.
Product Name | Tridecyl methacrylate |
Cas Number | 2549-53-3 |
Formula | C16H30O2 |
Molar Mass | 254.41 |
Density | 0.87 g/cm³ |
Boiling Point | 310-312°C |
Refractive Index | 1.442 |
Flash Point | 115°C |
Viscosity | 5-9 mPa·s at 20°C |
Appearance | Clear liquid |
Solubility | Immiscible in water |
Vapor Pressure | 0.00031 mmHg at 25°C |
Autoignition Temperature | Not available |
Melting Point | Not applicable |
Specific Heat Capacity | Not available |
What are the main applications of tridecyl methacrylate?
Tridecyl methacrylate is an organic compound with a variety of applications in different industries.Tridecylmethacrylate, an organic compound, has a wide range of applications across different industries.
One of the significant applications is in the coatings industry.Coatings are one of the most important applications. It is used as a monomer to produce polymers for coatings.It is used to make polymers for coatings. The resulting polymers can provide good film - forming properties.The polymers produced can have good film-forming properties. These coatings can be applied on various substrates, such as metals, plastics, and wood.These coatings are suitable for a variety of substrates including metals, wood, and plastics. They offer protection against environmental factors like moisture, corrosion, and abrasion.They protect against environmental factors such as moisture, corrosion, abrasion, and more. For example, in the automotive industry, coatings containing tridecyl methacrylate can enhance the durability and appearance of car bodies, ensuring that they withstand the rigors of daily use and different weather conditions.In the automotive industry, for example, coatings that contain tridecylmethacrylate can improve the durability and appearance, and ensure that car bodies are able to withstand the rigors and weather conditions of daily use.
In the adhesives field, tridecyl methacrylate plays an important role.Tridecylmethacrylate is a key ingredient in the adhesives industry. When incorporated into adhesive formulations, it can improve the adhesion strength between different materials.It can be used to improve adhesion between different materials when incorporated into adhesive formulas. It helps in creating a strong bond, whether it is bonding plastics to metals or different types of polymers together.It creates a strong bond when bonding metals to plastics or different polymers together. This is crucial in manufacturing processes where reliable joining of components is required, like in the production of electronic devices, where small parts need to be firmly adhered.This is important in manufacturing processes that require reliable joining of components, such as in the production electronic devices where small parts must be firmly adhered.
The plastic and polymer modification area also benefits from tridecyl methacrylate.Tridecylmethacrylate is also useful in the plastic and polymer modification field. By copolymerizing it with other monomers, the properties of the resulting polymers can be tailored.Copolymerizing tridecyl methacrylate with other monomers allows for tailoring the properties of polymers. For instance, it can enhance the flexibility of polymers.It can, for example, increase the flexibility of polymers. In the production of flexible plastics used in packaging materials, adding tridecyl methacrylate can make the plastic more pliable while still maintaining sufficient strength.Tridecylmethacrylate is added to flexible plastics for packaging materials in order to make them more flexible while maintaining their strength. This is useful for applications such as shrink - wrap films or flexible pouches that need to conform to different shapes.This is useful in applications such as shrink-wrap films or flexible pouches which need to conform to various shapes.
In the textile industry, tridecyl methacrylate can be used to modify fabrics.Tridecylmethacrylate is used in the textile industry to modify fabrics. It can be applied in finishes to improve the fabric's resistance to stains and wrinkles.It can be used in finishes to improve fabric resistance to stains and wrinkles. When treated with polymers containing this compound, fabrics become more durable and easier to maintain.Fabrics become more durable and easy to maintain when treated with polymers that contain this compound. Additionally, it can also enhance the feel of the fabric, making it softer or giving it a unique texture.It can also improve the feel of fabric by making it softer and giving it a unique appearance.
Finally, in the field of inks, tridecyl methacrylate can be part of the ink formulation.Tridecylmethacrylate is also used in the formulation of inks. It helps in improving the drying speed of the ink and its adhesion to the printing substrate.It improves the drying speed of inks and their adhesion to printing substrates. This is especially important in high - speed printing processes, where quick - drying and well - adhering inks are essential for efficient production and high - quality prints.This is particularly important for high-speed printing processes where fast-drying and well-adhering inks are crucial for efficient production and good-quality prints. Whether it is for printing on paper, cardboard, or other materials, the addition of tridecyl methacrylate can enhance the performance of the ink.Tridecylmethacrylate is a great additive for inks that are used to print on paper, cardboard or other materials.
