead to a change in the solubility and viscosity of the polymer.In acidic solutions the carboxylate anion can be protonated. This may change the solubility or viscosity. In basic solutions, the polymer remains in its anionic form, maintaining its high - water - absorbing and thickening abilities.In basic solutions, polymers remain in their anionic form and retain their high-water-absorbing and thickening properties.
2. ReactivityReactivity
It can participate in various chemical reactions.It can be involved in a variety of chemical reactions. For example, it can react with divalent or multivalent metal ions.It can, for example, react with metal ions that are divalent or multivalent. When in contact with metal ions like calcium or magnesium, cross - linking may occur.Cross-linking can occur when metal ions such as calcium or magnesium are in contact. This cross - linking can change the physical properties of the polymer, such as reducing its solubility and increasing its gel - like nature.This cross-linking can change the physical characteristics of the polymer. For example, it can reduce its solubility or increase its gel-like nature. Such cross - linked structures are often used in applications where a more stable, three - dimensional network is required, like in some water - retaining gels for agricultural use.These cross-linked structures are used in applications that require a stable, three-dimensional network, such as in some agricultural water-retaining gels.
3. Thermal StabilityThermal Stability
It has a certain degree of thermal stability.It has a certain level of thermal stability. However, at high temperatures, decomposition may occur.At high temperatures, however, decomposition can occur. The decomposition process may involve the breakdown of the polymer chains, accompanied by the release of volatile products.Decomposition can involve the breakdown of polymer chains and the release of volatile compounds. The exact temperature at which significant decomposition begins depends on factors such as the degree of polymerization and the presence of any impurities in the polymer.The exact temperature where significant decomposition starts depends on factors like the degree of polymerization or the presence of impurities within the polymer.
What are the advantages of using Polyacrylic Acid Sodium compared to other additives?
Polyacrylic Acid Sodium, also known as Sodium Polyacrylate, offers several distinct advantages when compared to other additives.Polyacrylic acid Sodium (also known as Sodium Polyacrylate) offers several distinct benefits when compared with other additives.
One of the key advantages is its excellent water - absorbing capacity.Its excellent water-absorbing capacity is one of its key advantages. It can absorb and retain an extremely large amount of water, often hundreds of times its own weight.It can absorb a large amount of moisture, sometimes hundreds of times more than its own weight. This property makes it ideal for applications such as in disposable diapers, where it effectively locks away moisture, keeping the skin dry.This property makes it perfect for applications like disposable diapers where it effectively locks moisture away, keeping the skin dried. In contrast, many other additives may not have such a high water - holding ability.Many other additives, however, may not have the same water-holding ability. For instance, traditional absorbents like cotton can only hold a fraction of the water that Sodium Polyacrylate can, and they may release the absorbed water more easily under pressure.Cotton, for example, can only hold a fraction as much water as Sodium Polyacrylate, and may release the absorbed moisture more easily when under pressure.
Another benefit is its stability in different environments.Another benefit is that it is stable in different environments. Sodium Polyacrylate is resistant to a wide range of pH values, which means it can maintain its performance in both acidic and alkaline conditions.Sodium Polyacrylate can perform in both acidic or alkaline environments. This adaptability is far from common among additives.This adaptability is not common among additives. Some other substances might degrade or lose their functionality when exposed to extreme pH levels.Other substances may lose their functionality or degrade when exposed to extreme pH levels. For example, certain organic polymers may break down in highly acidic solutions, while Sodium Polyacrylate remains functional, making it suitable for use in various industrial processes where the pH of the system can vary.For example, some organic polymers can degrade in highly acidic solution, but Sodium Polyacrylate is still functional and suitable for industrial processes that require a range of pH levels.
It also has good thickening properties.It also has good thickening qualities. In products such as paints, cosmetics, and adhesives, it can increase the viscosity of the formulation.It can increase the viscosity in products like paints, cosmetics and adhesives. This is more efficient in some cases compared to other thickeners.In some cases, this is more effective than other thickeners. Some natural thickeners may be affected by microbial growth over time, leading to spoilage and a change in product consistency.Some natural thickeners can be affected by microbial development over time. This can lead to spoilage and a shift in product consistency. Sodium Polyacrylate, on the other hand, is less prone to such issues, providing a more stable and long - lasting thickening effect.Sodium Polyacrylate is less susceptible to such issues and provides a more stable, long-lasting thickening effect.
In addition, Sodium Polyacrylate is relatively non - toxic.Sodium Polyacrylate, in addition, is relatively non-toxic. This makes it suitable for use in products that come into contact with humans, like personal care items.It is therefore suitable for products that are in contact with humans such as personal care products. Many other chemical additives may carry potential health risks, either due to their toxicity or the potential for allergic reactions.Many other chemical additives can pose health risks due to their toxicity, or allergic reactions. The low toxicity of Sodium Polyacrylate gives it an edge in applications where safety is a top priority.The low toxicity gives Sodium Polyacrylate an edge in applications that place safety as a priority.
Overall, the unique combination of high water - absorption, environmental stability, effective thickening, and low toxicity makes Polyacrylic Acid Sodium a highly favorable choice over many other additives in a wide variety of industries.Polyacrylic Acid Sodium is a great choice for many industries because of its unique combination of low toxicity, high water-absorption, environmental stability and effective thickening.