.
Product Name | Tetraethyleneglycol dimethacrylate |
Cas Number | 109-17-1 |
Formula | C16H26O6 |
Molar Mass | 314.38 g/mol |
Property 1 | Appearance: Clear liquid |
Property 2 | Boiling Point: 345-346 °C |
Property 3 | Density: 1.08 g/cm³ |
Property 4 | Flash Point: 185 °C |
Property 5 | Refractive Index: 1.456 |
Property 6 | Viscosity: 9-10 cps at 25°C |
Property 7 | Solubility: Soluble in organic solvents |
Property 8 | Stability: Stable under normal conditions |
Property 9 | Polymerization: Can polymerize when heated or under light |
Property 10 | Hazards: Irritant |
What is the chemical structure of Tetraethyleneglycol dimethacrylate?
Tetraethyleneglycol dimethacrylate is an organic compound with a specific chemical structure.Tetraethyleneglycol Dimethacrylate (TEGDMA) is a chemical compound with a unique structure.
The base of its structure is derived from methacrylate groups.The methacrylate group is the base of its structure. A methacrylate group has a structure where a methyl group is attached to the carbon atom of a carbon - carbon double bond, and this carbon is also part of an ester group.A methacrylate has a structure in which a methyl group attaches to the carbon atoms of a double bond carbon-carbon, and where this carbon is part of an ester group. The general formula for a methacrylate is CH2 = C(CH3)COO - R, where R represents the rest of the molecule to which the methacrylate is attached.The general formula of a methacrylate can be written as CH2 = C(CH3)COO-R, where R is the rest of molecule to which it is attached.
In tetraethyleneglycol dimethacrylate, there are two methacrylate groups.There are two methacrylate group in tetraethyleneglycol Dimethacrylate. These two methacrylate groups are connected by a tetraethylene glycol chain.The tetraethylene-glycol chain connects these two methacrylate group. The tetraethylene glycol part consists of a chain of four ethylene glycol units linked together.The tetraethylene part is made up of a chain consisting of four ethylene units linked together. An ethylene glycol unit has the formula - CH2CH2O -.The formula of an ethylene glycol unit is - CH2CH2O. When four of these units are connected in a row, it forms the backbone of the molecule between the two methacrylate groups.Four of these units connected in a line form the backbone of a molecule between the methacrylate groups.
So, the chemical structure of tetraethyleneglycol dimethacrylate can be written as CH2 = C(CH3)COO(CH2CH2O)4OOC(CH3)=CH2. Here, the (CH2CH2O)4 part represents the tetraethylene glycol chain.The (CH2CH2O )4 part represents a tetraethylene glycol chain. The two terminal parts, CH2 = C(CH3)COO - and - OOC(CH3)=CH2, are the methacrylate groups.The methacrylate groups are represented by the two terminal parts CH2 = C(CH3)COO and OOC(CH3)=CH2.
The presence of the carbon - carbon double bonds in the methacrylate groups makes tetraethyleneglycol dimethacrylate a reactive compound.Tetraethyleneglycol Dimethacrylate is a reactive compound due to the presence of carbon-carbon double bonds in the methacrylate group. These double bonds can participate in polymerization reactions.These double bonds are capable of participating in polymerization reactions. It is often used in the synthesis of polymers, such as in the production of certain types of resins and hydrogels.It is used to synthesize polymers such as certain types of hydrogels and resins. The tetraethylene glycol chain in the middle imparts some flexibility to the resulting polymers due to the relatively long and flexible nature of the polyether chain.The polyether chain is relatively long and flexible, which allows the tetraethyleneglycol chain to impart some flexibility to the polymers. This combination of reactive double - bond - containing end - groups and a flexible central chain gives tetraethyleneglycol dimethacrylate unique properties that are useful in various industrial and scientific applications.This combination of reactive end - groups containing double - bonds and a flexible central - chain gives tetraethyleneglycol dimethylacrylate unique properties useful in various industrial applications and scientific research.
