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Polyacrylic Acid Sodium Salt


Properties
Product Name Polyacrylic acid sodium salt
Cas Number 9003-04-7
Formula (C3H3NaO2)n
Molar Mass Variable
Density 1.35 g/cm³
Solubility Soluble in water
Ph 7-9 in solution
Appearance White powder or granules
Melting Point Decomposes before melting
Thermal Stability Stable under normal conditions
Viscosity Depends on molecular weight
Biodegradability Biodegradable
Hygroscopic Yes, absorbs moisture
Odor Odorless
FAQ

What are the main applications of polyacrylic acid sodium salt?

Polyacrylic acid sodium salt, also known as sodium polyacrylate, has a wide range of applications in various fields.The sodium polyacrylate salt, or sodium polyacrylic acid, is used in many different fields.
In the field of water - absorbing materials, it is a key component.It is a crucial component in the field of water-absorbing materials. Sodium polyacrylate has an extremely high water - absorption capacity.Sodium polyacrylate is a material with a high water-absorption capacity. It can absorb several hundred times its own weight of water, forming a gel - like substance.It can absorb hundreds of times its weight in water, forming a substance that looks like gel. This property makes it widely used in baby diapers, adult incontinence products, and sanitary napkins.This property makes it a popular choice for baby diapers, adult products that deal with incontinence, and sanitary pads. In these products, it quickly absorbs and locks in liquid, keeping the surface dry and comfortable for the user.It quickly absorbs liquid and locks it in, keeping the surface of these products dry and comfortable.

In the agricultural and horticultural sectors, it is used as a soil conditioner.It is used in the agricultural and horticultural sector as a soil conditioner. When added to the soil, it can improve the soil's water - holding capacity.It can improve the soils ability to hold water when added. In arid or semi - arid regions, this helps plants to better obtain water during dry periods.This helps plants in semi-arid or arid areas to better access water during dry periods. It also helps to improve soil structure, making it more porous and facilitating root growth and aeration.It also improves soil structure by making it more porous, facilitating root growth, and aeration. Additionally, in seed coating applications, sodium polyacrylate can help seeds to germinate better by providing a water - rich environment around the seeds.In seed coating applications, sodium acrylate can also help seeds germinate by creating a moist environment around them.

In the industrial field, it is used in water treatment.It is used to treat water in the industrial sector. Sodium polyacrylate can act as a dispersant.Sodium polyacrylate is a dispersant. In industrial water systems, such as in boilers and cooling towers, it can prevent the precipitation and aggregation of scale - forming substances like calcium carbonate and calcium sulfate.It can be used in industrial water systems such as cooling towers and boilers to prevent the precipitation of scale. By dispersing these substances in water, it helps to maintain the normal operation of the equipment, reduce energy consumption caused by scale accumulation, and extend the service life of the equipment.It helps maintain normal equipment operation, reduce energy consumption due to scale accumulation and extend equipment service life by dispersing these substances into water.

In the paint and coating industry, it is used as a thickener.It is used in the paint and coatings industry as a thickener. Sodium polyacrylate can adjust the viscosity of paint and coatings, improving their application performance.Sodium polyacrylate is used to adjust the viscosity and improve the application of paints and coatings. It ensures that the paint can be evenly applied on the surface, preventing issues such as dripping and uneven film formation.It prevents issues such as dripping or uneven film formation, and ensures that paint can be applied evenly on the surface. At the same time, it also helps to improve the stability of the paint system, preventing the sedimentation of pigments and fillers.It also helps improve the stability of paint systems by preventing pigments and fillers from settling.

In the food industry, it has some applications as a food additive.It has some applications in the food industry as a food ingredient. It can be used as a thickening agent, stabilizer, and water - retaining agent in some processed foods.It can be used in some processed food as a thickening, stabilizing, and water-retaining agent. For example, in jellies, puddings, and some dairy products, it helps to give the products a proper texture, improve their stability during storage, and enhance their water - holding capacity.It can be used to give jellies, puddings and some dairy products a good texture, increase their stability and water-holding capacity.

How is polyacrylic acid sodium salt produced?

