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Product Name | Glycidyl acrylate |
Cas Number | 106-90-1 |
Formula | C6H8O3 |
Molar Mass | 128.13 g/mol |
Boiling Point | 189 °C |
Density | 1.100 g/cm3 |
Refractive Index | 1.449 |
Viscosity | 1.6 mPa·s at 25 °C |
Flash Point | 75 °C |
Appearance | Clear liquid |
Odor | Acrylate odor |
Solubility | Slightly soluble in water |
Vapor Pressure | 0.17 mmHg at 25 °C |
Autoignition Temperature | 315 °C |
What is the main application of glycidyl acrylate?
Glycidyl acrylate is an important monomer with various applications.Glycidyl Acrylate is a monomer that has many applications.
One of the main applications is in the field of coatings.Coatings is one of the most common applications. It is used to formulate high - performance coatings.It is used in the formulation of high-performance coatings. In epoxy - acrylate coatings, glycidyl acrylate can participate in the cross - linking reaction.In epoxy-acrylate coatings, the glycidyl-acrylate can be used to participate in the reaction of cross-linking. The epoxy group in glycidyl acrylate can react with other functional groups such as carboxyl groups, hydroxyl groups, etc.The epoxy group of glycidylacrylate can react to other functional groups like carboxyl groups or hydroxyl groups. This cross - linking process improves the hardness, abrasion resistance, and chemical resistance of the coatings.This cross-linking process increases the coatings' hardness, chemical resistance, and abrasion resistance. For example, in industrial coatings for metal substrates like automotive parts or machinery components, these enhanced properties are crucial to protect the underlying metal from corrosion and wear.These enhanced properties are important in industrial coatings that protect metal substrates such as automotive parts or machinery components from corrosion and wear.
In the adhesive industry, glycidyl acrylate also plays a significant role.Glycidyl Acrylate is also a key ingredient in the adhesive industry. It can be incorporated into adhesive formulations to improve the adhesion strength.It can be added to adhesive formulations to increase adhesion. The epoxy group has the ability to react with polar surfaces, such as those of metals, ceramics, and some plastics.The epoxy group can react with polar surfaces such as metals, ceramics and some plastics. By forming chemical bonds with these surfaces, the adhesive becomes more firmly attached.The adhesive is more strongly attached by forming chemical bonds. This is especially useful in structural adhesives, where a high - strength and durable bond is required.This is particularly useful in structural glues where a strong and durable bond is needed. For instance, in the assembly of aerospace components, adhesives containing glycidyl acrylate can provide reliable bonding, reducing the need for mechanical fasteners and thus potentially saving weight.Adhesives containing glycidyl acrylicate, for example, can be used to bond aerospace components without the use of mechanical fasteners, potentially saving weight.
Another important application area is in the production of polymers and copolymers.The production of copolymers and polymers is another important application. Glycidyl acrylate can be copolymerized with other monomers.Glycidyl Acrylate can be copolymerized. For example, when copolymerized with vinyl monomers, it can introduce epoxy functionality into the polymer chain.When copolymerized, it can introduce epoxy functionality to the polymer chain. These copolymers have unique properties.These copolymers possess unique properties. They can be used in the manufacture of engineering plastics, where the epoxy groups can be further cross - linked to enhance the mechanical properties of the plastic.These copolymers can be used to manufacture engineering plastics where the epoxy groups are further cross-linked to enhance the mechanical property of the plastic. In addition, in the production of ion - exchange resins, glycidyl acrylate - based polymers can be modified to have ion - exchange capabilities.Glycidylacrylate-based polymers are also capable of being modified to provide ion-exchange capabilities in the production ion-exchange resins. The epoxy group can be reacted with appropriate reagents to introduce ionic groups, which are useful for applications such as water purification, where the resin can selectively remove certain ions from the water.The epoxy group can react with appropriate reagents in order to introduce ionic ions. This is useful for applications like water purification where the resin can remove certain ions selectively.
Overall, glycidyl acrylate's unique chemical structure, with both the acrylate double bond and the epoxy group, makes it a versatile compound in coatings, adhesives, and polymer - related industries.Glycidyl Acrylate is a versatile compound because of its unique chemical structure. It has both the acrylate and epoxy groups.
How is glycidyl acrylate synthesized?
Glycidyl acrylate is synthesized through an esterification reaction between acrylic acid and epichlorohydrin.Glycidyl Acrylate is produced by an esterification between acrylic acid, and epichlorohydrin. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
First, the raw materials acrylic acid and epichlorohydrin are prepared.First, the raw materials epichlorohydrin and acrylic acid are prepared. Appropriate amounts of these two substances are measured according to the reaction stoichiometry.The reaction stoichiometry is used to determine the appropriate amounts of these substances. Usually, a molar ratio needs to be carefully controlled to ensure good reaction results.To ensure good results, it is important to carefully control the molar ratio.
