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Trimethylolpropane Triacrylate


Properties
Product Name Trimethylolpropane triacrylate
Cas Number 15625-89-5
Formula C15H20O6
Molar Mass 296.32 g/mol
Density 1.1 g/cm³
Boiling Point >200°C (decomposes)
Flash Point 113°C
Viscosity 70-100 mPa·s at 25°C
Refractive Index 1.478 at 25°C
Solubility In Water slightly soluble
Appearance colorless to pale yellow liquid
Odor slight ester-like odor
Polymerization may undergo auto-polymerization when exposed to light or heat
Stability stable under recommended storage conditions
Vapor Density 8.3 (air = 1)
FAQ

What are the main applications of Trimethylolpropane Triacrylate?

Trimethylolpropane Triacrylate (TMPTA) has several important applications across different industries.Trimethylolpropane Triacrylate has many important applications in different industries.
In the coatings industry, TMPTA is widely used.TMPTA is widely utilized in the coatings industry. It serves as a cross - linking agent in radiation - curable coatings, like UV - curable and electron - beam - curable coatings.It is used as a cross-linking agent in radiation-curable coatings such as UV-curable and electron-beam-curable coatings. These coatings are applied in various settings, from automotive finishes to furniture coatings.These coatings can be applied in a variety of settings, including automotive finishes and furniture coatings. TMPTA helps to form a highly cross - linked and durable film.TMPTA forms a durable and highly cross-linked film. In automotive coatings, it provides excellent scratch resistance, chemical resistance, and hardness to the painted surfaces, protecting the vehicle's body from environmental damage such as weathering and road debris.In automotive coatings it provides excellent scratch resistance and chemical resistance to the painted surfaces. It protects the vehicle's surface from environmental damage, such as weathering or road debris. For furniture coatings, it gives a smooth, long - lasting finish that can withstand daily use.Furniture coatings benefit from a long-lasting, smooth finish that can withstand daily usage.

In the adhesives field, TMPTA plays a crucial role.TMPTA is a key ingredient in the adhesives industry. It is used in formulating high - performance adhesives, especially those that require rapid curing.It is used to formulate high-performance adhesives, particularly those that require rapid cure. For example, in the assembly of electronic devices, where quick bonding is essential, radiation - curable adhesives containing TMPTA can be used.Radiation-curable adhesives that contain TMPTA are useful in electronic device assembly, where rapid bonding is required. These adhesives can bond different materials like plastics, metals, and glass with high strength.These adhesives are able to bond materials such as plastics, metals and glass with a high degree of strength. The cross - linking ability of TMPTA ensures that the adhesive joints are stable and can endure mechanical stress and temperature variations.TMPTA's cross-linking ability ensures that adhesive joints are stable, and can withstand mechanical stress and temperature changes.

TMPTA is also significant in the production of inks.TMPTA plays a significant role in the production and formulation of inks. In UV - curable inks, which are commonly used in printing applications such as packaging printing, TMPTA acts as a reactive diluent and cross - linker.TMPTA is a cross-linker and diluent that can be used in UV-curable inks. This ink is commonly used for packaging printing. It helps to reduce the viscosity of the ink formulation, making it easier to print.It reduces the viscosity, making the ink formulation easier to print. At the same time, upon UV exposure, it enables the ink to cure rapidly, resulting in high - quality prints with good adhesion to the substrate.It also enables the inks to cure quickly upon exposure to UV light, resulting in high-quality prints with good adhesion. This is particularly important in packaging, where fast - drying inks are needed to keep up with high - speed production lines.This is especially important in packaging where fast-drying inks are required to keep up with production lines that run at high speeds.

