.

2-hydroxy Ethyl Acrylate


Properties
Product Name 2-Hydroxyethyl acrylate
Cas Number 818-61-1
Formula C5H8O3
Molar Mass 116.12 g/mol
Boiling Point 82-83 °C at 12 mmHg
Melting Point -60 °C
Density 1.092 g/mL at 25 °C
Refractive Index n20/D 1.453
Viscosity 4.3 cP at 25 °C
Flash Point 82 °C
Vapor Pressure 0.76 mmHg at 25 °C
Solubility miscible with water
Appearance clear colorless liquid
Odor acrylic odor
FAQ

What are the applications of 2-Hydroxyethylacrylate?

2 - Hydroxyethyl acrylate (HEA) has a wide range of applications across various industries.2 - Hydroxyethyl Acrylate (HEA), has many applications in various industries.
In the coatings industry, HEA is a key ingredient.HEA is a crucial ingredient in the coatings industry. It is used to improve the performance of coatings.It is used to enhance the performance of coatings. For instance, in water - based coatings, HEA can enhance adhesion.HEA, for example, can improve adhesion in water-based coatings. The hydroxyl group in HEA can form hydrogen bonds with the substrate, such as metal, wood, or plastic surfaces, ensuring that the coating adheres firmly.The hydroxyl group of HEA can form hydrogen bonding with the substrate such as metal, plastic, or wood surfaces. This ensures that the coating adheres firmly. This results in better protection against corrosion, wear, and environmental factors.This provides better protection against corrosion and wear as well as environmental factors. Additionally, HEA can be copolymerized with other monomers to adjust the film - forming properties of the coating.HEA may also be copolymerized to alter the film-forming properties of a coating. It can influence the hardness, flexibility, and gloss of the coating film.It can affect the hardness, gloss, and flexibility of the coating film. By controlling the amount of HEA in the copolymer, manufacturers can tailor the coating to meet specific requirements, like a hard - wearing floor coating or a flexible automotive paint.By controlling the amount HEA in a copolymer coating, manufacturers can tailor it to meet specific requirements. For example, a hard-wearing floor coating or flexible automotive paint.

The adhesives industry also benefits from HEA.HEA is also beneficial to the adhesives industry. It is used to synthesize pressure - sensitive adhesives.It is used in the production of pressure-sensitive adhesives. The presence of the acrylate group allows for polymerization, while the hydroxyl group provides opportunities for cross - linking.The presence of acrylate allows for polymerization while the hydroxyl groups provide opportunities for cross-linking. Cross - linked adhesives made with HEA have improved shear strength and tack.Cross-linked adhesives made from HEA are stronger and have better tack. They can adhere well to different materials and maintain their bond under various conditions.They adhere well to various materials and can maintain their bond in a variety of conditions. In the packaging industry, these adhesives are used on labels and tapes, where they need to stick firmly to a variety of surfaces, such as cardboard, glass, or plastic.These adhesives are used in the packaging industry on labels and tapes that need to adhere firmly to surfaces such as cardboard or plastic.

In the textile industry, HEA is used for textile finishing.HEA is used in the textile industry for textile finishing. It can be used to impart special properties to fabrics.It can be used to give fabrics special properties. For example, it can be used in the synthesis of durable press finishes.It can be used to create durable press finishes. When applied to cotton or cotton - blend fabrics, HEA - containing polymers can react with the cellulose fibers.HEA-containing polymers can react when applied to cotton or cotton – blend fabrics. This cross - linking reaction reduces the wrinkling of the fabric when it is laundered or worn, giving the fabric a more presentable appearance.This cross-linking reaction reduces the wrinkles of the fabric during washing or wearing, giving it a more attractive appearance. Moreover, HEA can be used to introduce hydrophilic properties to hydrophobic fabrics.HEA is also useful for introducing hydrophilic properties into hydrophobic fabrics. The hydroxyl group in HEA attracts water molecules, making the fabric more absorbent, which is useful for sports and performance - based textiles.The hydroxyl group of HEA attracts molecules of water, which makes the fabric more absorbent. This is good for sports and performance-based textiles.

