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Product Name | Neopentyl Glycol Diacrylate |
Cas Number | 2223-82-7 |
Formula | C11H16O4 |
Molar Mass | 212.24 |
Density | 1.054 g/cm³ |
Boiling Point | Unused |
Color | Colorless |
State | Liquid |
Viscosity | 10-15 mPa.s at 25°C |
Refractive Index | 1.463-1.465 |
Flash Point | 113°C |
Solubility In Water | Insoluble |
Polymerization | Prone to polymerization |
Hazard Class | Not listed |
Storage Temperature | Store below 40°C |
What are the main applications of neopentyl glycol diacrylate?
Neopentyl glycol diacrylate (NPGDA) has several main applications:NPGDA has many main applications.
1. Coatings industryCoatings industry
In the coatings field, NPGDA is widely used.NPGDA is widely utilized in the coatings industry. It serves as a reactive diluent in ultraviolet (UV) - curable coatings.It is used as a reactive dilutient in UV-curable coatings. UV - curable coatings have the advantage of rapid curing under UV light, which significantly shortens the production cycle.UV-curable coatings are cured rapidly under UV light. This reduces the production cycle. NPGDA can adjust the viscosity of the coating formulation.NPGDA has the ability to adjust the viscosity in the coating formulation. Its acrylate double - bonds participate in the cross - linking reaction during UV curing, improving the hardness, abrasion resistance, and chemical resistance of the cured coating film.Its acrylate double-bonds participate in the cross-linking reaction during UV curing. This improves the hardness, chemical resistance, and abrasion resistance of the cured film. For example, in the coating of wood furniture, NPGDA - containing UV - curable coatings can provide a smooth, durable, and high - gloss finish, protecting the wood from scratches, moisture, and chemicals.NPGDA-containing UV-curable coatings, for example, can provide a smooth and durable finish to wood furniture. They also protect the wood against chemicals, moisture and scratches.
2. Adhesives
NPGDA is an important component in some high - performance adhesives.NPGDA is a component of some high-performance adhesives. It can enhance the adhesion strength of the adhesive by participating in cross - linking reactions.It can increase the adhesion of the adhesive through cross-linking reactions. In structural adhesives, especially those used in the aerospace and automotive industries, NPGDA helps to create a strong and stable bond between different substrates.NPGDA is used in structural adhesives for aerospace and automotive applications. It helps to create a stable and strong bond between substrates. The cross - linked structure formed by the reaction of its double - bonds improves the shear strength and peel strength of the adhesive.The cross-linked structure created by its double-bonds improves the peel strength and shear strength of the adhesive. For instance, in the bonding of composite materials in aircraft manufacturing, adhesives with NPGDA can ensure reliable connections that can withstand high mechanical stresses.Adhesives with NPGDA, for example, can provide reliable connections in aircraft manufacturing when bonding composite materials.
3. Printing inksPrinting inks
UV - curable printing inks often incorporate NPGDA.NPGDA is often used in UV-curable printing inks. Similar to its role in coatings, it acts as a reactive diluent and cross - linking agent.It is a cross-linking agent and a reactive diluent, similar to its role as a coating. In the printing process, when the ink is exposed to UV light, NPGDA undergoes rapid polymerization, enabling the ink to dry quickly on the printed substrate.NPGDA undergoes rapid polymerization when exposed to UV light during the printing process. This allows the inks to dry quickly onto the printed substrate. This results in high - quality prints with good color fastness, scratch resistance, and abrasion resistance.This produces high-quality prints with excellent color fastness and scratch resistance. It is commonly used in the printing of packaging materials, such as cardboard for food packaging, where the fast - curing and non - toxic properties of UV - curable inks containing NPGDA are highly desirable.It is used for packaging materials such as cardboard packaging where the non-toxic and fast-curing properties of UV-curable inks with NPGDA are highly desired.