What are the main applications of Tetraethyleneglycol dimethacrylate?
Tetraethyleneglycol dimethacrylate (TEGDMA) has several main applications.The main applications of TEGDMA are numerous.
In the dental field, TEGDMA is a crucial component in dental composite materials.TEGDMA, a component of dental composite materials, is a vital component in the dental field. Dental composites are used for restoring teeth, such as filling cavities.Dental composites can be used to restore teeth, for example by filling cavities. TEGDMA helps in the polymerization process.TEGDMA aids in the polymerization. When combined with other monomers and fillers, it forms a cross - linked network upon exposure to light or chemical initiators.It forms a cross-linked network when combined with other monomers or fillers. This cross - linking gives the composite material the necessary mechanical properties like high strength and wear resistance, which are essential for withstanding the forces exerted during chewing.This cross-linking gives the composite material mechanical properties such as high strength and wear resistance which are necessary to withstand the forces exerted by chewing. Additionally, its chemical structure allows for good adhesion to tooth structures, ensuring a long - lasting and stable restoration.Its chemical structure also allows for good adhesion with tooth structures. This ensures a long-lasting and stable restoration.
TEGDMA is also widely used in the production of polymers and resins for coatings.TEGDMA can also be used to produce polymers and resins that are used for coatings. In industrial coatings, it can be incorporated into formulations to improve the hardness, abrasion resistance, and chemical resistance of the coating.In industrial coatings it can be added to formulations to increase the coating's hardness, chemical resistance, and abrasion resistance. For example, in automotive clear coats, TEGDMA - containing polymers can protect the underlying paint from scratches, UV radiation, and environmental pollutants.TEGDMA-containing polymers, for example, can protect the underlying paint against scratches, UV radiation and environmental pollutants. The ability of TEGDMA to form a highly cross - linked structure upon curing contributes to these enhanced properties.These enhanced properties are due to the ability of TEGDMA polymers to form a highly inter-linked structure upon curing.
Another important application is in the synthesis of ion - exchange resins.Synthesis of ion-exchange resins is another important application. Ion - exchange resins are used in water treatment, purification of pharmaceuticals, and separation processes in the chemical industry.Ion-exchange resins are used for water treatment, pharmaceutical purification, and separation processes within the chemical industry. TEGDMA can be used as a cross - linking agent in the preparation of these resins.TEGDMA is a cross-linking agent that can be used in the preparation of resins. The cross - linked structure formed by TEGDMA helps to maintain the integrity of the resin beads and provides the necessary pore structure for the exchange of ions.The cross-linked structure formed by TEGDMA maintains the integrity of resin beads, and provides the necessary pore structures for the exchange ions. This enables efficient removal of unwanted ions from solutions, such as the removal of heavy metals from industrial wastewaters or the softening of hard water by exchanging calcium and magnesium ions with sodium ions.This allows for the efficient removal of unwanted molecules from solutions. For example, heavy metals can be removed from industrial wastewaters by exchanging sodium ions with calcium and magnesium ions.
In the area of 3D printing, TEGDMA can be part of the photopolymerizable resin formulations.TEGDMA is a photopolymerisable resin that can be used in 3D printing. As 3D printing technology continues to evolve, the demand for resins with specific properties is increasing.As 3D printing technology evolves, the demand for resins that have specific properties increases. TEGDMA's ability to rapidly polymerize under light irradiation makes it suitable for use in vat polymerization - based 3D printing techniques.TEGDMA is suitable for 3D printing techniques that use vat polymerization because of its ability to polymerize rapidly under light irradiation. It can help create complex 3D structures with high precision, and the resulting polymers can have good mechanical strength, which is beneficial for applications such as prototyping and the production of small - scale functional parts.It can create complex 3D structure with high precision. The resulting polymers have a good mechanical strength which is useful for applications such a prototyping and small-scale functional parts.
What are the safety precautions when handling Tetraethyleneglycol dimethacrylate?
