.
Product Name | Tetrahydrofurfuryl acrylate |
Cas Number | 2399-48-6 |
Formula | C9H14O3 |
Molar Mass | 170.21 |
Boiling Point | 202°C |
Density | 1.072 g/mL |
Refractive Index | 1.470 |
Flash Point | 91°C |
Solubility In Water | Slightly soluble |
Viscosity | 6.5 cP |
Appearance | Clear liquid |
Odor | Mild acrylate odor |
Autoignition Temperature | 271°C |
Surface Tension | 29.5 mN/m |
Vapor Pressure | 0.45 mmHg at 25°C |
What is the application of tetrahydrofurfuryl acrylate?
Tetrahydrofurfuryl acrylate has several important applications.Tetrahydrofurfuryl Acrylate has many important applications.
One of its major uses is in the field of coatings.Coatings are one of its main uses. It can be incorporated into coating formulations to enhance various properties.It can be added to coating formulations to improve various properties. In UV - curable coatings, for example, tetrahydrofurfuryl acrylate acts as a reactive diluent.Tetrahydrofurfuryl Acrylate, for instance, is used as a reactive dilutient in UV-curable coatings. This means it can reduce the viscosity of the coating resin, making it easier to apply evenly on different substrates such as wood, metal, and plastic.It can reduce the viscosity, making it easier to evenly apply the coating resin on different substrates, such as wood, plastic, and metal. At the same time, during the UV - curing process, it participates in the polymerization reaction, becoming an integral part of the cured coating film.During the UV-curing process, it also participates in polymerization, becoming a part of the cured film. The resulting coating has improved hardness, abrasion resistance, and chemical resistance.The coating is harder, more resistant to abrasion, and has better chemical resistance. For instance, in the furniture industry, UV - curable coatings containing tetrahydrofurfuryl acrylate can provide a durable and attractive finish to wooden furniture, protecting it from scratches and environmental damage.UV-curable coatings that contain tetrahydrofurfuryl acrylicate, for example, can be used in the furniture industry to provide a durable, attractive finish on wooden furniture. They protect it from scratches and other environmental damage.
In the area of adhesives, tetrahydrofurfuryl acrylate plays a crucial role.Tetrahydrofurfuryl Acrylate is a key ingredient in adhesives. It can be used to modify the properties of adhesive formulations.It can be used to change the properties of adhesive formulas. By adding it to acrylate - based adhesives, the adhesive can achieve better adhesion to a wider range of materials.Add it to acrylate-based adhesives to improve adhesion. Its reactive nature allows it to form strong chemical bonds with the substrates during the curing process.Its reactive properties allow it to form strong chemical bonding with substrates during curing. This is especially useful in applications where high - strength adhesion is required, such as in the assembly of electronic devices.This is particularly useful in applications that require high-strength adhesion, such as the assembly of electronic devices. In the production of printed circuit boards, adhesives containing tetrahydrofurfuryl acrylate can firmly bond components to the board, ensuring reliable electrical connections and mechanical stability.Adhesives containing tetrahydrofurfuryl acrylicate can be used to firmly bond components onto printed circuit boards. This ensures reliable electrical connections and mechanical strength.
It is also applied in the production of inks.Inks are also produced using this material. In UV - curable inks, tetrahydrofurfuryl acrylate helps to improve the ink's performance.Tetrahydrofurfuryl Acrylate improves the performance of UV-curable inks. It enables the ink to cure rapidly under UV light, reducing drying times significantly.It allows the inks to cure quickly under UV light and reduces drying times. This is highly beneficial in high - speed printing processes, like flexographic and screen printing.This is especially useful in high-speed printing processes like flexographic or screen printing. The cured ink film formed with the help of tetrahydrofurfuryl acrylate has good resistance to fading, scratching, and chemicals.The cured ink films formed by tetrahydrofurfuryl acrylicate are resistant to chemicals, fading and scratching. For example, in the packaging industry, UV - curable inks with this compound are used to print vibrant and long - lasting labels on various packaging materials, ensuring the product information remains clear and intact throughout the product's shelf - life.In the packaging industry, UV-curable inks containing this compound are used to create vibrant and long-lasting labels on various packaging materials. This ensures that the product information is clear and intact for the entire shelf-life of the product.
