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Product Name | Diethyleneglycol dimethacrylate |
Cas Number | 2358-84-1 |
Formula | C12H20O4 |
Molar Mass | 228.29 |
Boiling Point | 235-240 °C |
Density | 1.065 g/mL |
Refractive Index | 1.45 |
Flash Point | >110 °C |
Viscosity | 15-25 cP at 25°C |
Solubility | Insoluble in water |
Appearance | Colorless liquid |
Odor | Characteristic |
Vapor Pressure | <0.1 mmHg at 20°C |
Autoignition Temperature | Not applicable |
Stability | Stable under recommended storage conditions |
What are the applications of diethyleneglycol dimethacrylate?
Diethyleneglycol dimethacrylate (DEGDMA) has a wide range of applications across different industries.Diethyleneglycol Dimethacrylate has many applications in different industries.
In the dental field, DEGDMA is a crucial component in dental composites.DEGDMA is an important component of dental composites. Dental composites are used for filling cavities and restoring teeth.Dental composites can be used to fill cavities and restore teeth. DEGDMA helps in cross - linking the polymer matrix of these composites.DEGDMA is used to cross-link the polymer matrix in these composites. It improves the mechanical properties of the dental materials, such as hardness, wear resistance, and compressive strength.It improves mechanical properties such as hardness and wear resistance of dental materials. This ensures that the dental fillings can withstand the forces exerted during chewing and have a long - lasting performance.This ensures the dental fillings are able to withstand the forces of chewing, and perform for a long time. Additionally, its ability to participate in polymerization reactions allows for precise shaping and curing of the dental restorations within the oral cavity.Its ability to participate in polymerization reaction allows for precise shaping of dental restorations and curing within the oral cavity.
In the production of polymers and plastics, DEGDMA is used as a cross - linking agent.DEGDMA acts as a cross-linking agent in the production of plastics and polymers. Cross - linking is essential for enhancing the physical and chemical properties of polymers.Cross-linking is crucial for improving the physical and chemistry properties of polymers. When added to a polymer system, DEGDMA forms covalent bonds between polymer chains.When DEGDMA is added to a system of polymers, it forms covalent bonds. This results in a three - dimensional network structure.This creates a three-dimensional network structure. Polymers cross - linked with DEGDMA exhibit increased chemical resistance, higher heat stability, and better mechanical integrity.Cross-linked polymers with DEGDMA have improved chemical resistance, heat stability and mechanical integrity. For example, in the manufacturing of engineering plastics, this can lead to components that can endure harsh environmental conditions, high temperatures, and mechanical stress.In the manufacture of engineering plastics for example, this can result in components that can withstand harsh environmental conditions, temperatures, and mechanical stresses.
In the area of coatings, DEGDMA plays a significant role.DEGDMA is a key player in the coatings industry. It is used to formulate high - performance coatings.It is used in the formulation of high-performance coatings. These coatings can be applied to various substrates, including metals, plastics, and wood.These coatings are suitable for use on a variety of substrates including metals and plastics. In coatings, DEGDMA helps to improve adhesion to the substrate, film formation, and hardness of the cured coating.DEGDMA is used in coatings to improve adhesion, film formation and hardness. It enables the formation of a durable and protective layer that can resist abrasion, corrosion, and chemical attack.It helps to form a durable, protective layer that is resistant to abrasions, corrosion and chemical attacks. For instance, in automotive coatings, DEGDMA - containing formulations can provide a glossy and long - lasting finish that protects the car body from environmental damage.DEGDMA-containing formulations in automotive coatings can provide a glossy, long-lasting finish that protects car bodies from environmental damage.
