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Triethyleneglycol Dimethacrylate


Properties
Product Name Triethyleneglycol dimethacrylate
Cas Number 109-16-0
Formula C14H22O6
Molar Mass 286.32
Density 1.10 g/cm³
Boiling Point 230-240°C
Melting Point <0°C
Flash Point 134°C
Viscosity 7-10mPa.s
Refractive Index 1.4590
Solubility In Water Practically insoluble
Vapor Pressure <0.01 mmHg at 20°C
Appearance Colorless liquid
Odor Slight characteristic odor
FAQ

What are the main applications of Triethyleneglycol dimethacrylate?

Triethyleneglycol dimethacrylate (TEGDMA) has several main applications across different fields.Triethyleneglycol Dimethacrylate (TEGDMA), a chemical compound, has many applications in different fields.
In the dental industry, TEGDMA is a crucial component.TEGDMA plays a vital role in the dental industry. It is used as a monomer in dental composite resins.It is used in dental composite resins as a monomer. Dental composites are widely used for restoring teeth, such as filling cavities.Dental composites are used to restore teeth, including filling cavities. TEGDMA helps in cross - linking the resin system.TEGDMA is used to cross-link the resin system. When combined with other monomers and photo - initiators, it can be polymerized under visible light.It can be polymerized with visible light when combined with other monomers or photo-initiators. This results in a hard and durable material that can mimic the natural properties of teeth.This produces a durable and hard material that mimics the natural properties found in teeth. Its ability to form a strong network upon polymerization ensures the long - term stability of dental restorations, withstanding the mechanical forces exerted during chewing.Its ability, upon polymerization, to form a solid network ensures long-term stability of dental restorations.

The coatings industry also benefits from TEGDMA.TEGDMA is also beneficial to the coatings industry. It can be incorporated into coatings formulations.It can be incorporated in coating formulations. For example, in automotive clearcoats, TEGDMA can improve the hardness and abrasion resistance of the coating.TEGDMA, for example, can improve the hardness of automotive clearcoats and their resistance to abrasion. When applied to the surface of a car, the coating formed with TEGDMA can better protect the underlying paint from scratches and environmental factors like UV radiation and chemicals.The coating created with TEGDMA on the surface of a vehicle can protect the paint underneath from scratches, UV radiation and chemicals. In industrial coatings, it can enhance the adhesion of the coating to the substrate, providing a more stable and long - lasting finish.In industrial coatings it can improve the adhesion between the coating and the substrate. This provides a more stable, long-lasting finish.

In the production of polymers and plastics, TEGDMA serves as a cross - linking agent.TEGDMA is used as a cross-linking agent in the production of plastics and polymers. By adding TEGDMA to a polymer system, the resulting polymer can have enhanced mechanical properties.By adding TEGDMA into a polymer, the resulting material can have improved mechanical properties. For instance, in the manufacturing of acrylic - based plastics, cross - linking with TEGDMA can increase the strength, toughness, and heat resistance of the plastic.In the manufacture of acrylic based plastics, for example, cross-linking with TEGDMA increases the strength, toughness and heat resistance of plastic. This makes these plastics suitable for applications where higher performance is required, such as in electronic enclosures or in some types of household appliances.These plastics are therefore suitable for applications that require higher performance, such as electronic enclosures and some types of household appliances.

TEGDMA is also used in the synthesis of hydrogels.TEGDMA can also be used to synthesize hydrogels. Hydrogels are three - dimensional networks of polymers that can absorb and retain a large amount of water.Hydrogels are polymer networks that are three-dimensional and can absorb a large amount water. TEGDMA can be used to cross - link hydrophilic polymers to form hydrogels.TEGDMA is a technique that can be used to cross-link hydrophilic polymers into hydrogels. These hydrogels have applications in areas like wound dressings, where they can provide a moist environment for wound healing.These hydrogels can be used in areas such as wound dressings where they can provide an environment that is moist for wound healing. They can also be used in drug delivery systems, as the cross - linked structure can control the release rate of drugs over time.They can be used as drug delivery systems because the cross-linked structure can control the rate of release over time.

