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Product Name | Ethyl acrylate |
Cas Number | 140-88-5 |
Formula | C5H8O2 |
Molar Mass | 100.12 |
Density | 0.923 g/cm³ |
Boiling Point | 99 °C |
Melting Point | -71 °C |
Solubility In Water | 1.5 g/L |
Vapor Pressure | 32 mmHg at 20 °C |
Flash Point | -2 °C |
Autoignition Temperature | 345 °C |
Refractive Index | 1.401 |
Viscosity | 0.39 cP at 20 °C |
Surface Tension | 27.37 dyn/cm at 25 °C |
Heat Capacity | 176.5 J/mol·K |
What are the main uses of ethyl acrylate?
Ethyl acrylate is a versatile chemical compound with several important applications.Ethyl Acrylate is a versatile chemistry compound that has many important applications.
One of the primary uses of ethyl acrylate is in the production of polymers.Ethyl Acrylate is used to produce polymers. It is a key monomer in the synthesis of acrylic polymers.It is used as a monomer for the synthesis of acrylics. These polymers find wide - spread use in the coatings industry.These polymers are widely used in the coatings sector. For example, they are used to formulate high - performance paints.They are used in the formulation of high-performance paints. Acrylic - based paints made from ethyl acrylate offer excellent durability, resistance to weathering, and good adhesion to various surfaces.Acrylic-based paints derived from ethyl acrylicate are extremely durable, resistant to weathering and adhere well to a variety of surfaces. They can be used on metal, wood, and plastic substrates, protecting them from corrosion, wear, and environmental damage.These paints can be applied to metal, wood and plastic surfaces, protecting them against corrosion, wear and environmental damage. In the automotive industry, these coatings are used to give cars a long - lasting and aesthetically pleasing finish.These coatings are used in the automotive industry to give cars an aesthetically pleasing and long-lasting finish.
Ethyl acrylate - derived polymers are also used in the adhesives sector.The adhesives industry also uses polymers derived from ethyl-acrylate. Pressure - sensitive adhesives (PSAs) are a major application area.Pressure-sensitive adhesives (PSAs), are one of the most common types. PSAs made from ethyl acrylate - based polymers have properties such as strong tack, which allows them to stick to surfaces upon light pressure, and good peel strength.PSAs made of ethyl-acrylate-based polymers are characterized by strong tack and peel strength. These adhesives are used in products like tapes, labels, and stickers.These adhesives can be found in products such as tapes, stickers, and labels. The ability to adhere well to different materials and remain stable over time makes them essential in packaging, where they ensure that labels stay firmly attached to products, and in the manufacturing of disposable medical products like band - aids, where reliable adhesion is crucial.They are used in products such as tapes, labels, and stickers because they adhere well to various materials and remain stable for a long time.
In the textile industry, ethyl acrylate is used to modify fibers.In the textile industry ethyl acrylicate is used to modify fibres. It can be copolymerized with other monomers to create polymers that are used to treat fabrics.It can be copolymerized to create polymers used to treat fabrics. These treatments can improve the fabric's properties, such as increasing its resistance to wrinkles, enhancing its water - repellent capabilities, or improving its dye - uptake.These treatments can improve a fabric's properties such as its wrinkle resistance, its water repellent abilities, or its dye-uptake. For instance, by applying ethyl - acrylate - based polymers to cotton fabrics, manufacturers can create wrinkle - free and more durable textiles.By applying ethyl-acrylate-based polymers to cotton fabric, manufacturers can create wrinkle-free and more durable textiles.
Another important use is in the production of plastics.Plastics are another important application. Ethyl acrylate can be incorporated into plastic formulations to enhance their properties.Ethyl Acrylate can be added to plastic formulations to improve their properties. For example, in the production of engineering plastics, it can improve impact resistance and flexibility.In the production of engineering materials, it can increase impact resistance and flexibility. This makes the plastics more suitable for applications where they need to withstand mechanical stress without breaking or cracking.This makes plastics better suited for applications that require them to withstand mechanical stresses without breaking or cracking.
