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Product Name | Methyl methacrylate |
Cas Number | 80-62-6 |
Formula | C5H8O2 |
Molar Mass | 100.12 g/mol |
Boiling Point | 100.5 °C |
Melting Point | -48 °C |
Density | 0.94 g/cm³ |
Refractive Index | 1.412 |
Flash Point | 10 °C |
Vapor Pressure | 29 mmHg at 20°C |
Solubility In Water | 1.5 g/L |
Appearance | Colorless liquid |
Odor | Acrid, fruity odor |
Viscosity | 0.6 mPa·s at 20°C |
Autoignition Temperature | 421 °C |
Explosive Limits | 2.1% - 12.5% |
What are the main uses of methyl methacrylate (MMA)?
Methyl methacrylate (MMA) is a versatile chemical with several important applications.Methylmethacrylate (MMA), a versatile chemical, has many important applications.
One of the primary uses of MMA is in the production of polymethyl methacrylate (PMMA).MMA is used to produce polymethyl methacrylate, or PMMA. PMMA is a widely - used thermoplastic known for its excellent optical clarity, high impact resistance, and weather - resistance.PMMA is an extremely popular thermoplastic that is known for its high impact resistance and weather resistance. It is often referred to as acrylic glass.Acrylic glass is often used to describe it. In the construction industry, PMMA is used for making skylights, windows, and partitions.PMMA is commonly used in the construction industry to make skylights, partitions, and windows. Its transparency and durability make it an ideal choice for applications where natural light needs to be maximized while maintaining structural integrity.Its durability and transparency make it a great choice for applications that require maximum natural light while maintaining structural integrity. For example, in large - scale commercial buildings, PMMA can be used to create stunning atriums that allow sunlight to penetrate multiple floors.PMMA can also be used in large-scale commercial buildings to create stunning atriums which allow sunlight to penetrate several floors.
In the automotive industry, PMMA made from MMA is used for manufacturing automotive lighting components such as headlight lenses.PMMA, made from MMA, is used in the automotive industry to manufacture automotive lighting components like headlight lenses. The material's ability to withstand high temperatures and its good optical properties ensure efficient light transmission, enhancing driving safety.The material's ability of withstanding high temperatures and its excellent optical properties ensure efficient lighting, which enhances driving safety. Additionally, MMA - based coatings are used on cars.MMA-based coatings can also be found on cars. These coatings provide a high - gloss finish, are scratch - resistant, and help protect the vehicle's body from environmental damage.These coatings are scratch-resistant, provide a high-gloss finish, and protect the vehicle from environmental damage.
The signage industry also relies heavily on MMA.Signage industry also heavily relies on MMA. Acrylic sheets made from MMA are used to create illuminated signs, storefront displays, and billboards.Acrylic sheets made of MMA are used for illuminated signs, billboards, and storefront displays. Their bright and vivid appearance, along with the ease of fabrication into various shapes and sizes, makes them a popular choice for advertisers.Advertisers love their bright and vivid appearance as well as the ease of fabrication in various shapes and sizes. For instance, neon - like acrylic signs can be made by shaping PMMA sheets and back - lighting them.PMMA sheets can be shaped and back-lit to create neon-like acrylic signs.
MMA is also used in the dental field.MMA is also used for dental prosthetics. Dental prosthetics, such as dentures and dental crowns, are often made using MMA - based polymers.Dental prosthetics such as dentures or dental crowns are often made with MMA-based polymers. These polymers can be customized to match the color and shape of natural teeth, providing a functional and aesthetically pleasing solution for patients.These polymers are customizable to match the shape and color of natural teeth. This provides a functional and aesthetically pleasing option for patients. The biocompatibility of MMA - derived materials is crucial in ensuring they do not cause adverse reactions in the oral cavity.Biocompatibility is key to ensuring that MMA-derived materials do not cause adverse reactions within the oral cavity.
In the production of adhesives, MMA is an important ingredient.MMA is a key ingredient in the production of adhesives. MMA - based adhesives have high bonding strength and are used in various applications, from bonding plastics to metal - to - plastic bonding.MMA-based adhesives are high-bonding and can be used for a variety of applications, including bonding plastics with metal -to-plastic bonding. They are especially useful in the assembly of electronic devices, where strong and reliable bonds are required between different components.They are particularly useful in the assembly and construction of electronic devices where strong and reliable bonding is required between different components.
Finally, in the textile industry, MMA can be used in the production of specialty fibers.MMA can also be used to produce specialty fibers in the textile industry. These fibers can have unique properties such as improved wrinkle - resistance and softness, enhancing the quality of fabrics.These fibers have unique properties, such as improved wrinkle-resistance and softness. They can enhance the quality of fabrics.
What are the safety precautions when handling MMA?