In the field of 3D printing, TEGDMA can be part of the resin formulations.TEGDMA is a component of resin formulations in the field of 3D Printing. As a cross - linking monomer, it enables the formation of complex 3D structures.It is a cross-linking monomer that allows for the formation of complex three-dimensional structures. The ability to precisely control the polymerization of TEGDMA - containing resins using techniques like stereolithography allows for the production of high - resolution 3D printed objects, which can be used in prototyping, jewelry making, and the production of customized medical devices.The ability to precisely control polymerization using stereolithography techniques allows for the creation of high - quality 3D printed objects. These can be used for prototyping, jewelry-making, and the manufacture of customized medical devices.

What are the safety precautions when handling Triethyleneglycol dimethacrylate?

Triethyleneglycol dimethacrylate is a chemical compound that requires certain safety precautions during handling.Triethyleneglycol Dimethacrylate (Tegdi) is a chemical that requires special handling precautions.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. When working with it, wear appropriate chemical - resistant gloves.Wear chemical-resistant gloves when working with it. Nitrile gloves are often a good choice as they can provide a barrier against contact with the chemical.Nitrile gloves can be a good option as they provide a barrier to contact with the chemical. This helps prevent skin absorption, which could lead to irritation or other health effects.This prevents skin absorption that could cause irritation or other health problems. Also, wear safety goggles or a face shield.Wear safety goggles and a face shield. Triethyleneglycol dimethacrylate can be harmful if it splashes into the eyes, potentially causing eye damage, including irritation, redness, and in severe cases, vision impairment.Triethyleneglycol Dimethacrylate is harmful if splashed into the eyes. It can cause irritation, redness and, in severe cases vision impairment.

Second, ensure proper ventilation. Work in a well - ventilated area, preferably under a fume hood.Work in an area that is well-ventilated, preferably under the fume hood. This chemical may release vapors, and inhaling these vapors can cause respiratory problems.Inhaling vapors from this chemical can cause respiratory problems. Good ventilation helps to dilute the vapors, reducing the risk of inhalation exposure.Good ventilation can dilute the vapors and reduce the risk of exposure through inhalation. If the work area is not well - ventilated, the vapors can build up, increasing the likelihood of respiratory irritation, coughing, or more serious respiratory issues over time.If the work area does not have adequate ventilation, vapors may build up and cause respiratory irritation, coughing or other respiratory issues.

Third, be cautious about storage.Third, be careful about storage. Store triethyleneglycol dimethacrylate in a cool, dry place away from heat sources and ignition sources.Store triethyleneglycol dimethylacrylate in a dry, cool place away from heat and ignition sources. It is flammable, so any heat or open flames near the storage area pose a significant fire risk.Any heat or open flames in the vicinity of the storage area can cause a fire. Keep it in a tightly sealed container to prevent leakage and evaporation.Keep it in a tightly-sealed container to prevent leaking and evaporation. Label the storage container clearly with the name of the chemical, its hazards, and any necessary handling instructions.Label the container with the name of chemical, its hazards and any necessary instructions.

Fourth, in case of spills.Fourth, in the event of spills. If a spill occurs, immediately evacuate the area if the spill is large or if there is a significant release of vapors.If there is a spill, evacuate the area immediately if it is large or if vapors are released. For small spills, carefully absorb the liquid using an appropriate absorbent material, such as sand or an approved spill - control kit.Use sand, or a spill-control kit, to absorb small spills. Do not use materials that could react with the chemical.Avoid using materials that may react with the chemical. Dispose of the contaminated absorbent in accordance with local environmental regulations.Dispose the contaminated absorbent according to local environmental regulations. Wash the spill area thoroughly with water and appropriate cleaning agents to remove any remaining chemical residues.To remove any remaining residues, thoroughly wash the spill area with water and cleaning agents.