4. Composite materialsComposite materials
In the production of composite materials, NPGDA can be used as a cross - linking monomer.NPGDA is a monomer that can be used to cross-link composite materials. It reacts with other polymers or monomers to form a three - dimensional network structure, enhancing the mechanical properties of the composite.It reacts with polymers or monomers, forming a three-dimensional network structure that enhances the mechanical properties of composites. For example, in glass - fiber - reinforced composites, NPGDA can improve the interfacial adhesion between the glass fibers and the resin matrix.NPGDA, for example, can improve the interfacial adhesiveness between the glass fibers matrix and the resin matrix in composites reinforced with glass fibers. This leads to an increase in the overall strength, stiffness, and impact resistance of the composite material, making it suitable for applications in construction, marine, and sports equipment industries.This increases the overall strength, stiffness and impact resistance of composite materials, making them suitable for applications in the construction, marine and sports equipment industries.
What are the properties of neopentyl glycol diacrylate?
Neopentyl glycol diacrylate has several notable properties.The properties of diacrylate neopentyl glycol are quite impressive.
In terms of physical properties, it is typically a clear, colorless liquid.Physically, it is a clear liquid. It has a relatively low viscosity, which allows for easy handling and processing in various applications.It is relatively low in viscosity which makes it easy to handle and process for various applications. This low viscosity enables it to flow smoothly during processes like coating, casting, or impregnation.Its low viscosity allows it to flow easily during processes such as coating, casting or impregnation. It also has a characteristic odor, although it is not overly pungent.It has a distinctive odor that is not too pungent.
Regarding chemical properties, neopentyl glycol diacrylate is highly reactive due to the presence of two acrylate double bonds.Due to its high reactivity, neopentyl diacrylate has two double acrylate bonds. These double bonds can participate in polymerization reactions, particularly radical - initiated polymerization.These double bonds are capable of participating in polymerization reactions. This makes it a valuable monomer in the production of polymers.It is therefore a valuable monomer for the production of polymers. When polymerized, it can form cross - linked structures, enhancing the mechanical and chemical resistance properties of the resulting polymers.When polymerized it can form cross-linked structures, which enhance the mechanical and chemical properties of the resulting Polymers.
The reactivity of neopentyl glycol diacrylate allows it to copolymerize with other monomers.Its reactivity allows it to copolymerize. This ability to copolymerize broadens its application scope.This ability to copolymerize expands its application range. For example, when copolymerized with other acrylate monomers, it can adjust the properties of the final polymer such as hardness, flexibility, and adhesion.When copolymerized, it can alter the properties of the polymer, such as its hardness, flexibility and adhesion.
In terms of solubility, it is soluble in many organic solvents.It is soluble in a wide range of organic solvents. This solubility is beneficial for formulating solutions for specific applications.This solubility makes it easy to formulate solutions for specific applications. For instance, in coatings, it can be dissolved in appropriate solvents to create a homogeneous mixture that can be evenly applied to a substrate.In coatings, for example, it can dissolve in appropriate solvents in order to create a homogeneous mix that can be applied evenly to a substrate.
Neopentyl glycol diacrylate also offers good weather resistance.Also, neopentyl diacrylate is resistant to weather. Polymers derived from it are able to withstand exposure to sunlight, moisture, and temperature variations without significant degradation.Its polymers are resistant to exposure to sunlight, moisture and temperature changes. This property makes it suitable for outdoor applications such as in coatings for building materials, automotive parts, and outdoor furniture.This property makes it ideal for outdoor applications, such as coatings for building material, automotive parts, or outdoor furniture.
In addition, it has relatively good thermal stability.It also has a good thermal stability. It can endure a certain range of temperatures without undergoing decomposition or significant chemical changes.It can withstand a certain temperature range without decomposition or chemical changes. This property is crucial in processes where heat is involved, like curing of coatings or the production of thermoset polymers.This property is important in processes that involve heat, such as the curing of coatings and the production of thermosets. Overall, these properties make neopentyl glycol diacrylate a versatile compound with wide - ranging applications in the polymer and coatings industries.These properties make the neopentyl diacrylate a versatile material with a wide range of applications in the polymer industry and coatings.
How is neopentyl glycol diacrylate produced?
Neopentyl glycol diacrylate is produced through an esterification reaction.Esterification is used to produce neopentyl glycol diacrylate. Here is a general overview of the production process.Here is an overview of the production.