Methyl methacrylate (MMA) is a chemical compound with certain risks, and the following safety precautions should be taken when handling it.When handling MMA, you should take the following safety precautions.
Firstly, in terms of personal protective equipment.First, personal protective equipment. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can resist the corrosive effects of MMA to a certain extent.Nitrile gloves can be a good option as they are resistant to the corrosive effect of MMA. Ensure that the gloves fit well to avoid any gaps where the chemical could seep in.Make sure the gloves are well fitted to avoid any gaps that could allow the chemical to seep through. Also, put on safety goggles to protect the eyes.Wear safety goggles as well to protect your eyes. MMA can cause severe eye irritation and potential damage, and the goggles should provide a full - face seal to prevent any splashes from reaching the eyes.The MMA can cause severe irritation to the eyes and even damage. Goggles that seal the face should be used. A lab coat or other protective clothing made of non - porous materials should be worn to safeguard the skin on the body.To protect the skin, a lab coat or other protective clothing should be worn. This clothing should be long - sleeved and cover as much of the body as possible.Clothing should be long-sleeved, and cover the entire body.
Secondly, consider the handling environment.Second, consider the handling conditions. Work in a well - ventilated area, preferably in a fume hood if available.Work in an area that is well-ventilated, preferably under a fume hood. MMA has a pungent odor and is volatile.MMA is volatile and has a pungent odor. Adequate ventilation helps to remove the vapors from the work area, reducing the risk of inhalation.Adequate ventilation will help to remove the vapors and reduce the risk of inhalation. If working in an enclosed space without proper ventilation, the concentration of MMA vapors can quickly build up, which may cause respiratory problems such as coughing, shortness of breath, and in severe cases, more serious lung damage.In an enclosed space, MMA vapors may build up quickly, causing respiratory problems like coughing, shortness-of-breath, and even more serious lung damage.
When it comes to storage, keep MMA away from heat sources and open flames.Keep MMA away form heat sources and open fires when storing. It is flammable, and a small spark or high temperature can cause it to ignite.It is flammable and can ignite with a small spark. Store it in a cool, dry place in a tightly - sealed container.Store it in a cool and dry place, in a tightly-sealed container. The container should be made of a material that is compatible with MMA, such as certain types of plastics or glass, to prevent leakage and chemical reactions.To prevent chemical reactions and leakage, the container should be made from a material compatible with MMA.
In case of accidental contact, if it gets on the skin, immediately wash the affected area with plenty of water for at least 15 minutes.If it accidentally gets on your skin, wash the area thoroughly with water for at least fifteen minutes. Then, remove any contaminated clothing and seek medical attention if there are signs of irritation or damage.Remove any contaminated clothing, and seek medical attention for any signs of irritation or damage. If it splashes into the eyes, flush the eyes with copious amounts of water for at least 15 minutes while keeping the eyelids open, and then seek immediate medical help.If it splashes in the eyes, rinse the eyes for at least 15 minute while keeping the lids open. Then seek immediate medical attention. If inhaled, move to an area with fresh air at once.If you inhale it, immediately move to a place with fresh air. If breathing difficulties persist, call for emergency medical services.If breathing problems persist, contact emergency medical services.
Finally, be careful during transfer and use.Be careful when transferring and using. Use appropriate funnels and containers to prevent spills.To prevent spills, use appropriate funnels and containers. When pouring MMA, do it slowly and steadily to avoid splashing.Pour MMA slowly and steadily in order to avoid splashing. And always follow proper procedures and guidelines established in the workplace or laboratory for handling this chemical.Always follow the guidelines and procedures established at your workplace or laboratory when handling this chemical.
How is MMA produced?
Methyl methacrylate (MMA), an important monomer for producing polymethyl methacrylate (PMMA) and other polymers, is produced through several methods.MMA, an important monomer used to produce polymethyl methacrylate and other polymers is produced by several methods.
One of the most common production routes is the acetone - cyanohydrin (ACH) process.The acetone cyanohydrin process (ACH) is one of the most popular production routes. In this method, acetone reacts with hydrogen cyanide in the presence of a basic catalyst.In this method, hydrogen cyanide and acetone are combined in the presence a basic catalyser. This reaction forms acetone cyanohydrin.This reaction produces acetone-cyanohydrin. Subsequently, the acetone cyanohydrin reacts with concentrated sulfuric acid to form methacrylamide sulfate.The acetone cyanohydrin then reacts with concentrated sulfuric acids to form methacrylamide. This intermediate is then hydrolyzed to produce methacrylic acid, and finally, esterification with methanol occurs to yield MMA.This intermediate is hydrolyzed into methacrylic acids, and then esterification occurs with methanol to yield MMA. The ACH process has been widely used for a long time, but it has some drawbacks.The ACH method has been used for a very long time but has some disadvantages. Hydrogen cyanide is highly toxic, which requires strict safety measures during production.Hydrogen cyanide, which is highly toxic, requires strict safety measures to be taken during production. Also, the process generates a large amount of ammonium sulfate as a by - product, which needs proper disposal.The process also generates large quantities of ammoniumsulfate, which must be disposed of properly.
