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Glycerol 1,3-dimethacrylate


Properties
Product Name Glycerol 1,3-dimethacrylate
Cas Number 1830-78-0
Formula C11H16O4
Molar Mass 212.24
Property1 Boiling point: 335 °C
Property2 Melting point: -30 °C
Property3 Density: 1.06 g/cm³
Property4 Solubility in water: Not soluble
Property5 Flash point: 150 °C
Property6 Refractive index: 1.473
Property7 Viscosity: 7 mPa·s
Property8 Appearance: Colorless liquid
Property9 Vapor pressure: 0.1 mmHg at 20 °C
Property10 Surface tension: 30 mN/m at 20 °C
FAQ

What is the application of Glycerol 1%2C3-dimethacrylate?

Glycerol 1,3 - dimethacrylate has several important applications.Glycerol 1,3-dimethacrylate is used in a variety of applications.
In the field of polymer chemistry, it is often used as a cross - linking agent.It is used in polymer chemistry as a cross-linking agent. When incorporated into a polymer system, it can form covalent bonds between polymer chains.When it is incorporated into a system of polymers, it can create covalent bonds between polymer chain. This cross - linking process can enhance the mechanical properties of the resulting polymers.This cross-linking process can improve the mechanical properties of polymers. For example, in the production of dental polymers, glycerol 1,3 - dimethacrylate helps to improve the hardness, wear resistance, and durability of dental restorative materials.In the production of dental materials, glycerol dimethacrylate can improve hardness, wear resistance and durability. It allows the polymer network to better withstand the mechanical forces exerted during chewing and oral functions.It allows the network of polymers to better withstand mechanical forces during chewing or oral functions.

In the area of hydrogels, this compound plays a crucial role.This compound is crucial in the field of hydrogels. Hydrogels are three - dimensional polymer networks that can absorb and retain large amounts of water.Hydrogels are polymer networks in three dimensions that can absorb large amounts of moisture. Glycerol 1,3 - dimethacrylate can be used to cross - link hydrophilic polymers to form hydrogels.Hydrogels can be formed by using Glycerol 1,3-dimethacrylate to cross-link hydrophilic polymers. These hydrogels have applications in wound dressings.These hydrogels are used in wound dressings. They can provide a moist environment for wound healing, adhere to the wound surface, and due to the cross - linking by glycerol 1,3 - dimethacrylate, maintain their structural integrity during use.These hydrogels can be used to provide a moist healing environment, adhere to the surface of the wound, and maintain their structural integrity when in use due to the cross-linking by glycerol, 1,3-dimethacrylate.

It is also utilized in the synthesis of specialty coatings.It is also used in the synthesis for specialty coatings. By including glycerol 1,3 - dimethacrylate in coating formulations, the coating can develop a cross - linked structure upon curing.When glycerol dimethacrylate is added to coating formulations, it can create a cross-linked structure. This leads to improved resistance to abrasion, chemicals, and weathering.This results in improved resistance to abrasions, chemicals, and weathering. Such coatings can be applied to various substrates, like metals, plastics, and wood, protecting them from environmental degradation and enhancing their aesthetic appearance.These coatings can be applied on a variety of substrates including metals, wood, and plastics. They protect them from environmental degradation, while also improving their aesthetic appearance.

In addition, in some advanced materials research, glycerol 1,3 - dimethacrylate is used to create porous polymers.In some advanced materials research, glycerol dimethacrylate 1,3 is also used to create porous Polymers. The cross - linking it promotes can be combined with appropriate porogen agents to fabricate materials with controlled pore structures.The cross-linking it promotes can also be combined with appropriate porogens to fabricate materials that have controlled pore structure. These porous polymers find applications in areas such as chromatography, where the pores can facilitate the separation of different chemical components based on their size and affinity.These porous polymers are used in areas like chromatography where the pores allow for the separation of chemical components according to their size and affinity. Overall, glycerol 1,3 - dimethacrylate is a versatile compound with diverse applications across multiple industries.Glycerol 1,3-dimethacrylate, as a versatile compound, has many applications in multiple industries.

What are the properties of Glycerol 1%2C3-dimethacrylate?

Glycerol 1,3 - dimethacrylate has several notable properties.Glycerol 1,3-dimethacrylate is a chemical with several interesting properties.
First, in terms of its chemical structure, it contains two methacrylate groups attached to a glycerol backbone.Its chemical structure is composed of two methacrylate groups that are attached to a backbone of glycerol. This structure endows it with unique reactivity.Its unique structure gives it a high level of reactivity. The methacrylate groups are highly reactive double - bond - containing moieties.The methacrylate moieties are highly reactive, double-bond containing moieties. They can participate in polymerization reactions, particularly radical - initiated polymerization.They can participate in polymerization, especially radical-induced polymerization. This allows glycerol 1,3 - dimethacrylate to be incorporated into polymer networks.This allows glycerol dimethacrylate 1,3 to be incorporated in polymer networks. For example, when exposed to a suitable initiator such as a radical initiator like benzoyl peroxide, the double bonds can break and form long - chain polymers.When exposed to a suitable radical initiator, such as benzoylperoxide, double bonds can break, forming long-chain polymers.