What are the physical and chemical properties of tridecyl methacrylate?
Tridecyl methacrylate is an organic compound with the following physical and chemical properties:Tridecylmethacrylate is a compound that has the following physical and chemistry properties:
Physical properties:Physical Properties
1. Appearance: It is typically a clear, colorless to pale - yellow liquid.Appearance: It's usually a clear, colorless liquid. This appearance is common for many organic esters in a pure state, and the relatively light color indicates a lack of significant chromophoric groups or impurities that could cause stronger coloration.This is a common appearance for many organic esters when they are in their pure state. The relatively light color indicates that there are no significant chromophoric group or impurities which could cause a stronger coloration.
2. Odor: It has a characteristic, somewhat sweet and ester - like odor.Odor: It is a characteristic, sweet and ester-like odor. Esters often have pleasant or at least distinct odors, which are related to their molecular structure containing the carbonyl and alkoxy groups.Esters have a pleasant or distinct odor, which is related to the molecular structure of their carbonyl and hydroxyl groups.
3. Solubility: Tridecyl methacrylate is soluble in common organic solvents such as hydrocarbons (e.g., hexane, toluene), chlorinated solvents (e.g., dichloromethane), and ethers (e.g., diethyl ether).Tridecyl Methacrylate is easily soluble in organic solvents, such as hydrocarbons, chlorinated solvents, and ethers, like diethyl-ether. This solubility is due to its non - polar long - chain alkyl group and the relatively non - polar nature of the methacrylate moiety, which can interact favorably with the non - polar solvents through van der Waals forces.This is due to the non-polar long-chain alkyl group, and the relatively non-polar nature of the moiety methacrylate. These can interact favorably with non-polar solvents via van der Waals forces. However, it has very low solubility in water.It is very insoluble in water. The long alkyl chain and the hydrophobic nature of the methacrylate group prevent significant interaction with the polar water molecules, following the principle of "like dissolves like."The hydrophobic and long alkyl chains of the methacrylate groups prevent significant interaction with polar water molecules. This is based on the principle "like dissolves as."
4. Boiling point and melting point: Due to the relatively long tridecyl chain, it has a relatively high boiling point.It has a relatively higher melting point due to its relatively long tridecyl chains. The long chain increases the intermolecular forces, specifically van der Waals forces, which require more energy to overcome for the compound to transition from the liquid to the gaseous state.The long chain increases intermolecular forces and van der Waals forces which require more energy for the compound to go from liquid to gaseous. The melting point is also relatively low but still higher than many small - molecule esters, as the long chain allows for some degree of molecular packing in the solid state.The melting point of this compound is relatively low, but still higher than that of many small-molecule esters. This is because the long chain allows some degree molecular packing when in the solid state.
Chemical properties:Chemical properties
1. Polymerizability: The methacrylate group in tridecyl methacrylate contains a carbon - carbon double bond.Polymerizability - The methacrylate groups in tridecylmethacrylate contain a double carbon-carbon bond. This double bond is highly reactive and can undergo polymerization reactions.This double bond can undergo polymerization reactions. Radical polymerization is a common method, where an initiator generates free radicals that react with the double bond, leading to the formation of long - chain polymers.Radical polymerization, where an initiator creates free radicals, reacts with the double bond to form long-chain polymers, is a common technique. These polymers can be used in various applications such as coatings, adhesives, and plastics, due to the good film - forming properties and the hydrophobic nature contributed by the long alkyl side - chain.These polymers are suitable for a variety of applications, including coatings, adhesives and plastics. This is due to their good film-forming properties and hydrophobic nature.
2. Hydrolysis: In the presence of water and an appropriate catalyst (such as an acid or a base), tridecyl methacrylate can undergo hydrolysis.Hydrolysis: Tridecylmethacrylate can be hydrolyzed in the presence of water, and a suitable catalyst (such an acid or base). In acidic hydrolysis, the ester bond is cleaved, forming methacrylic acid and tridecyl alcohol.In acidic hydrolysis the ester bond is broken, forming tridecyl alcohol and methacrylic alcohol. In basic hydrolysis (saponification), the reaction is more rapid, and the products are the carboxylate salt of methacrylic acid and tridecyl alcohol.In basic hydrolysis, the reaction is faster and the products are tridecyl and carboxylate methacrylic acids.