Then, a catalyst is added.Then, the catalyst is added. Common catalysts for this reaction can include some metal - based catalysts or organic bases.Catalysts can be metal-based catalysts or organic base. The catalyst plays a crucial role in promoting the reaction rate and selectivity.The catalyst is crucial in promoting reaction rate and selectivity. It helps to facilitate the esterification reaction between the carboxyl group of acrylic acid and the hydroxyl - related group in epichlorohydrin.It facilitates the esterification between the carboxyl groups of acrylic acid and hydroxyl-related groups in epichlorohydrin.
During the reaction process, temperature control is very important.Temperature control is crucial during the reaction process. The reaction is typically carried out within a certain temperature range.The reaction usually takes place within a specific temperature range. Usually, a moderately elevated temperature is required to accelerate the reaction, but too high a temperature may lead to side reactions such as polymerization of acrylic acid or decomposition of the reactants and products.A moderately high temperature is usually required to speed up the reaction. However, too high a heat can cause side reactions, such as the polymerization or decomposition, of the reactants or products.
As the reaction progresses, the carboxyl group of acrylic acid reacts with the relevant functional group in epichlorohydrin.As the reaction proceeds, the carboxyl groups of acrylic acid react with the functional group in the epichlorohydrin. Through a series of chemical bond - breaking and - forming processes, an intermediate product is formed first, and then further rearrangement and reaction occur to finally generate glycidyl acrylate.A series of chemical bond-breaking and -forming processes is used to first form an intermediate product, which is then rearranged and further reacted to produce glycidyl-acrylate.
After the reaction is completed, the reaction mixture needs to be processed.The reaction mixture must be processed after the reaction has been completed. This often involves steps such as separation and purification.This usually involves steps like separation and purification. For example, distillation can be used to separate glycidyl acrylate from unreacted raw materials, by - products, and the catalyst.Distillation can be used, for example, to separate glycidylacrylate from unreacted materials, by-products, and the catalyst. The distillation process needs to be carefully adjusted according to the boiling points of different substances in the mixture.The distillation process must be adjusted carefully according to the boiling point of the different substances in the mix. Through proper distillation conditions, pure glycidyl acrylate can be obtained, which can meet the requirements for subsequent use in various applications such as coatings, adhesives, and polymer synthesis.Purified glycidyl-acrylate can be produced by using the right distillation conditions. This can then be used in various applications, such as coatings and adhesives.
What are the safety precautions when handling glycidyl acrylate?
Glycidyl acrylate is a potentially hazardous chemical, and the following safety precautions should be taken when handling it.Glycidyl Acrylate is a potentially dangerous chemical. The following safety precautions must be taken when handling this substance.
Firstly, in terms of personal protective equipment.First, personal protective equipment. Wear appropriate chemical - resistant clothing, such as long - sleeved lab coats or coveralls made of suitable materials.Wear chemical-resistant clothing such as long-sleeved labcoats or coveralls. This helps prevent skin contact with glycidyl acrylate, which can cause skin irritation, burns, and possible allergic reactions.This will help prevent skin contact with the glycidyl-acrylate which can cause skin irritations, burns and possible allergic reactions. Additionally, use chemical - resistant gloves.Use chemical-resistant gloves. Nitrile or neoprene gloves are often good choices as they can provide a certain level of protection against the chemical's permeation.These gloves can offer a level of protection from chemical permeation. Safety goggles or a face shield must be worn to protect the eyes.To protect the eyes, safety goggles or face shields must be worn. Even a small splash of glycidyl acrylate into the eyes can lead to serious eye damage.Even a small splash can cause serious eye damage.
Secondly, proper ventilation is crucial.Second, ventilation is essential. Work in a well - ventilated area, preferably in a fume hood if available.Work in an area that is well-ventilated, preferably under a fume hood. Glycidyl acrylate has a pungent odor, and its vapors can be irritating to the respiratory system.Glycidyl Acrylate has a pungent smell and its vapors are irritating to the respiratory tract. Inadequate ventilation can cause inhalation of these vapors, leading to symptoms like coughing, shortness of breath, and potential long - term respiratory problems.Inadequate ventilation may cause inhalation, resulting in symptoms such as coughing, shortness-of-breath, and long-term respiratory problems. The fume hood can effectively capture and exhaust the vapors, minimizing the risk of inhalation.The fume hood will effectively capture and exhaust these vapors to minimize the risk of inhalation.