In the field of polymers and plastics, HEA is used as a monomer in copolymerization reactions.In the field polymers and plastics HEA is used in copolymerization. Copolymerizing HEA with other monomers like styrene or methyl methacrylate can modify the properties of the resulting polymers.The properties of polymers can be modified by copolymerizing HEA and other monomers such as styrene, methyl methacrylate or styrene. For example, it can improve the impact resistance and processability of plastics.It can, for example, improve the impact resistance of plastics and their processability. In the production of acrylic resins, HEA can be incorporated to enhance the resin's reactivity, solubility, and compatibility with other additives, leading to better - quality plastic products.HEA can enhance the reactivity, the solubility and the compatibility of acrylic resins with other additives. This will lead to better-quality plastic products.

Finally, in the biomedical field, HEA has potential applications.HEA also has potential applications in biomedical fields. Due to its relatively low toxicity and the presence of reactive groups, it can be used in the synthesis of biocompatible polymers.It can be used to synthesize biocompatible polymers due to its low toxicity and presence of reactive groups. These polymers can be used for drug delivery systems.These polymers are suitable for drug delivery systems. The hydroxyl group can be modified to attach drug molecules or targeting ligands.The hydroxyl groups can be modified to attach drugs molecules or targeting agents. Additionally, HEA - based polymers can be used in tissue engineering scaffolds, where their ability to form cross - linked structures and interact with cells can support cell growth and tissue regeneration.HEA-based polymers are also useful in tissue engineering scaffolds. Their ability to form cross-linked structures and interact directly with cells can promote cell growth and tissue regeneration.

What are the safety precautions when handling 2-Hydroxyethylacrylate?

2 - Hydroxyethyl acrylate is a chemical compound with certain reactivity and potential hazards.2 - Hydroxyethyl Acrylate is a chemical with a certain level of reactivity. It can also pose some potential hazards. Here are the safety precautions when handling it.Here are some safety precautions to take when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves, preferably made of materials like nitrile or neoprene, to prevent skin contact.Wear gloves made of materials such as nitrile, neoprene or other chemical-resistant materials to avoid skin contact. Skin exposure can lead to irritation, and in severe cases, may cause allergic reactions.Skin contact can cause irritation and, in some cases, allergic reactions. A full - body chemical - resistant suit should be worn in situations where there is a risk of splashing.In situations where there is the risk of splashing, a full-body chemical-resistant suit should be worn. This helps protect the entire body from potential contact with the chemical.This will protect the entire body against possible chemical contact. Also, safety goggles with side shields are essential to safeguard the eyes.Safety goggles with side-shields are also essential to protect the eyes. Even a small splash of 2 - Hydroxyethyl acrylate into the eyes can cause significant irritation, pain, and possible damage to the cornea.Even a small amount of 2 - Hydroxyethyl Acrylate in the eyes can cause irritation, pain and even damage to the cornea.

Second, ventilation is crucial.Ventilation is also crucial. When handling this substance, it should be done in a well - ventilated area, preferably under a fume hood.Handling this substance should be done in an area that is well-ventilated, preferably under a hood. 2 - Hydroxyethyl acrylate has a certain vapor pressure, and its vapors can be irritating to the respiratory system.The vapors of 2 - Hydroxyethyl Acrylate can be irritating to respiratory systems due to its high vapor pressure. Adequate ventilation helps to remove these vapors, reducing the risk of inhalation.Adequate ventilation can help remove these vapors and reduce the risk of inhalation. Inhalation of the vapors may cause coughing, shortness of breath, and irritation of the nose and throat.Inhaling the vapors can cause coughing, shortness in breath, and irritation to the nose and throat. In a poorly ventilated environment, the concentration of vapors can build up quickly, increasing the health risks.In an environment that is poorly ventilated, the concentration of vapors will quickly increase, increasing health risks.