Finally, be aware of first - aid measures.Be aware of the first-aid measures. In case of skin contact, immediately remove contaminated clothing and wash the affected area with plenty of soap and water for at least 15 minutes.In the event of skin contact, remove the contaminated clothing immediately and wash it with soap and water for 15 minutes. Seek medical attention if irritation persists. For eye contact, flush the eyes with copious amounts of water for at least 15 minutes, lifting the eyelids occasionally to ensure thorough rinsing, and then seek immediate medical help.If you have eye contact, rinse your eyes for at least 15 mins with plenty of water, lifting your eyelids periodically to ensure thorough rinsing. Then seek immediate medical attention. If inhaled, move the affected person to fresh air immediately.If inhaled immediately move the person to fresh air. If the person is not breathing, perform CPR if trained to do so and call for emergency medical assistance.If the person does not breathe, perform CPR on them if you are trained to do so. Call for emergency medical help.

How is Triethyleneglycol dimethacrylate produced?

Triethyleneglycol dimethacrylate is produced through a series of chemical reactions.Triethyleneglycol Dimethacrylate can be produced by a series chemical reactions.
The starting materials typically involve triethylene glycol and methacrylic acid.Triethylene glycol or methacrylic acids are usually the starting materials. One common method is the esterification reaction.Esterification is a common method. In this process, triethylene glycol reacts with methacrylic acid in the presence of a catalyst.Triethylene glycol reacts in the presence a catalyst with methacrylic acids. Sulfuric acid or p - toluenesulfonic acid are often used as catalysts.Catalysts are often sulfuric acid or p-toluenesulfonic acids. These catalysts help to speed up the reaction by lowering the activation energy.These catalysts can help speed up the reaction because they lower the activation energy.

The reaction can be represented as follows: Triethylene glycol has two hydroxyl (-OH) groups.Triethylene glycol contains two hydroxyl groups (-OH). Each of these hydroxyl groups can react with the carboxyl (-COOH) group of methacrylic acid.Each of these hydroxyl group can react with the carboxyl group (-COOH). During the reaction, a molecule of water is eliminated for each ester bond formed.During the reaction, one molecule of water per ester bond is eliminated. This is a condensation reaction.This is a condensation process.

To drive the reaction forward and increase the yield, the water produced during the reaction is often removed.The water produced by the reaction is often removed to accelerate the reaction and increase the yield. This can be achieved by using techniques such as distillation.This can be done by using techniques like distillation. By continuously removing the water, the equilibrium of the reaction is shifted towards the formation of triethyleneglycol dimethacrylate according to Le Chatelier's principle.According to Le Chatelier’s principle, by continuously removing water from the reaction, the equilibrium is shifted in favour of the formation of triethyleneglycol dimethylacrylate.

Another aspect is the purification of the product.Purification of the product is another aspect. After the reaction is complete, the mixture may contain unreacted starting materials, by - products, and the catalyst.After the reaction has been completed, the mixture can contain unreacted materials, by-products, and the catalyst. Purification steps are necessary to obtain pure triethyleneglycol dimethacrylate.To obtain pure triethyleneglycol dimethylacrylate, purification steps are required. Filtration can be used to remove any solid impurities.Filtration is a good way to remove solid impurities. Distillation is a common method to separate the product from other volatile components based on their different boiling points.Distillation can be used to separate volatile components from the product based on boiling points. Column chromatography can also be employed for further purification, especially when a high - purity product is required.Column chromatography is also a method for purification, particularly when a high-purity product is required.

In industrial production, safety and environmental considerations are crucial.Safety and environmental considerations in industrial production are vital. The handling of methacrylic acid, which is corrosive, requires proper safety measures.Safety measures are required when handling methacrylic acids, which are corrosive. Also, waste management from the reaction, such as the disposal of the catalyst residues and any unreacted materials, needs to be done in an environmentally friendly way.Waste management is also important, including the environmentally friendly disposal of catalyst residues, unreacted materials and other waste products.

What are the physical and chemical properties of Triethyleneglycol dimethacrylate?