In terms of physical properties, glycerol 1,3 - dimethacrylate is typically a viscous liquid at room temperature.Physically, glycerol dimethacrylate 1,3 is a viscous fluid at room temperature. Its viscosity is influenced by factors such as temperature.Temperature is one factor that influences its viscosity. As the temperature increases, the viscosity decreases, making it more fluid.As the temperature increases the viscosity will decrease, making the fluid more fluid. This property is important in processing applications, for instance, when it needs to be mixed with other monomers or additives.This property is crucial in processing applications. For example, when it has to be mixed with monomers or additives.

It has a relatively high boiling point due to the presence of polar groups in its structure.It has a high boiling point because of the presence polar groups. The glycerol part contains hydroxyl groups which can form hydrogen bonds, and the methacrylate groups also contribute to intermolecular forces.The glycerol component contains hydroxyl groups that can form hydrogen bonding, and the methacrylate group also contributes to intermolecular force. This high boiling point means that it is stable under normal ambient conditions and does not evaporate easily.This high boiling point indicates that it is stable in normal ambient conditions, and does not easily evaporate.

Glycerol 1,3 - dimethacrylate is also soluble in many organic solvents.Glycerol 1,3-dimethacrylate can also be dissolved in many organic solvents. It can dissolve in common solvents like acetone, toluene, and ethyl acetate.It can dissolve in common organic solvents such as acetone, ethyl-acetate, and toluene. This solubility property is beneficial for formulating solutions for coating applications or for preparing pre - polymer mixtures.This property makes it easy to formulate solutions for coating applications, or to prepare pre-polymer mixtures.

In terms of its use - related properties, it can improve the cross - linking density in polymers.It can improve the cross-linking density of polymers. When incorporated into a polymer system, the two reactive methacrylate groups can bridge different polymer chains, enhancing the mechanical properties of the resulting polymer.The two reactive methacrylate chains can bridge different polymer chain lengths when incorporated into a system of polymers, improving the mechanical properties. For example, it can increase the hardness, tensile strength, and chemical resistance of the polymer.It can, for example, increase the polymer's hardness, tensile resistance, and chemical resistance. Additionally, due to the glycerol moiety, it can introduce some flexibility and hydrophilicity into the polymer network, which can be useful in applications where water - interaction or a certain degree of flexibility is required, such as in some biomedical or dental polymers.The glycerol moiety can also introduce flexibility and hydrophilicity to the polymer network. This can be useful for applications that require a certain amount of flexibility or water-interaction, such as some biomedical polymers or dental polymers.

How is Glycerol 1%2C3-dimethacrylate synthesized?

Glycerol 1,3 - dimethacrylate can be synthesized through the following general steps:The following general steps can be used to synthesize Glycerol 1,3-dimethacrylate:
1. Starting materials preparationStart materials preparation
The main starting materials are glycerol and methacrylic acid.Glycerol is the main starting material, followed by methacrylic acids. Glycerol is a common polyol, readily available from various sources such as the hydrolysis of fats and oils.Glycerol, a polyol that is readily available through various sources including the hydrolysis or fats and oils, is a common polyol. Methacrylic acid is an unsaturated carboxylic acid.Methacrylic Acid is an unsaturated carboxylic. These materials need to be of high purity to ensure a good - quality product.To ensure high-quality products, these materials must be highly pure. Methacrylic acid may need to be purified by distillation to remove inhibitors and other impurities before use.It may be necessary to purify the methacrylic acid by distillation in order to remove inhibitors or other impurities.

2. Esterification reaction
The synthesis typically involves an esterification reaction between glycerol and methacrylic acid.This reaction is usually a esterification between glycerol methacrylic acid. A catalyst is usually required to accelerate this reaction.A catalyst is required to speed up this reaction. Sulfuric acid is a commonly used catalyst for esterification reactions.Sulfuric acids are commonly used as catalysts for esterification reactions. However, it can cause side - reactions such as dehydration and charring.It can cause side-reactions such as dehydration or charring. To avoid these issues, more selective catalysts like p - toluenesulfonic acid can be used.To avoid these problems, more selective catalysers like p-toluenesulfonic acids can be used.
The reaction is carried out in a suitable reaction vessel, often under reflux conditions.The reaction takes place in a suitable vessel, usually under conditions of reflux. The mixture of glycerol, methacrylic acid, and the catalyst is heated.The mixture of methacrylic and glycerol is heated. The reaction equation can be simply described as: glycerol + 2 methacrylic acid - glycerol 1,3 - dimethacrylate + 2 water.The reaction equation is: glycerol, 2 methacrylic acids, glycerol dimethacrylate and 2 water. During the reaction, water is produced as a by - product.Water is produced during the reaction. To drive the reaction forward according to Le Chatelier's principle, the water needs to be removed.Water must be removed from the reaction mixture to drive it forward in accordance with Le Chatelier’s principle. This can be achieved by using a Dean - Stark apparatus, which allows the separation of water from the reaction mixture while returning the organic components back to the reaction vessel.This can be done by using a Dean-Stark apparatus that allows water to be separated from the reaction mixture, while returning the organic ingredients back to the reaction vessel.