Reactants Preparation
The key reactants are neopentyl glycol and acrylic acid.The main reactants are acrylic acid and neopentyl glycol. Neopentyl glycol is a diol with two hydroxyl (-OH) groups.Neopentyl Glycol is a diol containing two hydroxyl groups (-OH). Acrylic acid contains a carboxylic acid (-COOH) group and a carbon - carbon double bond.Acrylic acid has a carboxylic (-COOH), and a double carbon-carbon bond. These starting materials need to be of high purity to ensure a good - quality product.To ensure high-quality products, these starting materials must be very pure. They are sourced from chemical manufacturers and may undergo pre - treatment steps such as purification through distillation to remove any impurities that could interfere with the reaction.These materials are obtained from chemical manufacturers, and may be subjected to pre-treatment steps such as distillation in order to remove impurities which could interfere with the reaction.
Esterification Reaction
The esterification reaction between neopentyl glycol and acrylic acid is catalyzed.Catalyzed esterification between neopentylglycol and acrylic acid. Commonly, an acidic catalyst like sulfuric acid or p - toluenesulfonic acid is used.Usually, an acidic catalyser like sulfuric or p-toluenesulfonic acids is used. The role of the catalyst is to speed up the reaction by providing an alternative reaction pathway with a lower activation energy.The catalyst's role is to speed up a reaction by providing a reaction pathway that has a lower activation energies.
The reaction equation is as follows: Neopentyl glycol (C5H12O2) + 2 acrylic acid (C3H4O2) - Neopentyl glycol diacrylate (C11H18O4)+ 2H2O.The reaction equation is: Neopentyl Glycol (C5H12O2)+2 acrylic acid (C3H4O2)-Neopentyl Glycol Diacrylate (C11H18O4)+2H2O. This is a reversible reaction, so to drive the reaction towards the formation of neopentyl glycol diacrylate, an excess of acrylic acid is often used.This is a reversible process, so an excess of acrylic acids is often used to accelerate the reaction. Also, the water produced during the reaction is removed continuously.The water produced by the reaction is also continuously removed. This can be achieved by techniques such as azeotropic distillation, where an azeotropic agent (a substance that forms a constant - boiling mixture with water) is added.Azeotropic distillation is one technique that can achieve this. An azeotropic substance (a substance which forms a constant-boiling mixture with water) will be added. The azeotropic mixture is then distilled off, separating the water from the reaction mixture and shifting the equilibrium towards the product side.The azeotropic mix is then distilled, separating water from the reaction and shifting equilibrium to the product side.
Reaction Conditions
The reaction is typically carried out at an elevated temperature, usually in the range of 80 - 120 degC.The reaction is usually carried out at a high temperature, typically between 80 and 120 degC. The specific temperature depends on factors such as the catalyst used and the desired reaction rate.The temperature is determined by factors such as the catalyst and the desired rate of reaction. Higher temperatures generally increase the reaction rate but also carry the risk of side - reactions.Higher temperatures increase the rate of reaction but can also cause side reactions. The reaction is usually conducted under a nitrogen atmosphere.The reaction is typically conducted in a nitrogen atmosphere. Nitrogen is an inert gas, and it helps to prevent oxidation of the reactants and products, especially the acrylic acid which has an unsaturated double bond that is prone to oxidation.Nitrogen is inert and helps to prevent the oxidation of reactants and products. This is especially true for acrylic acid, which has a double bond that's prone to oxidation.
Purification
After the reaction is complete, the reaction mixture contains the product neopentyl glycol diacrylate, unreacted starting materials, the catalyst, and any by - products.The reaction mixture will contain the neopentyl diacrylate product, unreacted materials, the catalyst and any by-products. First, the catalyst is neutralized.The catalyst must first be neutralized. This can be done by adding a base such as sodium carbonate or sodium hydroxide.Add a base, such as sodium hydroxide or sodium carbonate. The resulting salts are then removed by filtration.The salts that result are then removed through filtration.