Another method is the isobutylene - based process.Another method is isobutylene-based. Isobutylene, which can be obtained from refinery streams or by dehydration of tert - butyl alcohol, is first oxidized to methacrolein using a catalyst such as molybdenum - bismuth - based oxides.Isobutylene can be obtained by dehydrating tert-butyl alcohol or from refinery streams. It is then oxidized into methacrolein with a catalyst like molybdenum-bismuth-based oxides. Methacrolein is then further oxidized to methacrylic acid in the presence of air or oxygen and a suitable catalyst.In the presence of oxygen or air, methacrolein is further oxidized into methacrylic acids. Finally, the methacrylic acid is esterified with methanol to produce MMA.MMA is produced by esterifying methacrylic with methanol. This process has advantages over the ACH process as it does not involve the use of highly toxic hydrogen cyanide.This process is superior to the ACH because it does not use highly toxic hydrogen cyanide. It also has relatively high atom efficiency, which is more environmentally friendly.It also has a relatively high atom efficacy, which is more environmental friendly.
The propylene - based process is also emerging.Propylene-based processes are also emerging. Propylene reacts with carbon monoxide and methanol in the presence of a rhodium - based catalyst to form 2 - methoxypropionaldehyde. This intermediate is then oxidized to methyl methacrylate.This intermediate is then converted to methyl methacrylate. This process is still in the development stage but shows potential due to the wide availability of propylene as a feedstock.This process is in the development phase but has potential due to the availability of propylene.
In summary, the production of MMA has evolved over time.The production of MMA evolved over time. The ACH process has been traditional but is being gradually replaced or complemented by more environmentally friendly methods such as the isobutylene - based process.The ACH method is a traditional one, but it is gradually being replaced or complemented with more environmentally friendly methods like the isobutylene-based process. The propylene - based process may play an important role in the future as the industry continues to seek more sustainable and efficient production routes.The propylene-based process could play a major role in the future, as the industry continues its search for more sustainable and efficient production routes.
What are the properties of MMA?
MMA stands for methyl methacrylate, which is an important monomer in the polymer industry.MMA is a monomer that is used in the polymer industry. Here are some of its key properties:Here are some of the key properties:
Physical properties:Physical Properties
- MMA is a colorless liquid at room temperature.MMA is colorless at room temperature. It has a relatively low viscosity, which allows it to flow easily.It is a liquid with a low viscosity that flows easily. This property is beneficial in processes such as casting and coating, as it can evenly spread over surfaces.This property is useful in processes like casting and coating as it can spread evenly over surfaces.
- It has a characteristic, pleasant odor.It has a pleasant, characteristic smell. However, it should be handled with care as it is volatile.It is volatile and should be handled with caution. It has a relatively low boiling point of around 100 - 101 degrees Celsius.It has a low boiling point, around 100-101 degrees Celsius. This volatility means that it can quickly evaporate into the air, which can be a concern in terms of safety and environmental impact.This volatility can cause it to quickly evaporate into the air. This can be a problem for safety and environmental impacts.
- MMA has a density of approximately 0.94 g/cm3.MMA has a mass density of 0.94 g/cm3. This density is less than that of water, which can influence its behavior in various applications, for example, in liquid - liquid separation processes or when considering its buoyancy in certain systems.This density is lower than water, which can affect its behavior in different applications. For example, when considering its buoyancy within certain systems or in liquid-liquid separation processes.
Chemical properties:Chemical properties
- MMA is highly reactive due to the presence of the double bond in its structure.MMA is highly reactive due to its double bond. This double bond enables it to participate in polymerization reactions.This double bond allows it to participate in polymerization. It readily undergoes addition polymerization to form poly(methyl methacrylate) (PMMA), a widely used plastic.It is easily polymerized by addition to form poly(methylmethacrylate), a widely-used plastic.
- It is soluble in many organic solvents such as acetone, toluene, and chloroform.It is soluble with many organic solvents, such as toluene and chloroform. This solubility property is useful in formulating solutions for applications like painting, where the MMA - based polymer needs to be dissolved to create a workable coating.This property of solubility is useful when formulating solutions for applications such as painting, where MMA-based polymers need to be dissolved in order to create a coating that can be used. However, it is insoluble in water, which makes it suitable for applications where water resistance is required.It is not soluble in water and is therefore suitable for applications that require water resistance.
