.
Product Name | 1,6-Hexanediol diacrylate |
Cas Number | 13048-33-4 |
Formula | C12H18O4 |
Molar Mass | 226.27 g/mol |
Density | 1.069 g/cm³ |
Boiling Point | 150-160°C at 5 mmHg |
Flash Point | 138°C |
Refractive Index | 1.462 |
Viscosity | 14-16 cP at 25°C |
Appearance | Clear liquid |
Solubility | Slightly soluble in water |
Storage Conditions | Store at room temperature away from light |
Vapor Pressure | 0.1 mmHg at 25°C |
Hazard Statements | H315, H317, H319 |
Stability | Stable under recommended storage conditions |
What are the main applications of 1,6-Hexanediol diacrylate?
1,6 - Hexanediol diacrylate (HDDA) is a versatile acrylate monomer with a wide range of applications.1,6- Hexanediol Diacrylate (HDDA), a versatile monomer, has a wide range applications.
One of the major application areas is in the coatings industry.Coatings is one of the most important applications. HDDA is used in formulating UV - curable coatings.HDDA is used to formulate UV-curable coatings. These coatings can be applied to various substrates like wood, metal, and plastic.These coatings are suitable for wood, metal and plastic substrates. In the case of wood coatings, the UV - curable nature of HDDA - based coatings allows for rapid curing, providing a hard, durable, and scratch - resistant finish.The UV-curable nature of HDDA-based coatings makes it possible to cure wood coatings quickly, resulting in a durable, scratch-resistant finish. This not only protects the wood from environmental damage such as moisture and abrasion but also gives it an aesthetically pleasing appearance.This not only protects wood from environmental damage, such as moisture and wear, but also gives it a pleasing appearance. For metal coatings, HDDA helps in creating corrosion - resistant layers.HDDA is used to create corrosion-resistant layers for metal coatings. The double - bond structure of HDDA enables it to polymerize quickly under UV light, forming a continuous and dense film that acts as a barrier against rust and other forms of corrosion.HDDA's double-bond structure allows it to polymerize rapidly under UV light. This forms a dense and continuous film that acts as an effective barrier against corrosion and rust.
In the adhesives field, HDDA plays a crucial role.HDDA is a key component in the adhesives industry. It is often used in UV - curable adhesives.It is used in UV-curable adhesives. These adhesives are useful in bonding different materials together.These adhesives can be used to bond different materials. For example, in electronics manufacturing, they can be used to bond components to printed circuit boards.In electronics manufacturing, for example, they can be applied to bond components to printed-circuit boards. The quick - curing property of HDDA - containing adhesives allows for high - speed production processes.HDDA-containing adhesives have a quick-curing property, which allows for high-speed production processes. The cured adhesive has good mechanical strength, ensuring a reliable bond between the components.The cured adhesive is strong and durable, ensuring a solid bond between components. Additionally, HDDA - based adhesives can bond dissimilar materials, such as glass to plastic, due to its good wetting and adhesion properties.Due to their good wetting and adhesive properties, HDDA-based adhesives are also able to bond dissimilar materials such as plastic to glass.
HDDA is also utilized in the production of inks.HDDA is also used in the production inks. UV - curable inks formulated with HDDA are widely used in the printing industry.In the printing industry, UV-curable inks that are formulated with HDDA is widely used. They offer several advantages over traditional inks.They have several advantages over conventional inks. For instance, they have low volatile organic compound (VOC) emissions, which is more environmentally friendly.They emit less volatile organic compounds (VOCs), which is better for the environment. In high - speed printing operations, the fast - curing nature of these inks is a significant advantage.The fast-curing nature of these inks can be a major advantage for high-speed printing operations. They can be used for printing on a variety of substrates, including paper, cardboard, and flexible packaging materials.These inks can be printed on a wide range of substrates including paper, cardboard and flexible packaging. The cured ink films have good abrasion resistance and color fastness, ensuring that the printed products maintain their quality over time.The cured ink film has good abrasion resistance, and the color fastness ensures that the printed product maintains its quality over time.
In the area of 3D printing, HDDA can be part of the resin formulation.HDDA can be used in the formulation of resins for 3D printing. It contributes to the mechanical properties of the 3D - printed objects.It contributes to mechanical properties of 3D-printed objects. The ability of HDDA to polymerize under light allows for the precise layer - by - layer construction of 3D models.HDDA's ability to polymerize in the presence of light allows for precise layer-by-layer construction of 3D models. The resulting printed parts can have good strength and dimensional stability, making them suitable for applications such as prototyping, small - batch manufacturing of parts, and even some consumer products.The printed parts are strong and stable, making them ideal for prototyping and small-batch manufacturing of parts. They can also be used in consumer products.