Third, storage precautions.Third, storage precautions. Store 2 - Hydroxyethyl acrylate in a cool, dry place away from heat sources and direct sunlight.Store 2 - Hydroxyethyl Acrylate in a dry, cool place away from heat sources. Heat can accelerate its polymerization reaction, which can be dangerous as it may lead to an increase in pressure within the storage container.Heat can speed up the polymerization process, which is dangerous because it can lead to an increase of pressure in the storage container. Keep it away from oxidizing agents, as they can react violently with 2 - Hydroxyethyl acrylate.Keep it away oxidizing agents as they can react violently 2 - Hydroxyethyl Acrylate. Also, ensure that the storage containers are tightly sealed to prevent leakage and evaporation.Also, make sure that the containers are tightly closed to prevent leakage or evaporation.

Fourth, in case of accidental spills.Fourth, in the event of an accidental spill. Immediately evacuate the area if the spill is large.If the spill is large, evacuate the area immediately. For small spills, absorb the liquid with an appropriate absorbent material such as vermiculite or sand.If the spill is small, use an absorbent material like vermiculite or Sand to absorb the liquid. Do not use water to clean up the spill directly, as 2 - Hydroxyethyl acrylate is water - soluble and may spread the contamination.Avoid using water to clean the spill, as the 2 - Hydroxyethyl Acrylate is water-soluble and can spread contamination. After absorption, carefully place the contaminated absorbent in a suitable waste container for proper disposal according to local environmental regulations.After absorption, place the contaminated absorbent into a suitable waste container according to local environmental regulations.

Finally, emergency response training.Finally, emergency response education. All personnel who may come into contact with 2 - Hydroxyethyl acrylate should receive proper emergency response training.All personnel who could come into contact with 2-Hydroxyethyl-acrylate should receive emergency response training. They should know how to handle accidental exposures, such as flushing the eyes with plenty of water for at least 15 minutes in case of eye contact, and seeking immediate medical attention.They should be able to deal with accidental exposures such as flushing their eyes for at least 15 mins in the case of eye contact and seeking immediate medical assistance. In case of skin contact, the affected area should be washed thoroughly with soap and water.If skin contact occurs, the affected area must be thoroughly washed with soap and warm water. If inhalation occurs, move the person to fresh air and seek medical help if symptoms persist.Inhalation should be treated by moving the person to a fresh environment and seeking medical attention if symptoms persist.

What is the physical and chemical properties of 2-Hydroxyethylacrylate?

2 - Hydroxyethyl acrylate is an important monomer with distinct physical and chemical properties.Hydroxyethyl Acrylate is a monomer that has distinct physical and chemical characteristics.
Physical Properties

Appearance: It is usually a clear, colorless to slightly yellowish liquid.Appearance: It's usually a clear liquid that is colorless or slightly yellowish. This appearance makes it easily distinguishable in a laboratory or industrial setting.This makes it easy to distinguish in a laboratory setting or industrial environment. Its clarity allows for visual inspection of its purity and quality without the need for complex equipment in some cases.Its clarity makes it possible to visually inspect its purity and quality in some cases without the use of complex equipment.

Odor: It has a characteristic acrid and pungent odor.Odor: It emits a pungent and acrid smell. This strong smell serves as an important sensory cue.This strong smell is an important sensory cue. Workers handling the compound need to be aware of this odor as it can indicate potential exposure, and proper ventilation should be ensured to minimize inhalation of the vapors.Workers handling the compound should be aware of the smell as it can indicate exposure. Proper ventilation should be provided to minimize inhalation.

Boiling Point: The boiling point of 2 - Hydroxyethyl acrylate is around 190 - 192 degC at normal atmospheric pressure.Boiling point: The boiling temperature of 2 - Hydroxyethyl Acrylate is approximately 190-192 degC under normal atmospheric pressure. This relatively high boiling point means that it requires a significant amount of heat energy to convert from the liquid to the gaseous state.This high boiling point requires a large amount of heat energy in order to transform from a liquid to a gaseous state. This property is crucial in processes such as distillation, where separation from other substances with different boiling points can be achieved.This property is important in processes like distillation, which can separate substances with different boiling point.