Furthermore, in the field of composites, tetrahydrofurfuryl acrylate can be used as a cross - linking agent.Tetrahydrofurfuryl Acrylate can also be used in composites as a cross-linking agent. When incorporated into composite materials, it helps to form a three - dimensional network structure, enhancing the mechanical properties of the composite.When incorporated into composites, it helps form a three-dimensional network structure that enhances the mechanical properties of composites. This can lead to improved strength, stiffness, and impact resistance of the composite material, making it suitable for applications in aerospace, automotive, and construction industries.This can improve the strength, stiffness and impact resistance of composite materials, making them suitable for applications in the aerospace, automotive and construction industries. For example, in the manufacturing of lightweight composite parts for aircraft interiors, the use of tetrahydrofurfuryl acrylate can contribute to the overall durability and performance of the parts.In the manufacture of lightweight composite interior parts for aircraft, tetrahydrofurfuryl acrylicate can improve the overall durability and performance.
What are the properties of tetrahydrofurfuryl acrylate?
Tetrahydrofurfuryl acrylate has several notable properties.Tetrahydrofurfuryl Acrylate has several notable properties.
Physical properties:Physical Properties
It is a clear, colorless to slightly yellow liquid.It is a clear liquid that can range from colorless to slightly yellow. It has a characteristic odor.It has a distinctive odor. The liquid has a relatively low viscosity, which allows it to flow easily.The liquid is relatively low in viscosity and flows easily. This property makes it suitable for applications where good fluidity is required, such as in coatings and inks formulations.This property makes it ideal for applications that require good fluidity, such as coatings and ink formulations. It has a boiling point in a specific range that enables it to be processed under certain temperature conditions during manufacturing processes.It has a boiling range that allows it to be processed at certain temperatures during manufacturing processes.
Chemical properties:Chemical properties
Tetrahydrofurfuryl acrylate contains an acrylate group, which is highly reactive.The acrylate group in tetrahydrofurfuryl is highly reactive. This acrylate functionality enables it to participate in polymerization reactions.This acrylate functionality allows it to participate in polymerization. It can readily undergo addition polymerization when exposed to appropriate initiators, such as free - radical initiators.It is easily polymerized by addition when exposed to the appropriate initiators such as free radical initiators. This reactivity is crucial for its use in the production of polymers and copolymers.This reactivity makes it ideal for the production of copolymers and polymers. The presence of the tetrahydrofurfuryl group also imparts some unique chemical characteristics.The presence of tetrahydrofurfuryl also confers some unique chemical properties. The tetrahydrofurfuryl moiety can contribute to the solubility of the compound in various solvents.The tetrahydrofurfuryl group can also contribute to the solubility in different solvents of the compound. It can enhance the compatibility of the acrylate with different polymers and additives.It can improve the compatibility of acrylate with polymers and additives.
Curing properties:Curing properties
When used in UV - curable or thermally - curable systems, tetrahydrofurfuryl acrylate can cross - link rapidly.Tetrahydrofurfuryl Acrylate can cross-link rapidly when used in UV-curable or thermally-curable systems. In UV - curable applications, upon exposure to ultraviolet light in the presence of a photoinitiator, the acrylate double bonds break and form new chemical bonds, leading to the formation of a solid, cross - linked network.In UV-curable applications, the acrylate double-bonds break upon exposure to UV light in the presence a photoinitiator. This leads to the formation a solid cross-linked network. This rapid curing property is highly beneficial in industries like printing and coatings, as it allows for quick production times and high - throughput manufacturing.This rapid curing property can be very beneficial to industries such as printing and coatings. It allows for high-throughput manufacturing and quick production times. The cured films formed from tetrahydrofurfuryl acrylate exhibit good hardness and abrasion resistance.The cured films made from tetrahydrofurfuryl acrylicate are hard and resistant to abrasion.
