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Product Name | Trimethylolpropane trimethacrylate |
Cas Number | 3290-92-4 |
Formula | C15H20O6 |
Molar Mass | 296.32 |
Density | 1.07 g/cm³ |
Boiling Point | 217°C at 30 mmHg |
Melting Point | 30-40°C |
Flash Point | 220°F |
Appearance | Clear liquid |
Viscosity | 150-250 mPa·s at 25°C |
Refractive Index | 1.471-1.473 |
Vapor Pressure | <0.1 mmHg at 20°C |
Solubility In Water | Insoluble |
Stability | Stable under normal conditions |
Hazards | May cause skin irritation |
What are the main applications of Trimethylolpropane trimethacrylate?
Trimethylolpropane trimethacrylate (TMPTMA) has several important applications.Trimethylolpropane Trimethacrylate has many important applications.
One of the main uses is in the field of polymer modification.One of its main applications is in polymer modification. It serves as a cross - linking agent.It is used as a cross-linking agent. In polymers like polyethylene, cross - linking with TMPTMA can enhance the material's mechanical properties.Cross-linking with TMPTMA in polymers such as polyethylene can improve the mechanical properties of the material. For example, it can increase the tensile strength, making the polymer more resistant to breakage under stress.It can, for example, increase the tensile strengths, making the polymer less likely to break under stress. This is crucial in applications such as the production of high - performance pipes, where the pipes need to withstand high internal pressures without bursting.This is important in applications like the production of high-performance pipes, which must withstand high internal forces without bursting. In rubber materials, TMPTMA - induced cross - linking improves the rubber's heat resistance, abrasion resistance, and solvent resistance.TMPTMA induced cross – linking in rubber materials improves the rubber’s heat resistance and abrasion resistance. This allows rubber products like tires to have a longer lifespan and better performance under various harsh conditions.Rubber products, such as tires, can have a longer life span and perform better under harsh conditions.
TMPTMA is also widely used in the coatings industry.TMPTMA has also been widely used in the coatings sector. When added to coatings, it can help form a three - dimensional cross - linked network.It can be added to coatings to form a cross-linked three-dimensional network. This improves the hardness and scratch resistance of the coatings.This increases the hardness and scratch-resistance of the coatings. For instance, in automotive coatings, the addition of TMPTMA can protect the car's body from minor scratches during daily use, maintaining the vehicle's aesthetic appearance.In automotive coatings, TMPTMA is added to protect the vehicle's body against minor scratches. This helps maintain the vehicle's appearance. Moreover, the cross - linked structure formed by TMPTMA in coatings enhances their chemical resistance, making them more resistant to chemicals such as acids, alkalis, and solvents.TMPTMA's cross-linked structure in coatings increases their chemical resistance. They are more resistant to chemicals like acids, alkalis and solvents. This is beneficial for coatings used in industrial settings where they may come into contact with various corrosive substances.This is especially beneficial for coatings that are used in industrial settings, where they may be exposed to corrosive substances.
In the adhesives industry, TMPTMA plays an important role.TMPTMA is a key ingredient in the adhesives industry. It can be used to improve the adhesion strength and durability of adhesives.It can be used to increase the adhesion and durability of adhesives. By cross - linking the adhesive components, it forms a more stable and robust structure.Cross-linking the adhesive components creates a more robust and stable structure. This is especially useful in structural adhesives, which are required to bond different materials together firmly and withstand long - term stress.This is particularly useful in structural glues that are required to bond materials together firmly, and withstand long-term stress. For example, in the aerospace industry, structural adhesives with TMPTMA are used to bond components, ensuring the integrity of the aircraft structure.In the aerospace industry for example, structural adhesives containing TMPTMA can be used to bond components and ensure the integrity of aircraft structures.