Tetraethyleneglycol dimethacrylate is a chemical compound that requires certain safety precautions during handling.Tetraethyleneglycol Dimethacrylate (TEGDMA) is a chemical that requires special handling precautions.
First, personal protective equipment is essential.Personal protective equipment is a must. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a barrier against the chemical.Nitrile gloves can be a good option as they provide a barrier to the chemical. This helps prevent skin contact, which can lead to irritation, redness, and potential absorption of the chemical into the body.This can help prevent skin contact that could lead to irritation, rashes, and possible absorption of the chemicals into the body. Also, wear safety goggles or a face shield.Wear safety goggles, or a face shield. Since tetraethyleneglycol dimethacrylate can splash during handling, eye protection is crucial to avoid eye injuries such as corneal damage or irritation.Eye protection is essential to prevent eye injuries, such as corneal irritation or damage. In addition, a lab coat or other protective clothing should be worn to safeguard the body from spills.Wearing a labcoat or other protective clothing will also help protect the body from spills.
Second, proper ventilation is necessary.Second, it is important to have proper ventilation. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably under fume hoods. This chemical may emit vapors that can be irritating to the respiratory system.This chemical can emit vapors which can be irritating to respiratory systems. Adequate ventilation helps to dilute and remove these vapors, reducing the risk of inhaling them.Adequate ventilation can help to dilute and eliminate these vapors. This reduces the risk of inhaling. Inhalation of tetraethyleneglycol dimethacrylate vapors can cause coughing, shortness of breath, and other respiratory problems.Inhaling tetraethyleneglycol dimethylacrylate vapors may cause coughing, shortness in breath, and other respiratory issues.
Third, when handling the chemical, be careful to avoid spills.Avoid spills by being careful when handling the chemical. Keep the container tightly closed when not in use to prevent leakage.When not in use, keep the container tightly shut to prevent leakage. If a spill occurs, follow proper spill - cleanup procedures.Follow the proper spill-cleanup procedures if a spill occurs. Absorb the spill with an appropriate absorbent material, such as vermiculite or sand.Absorb spills with an absorbent material such as vermiculite, sand or other suitable absorbent materials. Then, place the contaminated absorbent in a suitable waste container for proper disposal according to local regulations.Place the contaminated absorbent into a suitable container for disposal according to local regulations. Do not rinse the spilled chemical directly down the drain as it can contaminate water sources.Do not flush the spilled chemical down the drain, as it could contaminate the water source.
Fourth, storage is important.Storage is also important. Store tetraethyleneglycol dimethacrylate in a cool, dry place away from heat sources and open flames.Store the tetraethyleneglycol dimethylacrylate in a dry, cool place away from heat and open flames. It is flammable, so any source of ignition should be kept at a safe distance.It is flammable so keep any source of ignition at a safe distance. Also, store it separately from oxidizing agents to prevent potential chemical reactions.Store it away from oxidizing agents in order to avoid chemical reactions.
Finally, be aware of the potential health hazards.Be aware of potential health hazards. In case of skin contact, immediately wash the affected area with plenty of soap and water for at least 15 minutes.In the event of skin contact, wash the affected area immediately with soap and water. This should be done for at least 15 min. If eye contact occurs, rinse the eyes thoroughly with water for a prolonged period and seek medical attention.If you have eye contact, wash your eyes with plenty of water for an extended period. Seek medical attention if symptoms persist. If inhaled, move to fresh air immediately and get medical help if symptoms persist.If inhaled move to fresh air as soon as possible and seek medical attention if symptoms persist. And in case of ingestion, do not induce vomiting but seek immediate medical advice.In the case of ingestion do not induce vomiting, but seek immediate medical attention. By following these safety precautions, the risks associated with handling tetraethyleneglycol dimethacrylate can be minimized.These safety precautions can help reduce the risks of handling tetraethyleneglycol dimethylacrylate.
What are the physical and chemical properties of Tetraethyleneglycol dimethacrylate?