Solubility and miscibility:Solubility and miscibility
It has good solubility in many organic solvents, including common solvents like acetone, toluene, and ethyl acetate.It is soluble in many organic solvents including common solvents such as acetone, ethyl-acetate, and toluene. This solubility property is useful in formulating solutions for various applications.This property of solubility is useful when formulating solutions. It also shows good miscibility with a wide range of other monomers and oligomers.It also exhibits good miscibility when mixed with a variety of monomers and oligomers. This miscibility enables the preparation of copolymer systems with tailored properties.This miscibility allows for the creation of copolymer system with tailored properties. For example, by copolymerizing tetrahydrofurfuryl acrylate with other monomers, it is possible to adjust the hardness, flexibility, and chemical resistance of the resulting polymer.By copolymerizing the tetrahydrofurfuryl acrylicate with other monomers it is possible, for example, to adjust the hardness and flexibility of the polymer.
Biological and environmental properties:Biochemical and environmental properties
In terms of biological aspects, tetrahydrofurfuryl acrylate should be handled with care as it may have some degree of skin and eye irritation potential.Tetrahydrofurfuryl Acrylate should be handled with caution in terms of biological aspects. It may cause irritation of the skin and eyes. From an environmental perspective, its degradation in the environment depends on various factors.In terms of environmental degradation, it depends on a variety of factors. In aerobic conditions, it may be subject to biodegradation over time, although the rate of degradation can be influenced by the presence of other substances in the environment.In aerobic conditions it can biodegrade over time. However, the rate of degradation is affected by other substances in the surrounding environment.
Overall, the combination of its physical, chemical, curing, solubility, and other properties makes tetrahydrofurfuryl acrylate a valuable monomer in a variety of industrial applications.Tetrahydrofurfuryl Acrylate is a valuable monomer for a wide range of industrial applications because of its combination of physical, chemical, curing and solubility properties.
Is tetrahydrofurfuryl acrylate harmful to the environment?
Tetrahydrofurfuryl acrylate (THFA) can have potential harmful effects on the environment.Tetrahydrofurfuryl acrylate can have harmful effects on the environment.
Firstly, in terms of aquatic ecosystems, if THFA is released into water bodies, it can pose risks to aquatic organisms.THFA can be toxic to aquatic organisms. It may be toxic to fish, invertebrates, and other aquatic life forms.It could be toxic to aquatic organisms, including fish, invertebrates and other aquatic species. Some studies suggest that it can disrupt their normal physiological functions.Some studies suggest it can disrupt their physiological functions. For example, it might interfere with the respiratory systems of fish or affect the growth and reproduction of invertebrates like daphnia.It could, for example, affect the respiratory systems of the fish or the growth and reproduction invertebrates such as daphnia. This can lead to a decline in the populations of these organisms, which in turn can disrupt the entire food chain in the aquatic ecosystem.This can lead a decline in these organisms' populations, which can disrupt the entire aquatic food chain.
Secondly, in soil environments, THFA can potentially contaminate the soil.Secondly, THFA in soil environments can potentially contaminate soil. If present in significant amounts, it could affect soil microorganisms.It could have a negative impact on soil microorganisms if it is present in large amounts. These microorganisms play crucial roles in processes such as nutrient cycling and soil structure maintenance.These microorganisms are crucial in processes like nutrient cycling and maintaining soil structure. The presence of THFA may inhibit the growth or activity of these beneficial soil microbes.The presence of THFA can inhibit the growth of beneficial soil microbes. This could lead to a decrease in soil fertility and have a negative impact on plant growth as well, since healthy soil microorganisms are essential for plants to obtain nutrients.This could result in a decrease of soil fertility, and negatively impact plant growth. Healthy soil microorganisms provide nutrients to plants.
Furthermore, THFA is volatile to some extent.THFA is also volatile in some degree. When it volatilizes into the atmosphere, it can contribute to the formation of air pollutants.It can contribute to air pollution when it volatilizes in the atmosphere. It may react with other chemicals in the air, such as ozone and hydroxyl radicals, to form secondary pollutants.It can react with other chemicals, such as ozone or hydroxyl radicals in the air to form secondary pollutants. These secondary pollutants can have adverse effects on air quality and human health.These secondary pollutants may have negative effects on air quality or human health. Additionally, the release of volatile organic compounds like THFA can also contribute to the formation of smog, which reduces visibility and has negative impacts on both the environment and human well - being.The release of volatile organic substances like THFA may also contribute to smog formation, which can have negative effects on the environment and human health.