Another application area is in the production of ion - exchange resins.A second application is the production of resins that exchange ions. TMPTMA can be copolymerized with other monomers to create a porous and cross - linked resin structure.TMPTMA is copolymerized to create a cross-linked resin structure. These ion - exchange resins are used in water treatment processes to remove impurities, such as heavy metal ions and hardness - causing ions.These ion-exchange resins are used to remove impurities from water, such as heavy-metal ions and hardness-causing ions. The cross - linked structure provided by TMPTMA gives the resin the mechanical strength and chemical stability needed to function effectively in the water treatment environment.The cross-linked structure provided by TMPTMA provides the resin with the mechanical strength and chemical stabilities needed to function in the water treatment environment.
In summary, Trimethylolpropane trimethacrylate has diverse applications across multiple industries, contributing to the improvement of material properties and the performance of various products.Trimethylolpropane Trimethacrylate is used in a wide range of industries and contributes to the improvement of the material properties and performance of products.
What are the properties of Trimethylolpropane trimethacrylate?
Trimethylolpropane trimethacrylate (TMPTMA) has several important properties.Trimethylolpropane Trimethacrylate (TMPTMA), a trimethylolpropane-trimethacrylate, has many important properties.
1. Physical state and appearance: It is typically a clear, colorless to slightly yellow liquid at room temperature.Physical state: It is usually a clear, colorless liquid that can be slightly yellow at room temperature. This liquid form makes it relatively easy to handle in various industrial processes, allowing for smooth mixing with other substances in formulations.Its liquid form makes it easy to handle and mix with other substances.
2. Chemical reactivity: TMPTMA contains three methacrylate groups.TMPTMA contains 3 methacrylate groups. These groups are highly reactive, particularly towards free - radical polymerization.These groups are highly reactive and especially towards free-radical polymerization. When exposed to appropriate initiators such as peroxides or azo - compounds, the double bonds in the methacrylate groups can be broken, leading to the formation of long - chain polymers.The double bonds of the methacrylate group can be broken by appropriate initiators, such as peroxides and azo - compounds. This leads to the formation long - chains polymers. This property is widely exploited in the production of cross - linked polymers.This property is widely used in the production cross-linked polymers.
3. Cross - linking ability: One of the most significant properties of TMPTMA is its capacity to act as a cross - linking agent.Cross – linking ability One of TMPTMA's most important properties is its ability to act as a chemical cross - linker. During polymerization, the multiple methacrylate groups can react with polymer chains, creating a three - dimensional network structure.During polymerization the multiple methacrylate chains can react with polymer chain, creating a 3-dimensional network structure. This cross - linking enhances the mechanical properties of the resulting polymers.This cross-linking enhances the mechanical properties in the resulting polymers. For example, in coatings, it can increase hardness, abrasion resistance, and chemical resistance.In coatings, for example, it can increase hardness and chemical resistance. In rubber compounds, it improves the tensile strength and heat resistance by cross - linking the rubber polymers.Cross-linking rubber polymers improves tensile strength, heat resistance and abrasion resistance.
4. Solubility: TMPTMA is soluble in many organic solvents, such as acetone, toluene, and methyl ethyl ketone.Solubility TMPTMA can be dissolved in many organic solvents such as acetone toluene and methyl ethyl ketone. This solubility is beneficial as it enables its incorporation into different solvent - based formulations.This solubility allows for its incorporation in different solvent-based formulations. It can be evenly dispersed in these solvents, facilitating its interaction with other components in the mixture, whether they are monomers, polymers, or additives.It can be evenly distributed in these solvents and facilitate its interaction with other components of the mixture, whether it is monomers, polymers or additives.
5. Low volatility: It has relatively low volatility, which means it does not easily evaporate at normal temperatures and pressures.Low Volatility: It is relatively low volatile, meaning it does not easily evaporate at normal temperatures and under normal pressures. This property is advantageous in applications where long - term stability of the formulation is required.This property is beneficial in applications that require long-term stability of the formulation. In coatings, for instance, it helps prevent the loss of the cross - linking agent during the drying and curing process, ensuring consistent and reliable performance.It is useful in coatings to prevent the loss of cross-linking agents during the drying and cure process. This ensures consistent and reliable performance.
