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Product Name | 1,4-Butanediol diacrylate |
Cas Number | 1070-70-8 |
Formula | C10H14O4 |
Molar Mass | 198.22 g/mol |
Boiling Point | 285°C |
Density | 1.071 g/cm³ |
Refractive Index | 1.454 |
Appearance | Colorless liquid |
Flash Point | 110°C |
Viscosity | 5.79 mPa·s at 25°C |
Vapor Pressure | 0.000321 mmHg at 25°C |
Solubility In Water | Slightly soluble |
Melting Point | -45°C |
Surface Tension | 30.43 mN/m |
What are the main applications of 1,4-Butanediol diacrylate?
1,4 - Butanediol diacrylate (BDDA) has several main applications:There are several applications for 1,4-Butanediol Diacrylate (BDDA).
In the field of coatings, BDDA is widely used.BDDA is widely utilized in the field of coatings. It can be incorporated into UV - curable coatings.It can be used in UV-curable coatings. UV - curable coatings have the advantage of rapid curing under ultraviolet light irradiation.UV-curable coatings are cured rapidly under ultraviolet light. BDDA, with its two acrylate functional groups, can participate in the cross - linking reaction during the curing process.BDDA can be used to participate in the cross-linking reaction during curing due to its two acrylate functional group. This helps to form a hard, durable, and abrasion - resistant coating film.This helps form a hard and durable coating film that is resistant to abrasion. For example, in the coating of wood furniture, BDDA - containing UV - curable coatings can provide a smooth and protective surface layer, enhancing the appearance and lifespan of the furniture.BDDA containing UV cured coatings, for example, can provide a smooth, protective surface layer to wood furniture. This will enhance the appearance and longevity of the furniture. In metal coatings, it can improve the adhesion of the coating to the metal substrate and enhance the corrosion resistance of the metal.In metal coatings it can improve adhesion and corrosion resistance.
BDDA is also important in the area of adhesives.BDDA plays a role in adhesives. It can be used as a reactive diluent in adhesive formulations.It can be used in adhesive formulations as a reactive diluteent. Reactive diluents not only reduce the viscosity of the adhesive but also participate in the polymerization reaction.Reactive diluents reduce the viscosity and also participate in polymerization reactions. In epoxy - based adhesives, adding BDDA can improve the cross - linking density of the adhesive network after curing.Adding BDDA to epoxy-based adhesives can improve the cross-linking density of the network after curing. This results in adhesives with higher shear strength and better heat resistance.This leads to adhesives that have a higher shear strength as well as better heat resistance. These adhesives are suitable for bonding various materials such as plastics, metals, and composites.These adhesives can be used to bond various materials, including plastics, metals and composites. For instance, in the assembly of electronic devices, adhesives with BDDA can firmly bond different components while withstanding the heat generated during device operation.Adhesives with BDDA, for example, can be used to firmly bond components in electronic devices while withstanding heat generated by the device.
In the production of polymers and composites, BDDA serves as a cross - linking agent.BDDA is used as a cross-linking agent in the production of composites and polymers. When used in the synthesis of polymers like polyacrylates, it can introduce cross - links between polymer chains.It can be used to introduce cross-links between polymer chains when it is used in the synthesis polymers such as polyacrylates. This cross - linking process can significantly improve the mechanical properties of the polymer.This cross-linking process can improve the mechanical properties significantly. For example, it can increase the tensile strength, modulus, and hardness of the polymer.It can, for example, increase the tensile, modulus and hardness. In composite materials, BDDA can enhance the interfacial adhesion between the matrix and the filler.BDDA can improve the interfacial adhesiveness between the matrix and filler in composite materials. In glass - fiber - reinforced composites, for example, it helps to better transfer stress between the glass fibers and the polymer matrix, thereby improving the overall mechanical performance of the composite.In composites with glass fibers, it can help to improve the mechanical performance by transferring stress better between the glass fibres and the polymer matrix.