Melting Point: It has a melting point in the range of -70 degC.Melting Point: The melting point is in the range -70 degC. The low melting point indicates that it remains in a liquid state under normal ambient temperatures, which is beneficial for its use in liquid - phase reactions and formulations.Its low melting point means that it remains liquid at normal ambient temperatures. This is ideal for liquid-phase reactions and formulations.

Solubility: It is soluble in many organic solvents such as ethanol, acetone, and toluene.Solubility: It's soluble in a variety of organic solvents, such as ethanol and acetone. This solubility in organic solvents broadens its application scope.Its solubility in organics solvents expands its application. For example, in the formulation of coatings and adhesives, it can be dissolved in these solvents to create homogeneous mixtures with other components.In the formulation of adhesives and coatings, for example, it can dissolve in these solvents in order to create homogeneous mixes with other components. Additionally, it is also slightly soluble in water.It is also slightly soluble with water. This partial water - solubility is due to the presence of the hydrophilic hydroxyl group in its molecular structure, which enables it to interact with water molecules to some extent.This partial water-solubility is due in part to the presence of a hydrophilic hydroxyl groups in its molecular structures, which allows it to interact to some extent with water molecules.

Chemical Properties

Reactivity: 2 - Hydroxyethyl acrylate is highly reactive due to the presence of the acrylate double bond and the hydroxyl group.Reactivity: Hydroxyethyl Acrylate is highly reactive because of the double bond acrylate and the hydroxyl groups. The acrylate double bond can participate in addition polymerization reactions.The acrylate double bonds can participate in additional polymerization reactions. This is the basis for its use in the production of polymers.This is why it can be used to produce polymers. For instance, it can polymerize with other acrylate monomers or co - monomers to form various types of polymers.It can, for example, polymerize with co-monomers or other acrylate monomers to produce various types of polymers. These polymers can have different properties depending on the co - monomers used and the polymerization conditions, such as being used in the manufacture of water - absorbent polymers, coatings with good adhesion properties, and thickening agents.These polymers have different properties depending upon the co-monomers used and the conditions of polymerization. For example, they can be used to manufacture water-absorbing polymers, coatings that adhere well, and thickening agents.

The hydroxyl group on 2 - Hydroxyethyl acrylate also endows it with reactivity.It is also reactive due to the hydroxyl group. It can participate in esterification reactions.It can be involved in esterification reactions. It can react with carboxylic acids or acid anhydrides to form esters.It can react to form esters with carboxylic acid or acid anhydrides. This property is useful in the synthesis of more complex organic compounds or in modifying the properties of polymers by introducing different functional groups through esterification reactions.This property can be used to synthesize more complex organic compounds, or to modify the properties of polymers through esterification reactions. In addition, the compound can undergo reactions with isocyanates, which is important in the production of polyurethane - based materials.The compound can also undergo reactions with isocyanates. This is important for the production of polyurethane-based materials. The hydroxyl group reacts with the isocyanate group to form urethane linkages, enabling the creation of materials with enhanced mechanical and chemical resistance properties.The hydroxyl group reacts to the isocyanate groups to form urethane links, enabling materials with enhanced mechanical resistance and chemical resistance.

How is 2-Hydroxyethylacrylate synthesized?

2 - Hydroxyethyl acrylate can be synthesized through the following main methods:The following methods are used to synthesize 2 - Hydroxyethyl Acrylate:
Esterification reaction between acrylic acid and ethylene oxideEsterification between acrylic acid and Ethylene Oxide

This is one of the most common synthesis routes.This is the most common way to synthesize acrylic acid. In this process, acrylic acid reacts with ethylene oxide.This process involves the reaction of acrylic acid with ethylene oxide. The reaction is usually catalyzed by specific catalysts.Usually, specific catalysts are used to catalyze the reaction. For example, Lewis acid catalysts like zinc chloride or some organic metal complexes can be used to promote the reaction.Lewis acid catalysts such as zinc chloride or certain organic metal complexes are useful for promoting the reaction.