Polyacrylic acid sodium salt, also known as sodium polyacrylate, is produced through the following main methods:The main methods of producing sodium polyacrylate (also known as sodium polyacrylic acid) are:
1. Free - radical polymerization methodFree radical polymerization method
- Monomer preparation: The starting material is usually acrylic acid.- Monomer Preparation: The starting substance is usually acrylic acid. Acrylic acid can be obtained through various routes, such as the oxidation of propylene.Acrylic acid can also be produced by other methods, such as oxidation of Propylene. Before polymerization, the acrylic acid may need to be purified to remove impurities that could interfere with the polymerization process.Acrylic acid may have to be purified before polymerization to remove impurities which could interfere with polymerization.
- Initiator addition: A free - radical initiator is added to the acrylic acid monomer.- Initiator Addition: A free-radical initiator is added into the acrylic acid monomer. Common initiators include peroxides like benzoyl peroxide or azo - compounds such as azobisisobutyronitrile (AIBN). These initiators decompose under specific conditions (usually heat or light) to generate free radicals.These initiators decompose in specific conditions (usually light or heat) to produce free radicals. For example, benzoyl peroxide decomposes to form benzoyloxy radicals, which then react with the double - bond in acrylic acid to start the polymerization reaction.For example, decomposition of benzoylperoxide produces benzoyloxyradicals which react with the double-bond in acrylic acid to initiate the polymerization.
- Polymerization reaction: In the presence of the initiator, acrylic acid monomers undergo chain - growth polymerization.In the presence the initiator, the monomers of acrylic acid undergo chain-growth polymerization. The free radicals attack the double - bond of acrylic acid monomers, forming new free - radical species at the end of the growing polymer chain.The free radicals attack double-bonds of acrylic acid monomers and form new free-radical species at the end growing polymer chain. This process continues, with more and more monomers being added to the chain, gradually forming polyacrylic acid.This process continues as more monomers are added to the chain. Polyacrylic acid is formed.
- Neutralization: After the formation of polyacrylic acid, it is neutralized with sodium hydroxide (NaOH).- Neutralization : After the formation, sodium hydroxide is used to neutralize polyacrylic acid (NaOH). The carboxyl groups (-COOH) in polyacrylic acid react with sodium hydroxide to form sodium carboxylate groups (-COONa), thus converting polyacrylic acid into polyacrylic acid sodium salt.The carboxyl groups in polyacrylic acids (-COOH), react with sodium hydroxide, forming sodium carboxylates (-COONa), converting polyacrylic to polyacrylic salt. The reaction equation is: \( -COOH+NaOH\rightarrow -COONa + H_2O\)

2. Reverse - phase suspension polymerization methodReverse-phase suspension polymerization method
- Emulsion formation: First, an organic solvent (such as cyclohexane) is used as the continuous phase, and an emulsifier is added.- Emulsion Formation: Firstly, an organic solvent is used (such as cyclohexane), and then an emulsifier. The emulsifier helps to disperse the aqueous phase containing acrylic acid monomer, initiator, and other additives into small droplets within the organic solvent.The emulsifier is used to disperse aqueous phase, which contains acrylic acid monomer and initiator, into small droplets in the organic solvent. This forms a stable water - in - oil (W/O) emulsion.This creates a stable oil - in- water (W/O).
- Polymerization in droplets: Similar to the free - radical polymerization method, the initiator decomposes to generate free radicals within the aqueous droplets containing acrylic acid monomers.- Polymerization of droplets: Similar in nature to the free radical polymerization, the initiator decomposes and generates free radicals inside the aqueous drops containing monomers of acrylic acid. The monomers then polymerize to form polyacrylic acid particles within these droplets.The monomers polymerize into polyacrylic acid in these droplets.
- Neutralization: After polymerization, sodium hydroxide is added to the reaction system.- Neutralization : After polymerization sodium hydroxide will be added to the reaction system. The neutralization reaction occurs within the particles, converting the polyacrylic acid in the particles into polyacrylic acid sodium salt.The neutralization reaction takes place within the particles and converts the polyacrylic acids in the particles to polyacrylic salt sodium. Finally, through processes such as separation, washing, and drying, the polyacrylic acid sodium salt product is obtained.Using processes such as washing, drying and separation, the final product is polyacrylic sodium salt. This method can produce polyacrylic acid sodium salt with relatively uniform particle size and good water - absorbing performance.This method produces polyacrylic sodium salts with a relatively uniform particle size, and good water-absorbing performance.

What are the properties of polyacrylic acid sodium salt?

Polyacrylic acid sodium salt, also known as sodium polyacrylate, has several important properties.The sodium polyacrylate salt, or sodium polyacrylic acid, has a number of important properties.
Firstly, it has excellent water - absorbing capacity.It has a great water-absorbing capacity. It can absorb a large amount of water, up to hundreds of times its own weight.It can absorb large amounts of water up to hundreds of its own weight. This property is due to the presence of numerous carboxylate groups in its molecular structure.This property is due the presence of many carboxylate groups within its molecular structures. These groups can interact with water molecules through hydrogen bonding and electrostatic forces.These groups can interact water molecules via hydrogen bonds and electrostatic forces. The high water - absorbing ability makes it widely used in applications such as disposable diapers, where it can quickly absorb and retain liquid, keeping the surface dry.Its high water-absorbing ability allows it to be widely used in applications like disposable diapers. It can quickly absorb and hold liquid, while keeping the surface dry.

