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Product Name | Sulfonated Polyacrylic Acid Copolymer |
Cas Number | 35641-59-9 |
Formula | (C3H3NaO2.C6H7NO3S)x |
Molar Mass | Variable; depends on polymerization |
Solubility | Soluble in water |
Appearance | Clear to slightly hazy liquid |
Ph | 4.0 - 6.0 (in 1% solution) |
Viscosity | 10 - 1000 cps |
Density | 1.2 - 1.3 g/cm3 |
Ionic Nature | Anionic |
Decomposition Temperature | > 200°C |
Storage Temperature | Below 40°C |
Biodegradability | Inherently biodegradable |
Stability | Stable under normal temperatures and pressures |
Refractive Index | 1.45 - 1.50 |
Compatibility | Compatible with other anionic and nonionic materials |
What are the main applications of sulfonated polyacrylic acid copolymer?
Sulfonated polyacrylic acid copolymer has several main applications:The main applications of sulfonated polyacrylic acids copolymer include:
1. In water treatmentIn water treatment
It serves as a scale inhibitor.It is a scale-inhibitor. In industrial water systems like boilers and cooling towers, the presence of calcium, magnesium, and other metal ions can lead to the formation of scale.The presence of metal ions such as calcium, magnesium and others can cause scale to form in industrial water systems, like cooling towers and boilers. Sulfonated polyacrylic acid copolymer can chelate these metal ions, preventing them from aggregating and depositing on the inner walls of pipes and equipment.The chelation of these metal ions by sulfonated copolymer polyacrylic acid can prevent them from aggregating or depositing on inner walls of pipes and other equipment. For example, in a power plant's boiler system, scale formation can reduce heat transfer efficiency and even cause damage to the boiler tubes.Scale formation, for example, can reduce the efficiency of heat transfer in a boiler system and even damage the boiler tubes. By adding this copolymer, the scale formation is inhibited, ensuring the smooth operation of the boiler and saving energy.This copolymer inhibits the formation of scale, ensuring a smooth operation of the system and saving energy.
It also acts as a dispersant.It can also be used as a dispersant. It can disperse suspended particles in water, such as silt and clay.It can disperse suspended water particles, such as clay and silt. In wastewater treatment plants, this helps to keep the contaminants in suspension, making it easier for subsequent treatment processes like sedimentation and filtration to remove them effectively.This helps keep contaminants in suspension at wastewater treatment plants. This makes it easier to remove them with subsequent treatment processes such as sedimentation and filtering.
2. In the cement industryIn the cement industry
As a superplasticizer, sulfonated polyacrylic acid copolymer significantly improves the workability of cement paste.As a superplasticizer sulfonated copolymer of polyacrylic acid improves the workability and consistency of cement paste. It adsorbs on the surface of cement particles, providing electrostatic repulsion and steric hindrance.It adsorbs onto the surface of cement particle, providing electrostatic repellence and steric hinderance. This allows the cement particles to be more evenly dispersed in the water, reducing the amount of water needed to achieve the desired fluidity.This allows the cement to be evenly dispersed within the water, reducing water required to achieve the desired fluidity. For instance, in large - scale construction projects like high - rise buildings and bridges, using this copolymer in the cement mixture can enhance the strength of the concrete while maintaining its workability during pouring, ensuring the quality and durability of the structures.In large-scale construction projects such as high-rise buildings and bridges using this copolymer can increase the strength of concrete while maintaining its workability when pouring. This ensures the quality and durability.
3. In the oilfieldIn the oilfield
During oil well drilling, it can be used as a fluid loss additive.It can be used to reduce fluid loss during oil well drilling. In the drilling process, the drilling fluid needs to maintain certain properties.The drilling fluid must maintain certain properties during the drilling process. This copolymer can form a thin and dense filter cake on the wellbore wall, reducing the amount of fluid lost into the formation.This copolymer forms a thin, dense filter cake along the wellbore walls to reduce the amount of fluid that is lost into the formation. This helps to keep the drilling fluid in the wellbore, ensuring the stability of the wellbore and the normal progress of the drilling operation.This helps keep the drilling fluid inside the wellbore. It also ensures the stability of wellbore as well as the normal progress of drilling operations.