In the synthesis of ion - exchange resins, DEGDMA is utilized.DEGDMA is used in the synthesis process of ion-exchange resins. Ion - exchange resins are important in water treatment processes, such as softening hard water and removing contaminants.Ion-exchange resins are used in water treatment processes such as softening and removing contaminants. DEGDMA is used to create the cross - linked structure of these resins.The cross-linked structure of these resins is created using DEGDMA. This cross - linking affects the porosity and ion - exchange capacity of the resins.This cross-linking affects the porosity of the resins and their ion-exchange capacity. By controlling the amount of DEGDMA in the synthesis, the properties of the ion - exchange resins can be tailored to meet specific water treatment requirements.By controlling the amount DEGDMA used in the synthesis of the resins, properties can be tailored to specific water treatment needs.
Finally, in the field of 3D printing, DEGDMA can be part of the resin formulations.DEGDMA is also a part of resin formulations in 3D printing. It contributes to the polymerization and cross - linking of the printed structures during the 3D printing process.It helps to polymerize and cross-link the printed structures in the 3D printing process. This allows for the creation of complex and precise 3D objects with good mechanical properties.This allows the creation of complex, precise 3D objects that have good mechanical properties. The ability of DEGDMA to rapidly cross - link under appropriate light or heat sources is beneficial for the efficient production of 3D - printed parts.DEGDMA's ability to cross-link rapidly under appropriate light or heating sources is beneficial for efficient production of 3D-printed parts.
What are the properties of diethyleneglycol dimethacrylate?
Diethyleneglycol dimethacrylate has several notable properties.Diethyleneglycol Dimethacrylate is a chemical with several interesting properties.
Physical properties:Physical Properties
It is a colorless to slightly yellow liquid at room temperature.At room temperature, it is a colorless or slightly yellow liquid. It has a characteristic odor.It has a characteristic smell. Regarding its solubility, it is sparingly soluble in water but shows good solubility in many organic solvents such as ethanol, acetone, and toluene.It is only sparingly soluble, but it is soluble in many organic solvents, such as ethanol and acetone. This solubility behavior is important as it allows for its incorporation into various organic - based formulations.This solubility is important because it allows its incorporation in various organic-based formulations. Its density is around 1.05 g/cm3, which is relatively close to that of water but slightly higher.Its density is approximately 1.05 g/cm3, which resembles water but is slightly higher. This density influences its handling and mixing in different processes.Its density affects its handling and mixing during different processes.
Chemical properties:Chemical properties
Diethyleneglycol dimethacrylate contains two methacrylate groups. These double - bond - containing groups are highly reactive, making it a key monomer in polymerization reactions.These double-bond - containing group are highly reactive and make it a key polymerization reaction. It can participate in free - radical polymerization.It can participate in the free - radical process of polymerization. When initiated, for example, by a free - radical initiator like benzoyl peroxide, the double bonds open up and link together to form long - chain polymers.When initiated by a free-radical initiator such as benzoyl - peroxide, double bonds are opened and linked together to form long-chain polymers. This ability to polymerize rapidly is crucial in applications such as the production of dental composites and some types of coatings.This ability to polymerize quickly is critical in applications like the production of dental composites or certain types of coatings. The resulting polymers are cross - linked due to the presence of two reactive sites per molecule.Due to the presence two reactive sites in each molecule, the resulting polymers will be cross-linked. Cross - linking imparts enhanced mechanical strength, chemical resistance, and thermal stability to the final polymer product.The final polymer product is strengthened by cross-linking. It also has improved chemical resistance and thermal stability.
The ester linkages in diethyleneglycol dimethacrylate also play a role in its chemical behavior.The ester links in diethyleneglycol Dimethacrylate play a part in its chemical behaviour. Although they are relatively stable under normal conditions, they can be hydrolyzed under acidic or basic conditions over time.They are relatively stable in normal conditions but can hydrolyze over time under acidic or base conditions. However, the rate of hydrolysis is relatively slow compared to some other esters, which allows for its use in many applications where long - term chemical stability is required.The rate of hydrolysis, however, is relatively low compared to other esters. This allows it to be used in many applications that require long-term chemical stability.
