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Product Name | 1,6-Hexanediol dimethacrylate |
Cas Number | 6606-59-3 |
Formula | C14H22O4 |
Molar Mass | 254.32 g/mol |
Density | 1.027 g/cm³ |
Boiling Point | 268 °C |
Flash Point | 113 °C |
Viscosity | 10.4 mPa·s |
Refractive Index | 1.459 |
Water Solubility | Slightly soluble |
Vapor Pressure | 0.0006 mmHg at 25°C |
Compatibility | Compatible with various methacrylate monomers |
Appearance | Clear liquid |
Odor | Mild |
What are the applications of 1,6-Hexanediol dimethacrylate?
1,6 - Hexanediol dimethacrylate (HDDA) has diverse applications across multiple industries.HDDA (hexanediol dimethylacrylate) is used in many industries.
In the coatings industry, HDDA is highly valued.HDDA is highly regarded in the coatings industry. It serves as a reactive diluent in UV - curable coatings.It is used as a reactive dilutient in UV-curable coatings. These coatings are used in various applications like wood finishing, metal coatings, and plastic coatings.These coatings can be used for a variety of applications, including wood finishing, metal coatings and plastic coatings. The addition of HDDA can improve the flow and leveling properties of the coating formulations.HDDA can be added to coating formulations to improve their flow and leveling. When exposed to UV light, it rapidly polymerizes, forming a hard, durable, and abrasion - resistant film.When exposed to UV, it quickly polymerizes and forms a durable, hard, and abrasion-resistant film. For example, in the furniture industry, UV - curable coatings with HDDA provide a smooth, scratch - resistant surface to wooden furniture, enhancing its aesthetic appeal and lifespan.In the furniture industry, UV-curable coatings with HDDA create a smooth and scratch-resistant surface on wooden furniture. This enhances its aesthetic appeal as well as its lifespan.
In the adhesives field, HDDA plays a crucial role.HDDA is a key ingredient in the adhesives industry. It can be incorporated into acrylate - based adhesives.It can be used in acrylate-based adhesives. These adhesives are known for their strong bonding strength.These adhesives are well known for their high bonding strength. HDDA helps in cross - linking the adhesive matrix, which increases the adhesive's resistance to heat, chemicals, and mechanical stress.HDDA increases the adhesive's resistance against heat, chemicals and mechanical stress by cross-linking the matrix. For instance, in automotive assembly, acrylate adhesives containing HDDA are used to bond different components such as plastics, metals, and composites.In automotive assembly, for example, acrylate glues containing HDDA can be used to bond components such as metals, plastics, and composites. The cross - linked structure formed by HDDA ensures that the bonds remain intact under the harsh conditions experienced by vehicles, including temperature variations and vibrations.HDDA's cross-linked structure ensures that bonds remain intact even under harsh conditions, such as temperature changes and vibrations.
HDDA is also widely used in the production of dental materials.HDDA is widely used in the manufacture of dental materials. In dental composites, it acts as a cross - linking agent.It is used as a cross-linking agent in dental composites. Dental composites are used for filling cavities.Dental composites can be used to fill cavities. The cross - linking ability of HDDA helps in creating a rigid and stable structure within the composite material.The HDDA's cross-linking ability helps to create a rigid, stable structure in the composite material. This results in dental fillings that can withstand the mechanical forces generated during chewing, have good wear resistance, and are biocompatible.This allows for dental fillings to be resistant to the mechanical forces created during chewing. They are also biocompatible and have good wear resistance. It also contributes to the long - term stability of the filling, reducing the need for frequent replacements.It also contributes towards the long-term stability of the fillings, reducing the frequency of replacement.
The ink industry also benefits from HDDA.HDDA is also beneficial to the ink industry. In UV - curable inks, it functions as a reactive monomer.In UV-curable inks it acts as a monomer. These inks are used in printing on a variety of substrates, including paper, cardboard, and plastics.These inks can be used to print on a variety substrates including paper, cardboard and plastics. HDDA enables the inks to cure rapidly upon exposure to UV light, which increases the printing speed and productivity.HDDA allows the inks cure quickly when exposed to UV light. This increases printing speed and productivity. Additionally, the cured inks have good adhesion to the substrates, high color fastness, and resistance to fading, making them suitable for high - quality printing applications such as packaging and label printing.The cured inks are also resistant to fading and have high color fastness. They are suitable for high-quality printing applications, such as label and packaging printing.