Secondly, it has good thickening properties.Second, it has excellent thickening properties. In aqueous solutions, polyacrylic acid sodium salt can increase the viscosity of the solution.In aqueous solution, the polyacrylic sodium salt can increase viscosity. The long - chain polymer molecules entangle with each other and with water molecules, creating a more viscous system.The long-chain polymer molecules entangle each other and water molecules to create a viscous system. This is useful in the formulation of paints, inks, and cosmetics.This is useful when formulating paints, cosmetics, and inks. In paints, for example, it helps to control the flow and leveling of the paint, ensuring an even coating.In paints, it is used to control the flow of the paint and ensure an even coating.

It also shows good solubility in water.It is also soluble in water. The sodium ions in the sodium polyacrylate dissociate in water, and the negatively charged polyacrylate chains are well - dispersed, resulting in a clear and stable solution.The sodium ions dissociate from the sodium polyacrylate in water and the negatively-charged polyacrylate chains well - disperse, resulting a clear, stable solution. This solubility is beneficial for its use in various industrial and consumer products that require aqueous - based formulations.This solubility makes it ideal for use in a variety of industrial and consumer products requiring aqueous-based formulations.

In addition, polyacrylic acid sodium salt has a certain degree of film - forming ability.The polyacrylic sodium salt also has a certain film-forming ability. When the water in its solution evaporates, it can form a continuous and relatively stable film.When the water in the solution evaporates, a relatively stable and continuous film can be formed. This property is utilized in the production of some protective coatings and adhesives.This property is used in the production of adhesives and protective coatings. The formed film can provide protection to the underlying substrates or help in adhering different materials together.The formed film can protect the substrates beneath or help to adhere different materials together.

Moreover, it has good chemical stability under normal conditions.It also has a good chemical stability in normal conditions. It is resistant to hydrolysis and oxidation to a certain extent, which allows it to maintain its properties during storage and use in many applications.It is resistant to oxidation and hydrolysis to a certain degree, which allows for it to maintain its properties while being stored and used in many applications. However, extreme pH conditions or the presence of strong oxidizing agents may affect its structure and properties.Its structure and properties can be affected by extreme pH conditions or strong oxidizing agents.

Overall, these properties of polyacrylic acid sodium salt make it a versatile material with wide - ranging applications in different industries.Polyacrylic acid sodium is a versatile material that has many applications in various industries.

Is polyacrylic acid sodium salt harmful to the environment?

Polyacrylic acid sodium salt, also known as sodium polyacrylate, has relatively low harm to the environment under normal circumstances.Under normal circumstances, the environmental impact of sodium polyacrylate (also known as polyacrylic acid sodium) is relatively low.
Firstly, in terms of biodegradability, although it is not highly biodegradable in the traditional sense, it does not persist indefinitely in the environment.In terms of biodegradability it is not very biodegradable, but it does not last forever in the environment. In sewage treatment systems, a portion of it can be removed through physical - chemical processes.In sewage treatment systems a portion can be removed by physical-chemical processes. For example, in activated sludge processes, the polymer can interact with the sludge flocs and be removed from the water phase to some extent.In activated sludge, for example, the polymer can interact and remove some of the sludge from the water phase.

Secondly, its environmental impact on aquatic life is limited.Second, its impact on aquatic life in general is minimal. When it enters water bodies in small amounts, it usually does not cause acute toxicity to most aquatic organisms.It is not toxic to aquatic organisms in large quantities. Laboratory studies have shown that fish and invertebrates can tolerate certain concentrations of sodium polyacrylate without significant immediate harm.Studies in the laboratory have shown that fishes and invertebrates are able to tolerate sodium polyacrylate at certain concentrations without immediate harm. However, if large amounts of it enter water bodies continuously, it might potentially affect the physical properties of water, such as water clarity and viscosity, which could indirectly impact aquatic ecosystems.If large amounts of it are continuously introduced into water bodies, it could potentially affect water properties such as clarity and viscosity. This could have an indirect impact on aquatic ecosystems.