Thermal properties:Thermal properties
The monomer has a relatively high boiling point, typically around 280 - 290 degC.Monomer has a high boiling point. It is usually around 280-290 degrees Celsius. This high boiling point makes it suitable for processes that involve heating, as it does not vaporize easily.This high boiling point is ideal for processes that require heating as it does not easily vaporize. In its polymerized form, the cross - linked nature of the polymer provides good thermal stability.The cross-linked nature of the polymer in its polymerized state provides good thermal stability. The polymer can withstand relatively high temperatures before significant degradation occurs, which is beneficial in applications such as high - temperature coatings or components in industrial settings where exposure to heat is common.The polymer is able to withstand relatively high temperature before significant degradation occurs. This is useful for applications such as high-temperature coatings or components used in industrial settings.
In summary, the combination of its physical, chemical, and thermal properties makes diethyleneglycol dimethacrylate a versatile monomer with wide - ranging applications in the polymer and materials science fields.Diethyleneglycol Dimethacrylate is a versatile monomer that has wide-ranging applications in polymer and materials science.
Is diethyleneglycol dimethacrylate harmful to human health?
Diethyleneglycol dimethacrylate is a chemical compound that can potentially be harmful to human health.Diethyleneglycol Dimethacrylate can be harmful to the human body.
Inhalation of its vapors can cause irritation to the respiratory system.Inhaling its vapors may cause irritation of the respiratory system. This may lead to symptoms such as coughing, shortness of breath, and a feeling of tightness in the chest.This can cause symptoms such as coughing and shortness of breathe, or a tightness in the chest. Prolonged or high - level exposure through inhalation could potentially cause more serious damage to the lungs, including inflammation and reduced lung function over time.Inhaling high-level exposure or prolonged exposure could cause lung damage, including inflammation and decreased lung function.
Skin contact with diethyleneglycol dimethacrylate can also be a problem.Contact with diethyleneglycol and dimethacrylate on the skin can be problematic. It may cause skin irritation, redness, itching, and in some cases, allergic reactions.It can cause skin irritation, redness and itching. In some cases, it may also cause allergic reactions. Allergic contact dermatitis can develop, which is an immune - mediated response.Allergic contact dermatitis, an immune-mediated response, can develop. Once the skin becomes sensitized, even small future exposures can trigger an allergic reaction.Even small exposures to allergens in the future can cause an allergic reaction once the skin has become sensitized.
Eye contact is another concern.Contact with the eyes is also a concern. If this chemical gets into the eyes, it can cause severe irritation, pain, redness, and potentially damage to the cornea.If this chemical gets in the eyes, it may cause severe irritation, pain and redness. It can also damage the cornea. Immediate and thorough rinsing of the eyes is crucial in case of such an exposure.In the event of an eye exposure, it is important to rinse your eyes immediately and thoroughly.
Ingestion of diethyleneglycol dimethacrylate is extremely dangerous.Ingestion of diethyleneglycol is dangerous. It can cause damage to the digestive tract, including nausea, vomiting, abdominal pain, and possible damage to internal organs such as the liver and kidneys.It can cause digestive problems, such as nausea, vomiting and abdominal pain. It may also damage internal organs, such as the kidneys and liver. Since it is not a substance meant to be ingested, even a small amount could have significant health consequences.It is not intended to be consumed, so even a small amount can have serious health consequences.
Furthermore, some studies have also suggested potential long - term health risks.Some studies have also indicated potential long-term health risks. There may be a concern regarding its mutagenic or carcinogenic potential.It may be that its carcinogenic or mutagenic potential is a cause for concern. Mutagenic substances can cause changes in DNA, which may lead to genetic disorders or an increased risk of cancer over time.Mutagenic substances may cause DNA changes that can lead to genetic disorders and an increased cancer risk over time. Although more research is needed to fully understand these long - term risks, the potential for such effects means that exposure to diethyleneglycol dimethacrylate should be minimized.Diethyleneglycol Dimethacrylate exposure should be minimized, even though more research is required to fully understand the long-term risks. Overall, due to these various potential health impacts, proper safety measures and handling procedures are essential when dealing with this chemical to protect human health.In order to protect human health, it is important to use proper safety procedures and follow the correct handling procedures when handling this chemical.
