.

Hydroxypropyl Methacrylate (hpma)


Properties
Product Name Hydroxypropyl methacrylate
Cas Number 27813-02-1
Formula C7H12O3
Molar Mass 144.17 g/mol
Density 1.051 g/cm³
Boiling Point 85 °C (185 °F) at 10 mmHg
Flash Point 101 °C (214 °F)
Refractive Index 1.450 - 1.452
Viscosity 4.1 mPa·s at 25 °C
Vapor Pressure 0.5 Pa at 20 °C
Melting Point -60 °C
Water Solubility soluble
Appearance clear liquid
Stability stable under recommended storage conditions
FAQ

What are the applications of Hydroxypropyl Methacrylate (HPMA)?

Hydroxypropyl Methacrylate (HPMA) has a wide range of applications across various industries.Hydroxypropyl methacrylate (HPMA), which is widely used in many industries, has many applications.
In the coatings industry, HPMA is used to improve the properties of coatings.HPMA is used in the coatings industry to improve coating properties. It can enhance adhesion, allowing the coating to better stick to different substrates such as metals, plastics, and wood.It can improve adhesion and allow the coating to stick better to different substrates like metals, wood, and plastics. This is crucial for ensuring the long - term durability of the coating.This is important for the durability of the coating. HPMA also contributes to the hardness and abrasion - resistance of the coatings.HPMA contributes to coatings' hardness and resistance to abrasion. For example, in automotive coatings, the addition of HPMA can make the paint more resistant to scratches and chips, maintaining the vehicle's appearance over time.HPMA, for example, can be added to automotive coatings to make them more resistant against scratches and chips. This will maintain the vehicle's look over time. Additionally, it can improve the chemical resistance of coatings, protecting the underlying material from corrosion and damage caused by chemicals.It can also improve the chemical resistance, protecting the underlying materials from corrosion and damage due to chemicals.

The adhesives sector also benefits from HPMA.HPMA is also beneficial to the adhesives industry. It can be incorporated into adhesive formulations to adjust the viscosity and curing characteristics.It can be added to adhesive formulations in order to alter the viscosity or curing characteristics. HPMA - containing adhesives often exhibit better bonding strength, especially when bonding materials with different surface energies.HPMA-containing adhesives are often stronger, especially when bonding different materials with different surface energy. This makes them suitable for applications in the electronics industry, where components with diverse materials need to be firmly attached.They are therefore suitable for electronics applications where components made of different materials need to be firmly adhered.

In the field of polymers and plastics, HPMA is used as a monomer for copolymerization.HPMA is used in the polymer and plastics industry as a monomer to copolymerize. Copolymers made with HPMA can have unique properties.HPMA copolymers can have unique properties. For instance, they can be designed to be water - soluble or have specific solubility profiles, which is useful in applications like drug delivery systems.They can be designed as water-soluble or with specific solubility profiles. This is useful for applications such as drug delivery systems. In drug delivery, HPMA - based polymers can be engineered to encapsulate drugs and release them in a controlled manner.HPMA-based polymers are useful in drug delivery because they can be engineered so that drugs are encapsulated and released in a controlled way. The hydroxypropyl groups in HPMA can interact with biological molecules, enabling targeted drug delivery to specific tissues or cells.The hydroxypropyl group in HPMA can interact biological molecules to enable targeted drug delivery.

In the textile industry, HPMA is used for textile finishing.HPMA is used in the textile industry for textile finishing. It can improve the wrinkle - resistance and dimensional stability of fabrics.It can improve the wrinkle-resistance and dimensional stability in fabrics. When applied to textiles, it forms a thin film that helps the fabric maintain its shape and reduces the formation of wrinkles during washing and wearing.It forms a thin layer on textiles that helps them maintain their shape and reduces wrinkles.

Finally, in the production of contact lenses, HPMA is used to impart hydrophilic properties.HPMA is also used to give contact lenses hydrophilic properties. Contact lenses made with materials containing HPMA can absorb water, which is essential for providing comfort to the wearer and maintaining the proper function of the eye.Contact lenses containing HPMA absorb water, which is important for comfort and proper eye function. The presence of HPMA allows the contact lens to remain moist on the eye surface, reducing the risk of dryness and irritation.The presence of HPMA in the material allows the contact lens surface to remain moist, reducing the risk for irritation and dryness.

What are the properties of Hydroxypropyl Methacrylate (HPMA)?