Finally, in the field of 3D printing, BDDA can be part of the photopolymer resin formulation.BDDA is also a component of photopolymer resins, which can be used in 3D printing. As 3D printing often uses photopolymerization techniques, BDDA's ability to quickly polymerize under light makes it suitable for forming three - dimensional structures.BDDA is a good choice for 3D printing, as it can quickly polymerize when exposed to light. The cross - linking ability of BDDA ensures the stability and mechanical integrity of the printed objects, enabling the production of high - precision and durable 3D - printed parts for various applications, from prototyping to small - batch manufacturing.The cross-linking ability of BDDA assures the stability and mechanical strength of the printed objects. This allows for the production of high-precision and durable 3D-printed parts, from prototypes to small-batch manufacturing.
Is 1,4-Butanediol diacrylate safe for use?
1,4 - Butanediol diacrylate is a chemical compound used in various industrial applications such as in the production of coatings, adhesives, and polymers.1,4-Butanediol Diacrylate is used in many industrial applications, such as the production of polymers, adhesives and coatings. When considering its safety for use, several aspects need to be taken into account.In order to determine its safety, it is important to consider several factors.
Toxicity is an important factor.Toxicity is a key factor. In terms of acute toxicity, it can be harmful if ingested, inhaled, or comes into contact with the skin.Acute toxicity can be harmful when ingested, absorbed through the skin, or inhaled. Exposure to high concentrations of the vapor may cause irritation to the respiratory tract, leading to symptoms like coughing, shortness of breath, and potentially more serious lung problems over time.Exposure to high concentrations can cause irritation of the respiratory tract. This may lead to symptoms such as coughing, shortness-of-breath, and possibly more serious lung problems with time. Skin contact can result in irritation, redness, and in some cases, allergic reactions.Contact with the skin can cause irritation, redness and, in some cases allergic reactions. This is because it can penetrate the skin and may trigger an immune response in sensitive individuals.It can penetrate the skin, triggering an immune reaction in sensitive individuals.
Regarding long - term effects, there are concerns about its potential carcinogenicity.Concerns are raised about its possible carcinogenicity in the long-term. While the evidence is not entirely conclusive, some studies have raised suspicions that repeated exposure could potentially pose a cancer risk.Although the evidence isn't conclusive, certain studies have raised concerns that repeated exposure to the substance could pose a cancer threat. This makes it necessary to handle the substance with caution in occupational settings, where workers may be exposed over extended periods.It is therefore important to use caution when handling the substance in workplace settings where workers could be exposed for extended periods.
In addition, 1,4 - Butanediol diacrylate is also a reactive compound.It is also a highly reactive compound. It can polymerize under certain conditions, such as in the presence of heat, light, or initiators.It can polymerize in certain conditions such as the presence of heat or light. This reactivity can pose risks during storage and transportation.This reactivity poses risks during storage and transport. If not properly stored, it could undergo unwanted polymerization, which may lead to container rupture or other safety hazards.If it is not stored properly, it may undergo an unwanted polymerization which could lead to container ruptures or other safety hazards.
Overall, 1,4 - Butanediol diacrylate is not considered completely safe for use without proper precautions.Overall, 1,4-Butanediol Diacrylate is not completely safe to use without taking proper precautions. In industrial settings, strict safety measures should be implemented.In industrial settings strict safety measures must be implemented. Workers should be provided with appropriate personal protective equipment, including respiratory protection, gloves, and safety goggles.Workers should have the appropriate personal protective gear, such as respiratory protection, gloves and safety goggles. Adequate ventilation systems must be in place to reduce vapor exposure.To reduce vapor exposure, ventilation systems that are adequate must be installed. For consumers, products containing this chemical should be used in well - ventilated areas, and contact with the skin and eyes should be avoided.Products containing this chemical must be used in well-ventilated areas and should not be used near the skin or eyes. When used in accordance with safety guidelines and with proper safety measures in place, the risks associated with 1,4 - Butanediol diacrylate can be minimized, but it still requires careful handling due to its potentially harmful properties.If used according to safety guidelines, and with the proper safety measures, the risks associated 1,4-Butanediol Diacrylate can be reduced. However, it still requires careful handling because of its potentially harmful properties.