It can also be applied in enhanced oil recovery.It can be used in enhanced oil recovery. By adjusting the rheological properties of the injected fluid, it can improve the sweep efficiency of the reservoir, enabling more oil to be displaced and recovered.By adjusting rheological properties, it is possible to improve the sweep efficiency in the reservoir. This allows for more oil to be displaced.
4. In the textile industryIn the textile industry
As a dye - leveling agent, sulfonated polyacrylic acid copolymer helps dyes to be evenly distributed on textile fibers.As a dye-leveling agent, the sulfonated copolymer of polyacrylic acid helps to evenly distribute dyes on textile fibers. It can interact with both the dye molecules and the fibers, preventing dye aggregation and promoting a more uniform dyeing process.It can interact both with the dye molecules and fibers to prevent dye aggregation. This promotes a more uniform dying process. This results in textiles with more consistent color and better color fastness.The result is textiles that are more uniform in color and have better color fastness.
How does sulfonated polyacrylic acid copolymer work?
Sulfonated polyacrylic acid copolymer is a versatile material with various applications, and its working mechanism is based on several key properties.The Sulfonated Polyacrylic Acid Copolymer is an extremely versatile material that has many applications. Its working mechanism is based upon several key properties.
First, its structure plays a crucial role.Its structure is crucial. The copolymer contains acrylic acid units along with sulfonated groups.The copolymer consists of acrylic acid units and sulfonated groupings. The carboxylic acid groups from the acrylic acid part are capable of dissociation in an aqueous environment.The carboxylic acids from the acrylic acid can dissociate in an aqueous solution. When in water, these carboxylic acid groups can release protons, making the copolymer anionic.These carboxylic groups can release protons in water, causing the copolymer to become anionic. This anionic nature allows it to interact with positively charged species.Its anionic nature allows for it to interact positively charged species. For example, in water treatment applications, it can bind to positively charged metal ions like calcium, magnesium, and iron.In water treatment, it can bind positively charged metal ions such as calcium, magnesium and iron. By sequestering these metal ions, it helps prevent the formation of scale.It helps prevent the formation or scale by sequestering metal ions. Scale formation occurs when metal ions in hard water react with anions such as carbonate to form insoluble precipitates.Scale is formed when metal ions react with anions, such as carbonate, to form insoluble precipitates. The sulfonated polyacrylic acid copolymer binds to the metal ions, keeping them in solution and thus inhibiting scale deposition on surfaces like pipes and heat exchangers.The sulfonated copolymer of polyacrylic acid binds the metal ions and keeps them in solution, preventing scale deposition.
The sulfonated groups also contribute to the copolymer's functionality.The functionality of the copolymer is also enhanced by the sulfonated group. These groups enhance the copolymer's solubility in water due to their hydrophilic nature.These groups are hydrophilic and enhance the copolymer’s solubility in liquids. Additionally, they can participate in electrostatic interactions.They can also participate in electrostatic interaction. In dispersant applications, for instance, the anionic nature of the copolymer, derived from both the carboxylate and sulfonate groups, enables it to adsorb onto the surface of particles.The anionic nature of this copolymer derived from the carboxylate group and the sulfonate group, allows it to adsorb on the surface of particles in dispersant applications. When added to a suspension of particles, like pigments in a paint formulation or clay particles in drilling fluids, the copolymer adsorbs onto the particle surfaces.The copolymer will adsorb onto the surface of particles when added to a suspension, such as pigments in paint formulations or clay particles in drilling liquids. This adsorption creates an electrostatic repulsion between the particles.This adsorption causes an electrostatic repellence between the particles. As a result, the particles are kept well - dispersed, preventing them from aggregating and settling out of the suspension.The particles are well-dispersed and do not aggregate or settle out of the suspension. This helps maintain the stability and homogeneity of the mixture, ensuring consistent performance in applications such as coatings, where good pigment dispersion is essential for color uniformity and film quality.This helps maintain stability and homogeneity in the mixture. It ensures consistent performance for applications such as coatings where good pigment dispersion and color uniformity are essential.