What are the physical and chemical properties of 1,6-Hexanediol diacrylate?
1,6 - Hexanediol diacrylate is a monomer commonly used in the field of polymer materials.1,6- Hexanediol Diacrylate is a common monomer used in the field polymer materials.
Physical properties:Physical Properties
1. Appearance: It is usually a clear, colorless to slightly yellow - colored liquid.Appearance: This liquid is usually clear, colorless or slightly yellow-colored. This clear appearance makes it suitable for applications where visual transparency is required, such as in some optical coatings.This clear appearance makes the liquid suitable for applications that require visual transparency, such as some optical coatings.
2. Odor: It has a characteristic acryl - like odor.It has an acryl-like odor. Although the exact description can vary, the smell is often associated with the acrylate functional groups present in the molecule.The smell can be described in many ways, but is usually associated with the acrylate groups that are present in the molecule.
3. Viscosity: The viscosity of 1,6 - hexanediol diacrylate is relatively low.Viscosity is low. This low viscosity allows for easy handling, such as during the process of mixing with other components in formulation preparation.This low viscosity makes it easy to handle, for example when mixing with other ingredients in formulation preparation. It can flow smoothly, which is beneficial for applications like casting and coating processes, enabling it to spread evenly over surfaces.It flows smoothly, which makes it ideal for casting and coating processes.
4. Solubility: It is soluble in many organic solvents, such as acetone, toluene, and ethyl acetate.Solubility: It's soluble in many organic solvants, including acetone, ethyl-acetate, and toluene. This solubility property provides flexibility in formulating solutions for different applications.This property of solubility allows for flexibility in formulating different solutions. For example, in the production of certain adhesives or coatings, it can be dissolved in appropriate solvents to achieve the desired concentration and application characteristics.In the production of certain coatings or adhesives, for example, it can dissolve in appropriate solvents in order to achieve the desired concentration.
Chemical properties:Chemical properties
1. Polymerizability: The most prominent chemical property is its high reactivity towards polymerization.Polymerizability is the most important chemical property. Its high reactivity to polymerization is the most notable. The two acrylate double - bonds in 1,6 - hexanediol diacrylate can participate in free - radical polymerization reactions.The two acrylate - double - bonds of 1,6 hexanediol - diacrylate are capable of participating in free radical polymerization. When initiated by heat, light, or a suitable initiator, these double - bonds break and form long - chain polymers.These double - bond break when heat, light or an initiator is used to initiate the reaction. This property is widely exploited in the production of polymers for various purposes, including the manufacture of coatings, adhesives, and composites.This property is widely used in the production and use of polymers, including coatings, adhesives and composites.
2. Cross - linking ability: Due to the presence of two acrylate groups per molecule, it can act as a cross - linking agent.Cross-linking ability: It can act as a chemical cross-linker due to the presence two acrylate groups in each molecule. During polymerization, it can form covalent bonds between different polymer chains, enhancing the mechanical properties of the resulting polymer network.During polymerization it can form covalent bond between different polymer chain, improving the mechanical properties of resulting polymer networks. For instance, in the production of cured coatings, cross - linking via 1,6 - hexanediol diacrylate can improve the hardness, abrasion resistance, and chemical resistance of the coating.Cross-linking via 1,6-hexanediol-diacrylate, for example, can improve the hardness of cured coatings as well as their chemical and abrasion resistance.
3. Reactivity with other functional groups: The acrylate groups can react with a variety of other functional groups.Reactivity with other groups: The acrylate group can react with many other functional groups. For example, they can react with amines in a Michael addition reaction.They can, for example, react with amines via a Michael addition. This reactivity can be used to modify the properties of polymers or to create new hybrid materials by combining with other polymers or compounds containing reactive amine groups.This reactivity is used to modify polymer properties or create new hybrid materials.
How is 1,6-Hexanediol diacrylate synthesized?
1,6 - Hexanediol diacrylate is synthesized through the following general process.The following general process is used to synthesize 1,6-hexanediol acrylate.
First, the starting materials are 1,6 - hexanediol and acrylic acid.The first materials to be used are 1,6-hexanediol, and acrylic acid. To initiate the reaction, a catalyst is needed.A catalyst is required to initiate the reaction. Commonly, sulfuric acid or p - toluenesulfonic acid can be used as catalysts.Catalysts are commonly sulfuric acid or the p-toluenesulfonic acids. These catalysts help to promote the esterification reaction between the hydroxyl groups of 1,6 - hexanediol and the carboxyl groups of acrylic acid.These catalysts promote the esterification between the hydroxyl group of 1,6-hexanediol, and the carboxyl group of acrylic acid.