In conclusion, tetrahydrofurfuryl acrylate has the potential to cause harm to different aspects of the environment, including aquatic ecosystems, soil, and the atmosphere.Conclusion: Tetrahydrofurfuryl Acrylate can harm different aspects of the ecosystem, including soil, aquatic ecosystems, and the air. Therefore, proper handling, storage, and disposal of this chemical are necessary to minimize its environmental impact.To minimize the environmental impact of this chemical, it is important to handle, store, and dispose of it properly.
How is tetrahydrofurfuryl acrylate synthesized?
Tetrahydrofurfuryl acrylate can be synthesized through the following common methods.The following common methods can be used to synthesize Tetrahydrofurfuryl Acrylate.
One approach is the esterification reaction.Esterification is one method. In this method, acrylic acid and tetrahydrofurfuryl alcohol are used as starting materials.This method uses acrylic acid and tetrahydrofurfuryl alchohol as starting materials. An acid catalyst is typically employed to facilitate the reaction.A catalyst acid is usually used to facilitate the reaction. For example, sulfuric acid or p - toluenesulfonic acid can be used as the catalyst.Catalysts can include sulfuric acid, p-toluenesulfonic acids or p-toluenesulfonic acids. The reaction is carried out under certain reaction conditions.The reaction takes place under specific conditions. Usually, the reactants are heated to an appropriate temperature, often in the range of 80 - 120 degC.The reactants are usually heated to a temperature that is suitable, which is often between 80 and 120 degC. At this temperature, the carboxylic acid group of acrylic acid reacts with the hydroxyl group of tetrahydrofurfuryl alcohol.The carboxylic acid group in acrylic acid reacts at this temperature with the hydroxyl groups of tetrahydrofurfuryl alchol. During the reaction, water is produced as a by - product.Water is produced during the reaction. To drive the reaction forward, methods such as removing water from the reaction system can be adopted.Methods such as removing the water from the system can be used to drive the reaction. This can be achieved by using a Dean - Stark apparatus to continuously separate the generated water from the reaction mixture.The Dean-Stark apparatus can be used to continuously separate the water generated from the reaction mixture.
Another method is the transesterification reaction.Transesterification is another method. Methyl acrylate or ethyl acrylate can be used as the acrylate source.As an acrylate, ethyl or methyl acrylate may be used. These esters react with tetrahydrofurfuryl alcohol in the presence of a transesterification catalyst.These esters react in the presence a transesterification catalyzer with tetrahydrofurfuryl alchohol. Metal alkoxides like sodium methoxide or potassium ethoxide are common transesterification catalysts.Transesterification catalysts are usually metal alkoxides such as sodium methoxide and potassium ethoxide. The reaction conditions also involve heating, typically around 60 - 100 degC.The reaction conditions include heating, usually between 60 and 100 degrees Celsius. The alkoxy group of the methyl or ethyl acrylate is exchanged with the hydroxyl group of tetrahydrofurfuryl alcohol, resulting in the formation of tetrahydrofurfuryl acrylate and the corresponding alcohol (methanol or ethanol).The alkoxy group in the methyl or the ethyl acrylicate is exchanged for the hydroxyl group in the tetrahydrofurfuryl Alcohol, resulting the formation of the tetrahydrofurfurylacrylate and corresponding alcohols (methanol or alcohol). Similar to the esterification reaction, removing the by - product alcohol from the reaction system can help shift the equilibrium towards the formation of the desired product.Similar to the esterification, removing by-product alcohol from the system can help shift equilibrium in the direction of the desired product.