Hydroxypropyl Methacrylate (HPMA) has several notable properties.HPMA is a polymer with several unique properties.
First, in terms of its physical state, HPMA is typically a clear, colorless liquid at room temperature.HPMA is a clear liquid that is colorless at room temperature. It has a relatively low viscosity, which makes it easy to handle and process in various manufacturing operations.It is relatively low in viscosity which makes it easier to handle and process during various manufacturing operations. This low viscosity also enables it to flow well, facilitating its incorporation into different formulations.Its low viscosity allows it to flow easily, which makes it easy to incorporate into different formulations.

HPMA is highly reactive due to the presence of the methacrylate double bond.HPMA is highly reactive due to the double bond of the methacrylate. This reactivity allows it to participate in polymerization reactions.This reactivity allows HPMA to participate in polymerization. It can copolymerize with a wide range of other monomers, such as methyl methacrylate, styrene, and acrylic acid.It can copolymerize a wide variety of monomers, including methyl methacrylate (MMA), styrene and acrylic acid. Through copolymerization, the resulting polymers can be tailored to have specific properties.Polymers can be modified to have specific properties through copolymerization. For example, by copolymerizing HPMA with other monomers, the glass transition temperature, mechanical strength, and solubility of the polymer can be adjusted.By copolymerizing HPMA and other monomers, for example, the glass-transition temperature, mechanical strength, or solubility of polymers can be adjusted.

The hydroxyl group in HPMA imparts unique properties as well.HPMA also has unique properties due to the hydroxyl group. It can participate in hydrogen bonding, which affects the interaction of the molecule with other substances.It can participate in hydrogen bonds, which affects how the molecule interacts with other substances. This property can be beneficial in applications where adhesion is required.This property is useful in applications that require adhesion. For instance, in coatings, the hydrogen - bonding ability of HPMA can enhance the adhesion of the coating to the substrate, improving the overall durability and performance of the coating.HPMA's hydrogen-bonding ability can improve adhesion in coatings. This will increase the durability and performance of coatings.

In addition, HPMA - based polymers often exhibit good biocompatibility.HPMA-based polymers are often biocompatible. This makes them suitable for applications in the biomedical field.This makes them ideal for biomedical applications. For example, they can be used in the synthesis of hydrogels for drug delivery systems.They can be used, for example, in the synthesis and delivery of drugs using hydrogels. The biocompatibility ensures that the materials do not cause significant adverse reactions when in contact with biological tissues.The biocompatibility of the materials ensures that they do not cause adverse reactions in biological tissues.

HPMA also has good solubility in many organic solvents, such as acetone, methyl ethyl ketone, and toluene.HPMA is also soluble in many organic solvents such as acetone and methyl ethylketone. This solubility property is useful in solution - based polymerization processes and in formulating products where a homogeneous solution is required.This property of solubility is useful for solution-based polymerization and formulating products that require a homogeneous liquid. It also allows for easy removal of the solvent during the production process if needed.This allows for the removal of the solvent easily during the production process, if necessary.

Overall, the combination of its reactivity, hydrogen - bonding ability, biocompatibility, and solubility makes Hydroxypropyl Methacrylate a versatile monomer with a wide range of applications in industries including coatings, adhesives, and biomedicine.Hydroxypropyl methacrylate is a versatile monomer that has many applications, including in coatings, adhesives and biomedicine.

How is Hydroxypropyl Methacrylate (HPMA) synthesized?

Hydroxypropyl Methacrylate (HPMA) is synthesized through a specific chemical process.A specific chemical process is used to synthesize Hydroxypropyl Méthacrylate (HPMA).
The synthesis of HPMA often starts with methacrylic acid and propylene oxide as the main raw materials.Methacrylic acid, and propylene dioxide are the two main raw materials used in the synthesis of HPMA. This reaction is typically carried out in the presence of a catalyst.This reaction is usually carried out in presence of a catalyser. The catalyst plays a crucial role in facilitating the reaction and promoting the formation of the desired product.The catalyst is crucial in facilitating the reactions and promoting the formation desired product.

One common method involves a reaction between methacrylic acid and propylene oxide under carefully controlled conditions.A common method involves a reaction of methacrylic and propylene oxide in carefully controlled conditions. The reaction temperature is an important factor.The temperature of the reaction is important. Usually, it is maintained within a certain range to ensure the efficiency and selectivity of the reaction.It is usually maintained within a range to ensure efficiency and selectivity. If the temperature is too low, the reaction rate may be slow, while if it is too high, side reactions may occur, reducing the yield of HPMA.If the temperature is low, the reaction may be slow. If it is high, side reactions can occur and reduce the yield of HPMA.