In addition to the catalyst, a polymerization inhibitor is also added.A polymerization inhibitor is added to the catalyst. This is crucial because acrylic acid and the reaction products are prone to polymerization during the synthesis process.This is important because acrylic acid, and the reaction products, are susceptible to polymerization. Hydroquinone or its derivatives are often used as polymerization inhibitors.As polymerization inhibiters, hydroquinone and its derivatives are commonly used. They prevent the formation of unwanted polymers, ensuring that the reaction proceeds to form the desired 1,6 - hexanediol diacrylate rather than polymers of acrylic acid or other side - reaction products.They prevent unwanted polymers from forming, ensuring the reaction proceeds to produce the desired 1,6-hexanediol-diacrylate instead of polymers of Acrylic acid or other side-reaction products.
The reaction is usually carried out under specific temperature and reaction time conditions.The reaction is usually carried under certain temperature and reaction time conditions. The reaction temperature is typically in the range of 80 - 120 degC.The reaction temperature ranges between 80 and 120 degC. At this temperature range, the reaction rate is sufficient to promote the esterification reaction between 1,6 - hexanediol and acrylic acid while also minimizing side reactions.This temperature range is ideal for promoting the esterification between 1,6-hexanediol, and acrylic acid. The reaction time can vary depending on factors such as the reaction scale, the amount of catalyst used, and the reaction temperature.The reaction time depends on a number of factors, including the scale of the reaction, the amount and temperature of the catalyst. Generally, it may take several hours to ensure the completion of the reaction.It may take several hours for the reaction to be completed.
After the reaction is completed, the reaction mixture needs to be purified.Purification is required after the reaction has been completed. The purification process often involves steps such as neutralization to remove the catalyst and any unreacted acid.Purification often involves neutralization, which removes the catalyst and unreacted acid. This can be achieved by adding a base, like sodium carbonate or sodium hydroxide, to adjust the pH.To adjust the pH, you can add a base like sodium hydroxide or sodium carbonate. Then, separation techniques such as distillation or extraction are used.Then, techniques of separation such as extraction or distillation are used. Distillation can separate the product based on its boiling point, while extraction can be used to separate the product from other impurities using an appropriate solvent.Distillation can be used to separate products based on their boiling point. Extraction can be used to remove impurities by using a suitable solvent. Through these purification steps, high - purity 1,6 - hexanediol diacrylate can be obtained.These purification steps can lead to high-purity 1,6-hexanediol-diacrylate.
What are the safety hazards and precautions when handling 1,6-Hexanediol diacrylate?
1,6 - Hexanediol diacrylate is a chemical compound used in various industries like coatings, adhesives, and printing inks.1,6-Hexanediol Diacrylate is a chemical used in many industries, such as coatings, adhesives and printing inks. When handling it, there are several safety hazards to be aware of.There are several safety hazards when handling it.
One significant hazard is its potential to cause skin and eye irritation.It can cause irritation to the skin and eyes. Direct contact with the skin can lead to redness, itching, and possible burns.Direct contact with skin can cause redness, itchiness, and even burns. If it gets into the eyes, it can cause severe irritation, pain, and may even damage the eyesight.If it gets in the eyes, it may cause severe irritation and pain, or even damage to the eyesight. Inhalation of its vapors or mists is also a concern.Inhaling its vapors and mists can also be dangerous. It can irritate the respiratory tract, leading to symptoms such as coughing, shortness of breath, and in more severe cases, it may cause long - term damage to the lungs.It can cause respiratory irritation, resulting in symptoms such as coughing and shortness of breathe. In more severe cases, the lungs may be permanently damaged. Additionally, 1,6 - Hexanediol diacrylate may be harmful if swallowed, which could result in internal organ damage.1,6-Hexanediol Diacrylate can also be harmful if swallowed. This could lead to internal organ damage.
Another safety risk is its flammability.Its flammability is another safety risk. It can catch fire easily in the presence of an ignition source, such as an open flame or a spark, and can burn rapidly, posing a risk of fire and explosion in a workplace environment.It can easily catch fire in the presence an ignition source such as an open fire or a spark. It can also burn rapidly, posing an explosion and fire risk in a work environment.