In both synthesis methods, after the reaction is completed, the product needs to be purified.Purification is required in both methods after the reaction has been completed. Purification can involve processes such as distillation.Purification may involve distillation. Tetrahydrofurfuryl acrylate has a specific boiling point, and by carefully controlling the distillation conditions, it can be separated from unreacted starting materials, catalysts, and other by - products to obtain a relatively pure product.Tetrahydrofurfuryl Acrylate has a specific melting point. By carefully controlling the conditions of distillation, it can be separated by unreacted starting materials and catalysts to obtain a relatively purified product.
What safety precautions should be taken when handling tetrahydrofurfuryl acrylate?
When handling tetrahydrofurfuryl acrylate, several safety precautions are essential.Safety precautions must be taken when handling tetrahydrofurfuryl acrylicate.
First, personal protective equipment (PPE) is crucial.Personal protective equipment (PPE), or PPE, is essential. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide a certain level of protection against tetrahydrofurfuryl acrylate.Nitrile gloves can offer a level of protection from tetrahydrofurfurylacrylate. This helps prevent skin contact, which can lead to irritation, redness, and potential allergic reactions.This can help prevent skin contact that could lead to irritation, rashes, and allergic reactions. In addition, safety goggles or a face shield should be worn.Safety goggles or face shields should also be worn. This protects the eyes from any splashes that could occur during handling.This will protect your eyes from any splashes which may occur during handling. The eyes are particularly vulnerable, and exposure to tetrahydrofurfuryl acrylate can cause severe eye irritation, pain, and even damage to vision.The eyes are especially vulnerable to the tetrahydrofurfuryl-acrylate, which can cause severe irritation, pain and even damage to sight.
Ventilation is another key aspect.Ventilation plays a key role. Tetrahydrofurfuryl acrylate has a certain vapor pressure, and its vapors can be harmful if inhaled.Tetrahydrofurfuryl Acrylate has a high vapor pressure and its vapors are harmful if inhaled. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably under the fume hood. A fume hood effectively captures and exhausts the vapors, reducing the risk of inhalation.A fume hood captures and exhausts vapors effectively, reducing the risk for inhalation. Inadequate ventilation can lead to respiratory problems such as coughing, shortness of breath, and irritation of the respiratory tract.Inadequate ventilation may cause respiratory problems, such as coughing and shortness of breathe, or irritation of the respiratory tract.
When storing tetrahydrofurfuryl acrylate, keep it in a cool, dry place away from heat sources and open flames.Store tetrahydrofurfuryl acrylicate in a cool and dry place, away from heat sources. It is flammable, and high temperatures or ignition sources can cause it to catch fire.It is flammable and can catch fire at high temperatures or from ignition sources. Store it in a tightly - sealed container to prevent evaporation and leakage.Store it in a tightly-sealed container to prevent evaporation. Also, make sure the storage area is separate from oxidizing agents as tetrahydrofurfuryl acrylate can react violently with them.Store it away from oxidizing agents, as tetrahydrofurfuryl acrylicate can react violently.
In case of accidental skin contact, immediately wash the affected area with plenty of soap and water for at least 15 minutes.If you accidentally touch your skin, wash it immediately with soap and water. If eye contact occurs, flush the eyes with copious amounts of water for at least 15 minutes and seek immediate medical attention.If eye contact occurs flush the eyes for at least 15 minute with large amounts of water and seek immediate medical assistance. In case of inhalation, move to fresh air immediately.In the event of inhalation, get to fresh air as soon as possible. If the person is experiencing difficulty breathing, provide artificial respiration if trained to do so and call for emergency medical help.If the person has difficulty breathing, if you are trained to do this, you can provide artificial respiration and call emergency medical help.
Finally, be aware of the spill response procedures.Be aware of the spill response procedure. In the event of a spill, first, isolate the area to prevent others from being exposed.First, isolate the spilled area to avoid exposing others. Use absorbent materials such as sand or vermiculite to soak up the spill.To absorb the spill, use absorbent materials like sand or Vermiculite. Dispose of the contaminated absorbent according to local regulations.Dispose of contaminated absorbents according to local regulations. Do not rinse the spill into the sewer as it can contaminate water systems.Do not flush the spilled liquid into the sewer system as it could contaminate the water systems.