The molar ratio of methacrylic acid to propylene oxide also significantly affects the synthesis.The molar proportion of methacrylic to propylene oxide has a significant impact on the synthesis. An appropriate ratio needs to be determined to optimize the production of HPMA.To optimize HPMA production, it is important to determine the right ratio. In addition, the reaction time is another parameter that requires careful adjustment.The reaction time is also a parameter that needs to be adjusted carefully. Sufficient reaction time is necessary to ensure that the reactants are converted into the product to a satisfactory extent.It is important to have a sufficient reaction time to ensure that the reactants can be converted into the final product.

After the reaction is completed, the resulting mixture usually contains the synthesized HPMA along with unreacted raw materials, by - products, and the catalyst.The mixture that results from the reaction usually contains HPMA, unreacted raw material, by-products, and the catalyst. Purification steps are then required to obtain pure HPMA.To obtain pure HPMA, further purification steps are required. This may involve processes such as distillation.This could include processes such as distillation. Distillation can separate HPMA from other components based on their different boiling points.Distillation can separate HPMA based on the boiling points of different components. Through precise control of the distillation conditions, high - purity HPMA can be obtained, which meets the requirements for various applications in industries like coatings, adhesives, and polymers.HPMA of high purity can be obtained by controlling the distillation conditions precisely. This meets the requirements in industries such as coatings, polymers, and adhesives. These industries rely on the unique properties of HPMA, such as its ability to form cross - linked structures and improve the performance of the final products.These industries rely heavily on HPMA's unique properties, including its ability to form cross-linked structures and improve the performance in the final products.

What are the safety precautions when handling Hydroxypropyl Methacrylate (HPMA)?

Hydroxypropyl Methacrylate (HPMA) is a chemical with certain reactivity and potential hazards.The chemical Hydroxypropyl methacrylate (HPMA), which is a reactive substance, can pose certain hazards. Here are the safety precautions when handling it.Here are some safety precautions to take when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain degree of protection against HPMA.Nitrile gloves can offer some protection against HPMA. This helps prevent skin contact which can lead to irritation, allergic reactions, or potential absorption through the skin.This can help prevent skin contact that could lead to irritations, allergic reactions or absorption through the body. Also, wear safety goggles or a face shield.Wear safety goggles and a face shield. HPMA can splash during handling, and getting it in the eyes can cause severe eye irritation, damage, or even vision - threatening consequences.HPMA can splash when handled, and getting it into the eyes can cause severe irritation, damage or even vision-threatening consequences. A lab coat or other protective clothing should be worn to cover the body and prevent the chemical from coming into contact with the skin and clothing.Wearing a lab coat or other protective clothing will cover the entire body and prevent the chemical coming into contact with skin and clothing.

Second, when it comes to handling in the workplace.When it comes to handling at work, second is the most important thing. Ensure good ventilation.Assure good ventilation. HPMA may release vapors, and a well - ventilated area can dilute these vapors, reducing the risk of inhalation.A well-ventilated area can dilute the vapors released by HPMA, reducing inhalation risk. If possible, conduct operations in a fume hood.If possible, perform operations in a fume-hood. This is especially important when performing tasks such as pouring, mixing, or heating HPMA.This is particularly important when performing tasks like pouring, heating, or mixing HPMA. Avoid generating dust or aerosols of HPMA.Avoid creating dust or aerosols from HPMA. For example, when weighing the solid form (if applicable), do it carefully to prevent the powder from becoming airborne, as inhalation of HPMA particles can irritate the respiratory tract.When weighing the solid form, be careful to avoid the powder becoming airborne. Inhalation of HPMA can cause irritation of the respiratory tract.

Third, in terms of storage.Third, when it comes to storage. Store HPMA in a cool, dry place away from sources of ignition.Store HPMA in an area that is cool and dry, away from ignition sources. HPMA is flammable, so keeping it away from heat, open flames, or electrical equipment that could potentially spark is crucial.HPMA is flammable so it is important to keep it away from heat sources, open flames or electrical equipment which could spark. Keep it in a tightly - sealed container to prevent evaporation and leakage.Keep it in a tightly-sealed container to prevent evaporation. Also, store it separately from oxidizing agents and strong acids or bases, as it may react with these substances, leading to dangerous situations such as fires, explosions, or the release of harmful gases.Store it away from strong acids and oxidizing agents. It may react with them, causing dangerous situations like fires, explosions or the release harmful gases.