In the field of cement additives, the sulfonated polyacrylic acid copolymer can act as a superplasticizer.The sulfonated copolymer of polyacrylic acid can be used as a superplasticizer in the cement additives field. It adsorbs onto the surface of cement particles, providing an electrostatic repulsive force.It adsorbs on the surface of cement particle, causing an electrostatic repelling force. This force separates the cement particles, reducing the friction between them.This force separates cement particles and reduces friction between them. As a result, the workability of the cement paste is improved.The workability of the paste is therefore improved. Less water is required to achieve the desired fluidity of the cement mixture.The cement paste is more fluid when less water is used. This not only helps in better placement of the cement but also improves the long - term mechanical properties of the hardened cement, as the reduced water - cement ratio leads to a denser microstructure.This helps to improve the placement of the cement and also the long-term mechanical properties of the hardened concrete.
What are the advantages of sulfonated polyacrylic acid copolymer compared to other polymers?
Sulfonated polyacrylic acid copolymer offers several notable advantages compared to other polymers.Comparing other polymers, the sulfonated copolymer of polyacrylic acid and acrylic acid offers a number of notable advantages.
One key advantage is its excellent water - solubility.Its excellent water-solubility is a key advantage. This property makes it highly suitable for applications in aqueous systems.This property makes it ideal for applications in aqueous environments. In contrast, some other polymers may have limited solubility in water, which restricts their use in processes that require homogeneous mixing in an aqueous environment.Some polymers are less soluble in water and therefore cannot be used in processes that require homogeneous mixture in an aqueous medium. For instance, in water - based coatings, the sulfonated polyacrylic acid copolymer can dissolve easily, ensuring uniform distribution of the polymer within the coating formulation.In water-based coatings, for example, the sulfonated copolymer of polyacrylic acid can dissolve easily. This ensures uniform distribution of polymer in the coating formulation. This leads to better film - forming properties and enhanced coating performance.This results in better film-forming properties and improved coating performance.
It also exhibits strong chelating ability.It also has a strong chelating capability. The sulfonate groups in the copolymer can effectively bind to metal ions.The sulfonate group in the copolymer is able to bind metal ions. This is beneficial in applications such as water treatment.This is useful in applications like water treatment. When compared to polymers lacking such functional groups, sulfonated polyacrylic acid copolymer can sequester metal ions like calcium, magnesium, and iron.Comparing sulfonated copolymers to polymers without such functional groups, the sulfonated copolymer is able to sequester metals like calcium, magnesium and iron. This helps prevent the formation of scale in industrial water systems, boilers, and heat exchangers.This helps to prevent the formation and accumulation of scale on industrial water systems, heat exchangers, and boilers. In textile dyeing processes, it can control the presence of metal ions that might otherwise interfere with the dyeing process, resulting in more consistent and high - quality dyeing results.It can be used to control metal ions in textile dyeing processes. This will result in more consistent, high-quality dyeing results.
The copolymer has good dispersing properties.The copolymer is a good disperser. It can disperse various particles, including inorganic pigments and fillers.It can disperse a variety of particles, including inorganic fillers and pigments. In the paint and ink industries, this is crucial.This is important for the paint and ink industry. While some polymers may cause particle aggregation, sulfonated polyacrylic acid copolymer can keep the particles well - dispersed.Sulfonated Polyacrylic Acid Copolymer, on the other hand, can prevent particle aggregation. This improves the stability of the paint or ink suspension, preventing sedimentation and maintaining the color uniformity and gloss of the final product.This increases the stability of paint or ink suspensions, preventing the sedimentation of color and gloss. In ceramic manufacturing, it can disperse ceramic powders, enabling better shaping and densification of ceramic products.It can be used to disperse ceramic particles in ceramic manufacturing. This allows for better shaping and densification.
Another advantage is its environmental friendliness.Its environmental friendliness is another advantage. In an era where environmental concerns are paramount, sulfonated polyacrylic acid copolymer stands out.In an age where environmental concerns are paramount the sulfonated copolymer of polyacrylic acid stands out. It is biodegradable to a certain extent, unlike some traditional polymers that persist in the environment for long periods.It is biodegradable up to a point, unlike some polymers that are persistent in the environment. This makes it a more sustainable choice in applications where waste disposal or environmental impact is a consideration, such as in agricultural applications for soil conditioners or in some packaging materials where biodegradability is desired.This makes it more sustainable in applications where environmental impact or waste disposal is a concern, such as agricultural applications for soil conditioners and in some packaging materials that require biodegradability.