In the field of 3D printing, specifically in some vat photopolymerization processes, HDDA can be part of the resin formulation.HDDA is a component of resin formulations in 3D printing. It participates in the polymerization reaction during the layer - by - layer building of the 3D object.It is involved in the polymerization process during the layer-by-layer construction of the 3D object. Its presence can influence the mechanical properties of the printed object, such as hardness, toughness, and dimensional stability.Its presence can affect the mechanical properties of the object printed, such as toughness, hardness, and dimensional stabilty. By adjusting the amount of HDDA in the resin, manufacturers can tailor the properties of the 3D - printed parts to meet the requirements of different applications, from prototyping to the production of functional end - use components.By adjusting the amount HDDA in the resin manufacturers can tailor properties of 3D-printed parts to meet different requirements, from prototyping, to functional end-use components.
What are the properties of 1,6-Hexanediol dimethacrylate?
1,6 - Hexanediol dimethacrylate is a monomer with several notable properties.1,6- Hexanediol Dimethacrylate monomer has several notable properties.
Physical properties:Physical Properties
In terms of appearance, it is typically a clear, colorless to slightly yellowish liquid.It is usually a clear, colorless or slightly yellowish liquid. It has a characteristic odor.It has a distinctive odor. The compound has a relatively low viscosity, which makes it easy to handle and mix with other substances in various applications.It is easy to mix and handle because of its low viscosity. This low viscosity allows for good flow during processes like coating and molding.This low viscosity makes it easy to flow during processes such as coating and molding. It has a density that is close to that of water, enabling it to blend well with other materials of similar density.Its density is similar to water, making it easy to mix with other materials.
Chemical properties:Chemical properties
1,6 - Hexanediol dimethacrylate contains two methacrylate functional groups.The dimethacrylate 1,6-hexanediol contains two functional methacrylate groups. These double - bond - containing functional groups are highly reactive.These functional groups with double-bonds are highly reactive. They can participate in polymerization reactions, such as free - radical polymerization.They can participate in polymerization processes, such as the free - radical type of polymerization. This reactivity is crucial in the formation of polymers and cross - linked materials.This reactivity is essential in the formation and cross-linking of polymers. It can react with other monomers or itself to form long - chain polymers.It can react either with other monomers, or by itself, to form long-chain polymers. The cross - linking ability provided by the two methacrylate groups leads to the formation of three - dimensional network structures.The two methacrylate group's cross-linking ability leads to the formation three-dimensional network structures. These cross - linked polymers often exhibit enhanced mechanical properties compared to linear polymers.These cross-linked polymers have often superior mechanical properties to linear polymers. It is also relatively stable under normal storage conditions when protected from heat, light, and oxidizing agents.It is relatively stable when stored under normal conditions, provided it is protected from heat, light and oxidizing agents. However, in the presence of initiators like peroxides or under UV light in the presence of photo - initiators, it rapidly polymerizes.It polymerizes rapidly in the presence or UV light, peroxides, and photo-initiators.
Thermal properties:Thermal properties
The resulting polymers from 1,6 - Hexanediol dimethacrylate have good thermal stability.The polymers that result from 1,6-hexanediol dimethylacrylate are thermally stable. They can withstand a certain range of temperatures without significant degradation.They can withstand certain temperatures without significant degradation. This makes them suitable for applications where the material may be exposed to elevated temperatures, such as in some industrial coatings and composites.They are therefore suitable for applications in which the material is exposed to high temperatures, like industrial coatings or composites. The cross - linked nature of the polymers formed from this monomer contributes to their ability to maintain their shape and mechanical integrity at higher temperatures.The polymers made from this monomer are cross-linked, which helps them maintain their shape and mechanical integrity even at higher temperatures.