3. Reactivity with nucleophiles: The carbonyl carbon in the methacrylate group is electrophilic.The carbonyl group in the methacrylate is electrophilic. Nucleophiles such as amines, alcohols, and thiols can react with it.Nucleophiles like amines and alcohols can react with this. For example, an amine can react with tridecyl methacrylate in a nucleophilic acyl substitution reaction, replacing the tridecyl group with the amine - derived group, forming an amide - like product.In a nucleophilic substitution reaction, an amine, for example, can react with tridecylmethacrylate, replacing the tridecyl groups with the amine-derived group and forming a amide-like product. This reactivity can be exploited in the synthesis of more complex organic molecules or in the modification of surfaces containing reactive groups.This reactivity is useful in the synthesis and modification of organic molecules containing reactive groups.
How is tridecyl methacrylate synthesized?
Tridecyl methacrylate can be synthesized through an esterification reaction.A tridecylmethacrylate can also be synthesized by an esterification process. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
1. Starting Materials Preparation
The synthesis of tridecyl methacrylate typically involves two main starting materials: methacrylic acid and tridecyl alcohol.Tridecylmethacrylate is typically synthesized from two main materials: methacrylic and tridecylalcohol. Methacrylic acid is a common monomer with a double - bond and a carboxylic acid group.Methacrylic is a monomer that has a double-bond and a carboxylic group. Tridecyl alcohol, on the other hand, contains a long - chain alkyl group with 13 carbon atoms.Tridecyl Alcohol, on the contrary, contains an alkyl long-chain group with 13 carbons. These starting materials need to be of high purity to ensure a good - quality product.To ensure high-quality products, these starting materials must be highly pure. They can be purchased from chemical suppliers or further purified through methods like distillation if necessary.These materials can be purchased at chemical suppliers, or they can be further purified by methods such as distillation.
2. Esterification Reaction
The core step is the esterification of methacrylic acid with tridecyl alcohol.The main step is the esterification between methacrylic and tridecyl alcohol. This reaction is usually catalyzed by an acid catalyst.This reaction is usually catalyzed with an acid catalyst. Sulfuric acid or p - toluenesulfonic acid is commonly used.Sulfuric or p-toluenesulfonic acids are commonly used. The reaction is as follows: Methacrylic acid (CH2 = C(CH3)COOH) reacts with tridecyl alcohol (C13H27OH) in the presence of the acid catalyst to form tridecyl methacrylate (CH2 = C(CH3)COOC13H27) and water (H2O).The reaction is as follow: Methacrylic Acid (CH2 = CC(CH3)COOH), reacts with Tridecyl Alcohol (C13H27OH), in the presence acid catalyst, to form tridecylmethacrylate (CH2= CC(CH3)COOC13H27), and water (H2O).
The reaction is carried out under reflux conditions.The reaction takes place under reflux conditions. Refluxing helps to maintain a constant reaction temperature, usually around the boiling point of the reaction mixture.Refluxing maintains a constant temperature for the reaction, usually around the boiling-point of the reaction mixture. This ensures that the reactants are in the liquid phase and continuously react.This ensures the reactants remain in the liquid phase, and continue to react. The reaction is reversible, so to drive the reaction towards the formation of the ester (tridecyl methacrylate), an excess of one of the reactants can be used.The reaction is reversible. To drive the reaction in the direction of the ester, (tridecylmethacrylate), you can use an excess of one reactant. For example, an excess of tridecyl alcohol can be added.An excess of tridecyl ethanol, for example, can be added. Also, removing the water formed during the reaction can shift the equilibrium towards the product side.Removing the water formed in the reaction can also shift the equilibrium to the product side. This can be achieved by using a Dean - Stark apparatus, which separates and removes the water from the reaction mixture.This can be done by using a Dean-Stark apparatus that separates and removes water from the reaction mixture.
3. Product Isolation and PurificationProduct Isolation & Purification
After the reaction has proceeded for an appropriate amount of time, as determined by techniques such as gas chromatography or thin - layer chromatography, the reaction mixture is worked up.After the reaction has been carried out for the appropriate time, as determined using techniques such as thin-layer chromatography or gas chromatography, it is worked up. First, the acid catalyst is neutralized.The acid catalyst must first be neutralized. This can be done by adding a base, such as sodium carbonate or sodium hydroxide, to the reaction mixture.Add a base such as sodium hydroxide or sodium carbonate to the reaction mixture. The resulting mixture then contains the crude tridecyl methacrylate, along with salts and unreacted starting materials.The crude tridecylmethacrylate is then added to the reaction mixture, along with unreacted materials and salts.