How is diethyleneglycol dimethacrylate synthesized?
Diethyleneglycol dimethacrylate is synthesized through an esterification reaction.Esterification is used to synthesize diethyleneglycol dimethacrylate. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
The starting materials for the synthesis of diethyleneglycol dimethacrylate are diethyleneglycol and methacrylic acid.Diethyleneglycol, and methacrylic acids are the starting materials in the synthesis diethyleneglycol dimethacrylate. First, appropriate amounts of diethyleneglycol and methacrylic acid are placed in a reaction vessel.In a reaction vessel, diethyleneglycol in the correct amounts is placed. To promote the esterification reaction, a catalyst is usually added.A catalyst is often added to promote the esterification. Commonly used catalysts include sulfuric acid, p - toluenesulfonic acid, etc.Catalysts are commonly used, such as sulfuric acid, and p-toluenesulfonic acids. These catalysts can increase the reaction rate by providing a favorable reaction environment for the formation of ester bonds.These catalysts can increase reaction rates by creating a favorable environment for ester bond formation.
During the reaction process, water is generated as a by - product.Water is produced as a by-product during the reaction process. To drive the reaction forward according to Le Chatelier's principle, it is necessary to remove the generated water.To move the reaction along according to Le Chatelier’s principle, the water generated must be removed. One common method is to use a Dean - Stark apparatus.The Dean-Stark apparatus is a common way to do this. This device can separate the water formed during the reaction from the reaction mixture, which helps to shift the equilibrium of the esterification reaction towards the formation of diethyleneglycol dimethacrylate.This device can separate water from the reaction mixture. This helps to shift equilibrium of the esterification reactions towards the formation diethyleneglycol Dimethacrylate.
The reaction is usually carried out under heating.The reaction is usually carried under heating. The reaction temperature needs to be carefully controlled.The temperature of the reaction must be carefully monitored. If the temperature is too low, the reaction rate will be slow, and if it is too high, side reactions may occur, such as polymerization of methacrylic acid or decomposition of the reactants and products.If the temperature is low, the rate of reaction will be slow. If it is high, side reactions, such as the polymerization or decomposition, of the reactants or products, may occur. Generally, the reaction temperature is in the range of about 80 - 120 degC.The reaction temperature ranges between 80 and 120 degC.
After the reaction is considered complete based on analysis methods such as gas chromatography to monitor the conversion rate of reactants, the reaction mixture needs to be post - treated.The reaction mixture must be treated after the reaction has been deemed complete using analysis methods like gas chromatography, which monitors the conversion rate of the reactants. This may involve neutralizing the catalyst.This may include neutralizing the catalyst. For example, if sulfuric acid is used as the catalyst, it can be neutralized with a base such as sodium carbonate.If sulfuric acid was used as a catalyst, it could be neutralized by a base like sodium carbonate. Then, the mixture is washed with water to remove the neutralized salts and other water - soluble impurities.The mixture is then washed in water to remove any neutralized salts or other water-soluble impurities.
Finally, the product can be purified by methods such as distillation.The product can also be purified using methods such as distillation. Diethyleneglycol dimethacrylate has a certain boiling point, and through distillation, it can be separated from unreacted starting materials, by - products, and other impurities to obtain relatively pure diethyleneglycol dimethacrylate.Diethyleneglycol Dimethacrylate is a liquid with a boiling point. Through distillation it can be separated from other impurities, unreacted materials, and by-products.
What safety precautions should be taken when handling diethyleneglycol dimethacrylate?
When handling diethyleneglycol dimethacrylate, several safety precautions must be taken.Diethyleneglycol Dimethacrylate must be handled with care.