Triethyleneglycol dimethacrylate is a chemical compound with distinct physical and chemical properties.Triethyleneglycol Dimethacrylate (TDMA) is a chemical with distinct physical and chemistry properties.
Physical properties:Physical Properties
In terms of appearance, it is typically a clear, colorless to pale - yellow liquid.It is usually a clear, colorless liquid that can range from pale yellow to clear. This liquid state at room temperature makes it relatively easy to handle in various industrial processes.Its liquid state at room temperatures makes it easy to handle for various industrial processes. It has a characteristic odor, although the exact nature of the smell can be described as somewhat sweet - like and pungent.It has a distinctive odor. The exact nature of the odor can be described as sweet-like and pungent.

The compound has a relatively high boiling point.The compound has a high boiling point. This is due to the presence of intermolecular forces such as van der Waals forces and dipole - dipole interactions.This is due the presence of intermolecular interactions such as van der Waals and dipole-dipole interactions. The high boiling point implies that it can withstand elevated temperatures without readily vaporizing, which is useful in applications where it needs to remain in a liquid phase during processing steps involving heat.Its high boiling point means that it can withstand high temperatures without vaporizing. This is useful for applications where the liquid phase must remain during heat-related processing steps. Its density is also an important physical property.Its density is another important physical property. It has a density greater than that of water, which means it will sink in water if the two substances are mixed.It has a greater density than water, so it will sink if you mix the two substances.

Solubility is another key physical aspect.Another important physical characteristic is soluble. Triethyleneglycol dimethacrylate is soluble in many organic solvents such as acetone, ethanol, and toluene.Triethyleneglycol Dimethacrylate can be dissolved in many organic solvents, such as acetone and ethanol. This solubility in organic solvents allows it to be incorporated into different formulations, enabling it to be used in coatings, adhesives, and inks.Its solubility in organic solvants allows it to easily be incorporated into a variety of formulations. This includes coatings, inks, adhesives and other products. However, it has limited solubility in water.It is only soluble in water. This is because the molecule is relatively non - polar due to the long carbon - chain and ester groups, which do not interact favorably with the polar water molecules.The molecule is non-polar due to its long carbon-chain and ester groups. These do not interact well with the water molecules.

Chemical properties:Chemical properties
The most prominent chemical feature of triethyleneglycol dimethacrylate is the presence of two methacrylate groups.The presence of two methacrylate group is the most notable chemical feature of triethyleneglycol dimethacrylate. These double - bond - containing functional groups are highly reactive.These functional groups with double-bonds are highly reactive. They can undergo polymerization reactions, either by themselves (self - polymerization) or with other monomers.They can undergo polymerization either by themselves (self-polymerization) or in combination with other monomers. This reactivity is exploited in the production of polymers.This reactivity can be used to produce polymers. For example, in the synthesis of cross - linked polymers, the double bonds react with each other or with other monomers to form a three - dimensional network structure.In the synthesis cross-linked polymers, for example, the double bond reacts with each other or other monomers to create a three-dimensional network structure.

The ester linkages in the molecule also confer certain chemical properties.The ester links in the molecule confer chemical properties as well. They are susceptible to hydrolysis under acidic or basic conditions.They are hydrolysable in acidic or basic conditions. In an acidic medium, the ester can be hydrolyzed to form the corresponding carboxylic acid and alcohol.In an acidic environment, the ester is hydrolyzed into the carboxylic acid or alcohol. In a basic medium, saponification occurs, where the ester is broken down into the carboxylate salt and alcohol.In a basic environment, saponification takes place, where the ester breaks down into alcohol and carboxylate salt. This hydrolysis reaction can be a concern in some applications where the compound is exposed to moisture and either acidic or basic environments, as it can lead to degradation of the molecule and a change in its performance characteristics.This hydrolysis reaction is a concern for some applications, especially when the compound is exposed moisture or acidic environments. It can cause degradation of the molecule as well as a change in performance characteristics. Additionally, the compound can participate in other reactions typical of unsaturated compounds, such as addition reactions with reagents that can react with the double bonds in the methacrylate groups.The compound can also participate in other reactions that are typical of unsaturated substances, such as the addition reactions with reagents which can react with double bonds in the groups methacrylate.