Another application area is in the manufacture of composites.Composites are another area of application. TMPTA can be incorporated into composite materials to enhance their mechanical properties.TMPTA can enhance the mechanical properties of composite materials by incorporating it. When combined with fibers like glass fibers or carbon fibers, it improves the matrix - fiber interface adhesion.Combining TMPTA with fibers such as glass fibers or Carbon Fibers improves the matrix-fiber interface adhesion. This leads to composites with better strength, stiffness, and impact resistance.Composites with improved strength, stiffness and impact resistance are the result. These composites are used in aerospace components, sports equipment, and marine applications.These composites can be used in marine applications, sports equipment and aerospace components. For instance, in the production of lightweight and strong aircraft parts, the addition of TMPTA - based matrices can optimize the performance of the composite materials.TMPTA-based matrices, for example, can be used to optimize the performance of composite materials in the production lightweight and strong aircraft components.

In the field of 3D printing, TMPTA is used in some resin formulations.TMPTA is a component of some resin formulations used in 3D printing. It participates in the photopolymerization process, allowing the creation of three - dimensional objects.It is involved in the photopolymerization, which allows the creation of three-dimensional objects. The ability of TMPTA to cross - link under light irradiation enables the precise formation of complex 3D structures with good dimensional stability and mechanical properties.TMPTA's ability to cross-link under light irradiation allows for the precise formation 3D structures that are stable and have good mechanical properties.

What are the key properties of Trimethylolpropane Triacrylate?

Trimethylolpropane Triacrylate (TMPTA) has several key properties that make it useful in various applications.Trimethylolpropane Triacrylate has several properties that make it useful for various applications.
One of the prominent properties is its high reactivity.Its high reactivity is one of its most prominent properties. TMPTA contains three acrylate groups.TMPTA contains 3 acrylate groups. These acrylate functional groups are highly reactive towards free - radical polymerization.These acrylate groups are highly reactive to free-radical polymerization. This enables it to rapidly polymerize upon exposure to appropriate initiators such as peroxides or photo - initiators under ultraviolet light.This allows it to polymerize rapidly when exposed to appropriate initiators, such as peroxides and photo-initiators under ultraviolet light. The high reactivity allows for quick curing processes, which is beneficial in industries like coatings, adhesives, and inks, where fast production cycles are essential.This high reactivity allows quick curing processes which is advantageous in industries such as coatings, adhesives and inks where fast production cycles are required.

TMPTA also has good solubility.TMPTA is also soluble. It can dissolve in a variety of organic solvents, which gives formulators flexibility in preparing solutions for different applications.It can dissolve in different organic solvents. This gives formulators the flexibility to prepare solutions for various applications. This solubility property is useful in the formulation of coatings, as it allows for easy dispersion of other additives such as pigments, fillers, and stabilizers.This property of solubility is useful when formulating coatings as it allows for the easy dispersion other additives like pigments, stabilizers, and fillers. Additionally, in the production of inks, its solubility helps in creating homogeneous mixtures that can be smoothly applied onto different substrates.In the production of inks its solubility is useful in creating homogeneous mixes that can be applied smoothly onto different substrates.

In terms of mechanical properties, polymers formed from TMPTA tend to have good hardness and abrasion resistance.Polymers made from TMPTA have good mechanical properties. They are hard and resistant to abrasion. The cross - linking that occurs during polymerization due to the three acrylate groups results in a rigid and durable network structure.The three acrylate groups cross-link during polymerization, resulting in a rigid network structure. In coatings applications, this means that the coated surfaces can withstand wear and tear, making them suitable for protecting industrial equipment, automotive parts, and floors.This means that in coatings, the surfaces coated can withstand wear, making them ideal for protecting industrial equipment and automotive parts.

Another important property is its low viscosity in its monomer form.Its low viscosity monomer form is another important property. This low viscosity allows for easy handling and processing.This low viscosity makes it easy to handle and process. It can be easily poured, mixed, and applied onto various substrates.It can be easily poured and mixed. In processes like spin - coating for optical applications or dip - coating for small parts, the low viscosity ensures uniform coverage.Low viscosity is important for processes such as spin-coating for optical applications, or dip-coating for small parts. It also reduces the energy required for pumping and mixing operations in industrial production settings.It also reduces energy requirements for pumping and stirring operations in industrial production settings.