In soil environments, polyacrylic acid sodium salt can have some beneficial effects.The polyacrylic sodium salt can be beneficial in soil environments. It is often used as a soil conditioner.It is commonly used as a soil conditioner. It can improve soil structure by increasing water - holding capacity, reducing soil erosion, and enhancing soil aeration.It can improve soil structure through increased water-holding capacity, reduced soil erosion, and enhanced soil aeration. This can promote plant growth and is thus generally considered to have a positive impact on the soil environment rather than a harmful one.This can encourage plant growth, and is therefore generally considered to have more of a positive impact than a negative one on the soil environment.

In the atmosphere, polyacrylic acid sodium salt is not volatile, so it does not contribute to air pollution problems.Polyacrylic acid sodium is not volatile in the atmosphere and does not contribute to air pollutants. Overall, while polyacrylic acid sodium salt is not completely without any environmental impact, with proper management of its production, use, and disposal, its harm to the environment can be minimized, and in some applications, it can even bring certain environmental benefits.While polyacrylic sodium salt does not have a zero-impact on the environment, it is still important to manage its production, use and disposal.

What is the difference between polyacrylic acid sodium salt and other polymers?

Polyacrylic acid sodium salt, also known as sodium polyacrylate, has several distinct differences compared to other polymers.The sodium polyacrylate salt, or polyacrylic acid sodium, is a polymer with several distinct differences from other polymers.
One key difference lies in its excellent water - absorbing property.The key difference is its excellent water-absorbing property. Sodium polyacrylate can absorb an extremely large amount of water, often hundreds of times its own weight.Sodium polyacrylate is able to absorb a large amount of water - often hundreds of times more than its own weight. This super - absorbent characteristic is far beyond what many common polymers can achieve.This super-absorbent property is beyond what most common polymers can achieve. For example, traditional polyethylene or polypropylene polymers do not have this water - absorbing ability at all.Polyethylene and polypropylene, for example, do not have the water-absorbing ability. This property makes sodium polyacrylate widely used in applications like disposable diapers, where it can quickly absorb and retain large volumes of liquid, keeping the surface dry.This property makes sodium acrylate widely used for applications such as disposable diapers. It can quickly absorb and hold large volumes of liquid while keeping the surface dry.

In terms of chemical structure, the presence of carboxylate groups in polyacrylic acid sodium salt imparts unique reactivity.The presence of carboxylates in the polyacrylic acid salts is a unique feature of their chemical structure. These carboxylate groups can participate in various chemical reactions such as ion - exchange reactions.These carboxylates can be involved in a variety of chemical reactions, such as ion-exchange reactions. In contrast, polymers like polystyrene, which have a relatively simple aromatic - based structure, lack such reactive functional groups.Polymers with a simple aromatic-based structure like polystyrene lack reactive functional groups. This reactivity allows polyacrylic acid sodium salt to be used in areas like water treatment, where it can interact with metal ions through ion - exchange mechanisms to remove contaminants.This reactivity makes it possible to use polyacrylic sodium salt in areas such as water treatment where it can interact through ion-exchange mechanisms with metal ions to remove contaminants.

The solubility of polyacrylic acid sodium salt also sets it apart.It is also distinguished by its solubility. It is water - soluble, which is different from many hydrophobic polymers.It is water-soluble, which makes it different from other hydrophobic polymers. This solubility enables it to be easily formulated into aqueous solutions for different industrial applications, like in the production of coatings and adhesives.This solubility allows it to be easily formulated as aqueous solutions, for various industrial applications such as the production of adhesives and coatings. Hydrophobic polymers like polyvinyl chloride need organic solvents for processing, which brings environmental and safety concerns.Hydrophobic polymers such as polyvinylchloride require organic solvents to be processed, which can have environmental and safety implications.

Another aspect is its role as a dispersant.Its role as a dispersant is another aspect. Polyacrylic acid sodium salt can effectively disperse particles in a liquid medium.The polyacrylic acid sodium can disperse particles effectively in a liquid medium. It adsorbs onto the surface of particles, preventing them from aggregating.It adsorbs on the surface of particles to prevent them from aggregating. This is useful in the paint and ceramic industries.This is particularly useful in the ceramic and paint industries. Many other polymers may not have this dispersing ability or may require additional additives to achieve similar effects.Other polymers may not be able to disperse as well or may need additional additives in order to achieve the same effect.

In summary, polyacrylic acid sodium salt's super - absorbent nature, unique chemical structure with reactive groups, water - solubility, and dispersing ability distinguish it from other polymers, making it valuable in a wide range of applications.The unique chemical structure of polyacrylic sodium salt, with its reactive groups and water-soluble nature, makes it different from other polymers. It is therefore valuable for a variety of applications.