What are the storage requirements for Triethyleneglycol dimethacrylate?

Triethyleneglycol dimethacrylate is a chemical compound with specific storage requirements to ensure its stability, safety, and usability.Triethyleneglycol Dimethacrylate (Tegdi) is a chemical compound that has specific storage requirements for its stability, safety and usability.
First and foremost, it should be stored in a cool place.It should be stored in an area that is cool. High temperatures can accelerate chemical reactions and potentially lead to decomposition or polymerization of the compound.High temperatures can speed up chemical reactions, which could lead to the decomposition or polymerization. An ideal storage temperature range is typically between 2 - 8 degrees Celsius.Ideal storage temperatures are typically between 2 and 8 degrees Celsius. This temperature control helps maintain the integrity of the chemical structure of triethyleneglycol dimethacrylate, preventing any unwanted changes in its properties over time.This temperature control helps to maintain the integrity of triethyleneglycol dimethylacrylate's chemical structure, preventing unwanted changes in its property over time.

It also needs to be stored in a dry environment.It should also be stored in a completely dry environment. Moisture can react with the compound, especially if it contains reactive functional groups.Moisture may react with the compound, particularly if it contains functional groups that are reactive. Water can initiate hydrolysis reactions or interfere with the polymerization process that might be intended for its use in applications such as making polymers or dental materials.Water can cause hydrolysis reactions or interfere in the polymerization of materials that are intended to be used for applications such as dental materials or polymers. A relative humidity level below 60% is often recommended to minimize the risk of moisture - related issues.It is recommended that relative humidity levels below 60% be maintained to reduce the risk of moisture-related issues.

The storage container is crucial.The storage container is important. Triethyleneglycol dimethacrylate should be stored in a tightly sealed container.Store triethyleneglycol dimethylacrylate in a tightly-sealed container. This is to prevent evaporation of the volatile components and to keep out contaminants such as dust, air - borne chemicals, or other substances that could interact with it.This will prevent the evaporation and keep out contaminants like dust, air-borne chemicals or other substances. A suitable container material is one that is chemically inert to triethyleneglycol dimethacrylate, such as certain types of high - density polyethylene or glass.Glass or certain types of high-density polyethylene are suitable containers because they are chemically inert towards triethyleneglycol Dimethacrylate. Glass containers are especially good as they do not react with many chemicals and provide a clear view of the contents, allowing for easy inspection of the compound's appearance.Glass containers are ideal as they don't react with many chemicals, and allow for a clear view of contents.

Furthermore, it should be stored away from sources of ignition and oxidizing agents.It should also be stored away form sources of ignition and from oxidizing agents. Triethyleneglycol dimethacrylate is flammable, and an oxidizing agent could potentially cause a violent reaction.Triethyleneglycol Dimethacrylate can be flammable and an oxidizing agent may cause a violent reaction. Keep it in a well - ventilated area separate from substances like peroxides or strong acids that could initiate combustion or other dangerous reactions.Keep it away from peroxides and strong acids, which could cause a violent reaction.

In addition, proper labeling of the storage container is essential.Labeling the container is also essential. The label should clearly indicate the name of the compound, its chemical formula, storage conditions, and any relevant hazard warnings.Labels should clearly state the name of the compound and its chemical formula. They should also include any relevant warnings. This ensures that anyone handling the storage or using the compound in the future is aware of its properties and the necessary precautions.This will ensure that anyone who handles the compound or uses it in the future, is aware of the properties and precautions.

Finally, regular inspection of the stored triethyleneglycol dimethacrylate is advisable.It is important to inspect the triethyleneglycol dimethylacrylate stored regularly. Check for any signs of discoloration, precipitation, or changes in viscosity.Check for signs of discoloration or precipitation. Also, check viscosity. If any such changes are observed, it may be an indication that the compound has started to degrade, and further assessment of its usability is required.If you notice any of these changes, it could be an indication that your compound is degrading and needs to be assessed further.