Finally, sulfonated polyacrylic acid copolymer has good thermal stability.The sulfonated copolymer of polyacrylic acid has excellent thermal stability. It can withstand relatively high temperatures without significant degradation.It can withstand high temperatures without significant degradation. This property is useful in applications such as oil - field chemicals, where it may be exposed to elevated temperatures in oil - well operations.This property is particularly useful in applications like oil-field chemicals, which may be exposed at high temperatures during oil-well operations. In contrast, some polymers may break down under high - temperature conditions, losing their functional properties.Some polymers, on the other hand, may lose their functional properties under high-temperature conditions.
What are the potential environmental impacts of sulfonated polyacrylic acid copolymer?
Sulfonated polyacrylic acid copolymer is a type of polymer with various applications, but like many chemical substances, it can have potential environmental impacts.Sulfonated Polyacrylic Acid Copolymer is one type of polymer that has many applications. However, like many chemicals, it may have environmental effects.
One of the main concerns is related to its persistence in the environment.One of the main concerns is its persistence in the environmental. If it does not degrade easily, it can accumulate in soil, water bodies, and sediment.If it is not easily degradable, it can accumulate on soil, in water bodies, or in sediment. In aquatic systems, this accumulation can potentially affect the organisms living there.This accumulation in aquatic systems can potentially affect organisms that live there. For example, it might interfere with the normal physiological functions of aquatic invertebrates, fish, and other organisms.It could interfere with the normal physiological function of aquatic invertebrates and fish. These organisms may absorb the copolymer through their gills, skin, or by ingesting contaminated water or food.These organisms can absorb the copolymer via their gills or skin, or ingest contaminated food or water. This absorption could lead to sublethal effects such as reduced growth rates, impaired reproduction, and weakened immune systems.This absorption can have sublethal effects, such as a reduced growth rate, impaired reproduction and weakened immunity systems.
Another aspect is its impact on water quality.A second aspect is the impact on water quality. If sulfonated polyacrylic acid copolymer is released into water sources, it can potentially change the chemical properties of the water.It is possible that sulfonated copolymer of polyacrylic acid can change the chemical properties in water. It might affect the pH, turbidity, or the solubility of other substances in the water.It could affect the pH, the turbidity or the solubility other substances in water. For instance, if it binds to certain metal ions in the water, it could either increase or decrease their bioavailability to aquatic life.If it binds with certain metal ions, it can either increase or decrease the bioavailability of those metal ions to aquatic life. An increase in the bioavailability of some heavy metals could be extremely harmful, as these metals can be toxic to organisms even at low concentrations.A bioavailability increase of certain heavy metals may be harmful to aquatic life, as they can be toxic even at low concentrations.
In the soil environment, the copolymer could influence soil structure and fertility.The copolymer can influence soil structure and fertility in the soil environment. If it accumulates in the soil, it might alter the soil's porosity, water - holding capacity, and the ability of roots to penetrate the soil.If it accumulates, it could alter the soil's water-holding capacity, porosity and ability of roots to reach the soil. This could have a cascading effect on plant growth.This could have a cascading impact on plant growth. For example, if the water - holding capacity is reduced, plants may not receive enough water, leading to reduced crop yields.If the water-holding capacity is reduced, for example, plants may receive insufficient water, resulting in reduced crop yields. Additionally, it could potentially interact with soil microorganisms, which play a crucial role in nutrient cycling.It could also interact with soil microorganisms that play a vital role in the nutrient cycle. A disruption in the normal functioning of these microorganisms could affect the availability of nutrients such as nitrogen, phosphorus, and potassium to plants.A disruption in their normal functioning could affect the availability of nutrients to plants, such as nitrogen, potassium, and phosphorus.
However, it's important to note that the actual environmental impacts depend on many factors.It's important to remember that the environmental impact depends on many factors. These include the quantity of the copolymer released, the environmental conditions such as temperature, pH, and the presence of other substances that can interact with it.The amount of copolymer released and environmental conditions like temperature, pH and the presence of substances that interact with it are all factors to consider. Also, if proper waste management and treatment processes are in place, the release of sulfonated polyacrylic acid copolymer into the environment can be minimized, reducing its potential negative impacts.If waste management and treatment procedures are implemented, the release of the sulfonated copolymer can be minimized. This will reduce its potential negative effects.