What are the physical and chemical properties of 1,4-Butanediol diacrylate?
1,4 - Butanediol diacrylate is an important monomer in the field of polymers.Butanediol Diacrylate, also known as 1,4-Butanediol Diacrylate, is an important monomer for polymers.
Physical properties
Appearance: It is usually a colorless to slightly yellow clear liquid.Appearance: It's usually a clear, colorless liquid. This clear - liquid state makes it easy to handle in various industrial processes, such as in coating and adhesive applications.This clear liquid state makes it easier to handle in different industrial processes, like coating and adhesive applications. It allows for good visibility during operations like mixing and application, facilitating quality control.It is easy to see during mixing and application operations, which facilitates quality control.
Odor: It has a characteristic acryl - like odor.Odor: It emits a characteristic acryl-like odor. The presence of this odor can be used as an early indicator of potential exposure during handling.This odor can be used to detect exposure early during handling. However, due to its pungent nature, proper ventilation is required when working with this substance.Due to its pungent smell, it is important to ensure that you have adequate ventilation when working with this substance.
Boiling point: The boiling point of 1,4 - butanediol diacrylate is relatively high.Boiling Point: The boiling point for 1,4-butanediol is relatively high. This property is beneficial in applications where heat stability is required.This property is useful in applications that require heat stability. For example, during the curing process of coatings or adhesives under elevated temperatures, the monomer remains in a liquid state long enough to react properly without evaporating too quickly.For example, when curing coatings or adhesions at elevated temperatures, monomer remains liquid long enough to react correctly without evaporating.
Viscosity: It has a moderate viscosity.It has a medium viscosity. This is crucial as it affects its flowability.This is important as it impacts its flowability. A moderate viscosity enables it to spread evenly over surfaces when used in coating applications.When used as a coating, a moderate viscosity allows it to spread evenly on surfaces. It also allows for proper mixing with other components in formulations, such as fillers or catalysts, ensuring a homogeneous mixture.It allows for the proper mixing of other components, such as catalysts or fillers, in formulations.
Chemical properties
Reactivity: It is highly reactive due to the presence of two acrylate double bonds.Reactivity: Due to the presence two double acrylate bonds, it is highly reactive. These double bonds can participate in a variety of polymerization reactions, such as free - radical polymerization.These double bonds are capable of participating in a wide range of polymerization reactions such as free radical polymerization. This reactivity makes it a key building block for the synthesis of polymers with different properties.This reactivity makes the diacrylate a key building-block for the synthesis and modification of polymers. For instance, in the production of cross - linked polymers, the double bonds of 1,4 - butanediol diacrylate can react with each other or with other monomers containing reactive groups, forming a three - dimensional network structure.In the production of cross-linked polymers, for example, the double bonds in 1,4-butanediol can react with eachother or with other monomers that contain reactive groups to form a three-dimensional network structure.
Polymerization behavior: When initiated by appropriate initiators, like peroxides or photoinitiators, 1,4 - butanediol diacrylate undergoes rapid polymerization.Polymerization behaviour: 1,4-butanediol is rapidly polymerized when initiated by appropriate initiators such as peroxides and photoinitiators. In the case of photo - initiated polymerization, it can be cured quickly under ultraviolet light, which is very useful in applications such as rapid prototyping in 3D printing or in the production of UV - curable coatings.Photo - initiated polymerization can be cured under ultraviolet light quickly, which is useful for applications such as rapid prototypes in 3D printing and the production of UV-curable coatings. The cross - linking ability during polymerization leads to the formation of polymers with enhanced mechanical properties, such as increased hardness, abrasion resistance, and chemical resistance.The ability to cross-link during polymerization results in polymers with improved mechanical properties such as increased hardness and abrasion resistance.