First, personal protective equipment (PPE) is crucial.Personal protective equipment (PPE), or personal safety equipment, is essential. Wear appropriate chemical - resistant gloves, such as nitrile gloves.Wear gloves that are resistant to chemicals, such as nitrile. Diethyleneglycol dimethacrylate can come into contact with hands during handling, and gloves prevent skin absorption.Gloves prevent skin absorption of diethyleneglycol dimethacrylate, which can come into contact during handling. Skin contact may lead to irritation, redness, and possible allergic reactions over time.Skin contact can cause irritation, redness and allergic reactions. A lab coat or protective clothing should also be worn to safeguard the body from splashes.Wearing a lab coat or protective clothing will also protect the body from splashes. Additionally, safety goggles or a face shield are necessary to protect the eyes.Safety goggles and a face shield will also protect your eyes. If the chemical splashes into the eyes, it can cause severe damage, including corneal abrasions and potential vision impairment.If the chemical splashes in the eyes, it could cause severe damage including corneal abrasions or vision impairment.
Second, ensure proper ventilation. Diethyleneglycol dimethacrylate has a certain vapor pressure, and its vapors can be inhaled.The vapors of diethyleneglycol dimethacrylate can be inhaled because they have a certain pressure. Working in a well - ventilated area, preferably under a fume hood, helps to minimize the inhalation of these vapors.Inhalation of these vapors can be minimized by working in an area that is well-ventilated, preferably under a fumehood. Inhalation may cause respiratory tract irritation, coughing, and shortness of breath.Inhalation can cause irritation of the respiratory tract, coughing and shortness in breath. If the ventilation is poor, the concentration of the vapors in the air can build up, increasing the risk of health problems.Poor ventilation can increase the concentration of vapors, which can lead to health problems.
Third, storage should be carefully managed.Third, the storage of diethyleneglycol dimethacrylate should be managed carefully. Store diethyleneglycol dimethacrylate in a cool, dry place away from heat sources and ignition sources.Store diethyleneglycol Dimethacrylate away from heat and ignition sources in a cool and dry place. It is a flammable substance, and heat or an open flame can cause it to catch fire.It is flammable and can catch fire if exposed to heat or an open flame. Keep it in a container with a tight - fitting lid to prevent leakage and evaporation.Keep it in a container that has a tight-fitting lid to prevent leaking and evaporation. Also, store it separately from oxidizing agents, as a violent reaction may occur if they come into contact.Store it away from oxidizing agents as they can cause a violent reaction if in contact.
Fourth, in case of accidental spills, immediate action is required.In the event of an accidental spill, immediate action must be taken. First, evacuate the area to prevent others from being exposed to the spilled chemical.First, evacuate the affected area to avoid exposing others to the chemical. Then, use absorbent materials like sand or vermiculite to soak up the spill.Use absorbent materials such as sand or Vermiculite to soak the spill. Place the contaminated absorbent in a proper waste container for disposal according to local regulations.Place the contaminated absorbent into a waste container that is in compliance with local regulations. Clean the spill area thoroughly to remove any remaining traces of the chemical.To remove all traces of chemical, thoroughly clean the spilled area.
Finally, be familiar with first - aid procedures.Be familiar with the first-aid procedures. In case of skin contact, immediately wash the affected area with plenty of soap and water for at least 15 minutes.In the event of skin contact, wash the affected area immediately with soap and water. This should be done for at least 15 min. For eye contact, flush the eyes with copious amounts of water for 15 minutes and seek medical attention promptly.If you have eye contact, flush your eyes with plenty of water for at least 15 minutes. Seek medical attention immediately. If inhaled, move the person to fresh air and call for medical help if breathing difficulties persist.If inhaled by the person, move them to fresh air. Call for medical assistance if breathing problems persist. If ingested, do not induce vomiting unless directed by a medical professional, and seek immediate medical assistance.If ingested do not induce vomiting without the direction of a medical professional. Seek immediate medical attention.