Mechanical properties:Mechanical properties
When polymerized, 1,6 - Hexanediol dimethacrylate - based polymers show good mechanical strength.Polymers based on 1,6- Hexanediol Dimethacrylate have good mechanical strength. The cross - linking helps in providing hardness and rigidity to the material.The cross-linking helps to give the material rigidity and hardness. At the same time, it can also possess some degree of flexibility depending on the polymerization conditions and the presence of other additives.It can also be flexible depending on the polymerization condition and the presence of additives. These mechanical properties make it useful in applications like dental restoratives, where the material needs to be strong enough to withstand chewing forces while also having some flexibility to adapt to the movement of the teeth.These mechanical properties are useful in applications such as dental restoratives where the material must be strong enough to withstand chewing force while also being flexible to adapt to the movements of the teeth.
Solubility properties:Solubility:
It has some solubility in common organic solvents such as acetone, methyl ethyl ketone, and toluene.It is soluble in organic solvents like acetone, methyl-ethyl-ketone and toluene. This solubility is beneficial for formulating solutions for coating applications or for dissolving it in the presence of other monomers during polymerization processes.This solubility can be used to formulate solutions for coating applications, or dissolve it in the presence other monomers when polymerization is taking place. However, it is insoluble in water, which makes it suitable for applications where water resistance is required, like in waterproof coatings.It is not soluble in water and is therefore suitable for applications that require water resistance, such as waterproof coatings.
How is 1,6-Hexanediol dimethacrylate synthesized?
1,6 - Hexanediol dimethacrylate can be synthesized through the following general steps.The following general steps can be used to synthesize 1,6-hexanediol dimethylacrylate.
The first step involves preparing the starting materials.The first step is to prepare the materials. 1,6 - hexanediol is a key starting compound, which is a diol with a six - carbon chain having hydroxyl groups at both ends.1,6-hexanediol, a diol containing a six-carbon chain with hydroxyl groups on both ends, is an important starting compound. Methacrylic acid is also required.Also required is methacrylic acid. Methacrylic acid contains a double bond and a carboxyl group, which is crucial for the formation of the ester bonds in the final product.Methacrylic acids contain a double bond as well as a carboxyl, which are crucial for the formation ester bonds.
The synthesis reaction is an esterification reaction.Esterification is the synthesis reaction. To carry out this reaction, a catalyst is needed.A catalyst is required to carry out this reaction. Commonly, sulfuric acid or p - toluenesulfonic acid can be used as catalysts.Catalysts are commonly sulfuric acid or the p-toluenesulfonic acids. These catalysts help to speed up the reaction by promoting the formation of the ester bond between the hydroxyl groups of 1,6 - hexanediol and the carboxyl groups of methacrylic acid.These catalysts speed up the reaction because they promote the formation of an ester bond between 1,6 -hexanediol's hydroxyl group and the carboxyl group of methacrylic acids.
The reaction is typically carried out under reflux conditions.Typically, the reaction is carried out in reflux conditions. A reflux apparatus is used to ensure that the volatile reactants and products are condensed and returned to the reaction mixture, thus maintaining a high concentration of reactants in the reaction system.A reflux apparatus is used in order to ensure that volatile reactants and product are condensed, and returned to reaction mixture. This maintains a high concentration reactants within the reaction system. This helps to drive the reaction towards the formation of the desired product.This helps to drive a reaction towards the desired product.
During the reaction, an acid - base reaction occurs between the hydroxyl group of 1,6 - hexanediol and the carboxyl group of methacrylic acid.During the reaction an acid-base reaction occurs between the carboxyl groups of methacrylic and 1,6-hexanediol. The catalyst protonates the carboxyl group of methacrylic acid, making it more reactive towards the nucleophilic attack by the hydroxyl group of 1,6 - hexanediol.The catalyst protonates methacrylic acids carboxyl groups, increasing their reactivity towards the nucleophilic attacks by the hydroxyl groups of 1,6-hexanediol. After the nucleophilic attack, a water molecule is eliminated, and an ester bond is formed.After the nucleophilic reaction, a water-molecule is eliminated and an ester is formed. Since 1,6 - hexanediol has two hydroxyl groups and methacrylic acid has one carboxyl group per molecule, two moles of methacrylic acid react with one mole of 1,6 - hexanediol to form 1,6 - hexanediol dimethacrylate.Since 1,6-hexanediol contains two hydroxyl groups, and methacrylic has one carboxyl per molecule of the acid, two moles react with 1 mole of 1,6-hexanediol in order to form 1,6-hexanediol dimethylacrylate.