The product is further purified by distillation.The product is purified further by distillation. Neopentyl glycol diacrylate has a different boiling point compared to the unreacted substances, allowing it to be separated.The neopentyl diacrylate is separated from the unreacted substances because it has a lower boiling point. Vacuum distillation may be employed to lower the boiling points of the components and prevent thermal decomposition of the product.Vacuum distillation can be used to lower the boiling point of the components, preventing thermal decomposition. Through these purification steps, a high - purity neopentyl glycol diacrylate product is obtained, which can be used in various applications such as in the production of coatings, adhesives, and polymers due to its reactive double bonds that can participate in polymerization reactions.These purification steps result in a high-purity neopentyl diacrylate, which is suitable for a variety of applications, including the production and use of adhesives, polymers, and coatings.
What are the safety precautions when handling neopentyl glycol diacrylate?
Neopentyl glycol diacrylate is a chemical compound that requires certain safety precautions during handling.Neopentyl Glycol Diacrylate is a corrosive compound that must be handled with care.
First, personal protective equipment (PPE) is essential.Personal protective equipment (PPE), first and foremost, is essential. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a barrier against contact with the skin.Nitrile gloves can be a good option as they provide a barrier to skin contact. Skin contact with neopentyl glycol diacrylate can cause irritation, redness, and possible allergic reactions over time.Contact with neopentyl diacrylate on the skin can cause irritation, rashes, and allergic reactions. In addition to gloves, protective clothing should be worn.Wear protective clothing in addition to gloves. This includes long - sleeved shirts and long - pants made of a material that can resist chemical penetration, preventing the chemical from reaching the skin.Long - sleeved shirt and long pants made from a material resistant to chemical penetration are recommended. This will prevent the chemical from reaching your skin. Safety goggles or a face shield should be used to protect the eyes.To protect the eyes, safety goggles or face shields should be worn. If the chemical splashes into the eyes, it can cause severe eye irritation, corneal damage, and potential loss of vision.If the chemical splashes in the eyes, it may cause severe irritation, corneal injury, and even loss of vision.
Ventilation is crucial.Ventilation is essential. Ensure that the area where neopentyl glycol diacrylate is being handled has good ventilation.Make sure that the area in which neopentyl diacrylate will be handled is well ventilated. This can be achieved through natural ventilation, such as opening windows, or by using mechanical ventilation systems like exhaust fans.You can achieve this by opening windows or using mechanical ventilation devices like exhaust fans. Adequate ventilation helps to prevent the build - up of vapors.Adequate ventilation prevents the build-up of vapors. Inhalation of these vapors can irritate the respiratory tract, leading to symptoms like coughing, shortness of breath, and in more severe cases, damage to the lungs.Inhaling these vapors may cause irritation of the respiratory tract and lead to symptoms such as coughing, shortness in breath, or, in more serious cases, lung damage.
When storing neopentyl glycol diacrylate, keep it in a cool, dry place away from heat sources and open flames.Store neopentyl diacrylate in a cool and dry place, away from heat sources. It is a flammable substance, and exposure to heat or ignition sources can lead to a fire or explosion.It is flammable and can cause an explosion or fire if exposed to heat. Store it in a container that is tightly sealed to prevent leakage and evaporation.Store it in a tightly sealed container to prevent leakage or evaporation. Also, store it separately from incompatible substances.Store it away from incompatible substances. For example, it should not be stored near strong oxidizing agents as this can lead to potentially dangerous chemical reactions.It should not, for example, be stored near strong oxygenating agents because this can cause potentially dangerous chemical reactions.
In case of accidental spillage, immediate action is required.Immediate action is needed in the event of an accidental spillage. First, evacuate the area to prevent exposure of others.First, evacuate the affected area to avoid exposing others. Then, wear appropriate PPE and use absorbent materials like sand or vermiculite to soak up the spill.Wear appropriate PPE, and use absorbent materials such as sand or Vermiculite to absorb the spill. Place the contaminated absorbent in a proper waste container for disposal according to local regulations.Place the contaminated absorbent into a waste container according to local regulations. Clean the area thoroughly to remove any remaining traces of the chemical.Remove all traces of chemical residue by thoroughly cleaning the area.