TMPTA also has good chemical resistance.TMPTA is also chemically resistant. Once polymerized, the resulting material is resistant to many chemicals, including acids, bases, and organic solvents to a certain extent.Once polymerized the material is resistant to a wide range of chemicals including acids, bases and organic solvents. This property makes it suitable for applications where the polymer may come into contact with corrosive substances, such as in chemical storage tanks' linings or protective coatings in chemical processing plants.This property makes the polymer suitable for applications in which it may come into contact corrosive substances. For example, in the linings of chemical storage tanks or protective coatings on chemical processing plants. However, its chemical resistance can be further enhanced or modified by formulating it with other monomers or additives.Its chemical resistance can also be enhanced or modified using other monomers or add-ons.

How is Trimethylolpropane Triacrylate produced?

Trimethylolpropane Triacrylate (TMPTA) is produced through an esterification reaction.Trimethylolpropane Triacrylate is produced by esterification.
The main raw materials for the production of TMPTA are trimethylolpropane and acrylic acid.Trimethylolpropane is the main raw material for TMPTA production. In a typical production process, trimethylolpropane and acrylic acid are first charged into a reaction vessel.In a typical production procedure, trimethylolpropane is first charged into the reaction vessel. An acid catalyst is then added to promote the esterification reaction.The esterification is then accelerated by adding an acid catalyst. Commonly used catalysts include sulfuric acid or p - toluenesulfonic acid.Catalysts commonly used include sulfuric or p-toluenesulfonic acids. These catalysts help to speed up the reaction by facilitating the formation of the ester bond between the hydroxyl groups of trimethylolpropane and the carboxyl groups of acrylic acid.These catalysts speed up the reaction because they facilitate the formation of an ester bond between the carboxyl group of acrylic acid and the hydroxyl group of trimethylolpropane.

During the reaction, water is generated as a by - product.Water is produced as a by-product during the reaction. To drive the reaction forward according to Le Chatelier's principle, it is necessary to remove the water from the reaction system.In order to drive the reaction according to Le Chatelier’s principle, the water must be removed from the system. This can be achieved through azeotropic distillation.This can be done by azeotropic distillation. Usually, an organic solvent that forms an azeotrope with water, such as toluene or xylene, is added.Toluene, xylene or other organic solvents that form an azeotrope when combined with water are usually added. The azeotrope of the solvent and water is distilled out of the reaction mixture, and then the water is separated from the solvent through a decanter.The azeotrope formed by the solvent and the water in the reaction mixture is distilled, and the water and solvent are separated using a decanter. The solvent is recycled back to the reaction system.The solvent is recycled into the reaction system.

As the reaction progresses, the conversion of reactants to TMPTA increases.As the reaction proceeds, the conversion rate of reactants into TMPTA increases. Once the reaction reaches a certain degree of completion, the reaction mixture is cooled.The reaction mixture is cooled once the reaction has reached a certain level of completion. Then, steps such as neutralization and washing are carried out.Then, neutralization and washing steps are performed. The catalyst is neutralized with a base, like sodium carbonate solution, to remove the acidic catalyst from the product.The catalyst is neutralized using a base like sodium carbonate to remove the acidic catalyst. After neutralization, the mixture is washed with water to remove any remaining salts and unreacted materials.After neutralization, water is used to wash the mixture to remove any salts or unreacted materials.

Finally, the product is purified further, often by distillation under reduced pressure.The final step is to purify the product, usually by distillation at reduced pressure. This process helps to separate TMPTA from any remaining impurities, unreacted monomers, or by - products, obtaining high - purity Trimethylolpropane Triacrylate.This process separates TMPTA from any impurities or unreacted monomers. It also helps obtain high-purity Trimethylolpropane Triacrylate. The purity of the final product is crucial for its applications in various fields such as coatings, adhesives, and composites, where high - quality performance is required.The purity of the end product is critical for its application in many fields, such as coatings and adhesives.

What are the safety precautions when handling Trimethylolpropane Triacrylate?