After the reaction is complete, the product mixture may contain unreacted starting materials, catalyst, and by - products.After the reaction has been completed, the product mix may contain unreacted materials, catalysts, and by-products. Purification steps are then necessary.Then, purification steps are required. One common purification method is distillation.Distillation is a common method of purification. Due to the differences in boiling points of 1,6 - hexanediol dimethacrylate, unreacted 1,6 - hexanediol, methacrylic acid, and other components, distillation can be used to separate 1,6 - hexanediol dimethacrylate from the mixture, obtaining a relatively pure product.Distillation can be used due to the difference in boiling points between 1,6-hexanediol Dimethacrylate and unreacted 1,6-hexanediol. Methacrylic Acid, as well as other components. Another purification method could be extraction, where appropriate solvents are used to selectively dissolve and remove impurities, leaving behind the 1,6 - hexanediol dimethacrylate.A second purification method is extraction, which uses appropriate solvents to dissolve and remove impurities while leaving behind 1,6 -hexanediol Dimethacrylate.
What are the safety precautions when handling 1,6-Hexanediol dimethacrylate?
1,6 - Hexanediol dimethacrylate is a chemical compound that requires certain safety precautions during handling.1,6- Hexanediol Dimethacrylate, a chemical compound, requires certain safety precautions when handling.
First, personal protective equipment (PPE) is essential.Personal protective equipment (PPE), first and foremost, is essential. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a barrier against contact with the chemical.Nitrile gloves can be a good option as they provide a barrier to contact with the chemical. This helps prevent skin absorption, which could potentially lead to skin irritation, allergic reactions, or more serious health effects.This can help prevent skin absorption that could lead to skin irritations, allergic reactions or other serious health effects. Also, wear safety goggles to protect the eyes.Wear safety goggles as well to protect your eyes. If the chemical splashes into the eyes, it can cause severe irritation, corneal damage, and even vision impairment.If the chemical splashes in the eyes, it may cause severe irritation, corneal injury, and even vision loss.
Second, ensure good ventilation.Second, make sure you have good ventilation. Work in a well - ventilated area or use local exhaust ventilation systems.Work in an area that is well-ventilated or use local exhaust ventilation. 1,6 - Hexanediol dimethacrylate may emit vapors that can be irritating to the respiratory system if inhaled in high concentrations.1,6-Hexanediol Dimethacrylate can emit vapors which are irritating to the respiratory tract if inhaled at high concentrations. Inhalation can lead to symptoms such as coughing, shortness of breath, and throat irritation.Inhalation can cause symptoms such as coughing and throat irritation. Adequate ventilation helps to dilute these vapors and reduce the risk of inhalation exposure.Adequate ventilation can help dilute these vapors, reducing the risk of exposure.
Third, avoid heat and open flames.Third, avoid heat or open flames. 1,6 - Hexanediol dimethacrylate is flammable.Hexanediol Dimethacrylate, 1,6 is flammable. Keep it away from sources of ignition, such as heaters, stoves, and welding equipment.Keep it away form sources of ignition such as heaters and stoves. Store it in a cool, dry place, away from direct sunlight.Store it in a dry, cool place away from direct sunlight. High temperatures can increase the risk of combustion and may also cause the chemical to degrade or react unpredictably.High temperatures can increase combustion risk and cause the chemical to degrade, or react in an unpredictable way.
Fourth, be careful during storage.Be careful when storing the chemical. Store the chemical in a properly labeled container.Store the chemical in an appropriately labeled container. The label should clearly indicate the name of the chemical, its hazards, and any necessary handling instructions.The label should clearly state the name of the substance, its hazards and any handling instructions. Keep it away from incompatible substances.Keep it away form incompatible substances. For example, it may react with strong oxidizing agents, acids, or bases, which could lead to dangerous chemical reactions, including the release of harmful gases or the generation of heat.It may react with strong acids, bases, or oxidizing agents. This could cause dangerous chemical reactions including the release or heat or harmful gases.