Tetraethyleneglycol dimethacrylate is an important chemical compound with specific physical and chemical properties.Tetraethyleneglycol Dimethacrylate, a chemical compound of importance with specific physical and chemistry properties.
Physical properties:Physical Properties
Appearance: It typically appears as a clear, colorless to pale - yellow liquid.Appearance: It appears as a clear liquid that is colorless or pale yellow. This clear nature allows for easy visual inspection in various applications.This clear liquid allows for easy visual inspection.
Odor: It has a characteristic, somewhat acrid odor.It has a characteristic acrid smell. Although not extremely pungent, the odor is noticeable and can be a distinguishing feature during handling.The odor is not very pungent but it is noticeable.
Boiling point: The boiling point of tetraethyleneglycol dimethacrylate is relatively high.The boiling point for tetraethyleneglycol dimethylacrylate is high. It boils at around 330 - 335 degC under normal atmospheric pressure.It boils around 330-335 degC at normal atmospheric pressure. This high boiling point makes it suitable for applications where elevated temperatures are involved without significant loss due to evaporation.This high boiling point allows it to be used in applications that involve elevated temperatures without significant loss from evaporation.
Melting point: The melting point is relatively low, usually around - 20 degC.Melting point: The melting temperature is usually around -20 degC. This low melting point means that it remains in a liquid state under most ambient and slightly cooled conditions, facilitating its use in processes that require a fluid substance.This low melting point allows it to remain in a liquid form under ambient and slightly cooled temperatures, making it ideal for processes that require fluid substances.
Density: It has a density of approximately 1.06 g/cm3.Density: Its density is approximately 1.06g/cm3. This density is close to that of water but slightly higher, which affects its behavior in mixtures with other substances, especially in liquid - liquid systems.This density is similar to water, but slightly higher. This affects the behavior of the mixtures, especially liquid-liquid systems.
Viscosity: The compound has a moderate viscosity.Viscosity : The compound is moderately viscous. This property is crucial as it determines how easily the liquid can flow.This property is important because it determines the ease with which liquids can flow. A moderate viscosity allows for good spreading and wetting characteristics when used in coatings, adhesives, or polymerization processes.When used in coatings or adhesives, or polymerization, a moderate viscosity will allow for good spreading and moistening characteristics.
Chemical properties:Chemical properties
Polymerizability: One of the most significant chemical properties is its ability to polymerize.Polymerisability: Its ability to polymerize is one of its most important chemical properties. It contains two methacrylate groups, which can undergo addition polymerization reactions.It contains two methacrylate group, which can undergo polymerization addition reactions. When exposed to appropriate initiators, such as free - radical initiators like benzoyl peroxide or heat - activated initiators, the double bonds in the methacrylate groups break and form long - chain polymers.Double bonds in methacrylate groups can be broken by initiators such as heat-activated initiators or free-radical initiators. This property is widely exploited in the production of various polymers, including dental composites, where it helps in creating hard, durable materials.This property is widely used in the production and development of polymers.
Reactivity with other compounds: It can react with a variety of compounds containing reactive functional groups.Reactivity with other compounds. It can react with many compounds that contain reactive functional groups. For example, it can react with amines in a reaction known as Michael addition.It can, for example, react with amines through a reaction called Michael addition. This reactivity can be used to modify the polymer structure or to create cross - linked networks with other polymers or monomers, enhancing the mechanical and chemical properties of the final material.This reactivity is used to modify polymer structures or create cross-linked networks with other monomers or polymers, improving the mechanical and chemical properties.
Hydrolysis sensitivity: Although it is relatively stable under normal conditions, tetraethyleneglycol dimethacrylate can undergo hydrolysis in the presence of strong acids or bases and water.Hydrolysis sensitivity. Although it is relatively stable in normal conditions, tetraethyleneglycol dimethylacrylate can undergo hydrolysis when present with strong acids or bases or water. Hydrolysis can break the ester bonds in the molecule, leading to the formation of carboxylic acid and alcohol groups.Hydrolysis can break ester bonds, resulting in the formation of carboxylic acids and alcohol groups. This property needs to be considered in applications where the compound may be exposed to harsh chemical environments.This property is important in applications where the compound will be exposed to harsh chemicals.