The product can be extracted into an organic solvent, like diethyl ether or dichloromethane.The product can also be extracted using an organic solvent like dichloromethane or diethylether. The organic layer is then washed several times with water to remove any remaining salts and water - soluble impurities.The organic layer will then be washed with water several times to remove any remaining impurities and salts. After that, the organic layer is dried over anhydrous sodium sulfate or magnesium sulfate to remove any traces of water.The organic layer is then dried over anhydrous magnesium sulfate, or sodium sulfate. This removes any traces of moisture. Finally, the solvent is removed by distillation under reduced pressure.The solvent is then removed under reduced pressure by distillation. This purification step helps to obtain pure tridecyl methacrylate, which can be characterized by techniques like nuclear magnetic resonance (NMR) spectroscopy and infrared (IR) spectroscopy to confirm its structure.This step of purification helps to obtain pure tridecylmethacrylate. It can be characterized using techniques such as nuclear magnetic resonance spectroscopy (NMR) and infrared spectroscopy (IR) to confirm its structural.
What are the safety precautions when handling tridecyl methacrylate?
Tridecyl methacrylate is a chemical compound.Tridecylmethacrylate is an organic chemical compound. When handling it, several safety precautions are necessary.It is important to take several safety precautions when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. This is crucial as contact with the skin can potentially lead to irritation or other adverse effects.It is important to wear gloves that are resistant to chemicals. Contact with the skin could cause irritation or other adverse reactions. The gloves should be made of materials that can withstand the corrosive or harmful nature of tridecyl methacrylate.Gloves should be made from materials that can withstand tridecylmethacrylate's corrosive and harmful nature. Additionally, goggles or a face shield are essential to protect the eyes.Goggles or a shield for the face are also essential to protect your eyes. In case of any splashes, these protective eyewear can prevent the chemical from getting into the eyes, which could cause serious damage such as burns or vision impairment.These protective eyewear can help prevent chemical splashes from entering the eyes and causing serious damage, such as vision impairment or burns.
Second, ensure proper ventilation. Work in a well - ventilated area, preferably in a fume hood if possible.Work in an area that is well-ventilated, preferably under a fume hood. Tridecyl methacrylate may release vapors that can be harmful if inhaled.Tridecylmethacrylate can release vapors which are harmful if inhaled. Adequate ventilation helps to disperse these vapors, reducing the risk of respiratory problems.Adequate ventilation can help disperse the vapors and reduce the risk of respiratory issues. Inhalation of its vapors might lead to irritation of the respiratory tract, coughing, shortness of breath, or more severe long - term health issues if exposure is prolonged.Inhaling its vapors can cause irritation of the respiratory tract. It may also cause coughing, shortness or breath, and more serious long-term health issues if exposed for a prolonged period of time.
Third, be cautious during storage.Third, take care when storing tridecyl methacrylate. Store tridecyl methacrylate in a cool, dry place away from sources of heat, ignition, and incompatible substances.Store tridecylmethacrylate in an area that is cool and dry, away from heat sources, ignitions, and incompatible materials. Heat can increase the volatility of the compound and may also cause it to react unpredictably.Heat can increase the volatile nature of the compound, and it may also cause an unpredictable reaction. Incompatible substances could lead to chemical reactions that might be dangerous, such as the release of toxic gases or an explosion.Incompatible substances can cause dangerous chemical reactions, such as toxic gas release or explosion.
Fourth, in case of spills.Fourth, in the event of spills. If a spill occurs, immediately evacuate the area if the amount is large or if there is a significant release of vapors.If there is a spill, evacuate the area immediately if it is large or if vapors are released. For small spills, use appropriate absorbent materials to clean it up.Use absorbent materials for small spills. Avoid direct contact with the spilled substance during the clean - up process.Avoid direct contact with spilled substances during the cleaning process. Dispose of the absorbent materials and any contaminated items in accordance with local environmental and safety regulations.Dispose of absorbent materials, contaminated items and any other contaminated items according to local environmental and safety regulations.