- It can react with other chemicals containing reactive groups.It can react with other chemical compounds containing reactive groups. For instance, it can participate in cross - linking reactions with compounds having functional groups like amines or alcohols under appropriate conditions.It can, for example, participate in cross-linking reactions with compounds that have functional groups such as amines or alcohols under the right conditions. This ability to cross - link can enhance the mechanical and chemical resistance properties of the resulting polymers.This ability to cross-link can enhance the mechanical and chemcial resistance properties of the polymers.
Mechanical properties (when polymerized to PMMA):Mechanical properties (when polymerized into PMMA)
- PMMA, the polymer derived from MMA, has excellent optical clarity.PMMA is a polymer derived by MMA that has excellent optical clarity. It has a high light transmission rate, similar to glass, making it a popular choice for applications such as acrylic sheets used in windows, displays, and optical lenses.It is a good choice for windows, displays and optical lenses because it has a similar high light transmission rate to glass.
- It has good mechanical strength.- It is a good mechanical material. It is relatively rigid yet has some flexibility compared to brittle materials like glass.It is flexible and rigid, but not as brittle as glass. It can withstand a certain amount of stress and impact without breaking easily, although it is not as tough as some engineering plastics.It can withstand some stress and impact, but it is not as strong as some engineering materials. The mechanical properties of PMMA can be further enhanced by techniques such as copolymerization or adding fillers.PMMA's mechanical properties can be enhanced further by techniques like copolymerization and adding fillers.
What are the potential health risks associated with exposure to MMA?
MMA, or methyl methacrylate, is a chemical used in various industries.MMA or methyl methacrylate is a chemical that is used in many industries. Exposure to MMA can pose several potential health risks.Exposure to MMA may pose several health risks.
One of the primary concerns is respiratory issues.Respiratory issues are a major concern. Inhalation of MMA vapors can irritate the nose, throat, and lungs.Inhaling MMA vapors may irritate the lungs, nose, and throat. It may cause coughing, wheezing, shortness of breath, and in more severe cases, can lead to bronchitis or other respiratory tract inflammations.It can cause coughing, wheezing and shortness of breathe. In more severe cases it can lead to bronchitis. Workers in factories where MMA is used, like those in the plastics manufacturing industry, are particularly at risk.Workers in plastics factories, or other factories that use MMA, are at a higher risk. Prolonged or high - level exposure through inhalation can also affect lung function over time, potentially reducing the ability of the lungs to efficiently exchange oxygen.Inhaling MMA at high levels or for long periods can affect lung function and reduce the lungs' ability to exchange oxygen.
Skin contact with MMA is another significant risk.Skin contact with MMA poses another risk. It can cause skin irritation, redness, itching, and in some cases, chemical burns.It can cause irritation, redness, itchiness, and in some instances, chemical burns. This is especially true if the skin is in contact with concentrated forms of MMA for an extended period.This is particularly true if the skin has been in contact with concentrated MMA forms for an extended time. People handling MMA - based products, such as those in the dental field where MMA is used in some dental materials, need to be cautious.People who handle MMA-based products, like those in the dental industry, where MMA is found in some dental materials, should be cautious. Repeated skin exposure can lead to allergic contact dermatitis, where the immune system reacts to the chemical, causing more severe and long - lasting skin problems.Repeated exposure to MMA can cause allergic contact dermatitis. The immune system will react to the chemical and cause more severe skin problems.
Eye exposure to MMA is extremely dangerous.Eye exposure to MMA can be extremely dangerous. Even a small amount of MMA in the eyes can cause intense pain, redness, and damage to the cornea.Even a small amount can cause severe pain, redness and corneal damage. If not promptly flushed out with large amounts of water, it can lead to permanent eye damage, including vision impairment or even blindness.If the MMA is not immediately flushed with large quantities of water, it may cause permanent eye damage including vision impairment or blindness. This risk is relevant in industrial settings where splashes may occur during the handling of MMA - containing substances.This risk is particularly relevant in industrial settings, where splashes can occur when handling MMA-containing substances.
There are also potential systemic health effects associated with MMA exposure.Exposure to MMA can also have systemic health effects. Some studies suggest that long - term exposure to MMA may have an impact on the nervous system.MMA exposure may affect the nervous system, according to some studies. It could potentially cause symptoms like headaches, dizziness, and fatigue.It could cause symptoms such as headaches, fatigue, and dizziness. There are also concerns about its possible effects on the reproductive system, although more research is needed to fully understand these risks.It is also possible that it could have adverse effects on the reproductive system. However, more research is required to fully understand these risks. In animal studies, exposure to high levels of MMA has shown some adverse effects on reproduction, such as reduced fertility.In animal studies, high levels of MMA exposure has caused adverse effects on reproduction in animals, including reduced fertility. Overall, proper safety measures and handling procedures are crucial to minimize the health risks associated with MMA exposure.To minimize the health risks associated MMA exposure, it is important to use proper safety procedures and handling procedures.