How is Tetraethyleneglycol dimethacrylate synthesized?
Tetraethyleneglycol dimethacrylate is synthesized through the following general process.The following general procedure is used to synthesize tetraethyleneglycol dimethylacrylate.
The starting materials typically involve tetraethylene glycol and methacrylic acid.Start materials are typically tetraethylene Glycol and methacrylic Acid. One common method is the esterification reaction.Esterification is a common method. In this reaction, an acid - catalyzed process is often employed.This reaction is often catalyzed by an acid.
Firstly, appropriate amounts of tetraethylene glycol and methacrylic acid are mixed in a reaction vessel.In a reaction vessel, first mix tetraethylene glycol and methacrylic acids in the appropriate amounts. A catalyst such as sulfuric acid or p - toluenesulfonic acid is added.Add a catalyst, such as sulfuric or p-toluenesulfonic acids. These acids can enhance the reaction rate by protonating the carbonyl group of methacrylic acid, making it more reactive towards the hydroxyl groups of tetraethylene glycol.These acids can increase the rate of reaction by protonating carbonyl groups in methacrylic acid.
The reaction is usually carried out under reflux conditions.Reactions are usually carried out in reflux conditions. Refluxing helps to maintain a constant reaction temperature, ensuring that the reactants are in a liquid state and in continuous contact for the reaction to occur.Refluxing maintains a constant temperature for the reaction, and ensures that the reactants remain in a liquid form. During the reflux, water is formed as a by - product of the esterification reaction.Water is formed during the esterification process. To drive the reaction forward according to Le Chatelier's principle, the water formed needs to be removed.The water produced must be removed to drive the reaction according to Le Chatelier’s principle. This can be achieved by using a Dean - Stark apparatus.The Dean-Stark apparatus can be used to achieve this. The Dean - Stark apparatus allows the separation of water from the reaction mixture, shifting the equilibrium towards the formation of tetraethyleneglycol dimethacrylate.The Dean - Stark device allows water to be separated from the reaction mixture and shifts the equilibrium in favor of the formation of dimethacrylate tetraethyleneglycol.
As the reaction progresses, the conversion of the reactants to the product can be monitored.The conversion of the reactants into the product can be monitored as the reaction progresses. This can be done through techniques such as gas chromatography or nuclear magnetic resonance spectroscopy.Gas chromatography and nuclear magnetic resonance spectroscopy are two techniques that can be used to monitor the reaction. Once the desired level of conversion is achieved, the reaction mixture is cooled.Once the desired conversion level is achieved, the reaction mix is cooled.
After cooling, the product mixture contains the tetraethyleneglycol dimethacrylate, unreacted starting materials, and the catalyst.After cooling, the product mix contains the tetraethyleneglycol dimethylacrylate, unreacted materials, and catalyst. To isolate the product, a series of purification steps are necessary.Purification steps are required to isolate the product. The mixture may first be washed with a suitable base, such as sodium carbonate solution, to neutralize the acid catalyst.To neutralize the acid catalyst, the mixture can be washed first with a base such as sodium carbonate. Then, it is washed with water to remove any water - soluble impurities.It is then washed in water to remove all water-soluble impurities. The organic layer containing the product is then dried over a desiccant, such as anhydrous magnesium sulfate.The organic layer that contains the product is dried over a desiccant such as anhydrous Magnesium Sulfate. Finally, the dried product can be further purified by distillation under reduced pressure to obtain pure tetraethyleneglycol dimethacrylate.The dried product can then be purified further by distillation at reduced pressure in order to obtain pure tetraethyleneglycol dimethylacrylate. This distillation step helps to separate the product from any remaining unreacted materials or high - boiling impurities.This step of distillation helps to separate the product and any unreacted materials, or high-boiling impurities.