To handle 1,6 - Hexanediol diacrylate safely, several precautions should be taken.To ensure safe handling of 1,6- Hexanediol Diacrylate, it is important to take a few precautions. When working with it, always wear appropriate personal protective equipment.Wear appropriate personal protective gear when working with it. This includes chemical - resistant gloves made of materials like nitrile, safety goggles or a face shield to protect the eyes, and a lab coat or chemical - resistant apron to safeguard the body.Wearing chemical-resistant gloves made from materials such as nitrile is important. Also, wear safety goggles, a face shield, or safety goggles to protect your eyes. You can also wear a lab coat, or a chemical-resistant apron, to protect your body. Ensure good ventilation in the work area.Assure that the work area is well ventilated. Use local exhaust ventilation systems if possible to remove vapors and mists from the air.If possible, use local exhaust ventilation systems to remove vapors or mists. In case of a spill, immediately isolate the area to prevent the spread of the chemical.If a spill occurs, isolate the area immediately to prevent the spread. Absorb the spill with an appropriate absorbent material, such as vermiculite or sand, and dispose of it properly according to local regulations.Use an absorbent material such as vermiculite, sand or other suitable absorbent materials to absorb the spill. Dispose of it according to local regulations. When storing 1,6 - Hexanediol diacrylate, keep it in a cool, dry place away from heat sources, ignition sources, and incompatible materials.Store 1,6-Hexanediol Diacrylate in a cool and dry place, away from heat sources, ignitions sources, and other incompatible materials. And in case of any contact with the skin or eyes, immediately rinse thoroughly with plenty of water for at least 15 minutes and seek medical attention.In the event of contact with skin or eyes, rinse immediately with plenty of water and seek medical attention. If inhalation occurs, move to fresh air and get medical help if symptoms persist.Inhalation symptoms should be treated by moving to fresh air. If they persist, seek medical attention.
What is the difference between 1,6-Hexanediol diacrylate and other diacrylates?
1,6 - Hexanediol diacrylate (HDDA) has several differences compared to other diacrylates.There are several differences between HDDA and other diacrylates.
Firstly, in terms of chemical structure, the length and nature of the spacer group between the two acrylate groups in HDDA is distinct.In terms of chemical structure, firstly, the length and type of the spacer groups between the two acrylate group in HDDA are distinct. The hexanediol moiety provides a relatively long, flexible aliphatic chain.The hexanediol molecule provides a relatively flexible, long aliphatic ring. In contrast, other diacrylates may have shorter or more rigid spacer groups.Other diacrylates can have spacer groups that are shorter or more rigid. For example, ethylene glycol diacrylate has a much shorter ethylene - based spacer.For example, the ethylene glycol diacrylate contains a much smaller ethylene-based spacer. This longer chain in HDDA imparts certain properties to the molecule.This longer chain in HDDA confers certain properties to molecule.
Secondly, the physical properties are affected by the structure.Second, the structure affects the physical properties. HDDA is a relatively viscous liquid at room temperature.HDDA is a viscous liquid when it is at room temperature. The long flexible chain can contribute to lower volatility compared to some diacrylates with shorter chains.The long flexible chains can contribute to a lower volatility than some diacrylates that have shorter chains. This lower volatility is beneficial in applications where minimizing evaporation and associated fumes is important, such as in coatings and inks.This lower volatility is advantageous in applications that minimize evaporation, including inks and coatings. Some other diacrylates with shorter chains may be more volatile, which could lead to faster drying times in some cases but also potential environmental and safety concerns due to increased vapor emissions.Some diacrylates that have shorter chains are more volatile. This could lead to faster drying in some cases, but also to potential environmental and safety issues due to increased vapor emission.
In terms of reactivity, the acrylate double - bonds in HDDA are highly reactive towards free - radical polymerization.The acrylate double-bonds in HDDA are highly reactive towards free-radical polymerization. However, the reactivity can be influenced by the surrounding structure.The surrounding structure can influence the reactivity. The long chain in HDDA may provide some steric hindrance compared to diacrylates with more compact structures.HDDA's long chain may cause some steric interference compared to diacrylates that have a more compact structure. But overall, it can still participate efficiently in curing reactions, often used in UV - curable formulations.It can still be used in UV-curable formulations, and it is a good curing agent. Some other diacrylates might have different reactivity rates depending on the electron - donating or - withdrawing nature of the groups attached to the acrylate double - bonds.Some diacrylates may have different reactivity depending on whether the groups attached to acrylate double-bonds are electron-donating or removing.
In applications, HDDA is popular in coatings, adhesives, and 3D printing.HDDA is used in 3D printing, coatings, and adhesives. In coatings, its long chain can contribute to good film - forming properties, enhancing the flexibility and toughness of the cured film.In coatings, the long chain can enhance the flexibility and toughness, as well as the film-forming properties. In 3D printing, it helps in creating parts with suitable mechanical properties.It helps create parts with mechanical properties that are suitable for 3D printing. Other diacrylates might be more specialized for different applications.Other diacrylates may be more specialized to suit different applications. For instance, some aromatic - containing diacrylates could be used in applications where higher heat resistance is required due to the inherent stability of the aromatic rings.Some aromatic-containing diacrylates, for example, could be used where a higher heat resistance is needed due to the inherent stability the aromatic rings.