The reaction mechanism is based on the electrophilic addition of the ethylene oxide to the carboxylic acid group of acrylic acid.The mechanism of the reaction is based on an electrophilic addition to the carboxylic acids of acrylic acid. First, the catalyst activates the ethylene oxide, making the epoxide ring more susceptible to nucleophilic attack.The catalyst first activates the ethylene dioxide, which makes the epoxide rings more susceptible to nucleophilic attacks. The carboxyl group of acrylic acid, which has a nucleophilic oxygen atom in the -OH part of the carboxyl group, attacks the less - substituted carbon atom of the ethylene oxide ring.The carboxyl of acrylic acid, with a nucleophilic atom of oxygen in the -OH portion of the carboxyl, attacks the less-substituted carbon atoms of the ethyleneoxide ring. This leads to the opening of the epoxide ring.This opens the epoxide rings. Subsequently, through a series of proton transfer steps, 2 - Hydroxyethyl acrylate is formed.Then, by a series of proton-transfer steps, 2 – Hydroxyethyl Acrylate is formed.

The reaction conditions need to be carefully controlled.The reaction conditions must be carefully controlled. The reaction temperature typically ranges from 50 - 100 degC.The reaction temperature is typically between 50 and 100 degC. If the temperature is too low, the reaction rate will be slow, and if it is too high, side reactions such as polymerization of acrylic acid or further reaction of the product might occur.If the temperature is low, the rate of reaction will be slow. If it is high, there may be side reactions, such as polymerization or further reaction of product. The molar ratio of acrylic acid to ethylene oxide also affects the reaction yield.The molar proportion of acrylic acid and ethylene oxide can also influence the reaction yield. Usually, a slight excess of acrylic acid is used to ensure the complete reaction of ethylene oxide and to minimize side reactions related to the self - reaction of ethylene oxide.A slight excess of the acrylic acid is usually used to ensure complete reaction of the ethylene oxide, and to minimize side effects related to the self-reaction of ethylene dioxide.

After the reaction, the product mixture may contain unreacted starting materials, catalyst residues, and possible by - products.After the reaction the product mixture can contain unreacted starter materials, catalyst residues and possible by-products. Purification steps are then required.Then, purification steps are required. Commonly, distillation is used to separate 2 - Hydroxyethyl acrylate from other components.Distillation is commonly used to separate the 2 - Hydroxyethyl Acrylate from other components. Since 2 - Hydroxyethyl acrylate has a specific boiling point, by carefully controlling the distillation temperature and pressure, the pure product can be obtained.By carefully controlling the temperature and pressure of the distillation, you can obtain the pure product.

Another method could be the reaction of acryloyl chloride with ethylene glycol.A reaction between acryloylchloride and ethylene glycol could also be used. However, this method has some drawbacks.This method is not without its drawbacks. Acryloyl chloride is a more reactive and corrosive substance compared to acrylic acid.Acryloyl Chloride is more reactive and corrosive than acrylic acid. The reaction with ethylene glycol needs to be carried out under strict anhydrous conditions to avoid hydrolysis of acryloyl chloride.To avoid hydrolysis, the reaction with ethylene-glycol must be carried out in anhydrous conditions. Also, the generation of hydrogen chloride gas as a by - product during the reaction requires proper handling to prevent environmental pollution and corrosion of equipment.The generation of hydrogen chloride as a reaction by-product requires careful handling to avoid environmental pollution and corrosion. So, the esterification of acrylic acid and ethylene oxide is more commonly used for the synthesis of 2 - Hydroxyethyl acrylate due to its relatively mild reaction conditions and better control over the reaction process.Due to its relatively mild conditions and better control of the reaction process, the esterification reaction of acrylic acid with ethylene oxide is used more often for the synthesis 2 - Hydroxyethyl Acrylate.