6. Compatibility: TMPTMA shows good compatibility with a wide range of polymers and monomers.Compatibility TMPTMA is compatible with a wide variety of monomers and polymers. It can be incorporated into formulations containing acrylic monomers, styrene - based monomers, and various types of polymers like polyesters and polyurethanes.It can be used in formulations that contain acrylic monomers, monomers based on styrene, and polymers such as polyesters and polyurethanes. This compatibility allows for the creation of hybrid materials with tailored properties, expanding its use in different industries such as adhesives, composites, and 3D printing resins.This compatibility allows the creation of hybrid material with tailored properties. Its use is expanding in different industries, such as adhesives and composites.
How is Trimethylolpropane trimethacrylate synthesized?
Trimethylolpropane trimethacrylate (TMPTMA) is synthesized through an esterification reaction.Trimethylolpropane Trimethacrylate is synthesized by an esterification process. Here is a general description of the synthesis process.Here is a description of the general synthesis process.
The raw materials mainly include trimethylolpropane and methacrylic acid.Trimethylolpropane is the main raw material. Methacrylic acid is also used. First, in a reaction vessel, an appropriate amount of trimethylolpropane is added.In a reaction vessel first, a suitable amount of trimethylolpropane must be added. Then, a stoichiometric excess of methacrylic acid is introduced.Then, a stoichiometric surplus of methacrylic is added. To promote the reaction, a catalyst is added.A catalyst is used to promote the reaction. Commonly used catalysts are sulfuric acid or p - toluenesulfonic acid.Catalysts commonly used are sulfuric or p-toluenesulfonic acids. These catalysts can speed up the esterification reaction rate between the hydroxyl groups of trimethylolpropane and the carboxyl groups of methacrylic acid.These catalysts can accelerate the esterification rate between the carboxyl group of methacrylic and the hydroxyl group of trimethylolpropane.
During the reaction process, to remove the water generated by the esterification reaction in a timely manner, azeotropic distillation is often employed.Azeotropic distillation can be used to remove water quickly from the esterification process. Usually, an organic solvent such as toluene is added.Toluene or another organic solvent is usually added. The toluene - water azeotrope can be distilled out of the reaction system, driving the reaction equilibrium towards the formation of TMPTMA.Toluene – water azeotropes can be distilled from the reaction system to drive the reaction equilibrium toward the formation of TMPTMA.
In addition, to prevent the polymerization of methacrylic acid during the reaction, a polymerization inhibitor is added.A polymerization inhibitor is also added to the reaction to prevent polymerization. Hydroquinone or its derivatives are often used as polymerization inhibitors.As polymerization inhibiters, hydroquinone and its derivatives are commonly used. They can effectively inhibit the self - polymerization of methacrylic acid monomers under reaction conditions, ensuring that the reaction proceeds mainly in the direction of esterification.They can effectively inhibit self-polymerization of monomers of methacrylic acids under reaction conditions. This ensures that the reaction proceeds in the direction of esterification.
After the reaction is completed, the reaction mixture needs to be post - processed.The reaction mixture must be processed after the reaction has been completed. First, the catalyst is neutralized.The catalyst must first be neutralized. For example, if sulfuric acid is used as the catalyst, an appropriate amount of a base such as sodium carbonate can be added to neutralize the remaining acid.If sulfuric acid was used as a catalyst, you can add a suitable amount of a base, such as sodium carbonate, to neutralize any remaining acid. Then, the organic layer containing TMPTMA is separated.The organic layer containing TMPTMA will then be separated. The separated organic layer may be further purified by processes such as washing with water to remove water - soluble impurities, and distillation to obtain pure trimethylolpropane trimethacrylate.The organic layer can be purified further by washing with water and distillation in order to obtain pure trimethylolpropane Trimethacrylate. Through this series of operations, high - purity TMPTMA can be obtained for various applications in the fields of coatings, adhesives, and polymer modification.This series of operations can produce high-purity TMPTMA for use in coatings, adhesives and polymer modification.
What are the safety precautions when handling Trimethylolpropane trimethacrylate?