Finally, have first - aid measures in place.Last but not least, ensure that you have first-aid measures in place. In case of skin contact, immediately wash the affected area with plenty of water for at least 15 minutes and remove any contaminated clothing.In the event of skin contact, wash the affected area immediately with plenty of water and for at least 15 minute. Remove any contaminated clothing. If it gets into the eyes, flush the eyes with copious amounts of water for a long time and seek immediate medical attention.If it gets in the eyes, wash the eyes for a long period of time with a lot of water. Seek immediate medical attention. In case of inhalation, move the affected person to fresh air and if breathing is difficult, provide artificial respiration and call for medical help.In the case of inhalation move the person to fresh air. If breathing is difficult provide artificial respiration. Call for medical assistance.
What are the storage requirements for tridecyl methacrylate?
Tridecyl methacrylate is an organic compound that requires specific storage conditions to maintain its quality and safety.Tridecylmethacrylate, an organic compound, requires specific storage conditions in order to maintain its quality.
Firstly, it should be stored in a cool place.It should be kept in a cool, dry place. High temperatures can accelerate chemical reactions, such as polymerization.High temperatures can speed up chemical reactions such as polymerization. An ideal storage temperature range is typically around 2 - 8 degrees Celsius.Ideal storage temperatures are typically between 2 and 8 degrees Celsius. This helps to slow down any potential degradation processes and maintain the chemical stability of tridecyl methacrylate.This will help to slow down any degradation processes and maintain tridecylmethacrylate's chemical stability. For example, in a well - regulated cold storage facility, the risk of unwanted reactions due to heat is minimized.In a cold storage facility that is well-regulated, the risk of unwanted reaction due to heat can be minimized.
Secondly, storage in a dry environment is crucial.Second, it is important to store the product in a dry atmosphere. Moisture can cause hydrolysis reactions in tridecyl methacrylate.Tridecylmethacrylate can be hydrolyzed by moisture. Water molecules can break down the ester bond present in the compound.Water molecules can break the ester bond in the compound. A humidity level of less than 60% is advisable.It is recommended to keep the humidity below 60%. This can be achieved by using desiccants in the storage area or storing the compound in a location with proper ventilation and dehumidification systems.This can be achieved using desiccants or by storing the compound at a location that has proper ventilation and dehumidification.
It also needs to be stored away from sources of ignition.Store it away from ignition sources. Tridecyl methacrylate is flammable.Tridecylmethacrylate can ignite. Keep it far from open flames, sparks from electrical equipment, or any other potential ignition sources.Keep it away from open flames or sparks from electrical appliances, as well as any other possible ignition sources. This includes areas where welding operations are taking place or near heaters that can generate high - temperature surfaces.This includes areas where welding is taking place or heaters that can produce high-temperature surfaces.
Furthermore, the storage containers should be carefully selected.The storage containers themselves should also be carefully chosen. They should be made of materials that are compatible with tridecyl methacrylate.The containers should be made from materials compatible with tridecylmethacrylate. For instance, containers made of certain plastics or metals that do not react with the compound.Containers made from certain metals or plastics will not react with tridecyl methacrylate. The containers should be tightly sealed to prevent evaporation and contamination.Containers should be tightly closed to prevent contamination and evaporation. A good - quality seal also helps in maintaining the purity of the tridecyl methacrylate over time.Seals of high quality help to maintain the purity of tridecylmethacrylate.
In addition, the storage area should be well - labeled.The storage area must also be clearly labeled. Clearly indicate that it contains tridecyl methacrylate, along with any relevant safety information such as its flammable nature.Indicate that the tridecylmethacrylate is present, as well as any safety information relevant to it such as its flammable properties. This ensures that anyone handling or working in the vicinity is aware of the potential hazards and takes appropriate precautions.This will ensure that anyone working or handling the product is aware of any potential hazards.
Finally, proper inventory management is necessary.It is also important to have a good inventory management system. Regularly check the stored tridecyl methacrylate for any signs of degradation, such as changes in color, odor, or viscosity.Check the tridecylmethacrylate stored for signs of degradation such as color, odor or viscosity. Rotate the stock to ensure that the older batches are used first, minimizing the risk of long - term storage - related issues.Rotate the stock so that older batches are used before the newer ones. This will minimize the risk of storage-related issues.