Stability: In the absence of initiators or under proper storage conditions, 1,4 - butanediol diacrylate is relatively stable.1,4-Butanediol Diacrylate is relatively stable in the absence of initiators and under appropriate storage conditions. However, it should be stored away from heat, light, and oxidizing agents to prevent premature polymerization.To prevent premature polymerization, the product should be stored away heat, light and oxidizing agents. Exposure to these factors can trigger the activation of the double bonds and start the polymerization process, rendering the monomer unusable.These factors can activate the double bonds, causing the polymerization to begin.
How is 1,4-Butanediol diacrylate synthesized?
1,4 - Butanediol diacrylate is synthesized through an esterification reaction.1,4 - Butanediol Diacrylate is synthesized by an esterification process. Here is a general synthesis process:Here is a general process for synthesis:
1. Reactants and catalysts preparationPreparation of reactants and catalysts
The main reactants are 1,4 - butanediol and acrylic acid.The main reactants in this reaction are 1,4-butanediol, and acrylic acid. To promote the reaction, a catalyst is required.A catalyst is needed to promote the reaction. Commonly used catalysts for this esterification reaction include sulfuric acid, p - toluenesulfonic acid, etc.Catalysts are commonly used for esterification reactions, such as sulfuric acid and p-toluenesulfonic acids. These catalysts can enhance the reaction rate by protonating the carboxylic acid group of acrylic acid, making it more reactive towards the hydroxyl groups of 1,4 - butanediol.These catalysts can increase the reaction rate by protonating carboxylic acid groups in acrylic acid.
2. Reaction setupReaction setup
1,4 - butanediol and acrylic acid are placed in a reaction flask in a certain molar ratio.In a reaction flask, 1,4-butanediol is combined with acrylic acid in a specific molar proportion. Usually, an excess of acrylic acid is used to drive the reaction forward according to Le Chatelier's principle.Le Chatelier's theory dictates that an excess of acid is added to the reaction to speed it up. The catalyst is added in an appropriate amount, typically a few percent based on the mass of the reactants.The catalyst is added at a suitable amount, usually a few percent of the mass of the reactants. The reaction flask is equipped with a reflux condenser to prevent the loss of volatile reactants and products during the reaction, and a stirring device to ensure good mixing of the reactants.The reaction flask has a reflux condenser that prevents the loss of volatile products and reactants during the reaction. It also has a stirring device for a good mix of the reactants.
3. Reaction processReaction process
The reaction mixture is heated to a suitable temperature.The reaction mixture is then heated to the desired temperature. The reaction temperature is typically in the range of 80 - 120 degC.The reaction temperature ranges between 80 and 120 degC. At this temperature, the esterification reaction between the hydroxyl groups of 1,4 - butanediol and the carboxylic acid groups of acrylic acid occurs.This temperature is the ideal temperature for the esterification of the hydroxyl groups in 1,4-butanediol with the carboxylic acids of acrylic acid. During the reaction, water is generated as a by - product.Water is produced as a side-product during the reaction. To shift the equilibrium of the reversible esterification reaction towards the formation of 1,4 - butanediol diacrylate, the generated water needs to be removed continuously.The generated water must be continuously removed to shift the equilibrium in the reversible esterification reaction towards formation of 1,4-butanediol acrylate. This can be achieved by using a Dean - Stark apparatus, which separates the water from the reaction mixture and returns the organic phase back to the reaction flask.This can be done by using a Dean-Stark apparatus that separates the water and returns the organic phase to the reaction flask.
4. Product purification4.
After the reaction is completed, the reaction mixture contains the product 1,4 - butanediol diacrylate, unreacted acrylic acid, catalyst, and some by - products.The reaction mixture will contain the 1,4-butanediol acrylate, unreacted acrylic acid, catalyst and some by-products. First, the catalyst can be neutralized with a base such as sodium carbonate.The catalyst can first be neutralized using a base, such as sodium carbonate. Then, the mixture is washed with water to remove the neutralized salts and unreacted acrylic acid as much as possible.The mixture is then washed with a solution of sodium carbonate to remove as much unreacted acrylic acids and neutralized salts as possible. Finally, the organic phase is dried over anhydrous sodium sulfate or magnesium sulfate to remove residual water, and then purified by distillation under reduced pressure to obtain pure 1,4 - butanediol diacrylate.The organic phase is dried on anhydrous sodium or magnesium sulfate, to remove any residual water. It is then purified using reduced pressure distillation to obtain pure 1,4-butanediol acrylate.