Trimethylolpropane trimethacrylate is a chemical compound with certain reactivity and potential hazards.Trimethylolpropane Trimethacrylate (TMP Trimethacrylate) is a chemical compound that has a certain level of reactivity. It also poses some potential hazards. Here are the safety precautions when handling it.Here are some safety precautions to take when handling it.
First, in terms of personal protective equipment.Personal protective equipment is the first thing to consider. Wear appropriate chemical - resistant gloves.Wear gloves that are resistant to chemicals. Nitrile gloves are often a good choice as they can provide effective protection against contact with Trimethylolpropane trimethacrylate.Nitrile gloves can be a good option as they provide effective protection from Trimethylolpropane Trimethacrylate. Skin contact can lead to irritation, so the gloves act as a barrier.The gloves protect the skin from irritation. Also, put on safety goggles.Wear safety goggles. This chemical can splash, and getting it into the eyes can cause severe eye damage, including burns and vision impairment.This chemical can splash and if it gets into the eyes, it can cause severe eye damage including burns and vision loss. A lab coat or protective clothing should be worn to prevent the chemical from coming into contact with the body through the clothes.Wear a lab coat or other protective clothing to prevent the chemical coming into contact with your body through your clothes.
Second, when handling in a workspace.Second, if you are handling items in a work area. Ensure good ventilation.Assure good ventilation. Trimethylolpropane trimethacrylate may emit vapors, and in a poorly ventilated area, these vapors can accumulate.Trimethylolpropane Trimethacrylate can emit vapors. In an area that is poorly ventilated, these vapors may accumulate. High - concentration vapors can be irritating to the respiratory system, causing coughing, shortness of breath, and potentially more serious lung problems over time.High-concentration vapors can cause irritation to the respiratory system. They can cause coughing, shortness in breath, and even more serious lung conditions over time. Use local exhaust ventilation systems if possible, especially when performing operations that may generate a significant amount of vapors, such as pouring or mixing large quantities of the chemical.If possible, use local exhaust ventilation systems, especially when performing operations which may generate a large amount of vapors.
Third, during storage.Third, during storage. Store Trimethylolpropane trimethacrylate in a cool, dry place away from heat sources and ignition sources.Store Trimethylolpropane Trimethacrylate away from heat and ignition sources in a cool and dry place. It is flammable, and heat or an open flame can cause it to catch fire.It is flammable and can catch fire if exposed to heat or an open flame. Keep it in a tightly - sealed container to prevent evaporation and leakage.Keep it in an airtight container to prevent evaporation. Label the storage container clearly with the name of the chemical, its hazards, and any relevant safety information.Label the container with the name of chemical, its hazards and any relevant safety info.
Fourth, in case of accidental exposure.Fourth, in the event of accidental exposure. If it comes into contact with the skin, immediately wash the affected area with plenty of water for at least 15 minutes.If it comes in contact with your skin, wash the affected area immediately with plenty of water and for at least 15 min. Remove any contaminated clothing during the washing process.Remove any contaminated clothes during the washing process. If it gets into the eyes, flush the eyes with copious amounts of water for at least 15 minutes, lifting the eyelids occasionally to ensure thorough rinsing, and then seek immediate medical attention.If it gets in the eyes, rinse them with plenty of water for 15 minutes. Lift the eyelids to ensure thorough rinsing. Seek immediate medical attention. In case of inhalation, move to an area with fresh air immediately.In the event of inhalation, you should immediately move to a place with fresh air. If breathing is difficult, provide artificial respiration and call for medical help.If breathing is difficult then call for medical assistance. If swallowed, do not induce vomiting unless directed by medical personnel, and seek emergency medical treatment right away.If you have swallowed something, do not induce vomiting without the direction of medical personnel. Seek immediate medical attention.
What are the advantages of using Trimethylolpropane trimethacrylate compared to other similar products?
Trimethylolpropane trimethacrylate (TMPTMA) offers several advantages over other similar products.Trimethylolpropane Trimethacrylate (TMPTMA), a product similar to other similar products, offers several advantages.