In the area of inks, ethyl acrylate - based polymers are used to formulate printing inks.Printing inks are made from ethyl-acrylate-based polymers. These inks offer good printability, fast drying times, and excellent color retention.These inks are easy to print, have a fast drying time, and offer excellent color retention. They are used in various printing processes, including flexography and gravure printing, for applications such as printing on packaging materials, magazines, and newspapers.They are used for a variety of printing processes including flexography, gravure printing and printing on magazines and newspapers.
What are the safety precautions when handling ethyl acrylate?
Ethyl acrylate is a hazardous chemical, and when handling it, the following safety precautions should be taken.When handling ethyl-acrylate, it is important to take the following safety precautions.
Firstly, in terms of personal protective equipment.First, personal protective equipment. Wear appropriate chemical - resistant clothing, such as full - body suits made of materials like butyl rubber or neoprene.Wear chemical-resistant clothing such as full-body suits made from materials like butyl or neoprene. This helps prevent skin contact with ethyl acrylate, which can cause skin irritation, burns, and potentially allergic reactions.This will help prevent skin contact with the ethyl acrylicate, which may cause skin irritations, burns and allergic reactions. For the eyes, use chemical - splash goggles or a face - shield.Use chemical splash goggles for the eyes or a face shield. Ethyl acrylate can cause severe eye damage if it splashes into the eyes.Ethyl Acrylate can cause serious eye damage if splashed into the eyes. Additionally, wear suitable respiratory protection.Wear respiratory protection as well. In areas with potential ethyl acrylate vapor exposure, use a self - contained breathing apparatus (SCBA) in high - concentration situations or a supplied - air respirator with a proper organic vapor cartridge for lower - level exposures.Use a self-contained breathing apparatus (SCBA), in high-concentration situations, or a supplied-air respirator with an organic vapor cartridge when exposed to lower levels.
Secondly, ensure proper ventilation in the handling area.Second, make sure that the area where you are handling the product is properly ventilated. Ethyl acrylate is volatile, and its vapors can be flammable and harmful if they accumulate.Ethyl Acrylate is volatile and its vapors are flammable and dangerous if they build up. Use local exhaust ventilation systems to capture vapors at the source, such as near storage containers or during transfer operations.Use local exhaust ventilation to capture vapors near storage containers and during transfer operations. General room ventilation should also be sufficient to maintain air quality and prevent the build - up of vapors.To maintain air quality and to prevent vapor build-up, general room ventilation is also sufficient.
When it comes to storage, store ethyl acrylate in a cool, well - ventilated area away from heat sources, flames, and oxidizing agents.Store ethyl acrylicate in a cool and well-ventilated area away from heat, flames and oxidizing agents. It should be kept in tightly closed containers to prevent leakage and vapor release.To prevent leakage or vapor release, it should be stored in tightly sealed containers. Label storage containers clearly with information about the chemical, including its hazards and handling instructions.Label containers with information about the chemicals, including their hazards and handling instructions.
During handling operations, be extremely cautious.Be extremely careful when handling materials. When transferring ethyl acrylate, use appropriate transfer equipment, such as grounded hoses to prevent static electricity build - up, which could potentially ignite the flammable vapors.Use grounded hoses when transferring ethylacrylate to prevent static electricity from building up. This could ignite the flammable vapours. Avoid any actions that may cause spills, such as over - filling containers.Avoid actions that could cause spills such as over-filling containers. In case of a spill, immediately evacuate non - essential personnel from the area.In the event of a spillage, evacuate all non-essential personnel from the area. Use absorbent materials like vermiculite, sand, or special spill - control kits to contain and clean up the spill.To contain and clean the spill, use absorbent materials such as vermiculite or sand. Dispose of the contaminated absorbent materials in accordance with local environmental regulations.Dispose the contaminated absorbent material in accordance with local regulations.