Finally, in case of skin contact, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If skin contact occurs, wash the area immediately with soap and water. This should take at least 15 minutes. If eye contact occurs, flush the eyes with copious amounts of water for at least 15 minutes and seek immediate medical attention.If eye contact occurs flush the eyes for at least 15 minute with plenty of water and seek immediate medical care. If inhaled, move to fresh air immediately and if symptoms persist, seek medical help.If inhaled, get to fresh air as soon as possible. If symptoms persist, consult a doctor.
What are the advantages of using neopentyl glycol diacrylate compared to other acrylate monomers?
Neopentyl glycol diacrylate offers several distinct advantages when compared to other acrylate monomers.Comparing neopentyl glycol diacrylate to other monomers, it offers several distinct benefits.
One key advantage is its relatively high cross - linking density.Its relatively high cross-linking density is a key advantage. With two acrylate functional groups per molecule, it can form a more extensive three - dimensional network during polymerization.It can form a larger three-dimensional network when polymerizing because it has two acrylate functional group per molecule. This results in polymers with enhanced mechanical properties.This results in polymers that have enhanced mechanical properties. For example, coatings made from neopentyl glycol diacrylate are likely to be more rigid and have better abrasion resistance compared to those formed from monomers with a single acrylate group.Coatings made of neopentyl diacrylate, for example, are likely to have a better abrasion resistant and be more rigid than those made from monomers containing a single acrylate. The increased cross - linking also improves chemical resistance.The increased cross-linking also improves chemical resistance. Polymers derived from this monomer can better withstand exposure to various chemicals, such as solvents and acids, as the tightly - knit network structure is less prone to degradation.The polymers made from this monomer are more resistant to chemicals such as acids and solvents, because the network structure is tightly-knit.
Another advantage lies in its low volatility.Its low volatility is another advantage. Neopentyl glycol diacrylate has a relatively high boiling point, which means it emits fewer volatile organic compounds (VOCs) during processing.The high boiling point of neopentyl diacrylate means that it emits less volatile organic compounds during processing. This is highly beneficial from an environmental and health perspective.This is a great thing for the environment and your health. In applications where air quality is a concern, such as in indoor coatings or adhesives, the use of this monomer helps to reduce the release of harmful vapors.This monomer is useful in applications where air quality, such as indoor coatings and adhesives, is a concern. It helps reduce harmful vapors. It also contributes to a more pleasant working environment as there is less pungent odor associated with the monomer.The monomer also contributes to an improved working environment, as it has a less pungent smell.
The structure of neopentyl glycol diacrylate also imparts good weather resistance to the resulting polymers.The resulting polymers are also weather resistant due to the structure of neopentyl diacrylate. The neopentyl group provides steric hindrance, protecting the acrylate double bonds from degradation by ultraviolet light and oxygen.The neopentyl groups provide steric hindrance which protects the acrylate double bond from degradation by oxygen and ultraviolet light. This makes it an ideal choice for outdoor applications, like in automotive coatings or exterior architectural finishes.It is therefore a good choice for outdoor applications such as automotive coatings and exterior architectural finishes. Polymers made from it can maintain their physical and chemical properties over long periods of exposure to sunlight, rain, and temperature fluctuations.Polymers made of it can maintain their chemical and physical properties even after prolonged exposure to sunlight, rainfall, and temperature fluctuations.
Furthermore, neopentyl glycol diacrylate shows good reactivity.The neopentyl diacrylate also shows good reactivity. It can polymerize relatively quickly under appropriate conditions, such as in the presence of a suitable initiator and heat or light.It can polymerize under certain conditions, like in the presence an initiator or heat. This allows for efficient production processes, reducing manufacturing time and potentially costs.This allows for more efficient production processes and reduces manufacturing time as well as costs. The monomer also has good compatibility with a wide range of other monomers and additives.The monomer is also compatible with a variety of monomers and additives. This flexibility enables formulators to create custom - tailored polymer systems with specific properties, whether it is adjusting the hardness, flexibility, or adhesion characteristics of the final product.This flexibility allows formulators to create polymer systems that are custom-tailored and have specific properties.