What are the storage requirements for 2-Hydroxyethylacrylate?

2 - Hydroxyethyl acrylate is a chemical compound that has specific storage requirements to ensure its safety and quality.2 - Hydroxyethyl Acrylate is a chemical compound with specific storage requirements for its safety and quality.
First, it should be stored in a cool, well - ventilated area.It should be stored in an area that is cool and well-ventilated. High temperatures can accelerate the polymerization process of 2 - Hydroxyethyl acrylate.High temperatures can speed up the polymerization of 2-hydroxyethylacrylate. The ideal storage temperature is usually in the range of 2 - 30degC.Ideal storage temperatures are usually between 2 and 30degC. Temperatures above this range may lead to self - polymerization, which not only ruins the product but can also pose a safety hazard, such as the generation of heat and pressure if the polymerization occurs in a closed container.Temperatures higher than this range can lead to self-polymerization. This not only destroys the product, but also poses a safety risk, as it can generate heat and pressure in a sealed container.

Secondly, the storage area must be away from sources of ignition, heat, and direct sunlight.Second, the storage area should be away from heat sources, open flames, and direct sunlight. As 2 - Hydroxyethyl acrylate is flammable, any source of ignition, like open flames, sparks from electrical equipment, or hot surfaces, can potentially cause a fire.Because 2 - Hydroxyethyl Acrylate is flammable and can cause a fire, any source of ignition such as open flames, sparks or hot surfaces could potentially cause a blaze. Direct sunlight can also increase the temperature of the stored product, promoting polymerization.Direct sunlight can also raise the temperature of the product being stored, causing it to polymerize.

It should be stored in tightly closed containers.Store it in tightly sealed containers. This is to prevent contact with air, especially oxygen.It is important to avoid contact with oxygen and air. Oxygen can react with 2 - Hydroxyethyl acrylate and initiate oxidation reactions, which may affect its chemical properties and quality.Oxygen can initiate oxidation reactions with 2-Hydroxyethyl Acrylate, which could affect its chemical properties. Additionally, a closed container helps to prevent the release of vapors, which are not only harmful if inhaled but also contribute to the flammability risk in the storage area.A closed container also helps prevent the release of vapors that are not only harmful to inhale but also contribute to flammability in the storage area.

When storing 2 - Hydroxyethyl acrylate, it is important to keep it separate from incompatible materials.It is important to store 2 - Hydroxyethyl Acrylate away from other materials. It should not be stored near strong oxidizing agents, bases, or acids.It should not be kept near strong acids, bases or oxidizing agents. Oxidizing agents can react vigorously with 2 - Hydroxyethyl acrylate, potentially leading to dangerous reactions.Oxidizing agents may react violently with 2-Hydroxyethyl Acrylate, causing potentially dangerous reactions. Bases and acids can also cause chemical changes in the compound, degrading its quality.Acids and bases can also cause chemical reactions in the compound that degrade its quality.

Proper labeling of the storage containers is crucial.Labeling the storage containers correctly is essential. The label should clearly indicate the name of the chemical, its hazards, and any special handling instructions.Labels should clearly state the name of the substance, its hazards and any special instructions. This helps to ensure that workers in the storage area are aware of the nature of the chemical and can take appropriate safety measures.This will help to ensure that the workers in the storage area know the nature of the chemicals and can take the appropriate safety measures.

Finally, regular inspections of the storage area and the containers are necessary.It is important to inspect the storage area as well as the containers regularly. Check for any signs of leakage, swelling of containers, or unusual odors.Check for signs of leakage or swelling of the containers. Also, check for unusual odors. Leakage can not only waste the product but also create a safety hazard.Leakage not only wastes the product, but can also be a safety risk. Swelling of containers may indicate an internal reaction, such as polymerization, which requires immediate attention.Containers that swell may indicate an internal reaction such as polymerization which requires immediate attention.