Finally, have an emergency response plan in place.Last but not least, you should have an emergency plan in place. Train employees on how to respond in case of an accident, such as a spill or exposure.Employees should be trained on what to do in the event of an accident such as a spillage or exposure. Provide access to safety showers and eyewash stations in the immediate vicinity of the handling area for quick de - contamination in case of skin or eye contact.Safety showers and eyewashes should be located near the handling area to allow for quick de-contamination in the event of skin or eye contact. And always have a first - aid kit available with instructions on treating ethyl acrylate - related injuries.Always have a first-aid kit with instructions for treating ethyl-acrylate-related injuries.
What are the environmental impacts of ethyl acrylate?
Ethyl acrylate is a chemical compound with potential environmental impacts.Ethyl Acrylate is a chemical compound that can have negative environmental effects.
In the atmosphere, ethyl acrylate can participate in photochemical reactions.It can be involved in photochemical reactions in the atmosphere. It contains carbon - carbon double bonds, which are reactive under the influence of sunlight and atmospheric radicals.It contains double carbon-carbon bonds that are reactive when exposed to sunlight and atmospheric radiance. When released into the air, it can react with hydroxyl radicals, one of the most important oxidizing species in the atmosphere.It can react with hydroxyl radics, which are one of the most important oxidizing agents in the atmosphere, when released into the air. These reactions can lead to the formation of secondary pollutants such as ozone and peroxyacetyl nitrate (PAN).These reactions can result in secondary pollutants like ozone and Peroxyacetyl Nitrate (PAN). Ozone at ground - level is a harmful pollutant that can cause respiratory problems for humans, and it also has negative impacts on plants, reducing their growth and productivity.Ozone is a pollutant at ground level that can cause respiratory issues for humans. It also has negative effects on plants by reducing their productivity and growth. PAN can damage the leaves of plants, affecting their photosynthetic ability.PAN can damage leaves, affecting photosynthetic abilities.
When ethyl acrylate is released into water bodies, it can have adverse effects on aquatic life.If ethylacrylate is released in water bodies, this can have negative effects on aquatic life. Although it has some solubility in water, it may partition to the sediment or be taken up by aquatic organisms.It may partition into the sediment or be absorbed by aquatic organisms, despite its solubility. Aquatic invertebrates and fish are particularly vulnerable.Invertebrates in water and fishes are especially vulnerable. Ethyl acrylate can act as a toxicant, interfering with the normal physiological functions of these organisms.Ethyl Acrylate can be toxic, interfering in the normal physiological functions. It may disrupt their respiratory systems, affect their ability to osmoregulate, and potentially cause damage to their nervous systems.It can disrupt their respiratory system, affect their ability osmoregulate and possibly cause damage to their nervous system. In addition, it can also have an impact on the reproduction and development of aquatic species.It can also affect the development and reproduction of aquatic species. For example, it may cause abnormal embryo development in fish, leading to reduced survival rates of the offspring.It may, for example, cause abnormal embryonic development in fish, resulting in reduced survival rates for the offspring.
In soil, ethyl acrylate can potentially contaminate the soil environment.In soil, ethylacrylate may contaminate soil. It may be taken up by plant roots, and then translocated within the plant.It can be absorbed by the roots of plants and then transported within them. This can lead to phytotoxic effects, such as reduced plant growth, chlorosis (yellowing of leaves), and in severe cases, plant death.This can cause phytotoxic effects such as reduced plant growth and chlorosis (yellowing leaves) or in severe cases plant death. Microorganisms in the soil are also affected.The soil microorganisms are also affected. Ethyl acrylate can inhibit the growth and activity of soil - dwelling bacteria and fungi, which play crucial roles in nutrient cycling, decomposition of organic matter, and soil structure maintenance.Ethyl Acrylate can inhibit the growth of bacteria and fungi that live in soil. These organisms are crucial for nutrient cycling, organic matter decomposition, and soil structure maintenance. If the activity of these microorganisms is disrupted, it can have a cascading effect on the entire soil ecosystem, potentially reducing soil fertility and overall ecosystem health.If the activity of microorganisms in the soil is disrupted, this can have a cascading impact on the soil ecosystem and reduce soil fertility. Overall, the environmental release of ethyl acrylate needs to be carefully managed to minimize its negative impacts on the air, water, and soil environments.The environmental release of ethyl-acrylate must be carefully managed in order to minimize its negative impact on the air, soil, and water environments.