3. Inhibitor addition and purificationAddition and purification of inhibitors
Since the product, glycerol 1,3 - dimethacrylate, contains double bonds, it is prone to polymerization during storage and handling.Due to the presence of double bonds in glycerol dimethacrylate (glycerol 1,3-dimethacrylate), it is susceptible to polymerization when stored and handled. To prevent this, an inhibitor such as hydroquinone monomethyl ether (MEHQ) is added.In order to prevent this, an additive such as hydroquinone Monomethyl Ether (MEHQ) can be added. After the reaction is complete, the product needs to be purified.Purification is required after the reaction has been completed. Purification methods can include washing with water to remove the catalyst and any unreacted methacrylic acid, followed by extraction with an organic solvent such as diethyl ether.Purification can be achieved by washing the product with water, removing the catalyst and unreacted methacrylic acids. This is followed by extraction using an organic solvent like diethylether. The organic layer is then dried over anhydrous sodium sulfate to remove any remaining water.The organic layer is dried over anhydrous Sodium Sulfate in order to remove any remaining moisture. Finally, the solvent is removed by distillation under reduced pressure to obtain the pure glycerol 1,3 - dimethacrylate product.The solvent is then removed by distillation at reduced pressure, resulting in the pure 1,3-dimethacrylate glycerol.

What are the safety precautions when handling Glycerol 1%2C3-dimethacrylate?

Glycerol 1,3 - dimethacrylate is a chemical compound that requires certain safety precautions during handling.Glycerol 1,3-dimethacrylate is an organic compound that must be handled with care.
Firstly, personal protective equipment is crucial.Personal protective equipment is essential. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a barrier against the chemical, protecting the skin from contact which could lead to irritation or potential absorption.Nitrile gloves can be a good option as they provide a barrier to the chemical and protect the skin from any contact that could cause irritation or absorption. Additionally, safety goggles should be worn at all times.Safety goggles must also be worn at any time. This compound can cause eye irritation, and getting it in the eyes could lead to serious damage, so goggles ensure that any splashes or accidental sprays are deflected away from the eyes.Goggles are essential to deflect any accidental splashes and sprays away from the eyes. This compound can cause irritation of the eyes, and if it gets into the eyes, serious damage could result. A lab coat or other protective clothing should also be donned to prevent the chemical from coming into contact with regular clothing and skin.Wearing a lab coat or other protective clothing will also prevent the chemical from contacting clothing and skin.

Secondly, proper ventilation is essential. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably with a fume hood. Glycerol 1,3 - dimethacrylate may emit vapors that can be harmful if inhaled.Inhaling vapors from Glycerol 1,3-dimethacrylate can be harmful. In a fume hood, the air is constantly being exhausted, removing these potentially harmful vapors from the breathing zone.In a fume-hood, the air is constantly exhausted, removing potentially harmful vapors. If a fume hood is not available, ensure that the room has good general ventilation, with fans or open windows to keep the air circulating.If a fume-hood is not available, make sure that the room is well ventilated, with fans or windows open to circulate the air.

Thirdly, be cautious about storage.Thirdly, you should be careful about storage. Store glycerol 1,3 - dimethacrylate in a cool, dry place away from heat sources and open flames.Store glycerol, 1,3-dimethacrylate in an area that is cool and dry away from heat sources or open flames. It is a flammable compound, and heat or a spark could potentially ignite it.It is a flammable substance, and heat or sparks could ignite it. Keep it in a container that is tightly sealed to prevent evaporation and leakage.Store it in a tightly sealed container to prevent evaporation or leakage. Also, store it separately from incompatible substances such as strong oxidizing agents, as they can react violently with glycerol 1,3 - dimethacrylate.Store it away from other substances that can react violently, such as strong oxidizing chemicals.