One key advantage is its high cross - linking ability.Its high cross-linking ability is a key advantage. TMPTMA has three methacrylate groups per molecule.TMPTMA contains three methacrylate groups in each molecule. This enables it to form a dense cross - linked network when polymerized.This allows it to form a dense network of cross-linked molecules when polymerized. In contrast, some similar monomers with fewer reactive groups result in less cross - linked structures.Some monomers similar to TMPTMA with fewer reactive group results in less cross-linked structures. The highly cross - linked polymers formed from TMPTMA exhibit enhanced mechanical properties.The highly cross-linked polymers formed by TMPTMA have enhanced mechanical properties. For example, they can have greater hardness, abrasion resistance, and dimensional stability.They can, for example, have higher hardness, abrasion resistant, and dimensional stabilty. In applications like coatings and composites, these properties are crucial.These properties are essential in applications such as composites and coatings. Coatings formulated with TMPTMA can better withstand wear and tear, protecting the underlying substrates for a longer time.Coatings formulated using TMPTMA are more resistant to wear, protecting the substrates beneath for a longer period of time.
TMPTMA also shows good thermal stability.TMPTMA has good thermal stability. The cross - linked polymers derived from it can endure higher temperatures without significant degradation.Cross-linked polymers made from TMPTMA can withstand higher temperatures without significant degradation. This is in contrast to some other monomers that may decompose or lose their mechanical integrity at relatively lower temperatures.This is in contrast with other monomers which may decompose at lower temperatures or lose their mechanical integrity. In high - temperature applications such as automotive parts and electrical insulation materials, TMPTMA - based polymers can maintain their performance.TMPTMA-based polymers are able to maintain their performance in high-temperature applications, such as automotive parts or electrical insulation materials. For instance, in the engine compartments of cars, components made with TMPTMA - containing polymers can resist the heat generated by the engine, ensuring long - term functionality.Components made from TMPTMA-containing polymers, for example, can resist heat generated by engines in car engine compartments, ensuring long-term functionality.
Another advantage is its reactivity.Reactivity is another advantage. TMPTMA can polymerize relatively quickly under appropriate conditions, such as in the presence of initiators and heat or light.TMPTMA polymerizes relatively quickly in certain conditions, like the presence of initiators, heat or light. This allows for efficient production processes in industries.This allows for efficient production in industries. Compared to some similar monomers that may require more complex or time - consuming polymerization methods, TMPTMA simplifies the manufacturing process.TMPTMA simplifies manufacturing processes compared to other monomers which may require more complex and time-consuming polymerization techniques. In the production of adhesives, for example, the fast - curing property of TMPTMA - based formulations can reduce production time and increase productivity.TMPTMA based formulations have a fast - curing characteristic that can reduce production time in the production of adhesives.
Moreover, TMPTMA has good solubility in many common organic solvents.TMPTMA is also soluble in a wide range of organic solvents. This solubility advantage makes it easier to incorporate into various formulations.This solubility makes it easier to incorporate in various formulations. It can be evenly dispersed in solvent - based systems, which is beneficial for applications like inks and paints.It can be dispersed evenly in solvent-based systems which is good for applications such as inks and painted surfaces. Inks formulated with TMPTMA can be easily printed onto different substrates, and the resulting printed patterns have good adhesion and durability due to the cross - linking ability of TMPTMA.TMPTMA-based inks can be printed on a variety of substrates. The resulting patterns are durable and adhere well to the substrate.
In addition, TMPTMA is relatively cost - effective considering its performance benefits.TMPTMA also offers a relatively low cost when compared to its performance benefits. While there may be some very specialized monomers that offer similar properties, they often come at a much higher cost.There are some monomers with similar properties that may be very specialized, but they can cost a lot more. TMPTMA provides a good balance between performance and cost, making it a popular choice in a wide range of industries from plastics and elastomers to coatings and adhesives.TMPTMA is a good choice for many industries, from plastics to elastomers, coatings to adhesives.