Thirdly, when storing glycidyl acrylate, keep it in a cool, dry place away from sources of heat, flames, and oxidizing agents.Thirdly, store glycidylacrylate in a cool and dry place, away from heat sources, flames, or oxidizing agents. It is flammable, so any ignition source nearby can pose a significant fire risk.It is flammable and any ignition source can cause a fire. Store it in tightly - sealed containers to prevent leakage and evaporation.Store it in tightly-sealed containers to prevent leakage or evaporation. Label the containers clearly with the chemical name, hazard warnings, and other relevant information.Label the containers with the chemical name and any warnings or hazards.
Fourthly, in case of spills.Fourthly, if there are spills. Immediately evacuate the area if the spill is large.If the spill is large, evacuate the area immediately. For small spills, wear appropriate protective equipment and use absorbent materials like sand or vermiculite to soak up the chemical.Wear protective gear and absorbent materials such as sand or Vermiculite for small spills. Dispose of the contaminated absorbent according to local regulations.Dispose the contaminated absorbent in accordance with local regulations. Do not rinse the spill directly into the drain as glycidyl acrylate can be harmful to the environment.Do not flush the spill directly down the drain, as glycidylacrylate can harm the environment.
Finally, be familiar with the first - aid procedures.Be familiar with the first-aid procedures. In case of skin contact, immediately remove contaminated clothing and wash the affected area with plenty of water for at least 15 minutes.If skin contact occurs, remove the contaminated clothing immediately and wash the affected area for at least 15 min. Seek medical attention if irritation persists. If it gets into the eyes, flush the eyes with copious amounts of water for at least 15 minutes and then seek immediate medical help.If it gets in the eyes, flush them with copious amounts water for at least fifteen minutes before seeking immediate medical attention. In case of inhalation, move the affected person to fresh air and, if breathing is difficult, provide oxygen and call for emergency medical services.In the case of inhalation move the person to fresh air. If breathing is difficult provide oxygen and call emergency medical services.
What are the properties of glycidyl acrylate?
Glycidyl acrylate is an important organic compound with several notable properties.Glycidyl Acrylate is a compound that has several important properties.
Physical properties:Physical Properties
It is a colorless to pale - yellow liquid.It is a colorless or pale-yellow liquid. It has a characteristic odor.It has a characteristic smell. Glycidyl acrylate has a relatively low boiling point, typically around 189 - 191 degC at normal atmospheric pressure.Glycidyl Acrylate has a low boiling point. It is usually around 189-191 degC under normal atmospheric pressure. This allows it to be vaporized under certain thermal conditions.It can be vaporized in certain conditions. Its density is approximately 1.074 g/cm3 at 20 degC.Its density at 20 degC is approximately 1.074g/cm3. It is sparingly soluble in water but is highly soluble in many organic solvents such as alcohols, ethers, and aromatic hydrocarbons.It is only slightly soluble in water, but highly soluble with many organic solvents like alcohols, aromatic hydrocarbons, and ethers. This solubility in organic solvents makes it convenient to use in various chemical processes where homogeneous reaction media are required.Its solubility in organic solvants makes it suitable for use in a variety of chemical processes that require homogeneous reaction medium.
Chemical properties:Chemical properties
One of the most significant chemical features of glycidyl acrylate is the presence of two reactive functional groups: the acrylate double - bond and the epoxy group.The presence of two reactive functional group: the acrylate double-bond and the epoxy group, is one of the most important chemical features of glycidyl acrylicate. The acrylate double - bond is highly reactive towards addition reactions.The acrylate double-bond is highly reactive to addition reactions. It can participate in radical - initiated polymerization reactions.It can participate in polymerization reactions initiated by radicals. For example, in the presence of a radical initiator like benzoyl peroxide, the double - bond can be induced to polymerize, forming long - chain polymers.In the presence of radical initiators like benzoylperoxide, for example, the double-bond can be induced into polymerization, forming long-chain polymers. These polymers are often used in the production of coatings, adhesives, and composites.These polymers are used to make coatings, composites, and adhesives.
The epoxy group in glycidyl acrylate is also very reactive.The epoxy group in Glycidyl Acrylate is also very reactive. It can react with nucleophiles such as amines, alcohols, and carboxylic acids.It can react with nucleophiles like amines and alcohols. With amines, it forms cross - linked structures through a reaction known as amine - epoxy curing.It forms cross-linked structures with amines through a reaction called amine-epoxy curing. This reaction is crucial in the manufacturing of epoxy - based thermosetting materials, which are widely used in applications where high mechanical strength and chemical resistance are required, like in aerospace components.This reaction is critical in the manufacture of epoxy-based thermosetting materials. These materials are widely used for applications that require high mechanical strength and chemical resistant, such as aerospace components. When reacting with alcohols, it can form ether linkages, and with carboxylic acids, it can form esters.It can form ether links when reacting with alcohols and esters when reacting with carboxylic acid. These reactions can be used to modify the properties of polymers or to create new chemical compounds with tailored characteristics.These reactions can be used for modifying the properties of polymers, or to create new chemical substances with tailored characteristics.