Fourthly, in case of accidental contact, know the proper first - aid procedures.In the event of accidental contact, you should know how to administer first aid. If it comes into contact with the skin, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If it gets on your skin, wash the area immediately with soap and water. If it gets in the eyes, rinse them thoroughly with water for at least 15 minutes and seek immediate medical attention.If it gets into the eyes, wash them thoroughly for at least 15 minute with water and seek immediate medical help. If inhaled, move to fresh air and get medical help if breathing difficulties persist.If you inhaled it, get medical attention if you have breathing problems. In case of ingestion, do not induce vomiting unless instructed by a medical professional, and seek emergency medical treatment right away.In the event of ingestion, you should not induce vomiting without medical advice. Seek immediate medical attention.

Finally, always follow proper handling procedures in the laboratory or workplace.Always follow the correct handling procedures, whether in a laboratory or at work. Read and understand the safety data sheet (SDS) for glycerol 1,3 - dimethacrylate before use.Before using, read and understand the safety information sheet (SDS). The SDS contains detailed information about the chemical's hazards, safety precautions, and first - aid measures.The SDS provides detailed information on the hazards of the chemical, safety precautions and first-aid measures. Be careful when measuring, transferring, or disposing of the compound to avoid spills and ensure that all waste is disposed of according to local regulations.Avoid spills by being careful when measuring, moving or disposing the compound.

What are the storage requirements for Glycerol 1%2C3-dimethacrylate?

Glycerol 1,3 - dimethacrylate is a chemical compound with specific storage requirements to maintain its quality and safety.Glycerol 1,3-dimethacrylate, a chemical compound, has specific storage requirements for maintaining its quality and safety.
Firstly, it should be stored in a cool environment.It should be kept in a cool place. High temperatures can accelerate chemical reactions, potentially leading to polymerization or degradation of the compound.High temperatures can speed up chemical reactions and lead to polymerization and degradation of the compound. A storage temperature preferably below 25 degrees Celsius helps to slow down any unwanted chemical changes.Storage temperatures below 25 degrees Celsius are best to help slow down unwanted chemical changes. For instance, storing it in a temperature - controlled warehouse or a cool storage area within a laboratory can ensure its stability.Store it in a temperature-controlled warehouse or a cool area within a lab to ensure its stability.

Secondly, it must be kept away from direct sunlight.Second, it should be kept out of direct sunlight. Ultraviolet (UV) light from sunlight can initiate photochemical reactions in glycerol 1,3 - dimethacrylate.The ultraviolet (UV) light of sunlight can trigger photochemical reactions in the glycerol dimethacrylate. These reactions can cause the formation of radicals, which may trigger polymerization.These reactions can lead to the formation of radicals that may trigger polymerization. Storing it in opaque containers or in a dark room can prevent exposure to UV light.Avoid UV exposure by storing it in opaque containers and in a dark environment.

Thirdly, the storage area should be dry.Thirdly, it is important that the storage area be dry. Moisture can react with glycerol 1,3 - dimethacrylate.Moisture can react glycerol dimethacrylate. Water can hydrolyze the ester groups present in the compound, changing its chemical structure and properties.Water can hydrolyze ester groups in the compound and change its chemical structure. Ensuring a relative humidity of less than 60% in the storage environment is advisable.It is recommended to maintain a relative humidty of less than 60 % in the storage area. This can be achieved through the use of desiccants in the storage containers or by having proper ventilation and dehumidification systems in the storage area.This can be achieved by using desiccants inside the storage containers, or by installing dehumidifiers and ventilation systems in the area.

Fourthly, the storage containers should be carefully selected.The fourth thing to consider is the choice of storage containers. It is best to use containers made of materials that are chemically inert towards glycerol 1,3 - dimethacrylate.It is best to choose containers made from materials that are chemically non-reactive with glycerol, 1,3 – dimethacrylate. Glass or certain types of high - density polyethylene (HDPE) containers are often suitable.Glass or certain types high-density polyethylene (HDPE), are often suitable. The containers should be tightly sealed to prevent evaporation of the compound and to keep out contaminants such as air, moisture, and dust.Containers should be tightly sealed in order to prevent evaporation and keep out contaminants like air, moisture and dust.

Finally, it is crucial to store glycerol 1,3 - dimethacrylate away from sources of ignition and oxidizing agents.Store glycerol dimethacrylate far away from ignition sources and oxidizing agents. As it is an organic compound, it is potentially flammable.It is flammable because it is an organic compound. Oxidizing agents can react violently with it, leading to dangerous situations.Oxidizing agents may react violently, resulting in dangerous situations. By following these storage requirements, the integrity of glycerol 1,3 - dimethacrylate can be maintained for an extended period, which is essential for its proper use in various applications such as in the production of polymers, dental materials, and coatings.By following these storage instructions, the integrity and longevity of glycerol, 1,3-dimethacrylate is extended. This is important for its use in various applications, such as the production of dental materials, coatings, and polymers.