Trimethylolpropane Triacrylate (TMPTA) is a type of acrylate monomer commonly used in the production of coatings, adhesives, and composites.Trimethylolpropane Triacrylate is a type acrylate monomer that is commonly used to produce coatings, composites, and adhesives. When handling TMPTA, several safety precautions should be taken to ensure personal safety and prevent potential hazards.To ensure safety and to prevent potential hazards, it is important to take several precautions when handling TMPTA.
First, proper personal protective equipment (PPE) is essential.Personal protective equipment (PPE), or personal protection gear, is essential. This includes chemical - resistant gloves.Chemical-resistant gloves are a must. Nitrile gloves are often a good choice as they can provide a barrier against TMPTA.Nitrile gloves can be a good option as they provide a barrier to TMPTA. Wearing safety goggles is also crucial to protect the eyes from splashes.Safety goggles are also essential to protect your eyes from splashes. In case of any accidental contact, immediate eye irrigation with copious amounts of water is required.If you accidentally come into contact with the substance, you must immediately rinse your eyes with large amounts of water. Additionally, a lab coat or other protective clothing should be worn to prevent skin contact.Wearing a labcoat or other protective clothing is also recommended to avoid skin contact.

Second, ensure good ventilation in the handling area.Second, make sure that the area where you are handling the product is well ventilated. TMPTA has a characteristic odor, and in high - concentration environments, the vapors can be irritating to the respiratory system.TMPTA has an odor and can be irritating in high-concentration environments. Working in a well - ventilated hood or an area with sufficient air exchange helps to dilute the vapors.The vapors can be diluted by working in an area with adequate air exchange or a well-ventilated hood. If the work involves large - scale handling, local exhaust ventilation systems may be necessary to effectively remove the vapors from the work area.Local exhaust ventilation systems are necessary if the work involves large-scale handling.

Third, be careful with fire and explosion hazards.Third, be cautious of fire and explosion hazards. TMPTA is flammable.TMPTA is flammable. Keep it away from heat sources, open flames, and sparks.Keep it away form heat sources, sparks, and open flames. Storage areas should be designed to prevent the accumulation of flammable vapors.Storage areas should be designed so that flammable vapors do not accumulate. Electrical equipment in the handling area should be explosion - proof to avoid igniting the flammable vapors.Electrical equipment in the handling areas should be explosion-proof to avoid igniting flammable vapors.

Fourth, in case of skin contact, immediately wash the affected area with soap and large amounts of water.In the event of skin contact, wash the affected area immediately with soap and water. If TMPTA gets on the skin, it may cause skin irritation.TMPTA can cause irritation if it gets on the skin. Prolonged or repeated contact can lead to more serious skin problems.Contact that is prolonged or repeated can cause more serious skin problems. For ingestion, do not induce vomiting unless directed by medical personnel.In the case of ingestion, you should not induce vomiting without medical advice. Seek immediate medical attention.Seek immediate medical care.

Finally, when storing TMPTA, it should be kept in a cool, dry place away from incompatible substances.TMPTA should be stored in a dry, cool place, away from other substances. It can react with strong oxidizing agents, so storage near such chemicals should be avoided.Storage near strong oxidizing agents should be avoided. Also, clearly label the containers to ensure proper identification and handling.Label the containers clearly to ensure proper identification. By following these safety precautions, the risks associated with handling Trimethylolpropane Triacrylate can be significantly reduced.Trimethylolpropane Triacrylate is a dangerous substance. By following these safety precautions you can reduce the risk.

What are the advantages of using Trimethylolpropane Triacrylate over other acrylate compounds?