In case of contact, take immediate action.Take immediate action in the event of contact. If it gets on the skin, wash the affected area thoroughly with soap and water for at least 15 minutes.If it gets in the eyes, flush the eyes with water and soap for at least 15 min. If it enters the eyes, flush the eyes with copious amounts of water for at least 15 minutes and seek medical attention promptly.If it gets into the eyes, flush them with plenty of water for 15 minutes. Seek medical attention immediately. In case of inhalation, move to fresh air immediately.In the event of inhalation, you should move to fresh air as soon as possible. If someone has ingested the chemical, do not induce vomiting unless directed by a medical professional, and seek emergency medical help right away.If someone has consumed the chemical, do NOT induce vomiting unless instructed by a medical professional. Seek emergency medical attention immediately.
What are the storage requirements for 1,6-Hexanediol dimethacrylate?
1,6 - Hexanediol dimethacrylate is a type of monomer commonly used in the production of polymers, coatings, and adhesives.1,6-Hexanediol Dimethacrylate, a monomer, is commonly used to produce polymers, adhesives, and coatings. Proper storage is crucial to maintain its quality and prevent potential safety hazards.It is important to store the product properly to preserve its quality and avoid potential safety hazards.
Firstly, storage should be in a cool and dry place.First, the storage area should be cool and dry. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. Since 1,6 - Hexanediol dimethacrylate is reactive, exposure to heat might lead to self - polymerization, which would render the substance unusable for its intended applications.Heat can cause self-polymerization in 1,6-hexanediol-dimethacrylate, which makes it unusable for the intended applications. A temperature range of around 2 - 8 degrees Celsius is often ideal for long - term storage.For long-term storage, a temperature range between 2 and 8 degrees Celsius is ideal. This can typically be achieved in a refrigerated storage facility.This can be achieved by using a refrigeration facility.
Secondly, it must be stored away from sources of ignition.Second, it should be stored away from ignition sources. 1,6 - Hexanediol dimethacrylate is flammable.1,6 - Hexanediol Dimethacrylate can be flammable. Any open flames, sparks from electrical equipment, or other ignition sources in the vicinity of the storage area can pose a significant fire risk.Open flames, sparks or other ignition sources near the storage area can be a fire hazard. The storage area should be well - ventilated to prevent the build - up of flammable vapors.To prevent the accumulation of flammable gases, the storage area must be well-ventilated. Good ventilation helps to disperse any vapors that may escape from the containers, reducing the concentration of potentially explosive mixtures in the air.Good ventilation will help disperse vapors from containers and reduce the concentration of explosive mixtures.
Containment is also of great importance.Containment also plays a major role. The substance should be stored in tightly sealed containers.The substance must be stored in tightly-sealed containers. This prevents contact with air, which can cause oxidation and other chemical changes.This will prevent contact with air which can lead to oxidation or other chemical changes. Additionally, it stops the evaporation of the monomer, ensuring that its concentration remains consistent over time.It also prevents the evaporation, which ensures that the monomer concentration remains constant over time. Suitable containers are usually made of materials that are resistant to the chemical, such as certain types of plastics or metal alloys that do not react with 1,6 - Hexanediol dimethacrylate.Containers made from materials resistant to the chemical are ideal, such as certain types plastics or metals alloys.
Finally, keep it away from incompatible materials.Keep it away from any incompatible materials. Substances like strong acids, bases, and oxidizing agents can react violently with 1,6 - Hexanediol dimethacrylate.1,6- Hexanediol Dimethacrylate can react violently when it comes into contact with substances like strong acids, bases and oxidizing agents. Storing them in close proximity can lead to dangerous chemical reactions, including fires, explosions, or the release of harmful gases.Storing them close together can cause dangerous chemical reactions such as fires, explosions or the release harmful gases. A proper inventory management system should be in place to ensure that incompatible substances are stored in separate areas.Incompatible substances should be stored in separate areas using a proper inventory management system. By following these storage requirements, the integrity and safety of 500 grams or any quantity of 1,6 - Hexanediol dimethacrylate can be maintained.These storage requirements will ensure the safety and integrity of 500 grams of 1,6-hexanediol dimethylacrylate.