How is ethyl acrylate produced?
Ethyl acrylate is an important monomer in the chemical industry with wide - spread applications in the production of polymers such as adhesives, coatings, and textiles.Ethyl Acrylate is a monomer that is widely used in the chemical industry. It can be found in many polymers, such as textiles, adhesives, and coatings. It is produced through the following main methods:It is produced by the following methods:
1. Esterification of acrylic acid with ethanolEsterification with ethanol of acrylic acid
This is the most common method.This is the most popular method. In this process, acrylic acid and ethanol react in the presence of a catalyst.This process involves the reaction of acrylic acid with ethanol in the presence a catalyst. Sulfuric acid has been traditionally used as a catalyst for this esterification reaction.As a catalyst, sulfuric acid is traditionally used for this esterification. The chemical equation for this reaction is:The chemical equation is:
CH2=CHCOOH + C2H5OH = CH2=CHCOOC2H5 + H2O
However, sulfuric acid as a catalyst has some drawbacks.But sulfuric acid has some disadvantages. It can cause side - reactions like dehydration of ethanol to form ethylene and can also corrode the reaction equipment.It can cause side reactions such as the dehydration of alcohol to form ethylene, and it can also corrode reaction equipment. To address these issues, more modern processes often use solid - acid catalysts such as ion - exchange resins.Modern processes use ion-exchange resins or solid - acids catalysts to address these issues. These solid - acid catalysts are more selective, easier to separate from the reaction mixture, and cause less corrosion.These solid - acids catalysts are more select, easier to separate from reaction mixtures, and cause less corrosive.
The reaction is typically carried out at elevated temperatures, usually in the range of 60 - 100degC, and under reflux conditions to ensure the continuous removal of water formed during the reaction.The reaction is usually carried out at high temperatures, typically between 60-100degC. It is also performed under reflux conditions, to ensure that the water formed during the process can be continuously removed. The removal of water drives the equilibrium of the reversible esterification reaction towards the formation of ethyl acrylate according to Le Chatelier's principle.According to Le Chatelier’s principle, the removal of water drives equilibrium of the reversible esterification reaction towards ethyl-acrylate.
2. Reaction of ethylene, carbon monoxide, and ethanol (Reppe process)Reaction between ethylene, carbon dioxide, and ethanol
This method involves the reaction of ethylene, carbon monoxide, and ethanol in the presence of a catalyst.This method involves the reaction between ethylene, carbon dioxide, and ethanol, in the presence a catalyst. The catalyst commonly used is a nickel - based complex.A nickel-based complex is the most common catalyst. The overall reaction can be represented as follows:The overall reaction is represented by the following:
C2H4 + CO + C2H5OH - CH2=CHCOOC2H5C2H4 + CO + CH2 = CHCOOC2H5
The reaction occurs under high - pressure conditions, typically around 10 - 50 atmospheres, and at temperatures ranging from 150 - 200degC.The reaction takes place under high pressure conditions, usually between 10 and 50 atmospheres. Temperatures range from 150 to 200degC. The advantage of this process is that it can use relatively inexpensive starting materials such as ethylene and carbon monoxide.This process has the advantage of using relatively inexpensive materials, such as ethylene or carbon monoxide. However, the high - pressure requirements make the process more complex and require specialized equipment to ensure safety.The high-pressure requirements make the process complex and require specialized safety equipment.
3. Trans - esterification
Ethyl acrylate can also be produced by trans - esterification.Trans - esterification can also produce ethyl acrylicate. For example, methyl acrylate can react with ethanol in the presence of a catalyst, such as an alkoxide or a metal - based catalyst.In the presence of a catalyser, such as an metal-based catalyst or an alkoxide, methylacrylate can react to ethanol. The reaction equation is:The reaction equation is as follows:
CH2=CHCOOCH3 + C2H5OH = CH2=CHCOOC2H5 + CH3OH
This method can be useful when methyl acrylate is more readily available or when the production of methyl alcohol as a by - product can be economically utilized in other processes.This method is useful when methyl-acrylate is readily available, or when methyl alcohol can be produced as a by-product and used in other processes. The reaction conditions for trans - esterification are similar to those of direct esterification, with temperature and catalyst selection being crucial factors to control the reaction rate and product selectivity.The trans-esterification reaction conditions are similar to direct esterification. Temperature and catalyst selection are crucial factors in controlling the reaction rate and selectivity.