How is sulfonated polyacrylic acid copolymer manufactured?
Sulfonated polyacrylic acid copolymer is typically manufactured through a series of chemical processes.Sulfonated Polyacrylic Acid Copolymer is usually manufactured using a series chemical processes. Here is a general overview of the manufacturing steps.Here is an overview of the steps involved in manufacturing.
The first step often involves the selection of raw materials.The first step is often the selection of raw material. Acrylic acid is a key monomer for the synthesis of polyacrylic acid.Acrylic acid is the key monomer in the synthesis polyacrylic acid. To introduce sulfonate groups, a sulfonating agent is also required.A sulfonating agents is required to introduce sulfonate group. Common sulfonating agents include compounds like sodium bisulfite or other sulfur - containing reagents capable of adding sulfonate (-SO3H or its salts) functional groups.Compounds like sodium bisulfite and other sulfur-containing reagents are common sulfonating agent.
The polymerization process is usually carried out in a suitable reaction medium.The polymerization is carried out in a reaction medium. Aqueous solutions are frequently used due to the good solubility of acrylic acid and related monomers in water, as well as the environmental friendliness of the aqueous system.Aqueous solutions have been used for many years due to the solubility of monomers and acrylic acid in water. In the reaction vessel, a polymerization initiator is added.In the reaction vessel, an initiator for polymerization is added. Initiators, such as persulfates (e.g., ammonium persulfate or potassium persulfate), are used to start the polymerization reaction.Initiators such as persulfates, e.g. ammonium persulfate, potassium persulfate, are used to initiate the polymerization. They decompose under certain reaction conditions (usually elevated temperatures) to generate free radicals.They decompose in certain reaction conditions (usually high temperatures) and generate free radicals. These free radicals then react with acrylic acid monomers, causing them to polymerize and form long - chain polyacrylic acid molecules.These free radicals react with acrylic acid monomers to cause them to polymerize, resulting in long-chain polyacrylic acids.
During the polymerization, the sulfonating agent is carefully introduced at an appropriate stage.The sulfonating agents are introduced at the right time during the polymerization. This can be either before the polymerization starts, during the polymerization process, or in a post - polymerization step.This can either be done before the polymerization begins, during the process of polymerization, or after the polymerization. When added during polymerization, the sulfonating agent reacts with the growing polymer chains.The sulfonating agents react with the polymer chains when added during polymerization. The sulfonate groups attach to the polyacrylic acid backbone, resulting in the formation of sulfonated polyacrylic acid copolymer.The sulfonate group attaches to the polyacrylic backbone, leading to the formation of the sulfonated copolymer. The reaction conditions, such as temperature, reaction time, and the ratio of monomers to the sulfonating agent, need to be precisely controlled.It is important to control the reaction conditions such as temperature, time and ratio of monomers with the sulfonating agents. Higher temperatures generally increase the reaction rate but may also affect the molecular weight and distribution of the copolymer.Higher temperatures increase the reaction rate, but can also affect the molecular mass and distribution of the polymer.
After the polymerization and sulfonation reactions are complete, the resulting product may need to be purified.Purification may be required after the polymerization reaction and the sulfonation reaction. This can involve processes such as filtration to remove any insoluble impurities, followed by dialysis or ultrafiltration in some cases to separate the copolymer from unreacted monomers, initiator residues, and other small - molecule by - products.This can include processes such as filtration, to remove any impurities that are insoluble, followed by dialysis, or ultrafiltration, in some cases, to separate the copolymer, from unreacted monomers and initiator residues, or other small-molecule by-products. The purified sulfonated polyacrylic acid copolymer can then be further processed into different forms, such as a concentrated solution or a solid powder, depending on its intended applications.Purified sulfonated copolymers can be further processed to different forms depending on their intended applications. For example, if it is to be used in water treatment, it may be formulated as a concentrated liquid for easy dosing, while for some industrial applications where long - term storage is required, it may be dried and ground into a powder.If it is intended to be used for water treatment, the liquid may be formulated in a concentrated form for easy dosing. For industrial applications, where long-term storage is required, the powder may be dried and ground.