Finally, in case of an accident.In the event of an accident, you should also be prepared. If HPMA comes into contact with the skin, immediately wash the affected area with plenty of water for at least 15 minutes and remove contaminated clothing.If HPMA gets on your skin, wash it immediately with plenty of water and remove any contaminated clothing. If it gets in the eyes, flush the eyes with copious amounts of water for at least 15 minutes and seek immediate medical attention.If it gets into the eyes, flush them with plenty of water for 15 minutes at least and seek immediate medical care. In case of inhalation, move the affected person to fresh air immediately.In the event of inhalation, it is important to move the person immediately to fresh air. If the person has difficulty breathing, provide artificial respiration if trained to do so and call for emergency medical help.If the person is having difficulty breathing, if you are trained to do this, you can provide artificial respiration and call emergency medical assistance. If HPMA is ingested, do not induce vomiting unless specifically instructed by a medical professional, and seek immediate medical assistance.If HPMA has been ingested, you should not induce vomiting without the specific instructions of a medical professional. Seek immediate medical attention.

What are the advantages of using Hydroxypropyl Methacrylate (HPMA) compared to other materials?

Hydroxypropyl Methacrylate (HPMA) offers several distinct advantages when compared to other materials.Comparing HPMA to other materials, it offers a number of distinct advantages.
One of the key benefits is its excellent solubility properties.One of its key benefits is the excellent solubility. HPMA can dissolve in a wide range of solvents, both polar and non - polar.HPMA dissolves in a variety of solvents both polar and non-polar. This solubility allows for greater flexibility in formulating various products such as coatings, adhesives, and inks.This solubility gives manufacturers more flexibility when formulating products like coatings, inks, and adhesives. For example, in the coating industry, the ability to dissolve HPMA in different solvents enables manufacturers to create coatings that can be applied to a diverse set of substrates, from plastics to metals.In the coating industry, for example, the ability to dissolve HPMA with different solvents allows manufacturers to create coatings which can be applied on a variety of substrates from plastics to metallics. In contrast, some other materials may have limited solubility, restricting their use in certain formulations.Some materials, however, may be limited in their solubility and therefore, restricted to certain formulations.

HPMA also exhibits good reactivity.HPMA is also a good polymerizer. It contains reactive double - bond groups, which can participate in polymerization reactions easily.It contains reactive double-bond groups that can easily participate in polymerization. This characteristic makes it a valuable monomer for synthesizing polymers with specific properties.This property makes it an ideal monomer to synthesize polymers with specific characteristics. For instance, by copolymerizing HPMA with other monomers, it is possible to tailor - make polymers with enhanced mechanical strength, improved chemical resistance, or specific surface - active properties.By copolymerizing HPMA and other monomers, for example, it is possible tailor-make polymers with enhanced mechanical properties, improved chemical resistance or specific surface-active properties. Many alternative materials may lack such high reactivity, making it difficult to modify their properties through polymerization reactions.Many alternative materials lack this high reactivity and it is difficult to modify the properties of these materials through polymerization reactions.

In terms of biocompatibility, HPMA stands out.HPMA is a leader in biocompatibility. It has been widely studied for its potential use in biomedical applications.Its potential biomedical uses have been extensively studied. Polymers based on HPMA have shown relatively low toxicity and good biocompatibility, which is crucial for applications like drug delivery systems and tissue engineering scaffolds.HPMA-based polymers have shown low toxicity, and are biocompatible. This is important for applications such as drug delivery systems and scaffolds for tissue engineering. In comparison, many traditional materials used in these fields may cause immune responses or have harmful effects on living cells.Many traditional materials used in this field can cause immune reactions or have harmful effects to living cells.

Another advantage is its film - forming ability.Its ability to form films is another advantage. HPMA - based polymers can form smooth, continuous, and adherent films.HPMA-based polymers are able to form smooth, continuous and adherent film. In the packaging industry, this property is highly desirable as it can be used to create protective films that not only provide a barrier against moisture and oxygen but also adhere well to the packaging materials.This property is highly desired in the packaging industry as it allows for the creation of protective films that are not only a barrier to moisture and oxygen, but also adhere well with the packaging materials. Some other materials might form brittle or non - adherent films, which are not suitable for packaging applications.Other materials may form brittle, non-adhesive films that are not suitable for packaging.

Furthermore, HPMA offers good thermal stability.HPMA also offers good thermal stability. Polymers made from HPMA can withstand relatively high temperatures without significant degradation.Polymers made of HPMA are able to withstand high temperatures without any significant degradation. This property is beneficial in applications where the material is exposed to heat, such as in some industrial processes or high - temperature environments.This property is useful in applications where materials are exposed to heat such as industrial processes or high-temperature environments. Materials with poor thermal stability would limit their use in such scenarios.Materials with poor thermal stabilities would be limited in their use.