What are the storage and handling requirements for 1,4-Butanediol diacrylate?
1,4 - Butanediol diacrylate is a chemical compound with specific storage and handling requirements to ensure safety and maintain its quality.1,4- Butanediol Diacrylate is a crystalline compound that requires specific storage and handling to maintain its quality and safety.
Storage Requirements
Firstly, it should be stored in a cool, dry, and well - ventilated area.It should be stored in an area that is cool, dry and well-ventilated. High temperatures can accelerate its polymerization reaction, leading to the formation of clumps or gels, thus reducing its usability.High temperatures can speed up the polymerization reaction and cause clumps and gels to form, reducing its usefulness. The ideal storage temperature is typically between 2 - 8 degrees Celsius.Ideal storage temperatures are typically between 2 and 8 degrees Celsius. A refrigerated storage facility with proper temperature control is often recommended.It is often recommended to use a refrigerated facility with temperature control.
Secondly, it must be stored away from sources of ignition.Second, it should be stored away from ignition sources. 1,4 - Butanediol diacrylate is flammable, and any potential for a fire - related incident must be minimized.1,4-Butanediol Diacrylate is flammable and any fire-related incident must be avoided. This means keeping it far from open flames, hot surfaces, and electrical equipment that could generate sparks.It is important to keep it away from open flames, surfaces that are hot, and electrical equipment which could spark.
It should also be stored in a tightly sealed container.It should be stored in a tightly-sealed container. Exposure to air can cause oxidation, which may lead to changes in its chemical properties.Exposure to the air can cause oxidation which can lead to changes in chemical properties. Additionally, moisture can initiate hydrolysis reactions, which can degrade the compound.Moisture can also initiate hydrolysis reactions that can degrade a compound. Therefore, a container with a good - quality seal is essential to prevent air and moisture ingress.A container with a high-quality seal is necessary to prevent moisture and air ingress.
Handling Requirements
When handling 1,4 - Butanediol diacrylate, appropriate personal protective equipment (PPE) must be worn.Wearing the appropriate PPE is required when handling 1,4-Butanediol Diacrylate. This includes chemical - resistant gloves, safety goggles, and a lab coat or other protective clothing.Chemical-resistant gloves, safety goggles and lab coats or other protective clothing are all required. The gloves should be made of materials like nitrile, which can resist the chemical's corrosive effects on the skin.The gloves should be made from materials such as nitrile that can resist the chemical’s corrosive effect on the skin.
During transfer operations, care must be taken to avoid spills.During transfer operations it is important to avoid spills. Use proper transfer equipment such as pumps or funnels designed for handling chemicals.Use transfer equipment designed for chemicals, such as pumps and funnels. If a spill does occur, immediate action is required.In the event of a spill, immediate action must be taken. First, isolate the area to prevent others from coming into contact with the spilled substance.Isolate the area first to prevent others from contacting the spilled substance. Then, absorb the spill using an appropriate absorbent material like vermiculite or sand.Absorb the spill with an absorbent material such as vermiculite, sand or other suitable absorbent materials. Dispose of the contaminated absorbent in accordance with local environmental regulations.Dispose the contaminated absorbent according to local environmental regulations.
In a production or laboratory setting, ensure that there is good ventilation.In a laboratory or production setting, make sure there is adequate ventilation. This helps to prevent the build - up of vapors, which can be harmful if inhaled.This will prevent the accumulation of vapors that can be harmful when inhaled. Install exhaust systems that can effectively remove any fumes generated during handling.Install exhaust systems to remove fumes produced during handling. Also, all equipment used for handling 1,4 - Butanediol diacrylate should be regularly inspected for leaks or damage to prevent any unforeseen releases of the chemical.All equipment used to handle 1,4-Butanediol Diacrylate should also be regularly inspected to detect any leaks or damage. This will prevent any unplanned releases of the chemical.