What are the storage requirements for ethyl acrylate?
Ethyl acrylate is a colorless liquid with a characteristic acrid smell.Ethyl Acrylate is a colorless, acrid liquid. It is widely used in the production of polymers, coatings, adhesives, and other industrial applications.It is widely used for the production of polymers and adhesives. Due to its chemical properties, proper storage is crucial to ensure safety and maintain its quality.Its chemical properties make it important to store it properly to maintain its quality and ensure its safety.
First, storage location is important.The first thing to consider is the storage location. Ethyl acrylate should be stored in a cool, well - ventilated area.Ethyl Acrylate should be kept in a well-ventilated, cool area. High temperatures can accelerate its decomposition or polymerization reactions.High temperatures can speed up the polymerization or decomposition reactions. A storage temperature preferably below 25 degrees Celsius is ideal.Ideal is a temperature of below 25 degrees Celsius. This helps to minimize the risk of self - reaction and potential explosion hazards.This will help to reduce the risk of self-reaction and explosion hazards.
Second, the storage container is of great significance.The storage container is also very important. It should be made of materials that are resistant to corrosion by ethyl acrylate.It should be made from materials that are resistant against corrosion by ethyl acrylicate. Commonly, stainless - steel containers are used.Stainless steel containers are commonly used. Avoid using materials like copper or its alloys, as they can catalyze the polymerization of ethyl acrylate.Copper or its alloys can cause ethylacrylate to polymerize. The container should be tightly sealed to prevent evaporation and contact with air.The container must be tightly sealed in order to prevent evaporation or contact with air. Air can oxidize ethyl acrylate, leading to the formation of peroxides over time.Air can oxidize the ethylacrylate, resulting in the formation of peroxides with time. These peroxides are highly unstable and can cause violent decomposition.These peroxides can cause violent decomposition.
Third, segregation is necessary.Third, segregation of chemicals is essential. Ethyl acrylate should be stored separately from oxidizing agents, strong acids, strong bases, and amines.Ethyl Acrylate should be kept away from strong acids, bases, amines, oxidizing agents and other strong chemicals. Contact with these substances can initiate chemical reactions, some of which may be exothermic and potentially dangerous.Contact with these substances may cause chemical reactions. Some of these reactions can be exothermic and dangerous. For example, reactions with strong bases can lead to hydrolysis of ethyl acrylate, altering its chemical properties.For example, reactions involving strong bases can cause ethylacrylate to hydrolyze, changing its chemical properties.
Fourth, regular inspection of the storage facility and containers is essential.It is important to inspect the storage area and containers regularly. Check for any signs of leakage, corrosion, or discoloration of the liquid.Check for signs of liquid leakage, corrosion or discoloration. If there are signs of peroxide formation, such as the presence of a precipitate or an increase in viscosity, appropriate measures should be taken immediately.If there are any signs of peroxide, such as a precipitate, or an increase in the viscosity of the liquid, immediate action should be taken. This may involve disposing of the contaminated material in a safe manner following local regulations.This could include disposing of the contaminated materials in a safe way according to local regulations.
Finally, fire safety measures must be in place.Fire safety measures are also necessary. Ethyl acrylate is flammable, so the storage area should be equipped with appropriate fire - fighting equipment, such as dry - chemical fire extinguishers, foam extinguishers, and sprinkler systems.Ethyl Acrylate is flammable. Therefore, the storage area must be equipped with fire-fighting equipment such as foam extinguishers and dry-chemical fire extinguishers. The storage area should also be designed to prevent the spread of fire in case of an ignition.The storage area must also be designed in a way that prevents the spread of a fire in the event of an ignition.