However, due to its high reactivity, glycidyl acrylate is also a potentially hazardous substance.Glycidyl Acrylate, however, is a potentially dangerous substance due to its high level of reactivity. It is considered a skin and eye irritant.It is considered an eye and skin irritant. Prolonged or direct contact with the skin can cause irritation, redness, and possible allergic reactions.Contact with the skin for a long time or directly can cause irritation, rashes, and allergic reactions. Inhalation of its vapors can also irritate the respiratory tract.Inhaling its vapors may also cause irritation to the respiratory tract. Therefore, appropriate safety measures must be taken when handling this compound, including the use of personal protective equipment such as gloves, goggles, and proper ventilation in the workplace.When handling this compound, it is important to take the appropriate safety measures, such as wearing gloves, goggles and ensuring that the workplace is properly ventilated.
What are the potential hazards of glycidyl acrylate?
Glycidyl acrylate is a chemical compound with several potential hazards.Glycidyl Acrylate is a chemical compound that can pose several hazards.
One of the primary concerns is its toxicity.One of the main concerns is its toxicity. It can be harmful if ingested, inhaled, or comes into contact with the skin.It can be harmful when ingested, if inhaled or if it comes into contact with skin. Ingestion may lead to various internal health issues, affecting the digestive system and potentially causing damage to vital organs.Ingestion can cause various internal health problems, including digestive issues and damage to vital organs. When inhaled, it can irritate the respiratory tract, leading to symptoms such as coughing, shortness of breath, and in more severe cases, may cause long - term respiratory problems.Inhaled, it can cause respiratory tract irritation, resulting in symptoms such as coughing and shortness of breathe. In more severe cases, it may cause long-term respiratory problems. Skin contact can result in irritation, redness, and may even cause allergic reactions in some individuals.Contact with the skin can cause irritation, redness and even allergic reactions in some people. Prolonged or repeated exposure to the skin can penetrate and potentially have systemic effects on the body.Repeated or prolonged exposure to the skin may have systemic effects.
Glycidyl acrylate is also a potential mutagen.Glycidyl Acrylate is another potential mutagen. Mutagens have the ability to cause changes in the DNA structure of cells.Mutagens can cause changes to the DNA structure of the cells. This means that exposure to glycidyl acrylate may increase the risk of genetic mutations.Exposure to glycidylacrylate can increase the risk of mutations in genetic material. These mutations can have far - reaching consequences, including an increased likelihood of developing certain types of cancers over time.These mutations may have long-lasting effects, including an increased risk of developing cancer over time. If cells' genetic material is damaged, it can disrupt normal cell functions and regulation, potentially leading to uncontrolled cell growth characteristic of cancer.If the genetic material of cells is damaged, this can disrupt normal cell functions, and regulate cell growth.
It is flammable, which poses a significant fire hazard.It is flammable and poses a serious fire risk. In the presence of an ignition source, such as an open flame, spark, or high - heat environment, glycidyl acrylate can catch fire easily.Glycidyl Acrylate can easily catch fire in the presence of an ignition, such as a spark, open flame or high-heat environment. Once ignited, it can burn rapidly, and the fire may be difficult to control.Once ignited, the fire can spread quickly and be difficult to control. The combustion of glycidyl acrylate may also release toxic and irritating fumes, which not only add to the fire - related danger but can also harm the health of those in the vicinity, both from the inhalation of the fumes and the potential for further chemical reactions in the body.The burning of glycidylacrylate can release toxic fumes that are irritating and toxic. This can not only increase the fire danger, but also cause harm to those nearby.
In addition, glycidyl acrylate can react with other chemicals in an uncontrolled manner.Glycidyl Acrylate can also react uncontrollably with other chemicals. It contains reactive functional groups, and under certain conditions, such as in the presence of specific catalysts or at high temperatures, it may polymerize spontaneously.It contains reactive functional group and, under certain conditions (such as the presence of specific catalysers or at high temperature), it can polymerize spontaneously. This polymerization can be dangerous as it may generate heat, potentially leading to an exothermic reaction that can cause a sudden release of energy, similar to an explosion, and can damage equipment, facilities, and harm nearby workers.This polymerization is dangerous because it can generate heat and lead to an exothermic chemical reaction. This can cause an explosive release of energy and damage equipment and facilities. Overall, due to these potential hazards, proper handling, storage, and safety precautions are essential when dealing with glycidyl acrylate.Glycidyl Acrylate is a potentially hazardous substance. It requires proper handling, storage and safety precautions.