Trimethylolpropane Triacrylate (TMPTA) offers several distinct advantages over other acrylate compounds.Trimethylolpropane Triacrylate offers distinct advantages over other acrylate substances.
One key advantage is its high functionality.Its high functionality is a key advantage. TMPTA has three acrylate groups per molecule.TMPTA molecules have three acrylate groups. In contrast, many other acrylate compounds may have only one or two reactive groups.Many other acrylate compounds have only one or even two reactive groups. This higher functionality allows for more cross - linking to occur during polymerization.This higher functionality allows more cross-linking to occur during the polymerization. As a result, polymers formed from TMPTA tend to have a more densely cross - linked structure.Polymers made from TMPTA have a densely cross-linked structure. This enhanced cross - linking leads to improved mechanical properties.This improved cross-linking leads to better mechanical properties. For example, the cured materials can exhibit greater hardness, abrasion resistance, and tensile strength.The cured materials, for example, can have greater hardness, abrasion resistant, and tensile strengths. In applications such as coatings for floors or industrial equipment, these properties are crucial as they need to withstand constant wear and tear.These properties are important in applications such as industrial equipment or floor coatings. They need to be able to withstand constant wear.

Another advantage is its relatively low viscosity compared to some multi - functional acrylate alternatives.Its low viscosity is another advantage compared to other multi-functional acrylate alternatives. Despite having three acrylate groups, TMPTA has a viscosity that makes it easier to handle in various processes.TMPTA is easier to work with in different processes despite having three acrylate groupings. This is beneficial in processes like inkjet printing or resin casting.This is advantageous in processes such as inkjet printing and resin casting. In inkjet printing, low viscosity is essential to ensure smooth and consistent droplet formation and ejection from the printhead.In inkjet, low viscosity ensures smooth and consistent droplet ejection and formation from the printhead. If the viscosity is too high, it can lead to clogging of the nozzles.A high viscosity can cause nozzle clogging. In resin casting, a lower viscosity allows for better flow of the resin into complex molds, ensuring accurate replication of the mold's features.A lower viscosity resin allows for a better flow into complex molds. This ensures accurate replication of the features of the mold.

TMPTA also shows good reactivity.TMPTA is also a good reactivity. The acrylate groups in TMPTA are highly reactive towards free - radical polymerization initiators.The acrylate groups of TMPTA are highly reactive towards free-radical polymerization initiators. This means that it can polymerize relatively quickly under appropriate conditions, such as exposure to ultraviolet (UV) light or heat in the presence of a suitable initiator.This means it can polymerize fairly quickly under the right conditions, such exposure to ultraviolet light (UV) or heat in presence of an initiator. Faster polymerization rates can be a significant advantage in high - volume manufacturing processes.A higher polymerization rate can be an advantage in high-volume manufacturing processes. It reduces the processing time, which in turn can increase production efficiency and lower costs.It can reduce the processing time which can in turn increase production efficiency and lower cost. For instance, in the production of UV - cured adhesives, the quick polymerization of TMPTA - based formulations allows for rapid bonding of components, enabling faster assembly lines.In the production of UV-cured adhesives, for example, the quick polymerization TMPTA-based formulations allow for rapid bonding, enabling faster assembly.

Furthermore, TMPTA has good chemical resistance.TMPTA also has a good chemical resistance. The highly cross - linked structure formed after polymerization provides resistance to a wide range of chemicals.The highly cross-linked structure formed after polymerization offers resistance to a variety of chemicals. This makes it suitable for applications where the material may come into contact with solvents, acids, or bases.This makes the material suitable for applications that may come into contact of solvents, acids or bases. For example, in chemical storage tanks or pipelines, coatings made from TMPTA can protect the underlying substrate from chemical corrosion, extending the lifespan of the equipment.TMPTA coatings can be used to protect chemical storage tanks and pipelines from chemical corrosion. This will extend the life of the equipment.

In terms of cost - effectiveness, TMPTA is often competitively priced compared to some other specialized acrylate compounds with similar functionality.TMPTA is usually more cost-effective than other specialized acrylate materials with similar functionality. Given its multiple advantages in terms of performance, this cost - effectiveness makes it an attractive choice for many industries, from automotive to electronics, where large volumes of acrylate - based materials are used.This cost-effectiveness, coupled with its performance advantages, makes TMPTA a popular choice in many industries.